475results about How to "Achieving controllable equipment" patented technology

The invention relates to an ultrathin nanosheet array electro-catalytic material with a nano-porous structure and oxygen vacancies. The material is a cobaltosic oxide primary nanosheet array which grows vertically on a conductive substrate and is doped with a metal; an ultrathin nanosheet with oxygen vacancies and nanopores is obtained on each primary nanosheet; the conductive substrate is a titanium sheet or a foamed nickel sheet, and the doped metal is zinc, nickel or manganese; and the thickness of each cobaltosic oxide ultrathin nanosheet doped with the metal is 1.22 nm, nanosheets are in a three-dimensional porous structure, and the nano-pore diameter is 3-6 nm. The ultrathin nanosheet array electro-catalytic material with the nano-porous structure and oxygen vacancies has the following advantages: the material can effectively reduce the overpotential and the spike potential of an oxygen evolution reaction, increase the conversion rate of a single cobalt atom and work continuously and stably in an alkali environment; the steps of a preparation method of the material are simple, the operation is convenient, the cost is low, and the material is environmental-friendly; and new ideas and strategies are provided for the function-oriented design and the performance optimization of an oxygen evolution catalyst of a water electrolysis system.

The invention discloses a Co@NC high-dispersion core-shell structure catalyst, and a preparation method and an application of the catalyst, and belongs to the technical field of energy source materials and electrochemistry. The preparation method of the catalyst comprises the steps of taking glucose as a C source, taking cyanoguanidine as a C-N source, taking Co(No3).6H2O as a Co source, and performing high temperature calcination. The cyanoguanidine performs high temperature decomposition to generate two-dimensional flaky g-C3N4; the glucose performs high temperature decomposition to generatea carbon intermediate and a metal species which are inserted into flakes of g-C3N4; and Co nanoparticles coated by an N-C layer in the catalyst are uniformly dispersed on a graphene carbon layer. Thecatalyst can serve as a cathode oxygen reduction electrocatalyst of a metal-air battery and a fuel battery. The catalyst is cheap and easy obtaining in raw material, and simple in preparation technology; amplification production is facilitated; in-situ decomposition of the cyanoguanidine provides rich N doped active sites for the catalyst; rich mesoporous structures are formed; the activity of the catalyst is improved; a channel is provided for transfer and transport of reaction participation substances in an ORR process; a mass transfer demand of a reaction process is met; and the catalyst is good in stability and high in methanol resistance.

The invention provides a ZnO/SnO2 nano composite gas-sensitive material with a flower-shaped grading structure. The ZnO/SnO2 nano composite gas-sensitive material is prepared by the following steps: dripping a sodium hydroxide water solution into an ethanol solution of cetyl trimethyl ammonium bromide and stannous chloride dihydrate under electromagnetic stirring; after dripping, preparing a precursor solution by the continuous electromagnetic stirring; adding the precursor solution into a reaction kettle, reacting at 130 DEG C; carrying out centrifuging on a reactant, washing and drying to obtain a flower-shaped stannous oxide sacrifice template; adding the flower-shaped stannous oxide sacrifice template into a zinc acetate solution; agitating and carrying out ultrasonic treatment; removing a solvent to obtain a ZnO/SnO2 precursor; and carrying out heat preservation on the ZnO/SnO2 precursor for 2-4 hours in an air atmosphere of 700 DEG to obtain the composite gas-sensitive material. According to the ZnO/SnO2 nano composite gas-sensitive material with the flower-shaped grading structure, the controllable preparation of the composite gas-sensitive material on the appearance and components can be realized; the mass percent content of zinc oxide in the composite gas-sensitive material is 5%-15%; a flower shape is assembled by sheet-shaped tin dioxide and zinc oxide nano particles; the ZnO/SnO2 nano composite gas-sensitive material has a good gas sensitive performance and has a wide application prospect in the aspect of manufacturing a novel high-efficient gas sensor.

The invention discloses a preparation method of a graphene composite anticorrosive coating. The preparation method comprises the following steps: (1) preparing an organic coating solution with a plurality of hydroxyls or amino groups; (2) preparing an oxidized graphene or modified graphene solution; (3) performing metal surface pretreatment; (4) performing electrodeposition to form an organic coating film; and (5) preparing the graphene composite anticorrosive coating. The method is simple and feasible in technology, the film forming speed is obviously improved, and the prepared coating is more compact and uniform; compared with a plain sample, the low-frequency impedance modulus value of the prepared composite coating is improved to 10<6.2> from 10<3.5> by performing electrochemical testing in 3.5wt% NaCl neutral electrolyte solution, the self-corrosion current is also remarkably reduced, and longer effective prevention effect on a matrix can be achieved. Compared with the conventional dip-coating method, the preparation method has lower requirement on the flatness of a metal surface, and controllable preparation can be effectively realized; the prepared coating is non-toxic and environment-friendly, controllable in thickness, and more compact and uniform, and more durable and stable protection effect on the metal matrix can be achieved.

The invention discloses a ternary positive-electrode material prepared by a solvothermal method and a preparation method thereof. The preparation method includes: dissolving nickel cobalt manganese salt in a solvent, adding a surfactant and hydrolysis auxiliaries, sufficiently stirring, transferring into a reaction kettle, performing solvothermal reaction under certain temperature for 2-24 hours,cooling to room temperature, using a suction filtration method to separate out a nickel cobalt manganese ternary product, washing, drying, and pre-calcining in air to obtain a precursor; grinding andmixing the precursor and a lithium compound, and calcining to obtain the ternary positive-electrode material. The ternary positive-electrode material and the preparation method thereof have the advantages that the ternary oxide precursor prepared by the solvothermal method is small in particle size, uniform in particle distribution and controllable in morphology as compared with a ternary precursor prepared by a conventional precipitation method, so that the finally prepared ternary material is small in granularity, uniform in particle size distribution and controllable in morphology and has excellent electrochemical performance, and the capacity and stability of the prepared ternary material are better than those of a ternary positive-electrode material prepared by the precipitation method.

The invention discloses a preparation method of three-dimensional porous silica powder, relates to a porous nanometer function material and belongs to the field of preparation of porous nanometer function materials. Silica powder with different purities fume is taken as a raw material, and metal nanoparticles (Ag, Au, Pd, Pt, Cu and the like) taken as catalysts are introduced on the surface of the silica Powder; in a reaction system with HF acid and an oxidizing agent, an MACE (metal-assisted chemical etching) method is adopted, and the porous silica powder with different pore structures and porosities is prepared under the room temperature condition. Compared with a traditional electrochemistry anode etching method, a magnesiothermic reduction method and the like, the method provided by the invention has the advantages of avoiding expensive single crystal silicon raw materials, harsh high-temperature reaction equipment and operation, being simple in equipment, easy in operation, low in cost, controllable in material structure and suitable for large-scale industrial production, and the like. The preparation method of the three-dimensional porous silica powder has wide application prospect in the fields of lithium ion batteries, photoelectric materials, biomedicine, sensors and the like.

The invention relates to a preparation method of a composite material, and concretely relates to a preparation method of an MoS2/ZnIn2S4 nanosheet composite material by using sheet MoS2. The low photocatalytic activity of a single ZnIn2S4 photocatalyst at present is a problem that remains to be solved in the invention. The method comprises the following steps: 1, mixing sheet MoS2 with anhydrous ethanol; 2, adding to a mixed solution comprising an indium salt, a sulfur source, a zinc salt, a polyol and anhydrous ethanol; and 3, reacting, washing, and drying. The method realizes the controllable preparation of the MoS2/ZnIn2S4 nanosheet composite material; and the prepared MoS2/ZnIn2S4 nanosheet composite material has a very good stability. The method is used for preparing the MoS2/ZnIn2S4 nanosheet composite material.

The invention discloses a method for preparing CsPbBr3 nanosheets with quantum size effects. The method includes dissolving cesium carbonate in oleic acid under argon filling conditions, and stirring the cesium carbonate and the oleic acid under heating conditions until the cesium carbonate is dissolved to obtain cesium oleate precursors; adding lead bromide, long-chain ligands and short-chain ligands into octadecene under argon filling conditions, carrying out reaction at the temperature of 100-150 DEG C until the lead bromide is dissolved, heating first reaction products until the temperature of the first reaction products reaches 120-150 DEG C, then injecting the cesium oleate precursors into the first reaction products, carrying out reaction for 5-15 s, then continuing to carry out reaction at the temperature of 100-130 DEG C for 1-5 min to obtain second reaction products and centrifuging the second reaction products. The method has the advantages that the transverse sizes of the CsPbBr3 nanosheets can be assuredly regulated and controlled in the range from 100 nm to 1 micrometer while the thicknesses which are equal to the thicknesses of a few atomic layers can be guaranteed; the thicknesses which are lower than the diameters of Bohr excitons can be kept, and accordingly the quantum size effects of the CsPbBr3 nanosheets can be reserved.

The invention relates to a preparation method of a self-assembly Ni-MOFs electrochromic QR code device. The method comprises the steps as follows: 1,4,5,8-naphthalenetetracarboxylic dianhydride and 5-amino-2-hydroxybenzoic acid are put in toluene, and an anhydride ligand is obtained; the ligand is dissolved in DMF and a solution A is obtained; nickel salt is dissolved in ethanol and a solution B is obtained; pretreated FTO glass is irradiated by ultraviolet ozone, the obtained FTO glass is sequentially placed in the solution A, ethanol, the solution B and ethanol for self-assembly, circulatingoperation is performed, and an FTO electrode with a Ni-MOFs film attached on the surface is obtained; a working electrode displaying QR code patterns is formed through laser etching, another FTO glass is used as a counter electrode, gel electrolyte is injected, and the device is obtained after packaging. Controllable preparation of the Ni-MOFs film is realized, the prepared QR code device can beswitched between display and hiding when positive and negative voltage is applied, and meanwhile, the device has good electrochromic performance and has wide application prospects in the fields of Internet of Things, intelligent wearable devices and the like.

The invention discloses a controllable preparation method based on high-stacking-degree graphene modified high-thermal-conductivity carbon-plastic alloy. The carbon-plastic alloy is prepared from thefollowing components in percentage by weight: high-stacking-degree graphene filler: 5 to 50%, thermosetting resin: 30 to 55%, a coupling agent: 0.2 to 2%, a resin diluent: 1 to 5%, a curing agent: 7 to 15%, reinforcing filler: 5 to 20%, and an auxiliary agent: 2 to 5%. The high-stacking-degree graphene filler is composed of carbon materials of four different specifications, wherein graphene A accounts for 5 to 15%, graphene B accounts for 2 to 5%, nanographite microchip C accounts for 15 to 45%, and nanographite microchip D accounts for 35 to 78%. The high-stacking-degree graphene filler is added to a thermosetting resin matrix to form a perfect heat transfer passage, and the high-thermal-conductivity carbon-plastic alloy material having a thermal-conductivity coefficient of 10-25 W/m.K can be controllably prepared. The high-thermal-conductivity carbon-plastic alloy prepared by the invention can be processed into various heat dissipation components by compression molding or injection molding, and is suitable for industrial heat dissipation, illumination heat dissipation, heat dissipation of electronic devices, etc.

The invention discloses a method for preparing silver nanowires. The silver nanowires are prepared controllably by the self-assembly characteristic of micelle of amphiphilic hyperbranched polymer. The method comprises the following specific steps of dissolving or dispersing the amphiphilic hyperbranched polymer in polyhydric alcohol; adding halogenous inorganic salt or sulfurated inorganic salt in the mixture; adding silver salt in the mixture after the halogenous inorganic salt or sulfurated inorganic salt is dissolved in the mixture completely; placing obtained mixed solution in a sealed reaction kettle; performing constant-temperature reaction at a certain temperature in a range of 120-240 DEG C; naturally cooling down a reaction product to obtain raw products of silver nanowires; and washing the raw products by using organic solvent and centrifugally separating the raw products to obtain the silver nanowires. A one-kettle solvothermal method is used, the amphiphilic hyperbranched polymer is used for preparation of the silver nanowires, and the silver nanowires with uniform sizes and morphologies can be obtained. The steps of the method are simple and are easy to operate; the controllability and the reproducibility are high; and the silver nanowires are easily produced in batches.

The invention relates to a method for preparing a nickel oxide electrochromic film by a hydrothermal method. The method comprises the following steps of: dissolving nickel acetate tetrahydrate in a mixed solution of alcohol and n-butyl alcohol, dropwise adding ammonia water to the mixed solution after the nickel acetate tetrahydrate is dissolved to obtain sol; coating the sol to the surface of FTO (Fluorine-doped Tin Oxide) conductive glass in a rotary manner, drying the sol to obtain the FTO conductive glass with a crystal seed layer; mixing the nickel acetate tetrahydrate, urea and a solvent to obtain a reaction solution; immersing the FTO conductive glass with the crystal seed layer to the reaction solution for carrying out hydrothermal reaction; keeping the reaction solution for 6 hours to 12 hours under the condition of 160 DEG C to 180 DEG C, cooling the reaction solution to the room temperature, cleaning, drying and roasting to obtain the nickel oxide electrochromic film. The preparation method disclosed by the invention is simple, low in cost and likely applied to the glass surface film-making industry. The nanometer structure nickel oxide film directly grows on the surface of the FTO conductive glass by a hydrothermal method, so that the nickel oxide and the substrate have better binding force for being beneficial to electron conduction. Meanwhile, the electrochemical stability of the film is also improved.

The present invention relates to a controllable preparation method of a nitrogen-doped porous carbon-supported metal monoatomic material, and belongs to the technical field of material science and engineering. According to the present invention, porphyrin and a metalloporphyrin are polymerized through a polymerization reaction. The proportions of the porphyrin and the metalloporphyrin are regulated to regulate a metal content (0.06-4.00wt%), and monoatomic metal types (A type, AB type, ABC type) are regulated by regulating different types of metalloporphyrins. According to the present invention, controllable preparation of a metal monoatomic material is realized with good expansibility and reproducibility; meanwhile, the problems of low metal content, few types and the like in the prior art are solved, and researches in the related fields such as the synthetic methodology of metal monoatomic materials and the like.

The invention particularly relates to a porous titanium nitride nanotube array film and a preparation method thereof. The technical scheme of the method is that: first, a polished and buffed titaniferous metal sheet is used as an anode to be put into electrolyte for carrying out anodic oxidation, the voltage of anodic oxidation is 10-60 V, and the time of anodic oxidation is 0.5-5 hours; then the titaniferous metal sheet after anodic oxidation is washed and dried, and the dried titaniferous metal sheet is subjected to annealing treatment at the temperature of 300 to 600 DEG C in the air; finally the titaniferous metal sheet after the annealing treatment is subjected to annealing at the temperature of 300 to 600 DEG C in the atmosphere that the volume of a nitrogenous precursor is 10-100 percent at a speed of 1-20 DEG C/min, and is cooled along a furnace; and the titanium nitride nanotube array film is obtained on the surface of the titaniferous metal sheet. The preparation method disclosed by the invention is simple, and the process is reliable. The prepared porous titanium nitride nanotube array film is uniformly distributed with nanometer-size holes from a tube mouth to a tube bottom, and the size of the holes can be adjusted. The porous titanium nitride nanotube array film is suitable for the field of electrochemistry.

The invention provides a method for quickly manufacturing Li2TiO3 tritium breeding small balls. The method comprises the following steps that (1) Li2TiO3 powder and binder powder are mixed to form mixed powder; (2) a small ball three-dimensional model is established in a computer and is stored in the format of STL; (3) the mixed powder obtained in the step (1) is transferred into 3D printing equipment, the small ball three-dimensional model in the format of STL is introduced into a system of the 3D printing equipment; (4) technological parameters are set and the 3D printing equipment is started to obtain small ball entities; (5) the small ball entities are placed into a cold isostatic press to be compacted; (6) binder removal processing is conducted on the small ball entities; (7) the small ball entities are sintered in a sintering furnace. The Li2TiO3 small balls manufactured through the method are high in degree of sphericity, compactness and crushing strength, and large-scale and mechanical production of the Li2TiO3 tritium breeding small balls can be realized.

The embodiment of the invention provides a NiFeMoS complex and a preparation method thereof. The preparation method of the NiFeMoS complex comprises the following steps: obtaining a reactant aqueous solution containing nickel salt, iron salt, molybdenum salt and urea; carrying out a hydrothermal reaction on the reactant aqueous solution at the temperature of 150 to 170 DEG C for 8 to 15 hours, andthen performing separation and washing to obtain a complex precursor; calcining and vulcanizing the complex precursor and sulfur powder in inert gas at the temperature of 300 to 600 DEG C for 0.5 to3 hours, wherein the heating rate is 3 to 8 DEG C/min. The NiFeMoS complex prepared by the preparation method provided by the embodiment of the invention has high catalytic performance for hydrogen evolution reactions.

The invention discloses a preparation method for a polyimide film with low water absorption. The preparation method comprises the following steps: under the protection of N2, mixing a diamine monomer A and a dianhydride monomer A in a polar solvent to obtain a flexible polyamide acid resin solution A; under the protection of N2, mixing a diamine monomer B and a dianhydride monomer B in the polar solvent to obtain a rigid polyamide acid resin solution B; under the protection of N2, co-mixing the flexible polyamide acid resin solution A with the rigid polyamide acid resin solution B, stirring, stopping reaction when viscosity of a to-be-reacted matter reaches 2000-3500 poises; and finally, adding an accelerant and a dehydrator to uniformly mix, salivating to form a film, and performing imidization treatment to obtain the polyimide film with the low water absorption. The polyimide film obtained by the preparation method provided by the invention has a water absorption rate lower than 1.2% which is far lower than a water absorption rate (2.3%-2.4%) of conventional polyimide; and meanwhile, excellent comprehensive performance such as mechanical and electrical performance is kept.

The invention relates to a titanium dioxide nanometer composite structure film and a preparation method thereof. The technical scheme of the preparation method comprises the following steps: using a polished titanium-containing metal plate as an anode to be placed in an electrolyte and perform anodic oxidation, wherein the voltage of anodic oxidation is 10-60V and the time of anodic oxidation is 0.5-5 hours; then cleaning the obtained titanium-containing metal plate after anodic oxidation, drying, then placing the dried titanium-containing metal plate in H2O or the mixed solution containing 5-95wt% H2O and 5-95wt% alcohol organic matter, performing a hydrothermal reaction in a sealed container at 80-300 DEG C for 0.5-24 hours, and naturally cooling to obtain the titanium dioxide nanometercomposite structure film on the surface of the titanium-containing metal plate. The preparation method is simple and reliable without adding a foreign material as a Ti source; and the load of TiO2 nanoparticles in nanotubes is controllable. In the prepared composite structure of TiO2 nanoparticles and nanotubes, TiO2 nanoparticles are distributed in the nanotubes evenly.

The invention belongs to the technical field of novel catalytic material preparation and discloses a NiTi hydrotalcite nanosheet catalyst responding to visible light and a preparation method of the catalyst. According to the invention, NiTi hydrotalcite nanosheets are synthesized by an anti-phase microemulsion method and show excellent catalytic performance by visible light. The preparation method realizes controllability of a microemulsion environment by adjusting and controlling the proportions of a surface active agent and water; and hydrotalcite is crystallized and grows in the microemulsion and the particle size of the hydrotalcite ranges from 30 nm to 80 nm. A solvent used in the method is low in cost and simple to operate and can be recycled. The obtained hydrotalcite nanosheet catalyst has the advantages of simple synthesizing conditions, cheap raw materials and easiness in large-scale industrial production. The NiTi hydrotalcite nanosheet catalyst prepared in the invention has an excellent characteristic of responding to visible light, is five times quicker than micron-sized hydrotalcite synthetized with a traditional codeposition method in water decomposition performance by visible light, and is hopefully expected to be widely applied to the fields like solar thermal utilization, adsorption and additives.