This invention belongs to the field of
thermodynamics and
phase equilibrium measurement technology of
metallurgical slag, and discloses a high-temperature
phase equilibrium determination method for vacuum-sealed
slag systems containing low-valent
titanium oxides. The raw materials are roasted or dried; they are placed in a high-temperature resistant container according to a preset composition ratio, placed inside a
quartz tube, and a deoxidizer is added; after vacuum preheating,
argon gas washing, and adjustment of the
vacuum level inside the tube, the
slag is high-temperature sealed to form a thermodynamically
closed system; the
slag sample is held at the experimental temperature until it reaches
thermodynamic equilibrium, and after the
holding period, it is rapidly quenched to preserve the high-temperature phase structure; finally, the
phase equilibrium is determined through characterization. This invention uses a
closed system to effectively isolate external gas interference, and relies on the slag sample's own
redox equilibrium to autonomously establish and maintain the ultra-
low oxygen potential required for the stable existence of low-valent
titanium oxides. This solves the technical problem that traditional
atmosphere-controlled
oxygen methods cannot meet the phase equilibrium determination of slag systems containing low-valent
titanium oxides, and achieves accurate and reliable determination of the
phase diagram of slag systems containing low-valent titanium oxides at
steelmaking temperatures.