255 results about "Quasi-solid" patented technology

The present invention provides a composite quasi-solid-state electrolyte, a composite quasi-solid-state electrolyte membrane, preparation methods of composite quasi-solid-state electrolyte and the composite quasi-solid-state electrolyte membrane, and a lithium battery or a lithium ion battery containing the composite quasi-solid-state electrolyte membrane. The composite quasi-solid-state electrolyte comprises a solid electrolyte, a lithium salt-containing liquid electrolyte, inorganic nanoparticles and a binder, wherein the static electricity or functional groups on the surface of the inorganic nanoparticles can adsorb the electrolyte so as to make the composite quasi-solid-state electrolyte have strong adsorption capacity and strong liquid retention ability, and the inorganic nanoparticles can adsorb the lithium salt so as to change the lithium ion conduction mechanism, reduce the interfacial resistance between the liquid electrolyte and the solid-state electrolyte, change the deposition morphology of lithium, hinder the formation of lithium dendrite, and reduce the pulverization of lithium. In addition, by adding the solid electrolyte, the composite quasi-solid-state electrolyteof the present invention can maintain the high conductivity and can effectively reduce the content of the liquid electrolyte so as to improve the safety of the battery.

An interface infiltrated quasi-solid alkali metal cell is provided by the invention and comprises a cathode layer, an anode layer and an electrolyte layer. The electrolyte layer is a solid electrolyte. The cathode layer and / or the anode layer comprise electrode active compounds and an interface infiltrating additive. The interface infiltrating additive is of a liquid state in a work temperature range, can conduct ions and can infiltrate the electrode active compounds and the solid electrolyte. Electrodes of the cell and a preparing method of the cell are also provided by the invention. The cell is high in safety characteristics and wide in voltage window and can work in a wide temperature range.

The invention relates to high-ionic conductivity electrolyte compositions. The invention particularly relates to high-ionic conductivity electrolyte compositions of semi-interpenetrating polymer networks and their nanocomposites as quasi-solid / solid electrolyte matrix for energy generation, storage and delivery devices, in particular for hybrid solar cells, rechargeable batteries, capacitors, electrochemical systems and flexible devices. The binary or ternary component semi-interpenetrating polymer network electrolyte composition comprises: a) a polymer network with polyether backbone (component I); b) a low molecular weight linear, branched, hyper-branched polymer or any binary combination of such polymers with preferably non-reactive end groups (component-ll and / or component-Ill, for formation of ternary semi-IPN system); c) an electrolyte salt and / or a redox pair, and optionally d) a bare or surface modified nanostructured material to form a nanocomposite.

A heat-resistant aluminum alloy material with high strength and preparation method thereof are provided. The aluminum alloy material comprises (by weight %): Cu: 1.0˜10.0, Mn: 0.05˜1.5, Cd: 0.01˜0.5, Ti: 0.01˜0.5%, B: 0.01˜0.2 or C: 0.0001˜0.15, Zr: 0.01˜1.0, R: 0.001˜3 or (R1+R2): 0.001˜3, RE: 0.05˜5, and balance Al:, wherein, R, R1, and R2 include Be, Co, Cr, Li, Mo, Nb, Ni, W. The Al alloy has the advantages of narrow quasi-solid phases temperature range of alloys, low hot cracking liability during casting improved high temperature strength and high heat resistance.

The invention discloses a Be-Cr-RE high-strength heat-resisting aluminum alloy material and a production method thereof. The Be-Cr-RE high-strength heat-resisting aluminum alloy material comprises the following components in percentage by weight: Cu: 1.0-10.0%; Mn: 0.05-1.5%; Cd: 0.01-0.5%; Ti: 0.01-0.5%; B: 0.01-0.2%; Zr: 0.01-1.0%; Cr: 0.01-1.0%; Be: 0.001-0.1%; RE: 0.05-5%; and the balance of Al. By adopting a high-quality melt, solid solution and phase diagram theory as guide and preferring main alloy element formula of Cu, Mn and RE, the invention reduces an alloy quasi solid phase temperature range and solves the problems of large heat crack tendency in casting, low high-temperature strength of products, and the like; in addition, by preferring a multiple microalloying element formula, the invention provides a material condition for culture and grain refining of a high temperature phase and a strengthening phase in the solid solution and finally produces the high-strength heat-resisting aluminum alloy material.

Replacing liquid electrolytes with solid or quasi-solid electrolytes facilitates the production of photovoltaic cells using continuous manufacturing processes, such as roll-to-roll or web processes, thus creating inexpensive, lightweight photovoltaic cells using flexible plastic substrates.

It is described an integrated gas sensor device comprising a silicon substrate and an oxide layer on the silicon substrate, as well as a working electrode, a counter electrode and a reference electrode, on the oxide layer, the working electrode and the counter electrode having respective active area exposed to an environmental air through at least a plurality of first openings and a plurality of second openings in the oxide layer in correspondence of the working electrode and of the counter electrode, further comprising an electrolyte layer portion and a hydrogel layer portion on the electrolyte layer portion, the electrolyte and hydrogel layer portions having a same size, suitable to cover at least the working, counter and reference electrodes, the hydrogel layer portion acting as a “quasi solid state” water reservoir.

The invention relates to a method for preparing an integrated quasi-solid zinc ion battery and relates to the technical field of batteries. The method is characterized by using a hydrogel as a substrate, and embedding the positive electrode material and the negative electrode material of the zinc ion battery in the hydrogel substrate to realize the integrated structure of the battery, thereby avoiding the problems such as interfaces, compatibility and short circuits caused by the layered assembly of the positive electrode, the diaphragm and the negative electrode of a traditional battery. Themethod uses the hydrogel as the gel electrolyte of the zinc ion battery, embeds the flexible zinc negative electrode prepared by electro-deposition, and then chemically polymerizes a polymer materialin situ on the surface of the gel electrolyte as a positive electrode. The integrated quasi-solid zinc ion battery with a customized shape can effectively reduce the interface impedance inside the battery and promotes the rapid transmission of electrolyte ions inside the electrode. The most important thing is that such design can provide more positive electrode material loading area for the battery, which greatly increases the energy density of the battery. The invention is used in the field of batteries.

The invention relates to an electrolyte of dye-sensitized solar cells, disclosing a quasi solid electrolyte and a preparation method thereof; the method in the invention comprises the following steps: (1) blending polymeric ionic liquid, nonpolymeric ionic liquid, ionic liquid cross linking agent and initiating agent according to the mass ratio of 15-60:20-80:2-10:1-5, and obtaining the polymer gel through random copolymerization at the temperature of 20-80 DEG C; and (2) immersing the polymer gel into iodic solution or iodic vapor for adsorption of iodic simple substance to obtain the electrolyte. In the invention, the well-prepared ionic liquid monomer / ionic liquid mixture is dipped between a light anode and a Pt electrode and quasi solid polymer gel is formed through in situ polymerization; the polymer gel is dipped into iodic solution or iodic vapor for the adsorption of iodic simple substance to prepare the quasi solid full-ionic liquid electrolyte which is used in solar cells, and the dye-sensitized solar cells are prepared simultaneously. The electrolyte prepared by the method has strong electrolytic adhesive ability and easy encapsulation, thus simplifying battery assembly program.

The invention discloses one quartz solid electrolyte and its process method, wherein, the electrolyte comprises ion liquid, inorganic layer materials, single iodide, light anode match agent and isothiocyanic acid through direct mixture method or organic solvent agent mixture evaporation, wherein, the ion liquid is of solvent agent and other element mole concentration as inorganic layer materials for 0.001-10mol / L; single mass iodide for 0.01-1mol / L; iodide; light anode match agent for 0.01-1mol / L; isothiocyanic acid for 0.01-1mol / L.

The invention discloses a torsional vibration adjustment device based on magnetorheology. A key hole is formed in the center of a flange plate of a flange, and the flange plate of the flange and a flange cover provided with holes are connected with an annular sleeve through bolts and located on the two sides of the sleeve correspondingly. A torsional vibration adjustment mechanism further comprises a lower cylinder body internally provided with a containing cavity, an upper cylinder body externally provided with a containing cavity, arc-shaped piston push rods, springs, connecting rods, and a rotary shaft cylinder, wherein the rotary shaft cylinder is connected with a driving shaft, the connecting rods are fixedly connected with the rotary shaft cylinder and the arc-shaped piston push rods, and the driving shaft drives the arc-shaped piston push rod to rotate in the containing cavity, containing magnetorheological fluid, of the upper cylinder body; and electromagnetic coils are wound in the containing cavity of the lower cylinder body and generate a magnetic field when current passes through the electromagnetic coils, and the magnetorheological fluid is in a quasi-solid state under the effect of the magnetic field, so that the torsional moment of a spindle is changed, and accordingly the purpose of adjusting torsional vibration is achieved. The torsional vibration adjustment device based on magnetorheology is simple and compact in structure, different degrees of torsional vibration can be actively and continuously adjusted in real time, and a good torsional vibration reduction effect is achieved.

The invention provides a quasi-solid-state single line laser radar based on an MEMS-like galvanometer, and an operating method of the quasi-solid-state single line laser radar. The quasi-solid-state single line laser radar comprises a laser device, a detector and a galvanometer, wherein the galvanometer comprises a base, magnets, a coil, a reflector, a torsion bar and a fixing member; the magnets are arranged on two opposite sides of the base separately, and the polarities of the isolated magnets at opposite positions are opposite; two ends of the coil are connected with an alternating current; the reflector is connected with the coil; the reflector reflects detection light emitted by the laser device to a detected object, and the detection light on the detected object enters the detector after passing through the reflector; one end of the torsion bar is fixed on the base by means of the fixing member, and the other end is connected with the coil; and the coil generates torque in a magnetic field formed by the magnets under the driving of the alternating current, so as to drive the reflector to twist by taking the torsion bar as an axis. The quasi-solid-state single line laser radar has the advantages of simple structure, low cost and the like.

The invention discloses a C-metamorphic Mo-W-RE high-strength heat-resistant aluminum alloy material. The aluminum alloy material comprises the following components in percentage by weight: 1.0 to 10.0 percent of Cu, 0.05 to 1.5 percent of Mn, 0.01 to 0.5 percent of Cd, 0.01 to 0.5 percent of Ti, 0.0001 to 0.15 percent of C, 0.01 to 1.0 percent of Zr, 0.01 to 1.0 percent of Mo, 0.01 to 1.0 percent of W, 0.05 to 5 percent of rare earth element and the balance of Al. In the invention, a high-quality melt, solid solution and a phase diagraph theory are taken as guidance, a C element serves as a high-efficiency modifier, and a preferable formula of principal alloy elements, namely Cu, Mn and RE is adopted, so that the alloy quasi solid-phase temperature range is narrowed and problems such as high heat cracking tendency during casting, low strength of a product at a high temperature and the like are solved; and a preferable formula of low-cost multiple microalloying elements is adopted, so that the high-strength heat-resistant aluminum alloy material is finally developed.

The invention discloses a solar cell gel electrolyte and a preparation method and application thereof. In the invention, the gel electrolyte is prepared by adding novel dendritic ionic liquid into liquid electrolyte of non-polymeric ionic liquid, additive and iodine monomer, hermetically stirring the mixture for 1 to 20 hours at the temperature of between 50 and 140 DEG C and uniformly dissolving the novel dendritic ionic liquid. The gel electrolyte is dropwise added or injected into the space between a photoanode dye titanium dioxide membrane and a Pt electrode while the gel electrolyte is hot; the gel electrolyte is further heated and subjected to evacuation, so that the gel electrolyte is completely impregnated into the titanium dioxide membrane serving as a porous membrane; and the components are packaged to prepare a quasi-solid fully ionic liquid gel solar cell. The gel electrolyte prepared in the invention does not comprise conventional toxic solvents and thus has the advantages of ready availability, easy package and high stability and high efficiency of the cell. The cell has a few assembly processes and low cost. When a xenon lamp is utilized to simulate the sunshine at the room temperature environment, the measured maximum photoelectric conversion efficiency of the cell is 6.0 percent under the condition that the light intensity is 100mW / cm<2>.

Provided is method of preparing an alkali metal-sulfur cell, comprising: (a) combining a quantity of a cathode active material (selected from sulfur, a metal-sulfur compound, a sulfur-carbon composite, a sulfur-graphene composite, a sulfur-graphite composite, an organic sulfur compound, a sulfur-polymer composite or a combination thereof), a quantity of an electrolyte, and a conductive additive to form a deformable cathode material, wherein the conductive additive, containing conductive filaments, forms a 3D network of electron-conducting pathways and the electrolyte contains an alkali salt and an ion-conducting polymer dissolved or dispersed in a solvent; (b) forming the cathode material into a quasi-solid cathode, wherein the forming includes deforming the cathode material into an electrode shape without interrupting the 3D network of electron-conducting pathways such that the cathode maintains an electrical conductivity no less than 10−6 S / cm; (c) forming an anode; and (d) forming a cell by combining the cathode and the anode.

The invention discloses a water-based solid electrolyte membrane, a preparation method thereof, and a secondary battery. The water-based solid electrolyte membrane comprises: a base film of 1 um-50 um, and a water-based solid electrolyte layer of 0.5 um-10um composed of a coating slurry coated on the base film or a coating slurry coated on the base film and permeating into the base film, wherein the coating slurry comprises: 1-40 parts of composition and 60-99 parts of deionized water in parts by mass; the composition comprises: 94 wt%-99.97 wt% of solid electrolyte powder, 0.01 wt%-2 wt% of water soluble binder, 0.01 wt%-2 wt% of water soluble dispersant, and 0.01 wt%-2 wt% of water soluble adjuvant. The water-based solid electrolyte membrane has good liquid absorption, uniform thickness,high temperature resistance and high ion conductivity, and may be used in liquid, semi-solid, quasi-solid, all-solid lithium batteries and metal lithium batteries.

The present invention discloses a quasi-solid dye sensitized flexible solar cell battery and a preparation method of the battery. A layer of TiO2 nanometer fiber film is attached as optical anode to a metal wire mesh coated with TiO2 nanometer particles, a sort of organic dye is used as sensitizer, polymer gel electrolyte is filled, a stainless steel plate coated with conductive polymer is used as the counter electrode, a non-conductive polyester film with good light transmittance performance is used as an encapsulation film to encapsulate the assembly, to obtain a quasi-solid flexible solar battery. The battery provided in the present invention has good stability and low cost, and is free of electrolyte leakage or encapsulation difficulty, etc., and can be easily stored, transported, installed, and used.

The invention relates to a column quinone positive pole material for a lithium ion battery, wherein the material is a cyclic compound which is formed by connecting 5-7 p-benzoquinone units in para-positions through methylene by taking carbonyls of the p-benzoquinone units as electrochemical redox reaction sites. The column quinone positive pole material is used for preparing a solid state lithium ion battery. The method comprises the following steps: 1) grinding an active matter, a conductive agent and a binder in an organic solvent to form a paste, coating the paste on a current collector, and drying in air to prepare an electrode; 2) by taking the electrode as a positive pole and lithium metal as a counter electrode and a reference electrode, separating the two electrodes by a PMA / PEG (Polymethyl Methacrylate / Polyethylene Glycol) gel polymer electrolyte, and assembling in argon or dried air to form the battery. The material provided by the invention has the advantages that the column quinone positive pole material has high carbonyl utilization ratio and high specific capacity; the column quinone positive pole material applied to a quasi solid lithium ion battery is high in specific discharge capacity and good in cycle performance, and is expected to be applied to the next generation of energy storage batteries with high high-energy density, high power density and long cycle life.

The invention discloses a Li-W-RE high-strength heat resistant aluminum alloy material modified with C. The alloy comprises the following components by weight percent: 1.0 to 10.0 percent of Cu, 0.05 to 1.5 percent of Mn, 0.01 to 0.5 percent of Cd, 0.01 to 0.5 percent of Ti, 0.0001 to 0.15 percent of C, 0.01 to 1.0 percent of Zr, 0.1 to 3.0 percent of Li, 0.01 to 1.0 percent of W, and 0.05 to 5 percent of rare earth element and the rest is Al. Through optimally choosing alloy host element Cu, Mn and RE prescription, the invention reduces alloy quasi-solid phase temperature range and solves the problems of large hot tear tend and low product high temperature strength in the casting process, guided by high quality melt, solid solution and phase diagram theory and taking a C element as modificator. The low cost multiple microalloyed element prescription is optimally choosen. Finally, a high-strength heat resistant aluminum alloy material is developed.

The invention relates to a three-phase organic / inorganic composite gel state polymer electrolyte and a preparation method thereof to solve the technical problem that the mechanical property of an electrolyte membrane is degraded by introducing PEO. The three-phase organic / inorganic composite gel state polymer electrolyte comprises g-C3N4, PVDF-HFP and PEO, The g-C3N4 is in a lamellar and microsphere shape, and is distributed in PVDF-HFP and PEO systems. The mass of g-C3N4 accounts for 0.1%-20% of the total mass of the electrolyte. The invention also provides a method for preparing the three-phase organic / inorganic composite gel state polymer electrolyte. The three-phase organic / inorganic composite gel state polymer electrolyte can be used in the field of preparation of quasi-solid state lithium ion batteries.

Provided is an alkali metal cell comprising: (a) a quasi-solid cathode containing 30% to 95% by volume of a cathode active material, about 5% to about 40% by volume of a first electrolyte containing an alkali salt dissolved in a solvent and an ion-conducting polymer dissolved, dispersed in or impregnated by a solvent, and about 0.01% to about 30% by volume of a conductive additive wherein the conductive additive, containing conductive filaments, forms a 3D network of electron-conducting pathways such that the quasi-solid electrode has an electrical conductivity from about 10−6 S / cm to about 300 S / cm; (b) an anode; and (c) an ion-conducting membrane or porous separator disposed between the anode and the quasi-solid cathode; wherein the quasi-solid cathode has a thickness from 200 μm to 100 cm and a cathode active material having an active material mass loading greater than 10 mg / cm2.

Provided is method of preparing an alkali metal cell, the method comprising: (a) combining a quantity of an active material, a quantity of an electrolyte, and a conductive additive to form a deformable and conductive electrode material, wherein the conductive additive, containing conductive filaments, forms a 3D network of electron-conducting pathways and the electrolyte contains an alkali salt and an ion-conducting polymer dissolved or dispersed in a solvent; (b) forming the electrode material into a quasi-solid polymer electrode, wherein the forming includes deforming the electrode material into an electrode shape without interrupting the 3D network of electron-conducting pathways such that the electrode maintains an electrical conductivity no less than 10−6 S / cm; (c) forming a second electrode; and (d) forming an alkali metal cell by combining the quasi-solid electrode and the second electrode. The second electrode may also be a quasi-solid polymer electrode.

The invention provides a polyionic liquid base micropore quasi solid state electrolyte preparation method, belonging to the field of preparation process technology of solid state electrolyte; in the method, imidazole iodide ion liquid containing unsaturated double bond at side chain is prepared, and then radical polymerization is carried out to obtain polyionic liquid, and then the polyionic liquid is mixed with polyvinylidene fluoride, a polymer micropore film is prepared by a phase transition method, and then the polymer micropore film is soaked in the electrolyte to obtain the polyionic liquid base micropore quasi solid state electrolyte; the polyionic liquid base micropore quasi solid state electrolyte is applied to dye sensitization solar batteries, the problem that the battery is encapsulated difficultly is not only solved, and the long-time stability of the battery is improved, but also the charge transmission capacity in the quasi solid state electrolyte system is effectively improved and the performance of the quasi solid state dye sensitization solar battery is effectively improved.

Mold-free resin-insulated coil windings are obtained by applying continuous fibers embedded in a quasi-solid-state epoxy-resin matrix, e.g. in the form of a tape, to the coil windings. The tape is locally heated up to the melting point of its polymer matrix, and is subsequently pressed against the winding body. The heated and fused resin of the tape, which is pressed onto the coil, flows under pressure into the voids and gaps between the coil windings and fills them up, thereby hermetically insulating the coil windings. After leaving the heating and pressing apparatus the fused epoxy resin becomes solid again. The resulting curing process is thus considerably simplified and shortened, compared to the state of the art.

The invention discloses an Ag-RE high-strength high-toughness aluminum alloy material and a preparation method thereof. The alloy comprises the following components in percentage by weight: 1.0 to 10.0 percent of Cu, 0.05 to 1.5 percent of Mn, 0.01 to 0.5 percent of Cd, 0.01 to 0.5 percent of Ti, 0.01 to 0.2 percent of B, 0.01 to 1.0 percent of Zr, 0.01 to 1.0 percent of Ag, 0.05 to 5 percent of RE, and the balance of Al. High-quality melt, solid solution and a phase diagram theory are taken as guidance, and by using a preferable alloy main element formula of Cu, Mn and RE, the quasi solid temperature range of the alloy is reduced, and the problems of large hot tearing tendency in the casting process, low high-temperature strength of products and the like are solved; by using a preferable multielement microalloying element formula, material foundation conditions are created for the cultivation of a strengthening phase in the solid solution and grain refining effect; and the high-strength high-toughness aluminum alloy material is finally manufactured by optimizing smelting and thermal treatment process technology.

It is an objective of the invention to provide a quasi-solid state electrolyte that has a well-balanced combination of contact performance with electrode active materials, conductivity, and chemical and structural stability, each at a high level, and an all solid state lithium secondary battery using the quasi-solid state electrolyte. There is provided a quasi-solid state electrolyte comprising: metal oxide particles; and an ionic conductor, the ionic conductor being a mixture of either a glyme or DEME-TFSI and a lithium salt that includes LiFSI, and being carried by the metal oxide particles.

The invention discloses a quasi-solid tungsten trioxide electrochromic device and a preparation method thereof. The quasi-solid tungsten trioxide electrochromic device comprises a working electrode, an electrolyte layer, a counter electrode and a transparent conducting layer, wherein the working electrode is tungsten oxide, the electrolyte layer is a choline chloride ethylene glycol gel containinglithium salt, and the counter electrode is nano cerium oxide. A tungsten trioxide electrochromic film electrode and a cerium oxide counter electrode are prepared by adopting a spraying method, gel electrolyte is taken as pseudo ionic liquid, the gel electrolyte has the advantages of being low in cost, green and environment-friendly, highly transparent, not easy to leak, and high in ionic conductivity, so that the device prepared by the electrolyte has the characteristics of high response speed, large optical density difference and low cost.

The invention discloses an ionic-liquid-gel-electrolyte-based quasi-solid flexible self-powered ZnO-based ultraviolet detector comprising a transparent conductive flexible substrate, a ZnO seed crystal layer, a ZnO nano array, an ionic liquid gel electrolyte layer, a Pt conductive layer and a flexible substrate. The edge of the detector is sealed by a sealant. According to a preparation method for the detector, a ZnO seed crystal layer grows on a transparent conductive flexible substrate and then a ZnO nano array grows; the ZnO nano array layer is coated with an ionic liquid gel electrolyte; a Pt conductive layer is plated on another flexible substrate; and after binding and sealing, the detector is obtained. Compared with the traditional ultraviolet detector, the provided detector has advantages of not needing an external bias voltage, being carried conveniently, having fast speed, and being capable of bent for usage; and the preparation process is simple and large-area batch production can be realized. Besides, the detector can work stably and continuously without the need to replace an electrolyte frequently.

The invention discloses a Sc-Ni-RE high-strength heat-resistant aluminium alloy material and a preparation method thereof. The Sc-Ni-RE high-strength heat-resistant aluminium alloy material comprises the components in percent by weight: 1.0-10.0 percent of Cu, 0.05-1.5 percent of Mn, 0.01-0.5 percent of Cd, 0.01-0.5 percent of Ti, 0.01-0.2 percent of B, 0.01-1.0 percent of Zr, 0.01-1.0 percent ofNi, 0.01-1.0 percent of Sc, 0.05-5 percent of RE and the balance of Al. With an excellent-quality melt, a solid solution and a phase diagram theory as guidance and through preferably selecting alloy principal elements of Cu, Mn and RE, the invention reduces the alloy quasi solid phase temperature range and solves the problems of large heat cracking tendency, low high-temperature strength of the product, and the like during the casting; and preferably, a multielement microalloying element formula is selected, the material base condition is created for carrying out culturing and grain refining on a high-temperature phase and a strengthening phase in the solid solution, and a high-strength heat-resistant aluminium alloy material is finally developed.