The invention relates to a preparation method of an Fe, W and C
ternary phase carbide Fe3W3C, which comprises the steps of taking reduced
iron powder, W
powder, and carbon
powder as reactor raw materials, preparing Fe-W-C mixed
powder according to a stoichiometric ratio (Fe / W / C) of (3-4):(3-4):(1-2), adding a certain amount of
raw material mixed powder and a
grinding ball into a ball milling
jar, after vacuumizing the ball milling
jar, charging
argon, performing ball milling on the Fe-W-C mixed powder under the
argon shield for 30-50h with the
steel ball having the
diameter of 7-12mm at a ratio of a
grinding medium to a material of (7-10):1, allowing the rotating speed of a
ball mill to be 400-500r / min, after the ball milling is finished, opening the
jar with a glove box to take the powder, performing compaction on the ball-milled powder via a stretcher, selecting a
hollow cylinder with the pressure of 400-600MPa and the die dimension of phi 10-30, after the compaction, putting into an SL63-7B vacuum carbon
tube furnace for
sintering at a heating rate of 10-50 DEG C / min, holding at 1000-1500 DEG C for 0.5-5h, then cooling to the
room temperature with the furnace, taking out, and obtaining a block material mainly comprising the ternary
carbide Fe3W3C.