The invention belongs to the technical field of
lithium metal battery safety, and relates to a preparation method of a
lithium metal battery based on a
flame-retardant local high-concentration
polymer electrolyte. The preparation method comprises the following steps: preparing an intrinsic
flame-retardant high-molecular
polymer into
spinning solutions with different concentrations, and preparing an intrinsic
flame-retardant
nanofiber membrane through an electrostatic
spinning technology; the preparation method comprises the following steps: preparing an
ether or ester
electrolyte, adding a
diluent, a catalyst and a cross-linking agent into the
ether or ester
electrolyte in proportion to prepare a pre-polymerized solution, finally assembling a button
cell according to a sequence of a positive
electrode, a
nanofiber membrane, the pre-polymerized solution and a negative
electrode, after packaging, standing for a period of time under a certain condition, and carrying out in-situ free radical combination under a heating condition to obtain the button
cell. The
lithium metal battery based on the flame-retardant local high-concentration
polymer electrolyte is obtained, and then the battery is connected to an electrochemical measurement
system to measure the electrochemical performance of the battery. The preparation process is simple, the equipment technology is mature, and the safety performance and the electrochemical performance of the battery can be effectively improved.