2384 results about "Composite oxide" patented technology

The present invention relates to a positive electrode active material, and to a positive electrode active material including a lithium transition metal composite oxide in a form of a single particle which contains nickel, cobalt, and manganese, wherein the lithium transition metal composite oxide contains 60 mol% or more of the nickel among total transition metals and has a D50 of 5 µm or more, and a positive electrode and a lithium secondary battery which include the same.

A positive electrode active material, a method of preparing the same, and a positive electrode and rechargeable lithium battery including the same, the positive electrode active material including core particles including a layered lithium nickel-manganese-based composite oxide; and a coating layer located on the surface of the core particle and containing aluminum and zinc.

The invention discloses a multi-component composite oxide dispersion strengthening molybdenum alloy and a preparation method thereof, and relates to the technical field of refractory metal powder metallurgy preparation. The molybdenum alloy comprises a molybdenum matrix and a Y-X-O composite oxide nano precipitated phase dispersed and distributed in the molybdenum matrix. The molybdenum alloy comprises the following components in percentage by mass: 1%-2% of Y2O3, 0.3%-1.2% of an active element X, 96.5%-98.7% of molybdenum and inevitable impurities, wherein X is selected from one of Ti, Zr and Hf; the Y-X-O composite oxide nano precipitated phase and the molybdenum matrix form a coherent or semi-coherent interface, and the interface mismatch degree is less than or equal to 5%. The molybdenum alloy has excellent high-temperature strength and creep resistance, and can be applied to the high-temperature fields of nuclear industry, aerospace and the like.

A positive electrode active material, a method of preparing the same, a positive electrode, and a rechargeable lithium battery including the positive electrode are provided. The positive electrode active material includes core particles and a coating layer on the surface of the core particles. The core particles include a layered lithium nickel-manganese-based composite oxide having a nickel content (e.g., amount) of greater than, or equal to, about 60 mol % based on 100 mol % of a total metal amount excluding lithium. The coating layer includes Al and P.

The invention discloses a method for synthesizing methylal through acetalation by using a strongly acidic composite metal oxide, and particularly relates to preparation of a strongly acidic composite metal oxide catalyst and a method for preparing methylal through condensation of methanol and formaldehyde by using the strongly acidic composite metal oxide catalyst. The preparation method comprises the following steps: preparing a ZrO2-SiO2 composite oxide precursor by adopting a coprecipitation method, dipping and loading active metal and an auxiliary agent on the composite oxide precursor, and applying the active metal and the auxiliary agent to a process of preparing methylal through acetalation. The method has the advantages of simple synthesis, no corrosion to equipment, mild reaction conditions, capability of improving the activity and stability of the catalyst, and the like.

The invention discloses a rare earth antibacterial ceramic and a preparation method thereof, and belongs to the technical field of ceramic materials, the rare earth antibacterial ceramic comprises a base material, a rare earth antibacterial agent and an auxiliary additive, the base material is coated with a zirconium silicate coating layer; the matrix material is one of aluminum oxide or zirconium oxide, the rare earth antibacterial agent is a ternary composite oxide composed of at least three lanthanide elements, the lanthanide elements comprise Ce, Y, La and Nd, and the invention provides a preparation method of the composite material. Through collaborative innovation of ternary rare earth composite modification, zirconium silicate interface coating and a gradient sintering process, the core problems of single antibacterial spectrum, high-temperature failure and insufficient durability of traditional antibacterial ceramic are solved, and the antibacterial property, stability, biological safety and mechanical property are remarkably improved; and the method has clear technical progress and industrial application value.

The invention discloses an anode material for adipic acid monoester electrolysis and a preparation method of the anode material, the electrode solves the key problems that a platinum layer is easy to fall off, the catalytic activity is low, the organic matter poisoning resistance is poor and the like of a traditional titanium platinum-plated electrode through multi-scale interface strengthening and nano structure regulation and control; the preparation method comprises the following core steps: constructing a porous ZrO2-TiO2 composite oxide layer on the surface of a titanium substrate by adopting a micro-arc oxidation-hydrothermal composite process, and generating platinum nanoparticles in situ to pre-fill pores, so that the anchoring effect of a platinum layer is remarkably enhanced; depositing a platinum / carbon nano tube (Pt / CNT) composite catalyst layer on the surface of the oxide layer through a pulse-ultrasonic synergistic electroplating technology, wherein the carbon nano tube is used as a conductive framework to inhibit platinum agglomeration; through vacuum annealing and electrochemical activation treatment, the interface bonding force and active site exposure are further optimized; the electrode shows excellent performance in an adipic acid monoester electrolysis system, and efficient electrocatalytic conversion from adipic acid monomethyl ester to dimethyl sebacate is achieved.

The invention provides a low-cost high-specific-surface-area cerium-aluminum composite oxide, a preparation method and application thereof, and relates to the technical field of catalysts, the preparation method comprises the following steps: step S1, adding 10-40% of cerium salt, 50-90% of aluminum salt and 0-10% of lanthanum source or zirconium source into deionized water, stirring and mixing, filtering, and washing to be neutral to obtain a cerium-containing solution; step S2, impregnating an alumina carrier in the cerium-containing solution prepared in the step S1, and standing to enable the cerium-containing solution to be impregnated on the alumina carrier, so as to obtain impregnated slurry; and S3, drying the dipping slurry, and then roasting in an inert atmosphere to obtain the cerium-aluminum composite oxide. The stable cerium-aluminum composite material is formed by doping one of lanthanum and zirconium with different masses into aluminum oxide or cerium oxide, the problem that the adsorption capacity of a traditional ammonia trapping method is limited is effectively solved, and the adsorption capacity of the material to ammonia is remarkably improved.

The invention relates to the field of lithium battery negative electrode materials, in particular to a silicon-based compound negative electrode material and a preparation method thereof.The negative electrode material comprises a compound of a silicon-based material and niobium-based composite oxide and metal nanoparticles loaded on the compound, the surface of the silicon-based material is coated with at least part of the niobium-based composite oxide, and the surface of the silicon-based material is coated with at least part of the niobium-based composite oxide. The negative electrode material is relatively good in conductivity, the conductivity and the lithium intercalation potential of the silicon-based composite negative electrode material are improved, the silicon-based material is prevented from generating side reaction with a solid electrolyte of a solid-state battery under low potential, meanwhile, the volume expansion of the silicon-based material in the charging and discharging process is relieved, and the comprehensive performance of the silicon-based solid-state battery is effectively improved.

An embodiment of the present invention provides a steel material, for a pressure vessel, comprising, in weight %, 0.06-0.25% of carbon (C), 0.05-0.50% of silicon (Si), 1.0-2.0% of manganese (Mn), 0.005-0.40% of aluminum (Al), 0.010% or less of phosphorus (P), 0.0010% or less of sulfur (S), 0.001-0.03% of niobium (Nb), 0.001-0.03% of vanadium (V), 0.001-0.03% of titanium (Ti), 0.01-0.20% of chromium (Cr), 0.05-0.15% of molybdenum (Mo), 0.01-0.50% of copper (Cu), 0.05-0.50% of nickel (Ni), 0.0005-0.0050% of magnesium (Mg), 0.0005-0.0050% of calcium (Ca), 0.0020% or less of oxygen (O), and the remainder being Fe and other unavoidable impurities. A microstructure comprises in terms of area fraction 30% or less of pearlite and the remainder being ferrite. A non-metallic inclusion contains Mg—Al—Ca—O composite oxide.

The invention discloses an annular furnace heat-resistant supporting forged chassis and an additive manufacturing process and a fixing device thereof, and belongs to the technical field of plating of metal materials, and the annular furnace heat-resistant supporting forged chassis comprises the steps that heat-resistant alloy steel base metal with specific components is prepared; carrying out laser texturing and nickel-based alloy bottom layer pretreatment on the surface of the steel plate; performing laser cladding on high-silicon high-temperature alloy powder containing niobium and rare earth elements to form a functional cladding layer, and performing gradient cladding on the edge of the atmosphere guide hole; and finally, carrying out heat treatment and assembling with a fan-shaped refractory brick fixing device. A composite oxide film and a multi-scale strengthening system are constructed, hydrogen resistance and brittleness resistance are effectively achieved, interface thermal stress is relieved, cracking and stripping of a cladding layer are avoided, a fixing device adapts to thermal expansion, the atmosphere is dredged, and the annealing uniformity of a steel coil is improved; the problems of creep deformation, hydrogen embrittlement, cladding layer stripping and thermal stress cracking of a traditional supporting component under the conditions of high temperature, heavy load and nitrogen and hydrogen atmosphere are solved.

An object of the present invention is to provide a negative thermal expansion material having better negative thermal expansion characteristics. The present invention is a negative thermal expansion material, comprising copper vanadium composite oxide powder dissolving Al atoms and represented by the following general formula (1), CuxMyVzOt (1). In general formula (1), M represents a metallic element with an atomic number of 11 or more other than Cu, V, and Al, 1.60≤x≤2.40, 0.00≤y≤0.40, 1.70≤z≤2.30, 6.00≤t≤9.00, 1.00≤x+y≤3.00, and a molar number of the Al atoms in terms of atoms>a molar number of M atoms in terms of atoms if an M element is contained.

The invention relates to the technical field of coating materials, and discloses a pure titanium micro-arc oxidation coating for a vacuum cup and a preparation method thereof.The preparation method comprises the following steps that surface pretreatment is conducted, specifically, a pure titanium vacuum cup inner container workpiece is sequentially subjected to degreasing, acid pickling and ultrasonic cleaning; preparing an electrolyte, namely adding 15-25 parts by weight of a silicon-containing compound, 5-12 parts by weight of metal salt, 3-8 parts by weight of an antibacterial agent and 1-5 parts by weight of a stabilizer into deionized water, and controlling the pH value to be 8.5-10.5; and performing micro-arc oxidation treatment. According to the invention, a silane compound in the micro-arc oxidation electrolyte contains a high-activity silanol group which is subjected to condensation reaction with titanium hydroxyl on the surface of a pure titanium substrate under the action of an electric field to form stable covalent bonding, so that the bonding strength of the coating and the substrate is enhanced; metal ions generated by metal salt electrolysis are co-deposited with titanium ions through plasma discharge, a composite oxide structure is constructed, and micro defects on the surface of a titanium substrate are sealed.

The invention relates to an oxide catalyst for high-activity and high-selectivity production of a target product pyromellitic dianhydride in the process of producing pyromellitic dianhydride through durene air selective oxidation. A multi-component efficient system is used for construction for preparation. The preparation method comprises the following steps: fully and uniformly mixing a certain amount of a main active component oxide and an auxiliary agent metal hydrochloric acid or an ionic liquid aqueous solution, carrying out a hydrothermal enhancement process to obtain catalyst active precursor slurry, adding a dilution auxiliary agent, and drying and roasting the slurry prepared in the previous step under certain conditions to obtain the efficient metal synergistic oxide catalyst. On the basis of coordinated benefit application of different components in a composite oxide material, the metal synergistic oxide is synthesized through hydrothermal heat assistance, the metal synergistic oxide has excellent catalytic performance in a reaction for producing pyromellitic dianhydride from durene, the yield of a target product is increased, and the metal synergistic oxide is suitable for industrial application.

The invention belongs to the technical field of ferrous metallurgy and high-strength wear-resistant materials, and discloses large-thickness high-toughness NM550 wear-resistant steel and a preparation method thereof. Nb, Ti and V are cooperated according to the mass ratio of 1: 1: 2 to form a multi-element nano carbide (Nb, Ti, V) C main strengthening phase with the average particle size of 5-50 nm; in the controlled rolling and austenitizing stages, Cr and Mo elements form fine carbides, a main strengthening phase is induced to be separated out preferentially, and cluster aggregation is prevented; al initial deoxidation and Ce and Ca composite denaturation treatment are adopted to form spherical Ce-Ca-Al-O composite oxide inclusions, and the average particle size is smaller than or equal to 2 microns. By adopting clean smelting, uniform-temperature heating, temperature-controlled rolling, three-stage flow-regulating water cooling and two-stage tempering treatment, uniform regulation and control and multi-scale strengthening of the structure are realized. The yield strength is greater than or equal to 1400 MPa, the tensile strength is greater than or equal to 1850 MPa, the ductility is greater than or equal to 15%, the ballistic work at-20 DEG C is greater than or equal to 40 J, and the surface hardness is greater than

Disclosed are a positive electrode active material, a positive electrode including the same, and a rechargeable lithium battery, the positive electrode active material includes a first positive electrode active material including a layered lithium nickel-manganese-based composite oxide and a second positive electrode active material including a lithium-manganese rich composite oxide in which a molar ratio of lithium to a total metal excluding lithium is about 1.1 to about 3 and a manganese content is greater than or equal to about 60 mol % based on 100 mol % of a total metal excluding lithium in the lithium-manganese rich composite oxide.

The invention relates to a desolventizing layer modified silicon-carbon negative electrode and a preparation method, the desolventizing layer modified silicon-carbon negative electrode comprises a silicon-carbon negative electrode, the silicon-carbon negative electrode comprises porous carbon mainly comprising mesopores and a silicon substrate attached in the pores of the porous carbon, and the desolventizing layer is covered on the surface of the silicon-carbon negative electrode. The desolventizing layer is an oxide of an amorphous active metal and a composite oxide of the amorphous active metal and lithium, the desolventizing layer at least covers the surface of the silicon substrate in the pores of the porous carbon, the desolventizing layer is made of amorphous titanium oxide, lithium titanate, niobium oxide, lithium niobate and titanium niobate, and after the electrolyte permeates into the pores of the porous carbon, the surface of the silicon substrate is coated with the desolventizing layer. And the lithium ions subjected to desolvation through the desolvation layer are alloyed with a silicon substrate. And the structural stability, the charge-discharge efficiency and the rate capability of the silicon-carbon negative electrode material are improved.

The invention relates to a preparation method of a lanthanum-doped lithium borate coated LATP solid electrolyte, which comprises the following steps: S1, mixing a lithium source, an aluminum source, a lanthanum source, a titanium source and a phosphorus source, putting the mixed material into a dispersing agent, putting into a constant-temperature water bath stirrer, and heating and stirring until the mixture is completely dried to obtain a mixed raw material; s2, performing high-temperature primary sintering on the mixed raw material in an air atmosphere to obtain a composite oxide; s3, performing crushing treatment on a composite oxide, adding lithium borate, and performing uniform mixing to obtain a mixture; the mass ratio of the lithium-containing compound to the composite oxide is (0.01-0.05): 1; and S4, tabletting the mixture, and carrying out high-temperature secondary sintering in an air atmosphere to obtain the finished product lithium titanium aluminum phosphate material. The problems that in an existing scheme, the final calcination temperature of a solid electrolyte is generally up to 1100 DEG C or above, high energy consumption is likely to be caused, meanwhile, Li loss is caused, non-conductive AlPO4 is introduced, the crystal structure is unstable, the powder sintering performance is poor, and the ionic conductivity is reduced are solved.

The invention discloses an efficient refining method for red impure copper. The efficient refining method comprises the following steps: (1) preparing calcium-cerium composite oxide powder; (2) preparing boron-phosphorus doped powder; (3) preparing a refining auxiliary agent; (4) red impure copper is put into a crucible, a medium-frequency induction furnace is adopted for heating and melting the red impure copper into a melt, the melt is covered with charcoal after being completely melted, the temperature of the melt is kept at 1110-1120 DEG C, then the refining auxiliary is added, and the mass ratio of the refining auxiliary to the melt is (3-4) kg: 1 t; and after charging, stirring the melt at a constant temperature of 1110-1120 DEG C for 10 minutes, then standing for 15 minutes, deslagging, casting and molding to obtain the refined impure red copper. After refining through the method, the tensile strength and the electric conductivity of the impure red copper can be remarkably improved, and the use performance of the impure red copper is improved.

The invention relates to a manganese-based denitration catalyst with a core-shell structure as well as a preparation method and application thereof, and belongs to the technical field of environment-friendly catalysts. The technical problems that a catalyst cannot meet the purification requirement of a wide temperature range, the nitrogen selectivity is poor, the reaction path is difficult to control, new pollutants are generated through excessive oxidation, and the denitration capacity in the wide temperature range is poor are solved. The invention relates to a manganese-based denitration catalyst with a core-shell structure. The composition of the manganese-based denitration catalyst is AMnOx (at) BOy, aMnOx is a composite oxide of coated manganese and doped elements, and BOy is an acidic metal oxide shell; and a reverse coprecipitation method is adopted for preparation. The manganese-based denitration catalyst with the core-shell structure has high surface acidity and oxidation-reduction capacity, the adsorption capacity of the catalyst to NH3 can be enhanced, and the manganese-based denitration catalyst has high catalytic activity and nitrogen selectivity at the active temperature of 150-400 DEG C.

The invention relates to a preparation method of a pectin-derived carbon-coated amorphous tin-zinc composite oxide lithium ion battery negative electrode material. The method comprises the following steps: dropwise adding a tin tetrachloride solution and an acidified zinc oxide solution into a pectin solution to obtain a metal ion-pectin dispersion liquid; adding ammonia water to obtain a pectin precursor solution; freezing and solidifying with liquid nitrogen; and after freeze-drying, roasting for 3-5 hours to obtain the pectin derived carbon coated amorphous tin-zinc composite oxide lithium ion battery negative electrode material. The reversible specific capacity of the obtained composite material reaches 1339 mA h g <-1 > after 100 cycles under the current density of 0.2 A g <-1 >.

The invention discloses modified biogas residue-based hydrothermal carbon, a preparation method thereof and a dry digestion method for kitchen waste, and belongs to the technical field of waste organic matter recycling. The preparation method comprises the following steps: soaking biogas residues in a phosphoric acid solution to obtain pretreated biogas residues; mixing the pretreated biogas residues, transition metal salt, biochar loaded with vitamin B12 and water with the mass being 8-15 times that of the pretreated biogas residues, and performing hydrothermal reaction for 1-4 hours under the conditions that the temperature is 180-250 DEG C and the pressure is 1.5-4 MPa to obtain a hydrothermal product; and activating the hydrothermal product for 1-2 hours under the protective atmosphere of 300-400 DEG C to obtain the modified biogas residue-based hydrothermal carbon. The surface Fe-Cu composite oxide sequentially catalyzes and oxidizes H2S into elemental sulfur and sulfate ions, the vitamin B12-loaded biochar can promote MA directional proliferation, the sulfate ions can competitively inhibit SRB substrate uptake, the quantity ratio of MA to SRB is increased, and the methane production efficiency is effectively improved.

The invention discloses a micron-sheet rare-earth-based denitration and chlorobenzene removal catalyst as well as a preparation method and application thereof. The catalyst takes micron-sheet reduced graphene oxide as a carrier, a composite oxide of cerium oxide and vanadium oxide as an active component and a hexahydrotriazinyl covalent organic framework as an active site protective agent; on the basis of the mass of the carrier, the mass percentage of the active component is 5-10%, and the mass percentage of the active site protective agent is 1-5%. The catalyst synthesized by the method has the advantages of high specific surface area, difficult deposition of ammonium bisulfate, long service life, stable activity and the like, and can realize the target of low-temperature denitration and chlorobenzene removal in the non-electric industry.

The invention relates to a preparation method of a hydrophobic manganese-based low-temperature denitration catalyst. According to the catalyst, a composite oxide of CeO2 and MnO2 is used as an active component, and polyacrylonitrile submicron fibers are used as a carrier; a mixed solution of carbon tetrachloride and gamma-aminopropyltriethoxysilane is used as a hydrothermal solution substrate, a mixed solution of ethyl acetate and gamma-aminopropyltriethoxysilane is used as a hydrothermal solution supernatant, and a hydrothermal-electrostatic spinning method is adopted for preparation; on the basis of the mass of the polyacrylonitrile submicron fiber carrier, the mass percentage of the active component is 10-20%, and the mass ratio of CeO2 to MnO2 in the active component is 1: (1-2). The catalyst not only can be used for catalytically reducing NO into N2 at low temperature, but also can be used for filtering particles in flue gas, has excellent water and sulfur poisoning resistance, and has relatively high economic value and wide market application prospect.

The invention belongs to the technical field of inorganic mineral fiber preparation, and provides a high-strength and high-modulus inorganic mineral fiber prepared from water-quenched slag and a preparation method of the high-strength and high-modulus inorganic mineral fiber. Firstly, the chemical purity of raw materials is improved through density separation and acid pickling, meanwhile, Na2CO3 and Fe2O3 are added, the tendency of crystal precipitation is reduced, and the vitrification characteristic of water-quenched slag is improved; secondly, the composite oxide modifier further optimizes the structure of the glass network, and B2O3 enhances the chemical stability of the glass network and reduces the melt viscosity by forming a B-O-Si bond; y2O3 provides high electric field intensity, inhibits crystal precipitation and enhances the crosslinking degree of a network; v2O5 provides a redox buffer function through a variable valence state, so that the chemical environment in the melting process is optimized, and the creep resistance is improved; and finally, a compact Al2O3 coating is formed on the surface of the fiber, so that the mechanical strength, the oxidation resistance, the corrosion resistance and the high-temperature stability of the fiber are improved.

The invention belongs to the field of metal recovery through an electrolytic method, and discloses an electrolytic recovery and reutilization method of a waste lithium-rich manganese-based positive electrode material, which comprises the following steps: firstly, carrying out electric field driven lithium removal on the lithium-rich manganese-based positive electrode material of a waste lithium ion battery through an electrolytic method, and then annealing the lithium-rich manganese-based positive electrode material after lithium removal, the manganese-based composite oxide capable of being used as the water-based zinc ion battery positive electrode material is obtained; and precipitating and recycling the removed Li ions by adding a precipitating agent. According to the method disclosed by the invention, the manganese-based composite oxide which can be used as an aqueous zinc ion battery positive electrode material is obtained while the lithium element is effectively recovered, and the process is simple, easy to implement and beneficial to popularization and application.

The invention discloses a catalyst for dehydrogenation of a liquid organic hydrogen energy carrier as well as a preparation method and a dehydrogenation method of the catalyst. The catalyst for dehydrogenation of the liquid organic hydrogen energy carrier comprises an active component, an auxiliary agent and a carrier, the active component is Pt, the auxiliary agent is CeO2, and the carrier is MgO-Al2O3 composite oxide; the CeO2 is dispersed on the surface of the MgO-Al2O3 composite oxide in an island form; pt is selectively dispersed on the CeO2 islands. The catalyst can inhibit agglomeration and growth of Pt particles and deposition of organic carbides on the surface of the catalyst in the dehydrogenation reaction process, and shows excellent activity and stability.

A positive electrode active material includes a layered lithium nickel-based composite oxide, wherein, based on 100 mol% of a total mole of metals of the layered lithium nickel-based composite oxide excluding lithium, a nickel content is greater than or equal to about 60 mol%, an aluminium content is about 0.8 mol% to about 1.5 mol%, a zirconium content is about 0.1 mol% to about 0.3 mol%, a ratio of the aluminium content relative to the zirconium content (AI / Zr) is greater than or equal to about 5, and the positive electrode active material is in a form of a single particle with an average particle diameter (D50) of about 1 µm to about 4 µm. Also disclosed are a positive electrode comprising a positive electrode current collector having a layer of said positive electrode active material located thereon, and a rechargeable lithium battery comprising said positive electrode, a negative electrode and an electrolyte. Further disclosed is a method of preparing the positive electrode active material.

The invention discloses a method for preparing glyceric acid by catalytically oxidizing glycerol with a non-noble metal catalyst, which comprises the following steps of: catalytically oxidizing glycerol under the action of oxygen by taking a CuZrOx composite oxide as a catalyst to obtain glyceric acid; wherein the CuZrOx composite oxide is prepared by a deposition-precipitation method through high-temperature calcination. The internal structure of the catalyst is changed due to introduction of Cu, two metal components are combined more tightly and have strong interaction due to doping of Cu, and meanwhile, compared with a single-metal catalyst, the number of oxygen vacancies of the composite oxide catalyst is increased, the number of strongly acidic sites and strongly basic sites on the surface is increased, and the catalytic activity of the catalyst is improved. According to the present invention, the catalyst has a certain acid-base property so as to produce the good catalysis effect, such that the high glycerol conversion rate and the high glyceric acid selectivity are achieved while the production cost is reduced, and the catalyst can be repeatedly used.

This positive electrode active material for nonaqueous electrolyte secondary batteries contains a lithium transition metal composite oxide that is represented by composition formula LixMnyNizPaMbO2-cFc(wherein M represents at least one element that is selected from among Ti, Co, Si, Sr, Nb, W, Mo, Ca, Mg, Sb, Na, B, V, Cr, Fe, Cu, Zn, Ge, Zr, Ru, K and Bi; 1.0<x≤1.2; 0.4≤y≤0.8; 0≤z≤0.4; 0<a<0.01; 0<b<0.05; 0<c<0.1; and (x+y+z+a+b)≤2).