1604 results about "Ionic polymerization" patented technology

Methods, systems and devices for removing iodide from an aqueous solution including submerging an iodophilic electrode in an aqueous solution containing iodide, applying a current to the electrode, and electrochemically oxidizing the iodide to iodine within the electrode. The electrode may include an iodophilic material and an electrically conductive material. It may also include a binder. The iodophilic material may be a starch, chitosan, carboxycellulose, cationic polymer, or an anion exchange membrane material, for example. After oxidizing the iodide to iodine within the electrode, the electrode may be submerged in a second solution and a current may be applied to reduce the iodine and release it from the electrode in the form of iodide into the second solution.

The invention relates to the technical field of daily chemicals, and provides shampoo and a preparation method and application thereof.The shampoo is prepared from, by mass, 3%-15% of a sulfate-free anionic surfactant, 8%-20% of an ampholytic surfactant, 0-5% of a nonionic surfactant, 0.3%-1% of a hair cationic conditioner and 0.1%-3% of emulsified silicone oil based on the total mass of the shampoo; the cationic conditioner for hair comprises a polyquaternium cationic polymer and cationic guar gum, and the mass ratio of the polyquaternium cationic polymer to the cationic guar gum is (1: 2)-(2: 1). According to the application, the polyquaternium cationic polymer and the cationic guar gum are selected as the cationic conditioner for hair, and the sulfate-free anionic surfactant and the emulsified silicone oil are matched, so that mild cleaning of scalp can be realized, water-oil balance of the scalp can be maintained, damage to hair scales can be reduced, and the combability and fluffy effect of the hair can be improved.

The invention discloses an epoxy group modified zwitterionic polymer / heparin composite coating and a preparation method thereof. The preparation method comprises the following steps: firstly, constructing an amino-containing adhesion layer on the surface of a substrate by adopting a dip-coating method; then, the substrate is soaked in a mixed solution of the zwitterionic polymer and the heparin, and grafting of the zwitterionic polymer and the heparin on the surface of the medical material is completed through incubation. The coating provided by the invention has excellent hydrophilicity, can form a hydration layer, provides a physical barrier, and remarkably prevents adhesion and colonization of microorganisms. The inhibition rate of the coating on escherichia coli and staphylococcus aureus exceeds 99%, protein adhesion is remarkably reduced in an anti-protein adhesion experiment, and the coating is simple in strategy design, has a potential application prospect in the aspect of preventing blood contact catheter related infection and thrombosis, and has a wide application prospect. The complication occurrence rate and the medical care cost can be reduced.

The invention discloses a porous substrate reinforced anion exchange membrane and a preparation method and application thereof, and relates to the technical field of anion exchange membranes. The porous substrate reinforced anion exchange membrane is prepared by the following steps: uniformly mixing a polyarylene alkylene type cationic polymer solution and a C1-C10 alcohol solvent, then coating two sides of a porous substrate with the mixture, and drying to obtain the porous substrate reinforced anion exchange membrane. And removing the solvent to obtain the product. According to the method, the porous substrate can be well infiltrated by the cationic polymer solution without pre-treating the porous substrate, so that the porous substrate reinforced anion exchange membrane with a sandwich-like structure is obtained. The film has outstanding swelling resistance and excellent mechanical properties, has good electrochemical properties, and has good application prospects in alkaline film energy conversion devices.

The invention relates to the field of quantum dot ink, and discloses diffusion plate printing quantum dot ink and a preparation method thereof.The diffusion plate printing quantum dot ink comprises acrylic resin, hyperbranched polyester resin, a quantum dot material, modified boron nitride, a reactive diluent, a photoinitiator, a wetting agent and a defoaming agent; the hyperbranched polyester resin is prepared by reacting hyperbranched polyester acrylate and a sulfydryl-terminated silicon-containing reaction monomer, wherein the hyperbranched polyester acrylate is prepared by reacting pentaerythritol with 2, 2-dimethylolpropionic acid and then carrying out esterification reaction with acrylic acid; the sulfydryl-terminated silicon-containing reaction monomer is prepared by reacting eugenol with 1, 1, 3, 3-tetramethyldisiloxane and then carrying out esterification reaction with 3-mercaptopropionic acid; the modified boron nitride is prepared by modifying a cationic polymer which is prepared by carrying out a Mannich reaction on triethylene tetramine, formaldehyde and acetone and then carrying out a condensation polymerization reaction with formaldehyde. After the ink prepared by the invention is cured, a coating film is high in hardness, adhesive force and heat conductivity coefficient, and good in flexibility, heat resistance and migration barrier property.

There has been demand for an additional method for producing antibodies. The present invention provides: a polymer-coated crosslinked alginate gel fiber in which a core layer containing a crosslinked alginate gel and either antibody-producing cells (e.g., antibody-producing CHO cells) or bioactive-substance-producing cells (e.g., MIN6 cells derived from pancreatic β cells) is coated with a cationic polymer; and a method for producing antibodies, a bioactive substance, etc., using the fiber.

The invention discloses an anti-scale cross-linked polymer fracturing fluid and a preparation method thereof, and relates to the technical field of petroleum fracturing fluids. When the anti-scale cross-linked polymer fracturing fluid is prepared, allylamine hydrochloride and epoxy chloropropane react to prepare a double-bond chlorinated intermediate; reacting the double-bond chlorinated intermediate with lauramidopropyl dimethylamine to prepare a cationic monomer; copolymerizing a cationic monomer and acrylamide to prepare a cationic polymer; the preparation method comprises the following steps: reacting L-lysine with formaldehyde and phosphorous acid to prepare phosphoric acid modified lysine; reacting the phosphoric acid modified lysine with allyl glycidyl ether to prepare a phosphoric acid modified monomer; acrylamide and an anionic monomer are copolymerized to prepare an anionic polymer; the anionic polymer and the cationic polymer are dissolved in water to prepare the anti-scale cross-linked polymer fracturing fluid. The anti-scale cross-linked polymer fracturing fluid prepared by the invention has the advantages of scale prevention, good temperature resistance, good shear resistance and self-crosslinking.

The invention discloses a magnetic nano-enzyme probe and a preparation method thereof, a kit for detecting helicobacter pylori and application of the magnetic nano-enzyme probe, the core of the magnetic nano-enzyme probe is Fe3O4 nano-particles, magnetic enrichment capacity is provided, and interference of a complex matrix in a sample is eliminated; a layer of Pt nano-particles is electrostatically adsorbed through the cationic polymer to serve as a colorimetric interlayer, and a strong colorimetric signal is provided; au (at) Pt for modifying 5, 5 '-dithiobis (2-nitrobenzoic acid) is arranged on the surface layer and is used for providing strong catalytic signals and sites coupled with a large number of specific antibodies; meanwhile, the inner and outer layers of nano enzyme particles can synergistically enhance the catalytic action. The magnetic nano-enzyme probe disclosed by the invention has strong magnetic responsiveness, high colorimetric signal, strong catalytic activity and specific bacterium capturing capacity, realizes rapid enrichment and quantitative analysis of helicobacter pylori in a sample to be detected, eliminates matrix interference in practical application, and has high sensitivity and high specificity. The method has great potential in the aspects of high sensitivity and clinical monitoring of bacterial infection or pollution.

The invention discloses a high-stability endotoxin-free PHA nano-emulsion and a preparation method thereof, and belongs to the technical field of biodegradable high polymer material compositions and processing thereof. The nano-emulsion is characterized in that the endotoxin content is not higher than 0.10 EU / g, the median particle size d50 is 100-200 nm, and the PDI is not higher than 0.15, and the nano-emulsion is stable in long-term storage. The preparation method is a continuous solvent-free process and comprises the steps of melt extrusion, high-pressure thermal emulsification and deep endotoxin removal. By adopting the specific pH-insensitive cationic polymer emulsifier and the crystallization inhibitor, the chemical contradiction that an efficient alkaline purification process is incompatible with a nano-emulsion stable system is solved, physical aging is inhibited, and an unexpected technical effect is obtained. The invention also discloses an O / W type cream containing the nano emulsion.

The invention discloses a cationic polymer-based proteolysis targeting chimera as well as preparation and application thereof, and belongs to the fields of targeting protein degradation and nanotechnology. According to the chimera, a cationic polymer is used as a connecting arm to connect a target protein ligand and an E3 ubiquitin ligase ligand to form a ternary complex, so that efficient degradation of target protein is realized. By adjusting the ligand proportion, chimeras with different degradation efficiencies can be synthesized, and accurate regulation and control are realized. The pH-responsive nano-drug obtained by hydrolyzing the targeting chimera by using the targeting protein can respond to an acidic tumor microenvironment, specifically release the chimera, and improve the targeting property and the treatment effect of the drug. Compared with the traditional PROTACs, the compound has higher bioavailability and tumor permeation effect; the preparation method of the nano-drug is simple and easy to implement, provides possibility for preparation of high-performance nano-drugs, shows potential in preparation of anti-tumor cell drugs, provides new thoughts and methods for tumor treatment, and has important clinical application value.

The invention provides a diaphragm and a preparation method thereof and a lithium ion battery, the diaphragm comprises a base membrane layer and a composite functional layer, the composite functional layer comprises hydrophobic SiO2 aerogel modified by a hydrophobic agent, a conductive ion polymer and a solid electrolyte, and the composite functional layer respectively accounts for 3-12wt%, 0.5-1.0 wt% and 0.5-1.5 wt% of the total mass of the diaphragm; the hydrophobic agent comprises trimethylchlorosilane, hexamethyldisilazane, perfluorooctyltriethoxysilane, polyvinylidene fluoride, polydimethylsiloxane and the like, the conductive ionic polymer comprises polyvinylpyrrolidone, lithium polymethacrylate, lithium polystyrene sulfonate, polyacrylamide and the like, and the solid electrolyte comprises lithium lanthanum titanium oxide, lithium lanthanum zirconium oxide, lithium lanthanum zirconium tantalum oxide and the like. The wettability is improved by the high porosity of the hydrophobic SiO2 aerogel, the stability and strong conductivity of a physical conductive network of the solid electrolyte and the ion affinity and amphoteric binding capacity of the conductive ion polymer are optimized, the electrochemical performance and thermal stability of the interface are optimized, and comprehensive optimization of the thermal-electric-interface performance of the diaphragm is realized through combination.

The invention discloses a fluorine removal agent as well as a preparation method and application thereof, and relates to the technical field of fluorine ion treatment. The fluorine removal agent comprises the following preparation raw materials: metal salt containing aluminum and iron, an acrylamide monomer and a cationic polymer monomer. The fluorine removal agent can achieve deep fluorine removal of industrial fluorine-containing wastewater, flocs generated in the fluorine removal process are large, compact and high in settling speed, and the fluorine removal agent has the advantages of being wide in pH use range, high in removal efficiency and the like, can rapidly reduce the concentration of fluorine ions in the wastewater to 1.0 mg / L or below, still has the fluorine removal rate of 80% or above for fluorine-containing wastewater with the concentration lower than 10 mg / L, and has a good application prospect. And the dosage of the fluorine removal agent is low, and an excellent fluorine removal effect can be realized when the dosage is less than 500mg / L.

The invention relates to the technical field of oil-gas field development, in particular to a zwitterionic polymer filtrate reducer and a preparation method thereof.The zwitterionic polymer filtrate reducer is prepared from an acrylamide monomer, a hydrophilic monomer, a rigid monomer, a salt-tolerant monomer, a copolymerization adjusting monomer, starch, aluminum oxide powder, KH560 modified nano-silica, a cationic monomer and an anionic monomer; mixing an acrylamide monomer, a hydrophilic monomer, a rigid monomer, a salt-tolerant monomer, a copolymerization adjusting monomer, a cationic monomer, an anionic monomer and a solvent to obtain a monomer mixed solution; introducing nitrogen to remove oxygen; adding an initiator, heating and carrying out copolymerization reaction; adding starch and continuously stirring to obtain a material flow A; uniformly mixing KH560 modified nano silicon dioxide and aluminum oxide powder, and adding the mixture into the material flow A; and drying, crushing and grinding to obtain zwitterionic polymer filtrate reducer powder. When in contact with a well wall, the filtrate reducer can be spread and adhered to the surface of the well wall to form a low-permeability, flexible, thin and compact filter cake, so that the filter loss of a drilling fluid is reduced.

The invention discloses a zwitterionic polymer, an electrochemical sensor and a preparation method and application of the zwitterionic polymer, the zwitterionic polymer is a sulfobetaine type zwitterionic polymer and has high hydrophilicity and electric neutrality, and a hydration layer can be formed on the surface of the zwitterionic polymer through the solvation effect, the hydrogen-bond effect and the like of charged functional groups. The surface of the hydration layer can effectively resist non-specific adsorption, has high anti-pollution performance, and has huge application potential in the field of anti-pollution electrochemical sensors. The invention further provides an electrochemical sensor, the anti-fouling layer formed by the zwitterionic polymer on the electrochemical sensor can effectively resist non-specific adsorption, has high anti-fouling performance, and can reduce and eliminate signal interference in actual sample detection, so that sample pretreatment work is reduced, and the detection accuracy is improved. The method has the characteristics of high anti-interference capability, good reproducibility and the like in chloramphenicol detection.

A new polyelectrolyte multilayer coated proton-exchange membrane for electrolysis and fuel cell applications has been developed for electrolysis and fuel cell applications. The polyelectrolyte multilayer coated proton-exchange membrane comprises: a cation exchange membrane, and a polyelectrolyte multilayer coating on one or both surfaces of the cation exchange membrane. The polyelectrolyte multilayer coating comprises alternating layers of a polycation polymer and a polyanion polymer. The polycation polymer layer is deposited on and is in contact with the cation exchange membrane. The top layer of the polyelectrolyte multilayer coating can be either a polycation polymer layer or a polyanion polymer layer.

Methods, systems and devices for removing iodide from an aqueous solution including submerging an iodophilic electrode in an aqueous solution containing iodide, applying a current to the electrode, and electrochemically oxidizing the iodide to iodine within the electrode. The electrode may include an iodophilic material and an electrically conductive material. It may also include a binder. The iodophilic material may be a starch, chitosan, carboxycellulose, cationic polymer, or an anion exchange membrane material, for example. After oxidizing the iodide to iodine within the electrode, the electrode may be submerged in a second solution and a current may be applied to reduce the iodine and release it from the electrode in the form of iodide into the second solution.

There is provided a method for improving grease and oil resistance of a moulded fiber based article comprising introducing to a fiber stock a composition comprising a synthetic polymer component and a cationic polymer component and thermoforming the fiber stock. There is also provided a moulded fiber based article and a use of the composition improving grease and oil resistance of a moulded fiber based article. There is also provided a method for preparation of a moulded fiber based article.

A detergent composition containing water, a component (A) which is a silica capsule enclosing a functional agent, and a component (B) which is a cationic polymer having a weight average molecular weight of 500,000 or more and 5,000,000 or less and obtained by polymerizing an unsaturated monomer having a cation group (excluding those enclosed in the silica capsule of the component (A)).

The invention provides a dry electrode, a preparation method thereof and a battery, and particularly relates to the technical field of batteries. The dry-method electrode comprises a current collector and a dry-method electrode film arranged on at least one side surface of the current collector, the dry-method electrode film comprises an active material, a conductive agent, a first binder and a second binder, the first binder comprises polytetrafluoroethylene, and the second binder is selected from an ionic polymer. According to the invention, the first binder and the second binder are added into the dry electrode at the same time, so that the binding power of the dry electrode can be improved, and the electrical properties such as first effect, rate, cycle and the like of the battery can be improved.

The invention relates to the field of medical materials, in particular to a hydrophilic antibacterial dressing and a preparation method thereof. The hydrophilic antibacterial dressing is prepared by mixing and foaming an isocyanate-terminated antibacterial hydrophilic prepolymer and a functional foaming mixture according to the mass ratio of (1-2): (1-2), wherein the isocyanate-terminated antibacterial hydrophilic prepolymer is prepared from the following raw materials in parts by weight: 10 to 100 parts of polyol I, 1 to 20 parts of a cationic polymer, 10 to 40 parts of isocyanate, 0.1 to 5 parts of a chain extender and 0.3 to 7 parts of an antioxidant; the functional foaming mixture is prepared from the following raw materials in parts by weight: 1-50 parts of polyol II, 1-20 parts of a hydrophilic surfactant, 1-20 parts of a foam stabilizer and 1-100 parts of purified water. According to the hydrophilic antibacterial dressing, an antibacterial group of a cationic polymer is grafted on a polyurethane chain segment to prepare a polyurethane prepolymer, the finally prepared polyurethane foaming dressing has lasting antibacterial performance and high water absorption, and the wound healing speed can be remarkably increased.

The invention relates to the technical field of biopolymer materials, in particular to a preparation method and application of a cationic polymer gene vector with a fluorinated end group. The invention provides a cationic polymer with a fluorinated end group. The structure of the cationic polymer is shown in the specification. According to the method, a fluorinated group is introduced through a fluorinated initiator by a one-step method to initiate synthesis of various terminal group fluorinated linear polyethyleneimine F-PEI with different molecular weights, the gene transfection efficiency is improved by introduction of the fluorine group, and high-efficiency DNA transfection is realized. The gene vector can achieve an efficient transfection effect in the cell transfection process, the toxicity generated to cells in the transfection process is small, gene molecules can be effectively and safely conveyed into the cells, and the gene transfection vector has the advantages of being efficient, low in toxicity, low in price, easy to synthesize and the like. The method has the advantages of simple reaction, easily available raw materials, low preparation cost, easily controlled molecular weight, high yield and simple post-treatment, and is suitable for large-scale production. # imgabs0 #

The invention relates to the technical field of pharmaceutical preparations, and provides double-shell JAK inhibitor nanoparticles, a preparation method thereof and targeted delivery eye drops. The double-shell JAK inhibitor nanoparticle provided by the invention comprises a core, an inner shell and an outer shell, wherein the core comprises a nanostructure lipid carrier and a JAK inhibitor; the inner shell layer is a cationic polymer, and the outer shell layer is hyaluronic acid. Through the design of the positive charge inner shell layer and the negative charge outer shell layer, the dual functions of mucosa adhesion and active targeting are achieved, the surface of the nanoparticle is electronegative finally, cytotoxicity possibly caused by direct exposure of a cationic polymer is reduced, non-specific aggregation of the cationic polymer and electronegative protein in tears is avoided, and the stability of tears is improved. And the stability of the preparation is improved. The eye drops provided by the invention can obviously prolong the residence time of the JAK inhibitor on the ocular surface, enhance the cornea permeability, can actively target to ocular inflammatory cells, and have a wide application prospect.

The invention relates to the technical field of microcapsules, provides a magnetic microcapsule capable of preventing particle sedimentation, a preparation method of the magnetic microcapsule and a magnetic film, and aims to solve the problems of low writing smoothness and poor trace durability due to particle sedimentation and aggregation in the prior art. The magnetic microcapsule comprises a wall material and a core material, the wall material is a mixture comprising an anionic polymer and a cationic polymer, and the core material is a mixture comprising magnetic particles, non-magnetic particles, an oily solvent and a suspension stabilizer; the suspension stabilizer comprises any one or more of phthalic ester, polyamide wax, polysiloxane, sorbitan oleate, sorbitan monostearate, silicon dioxide, magnesium aluminum silicate and magnesium lithium silicate; according to the invention, magnetic particles and non-magnetic particles can be prevented from settling and gathering, and writing fluency and trace durability are ensured.

The invention relates to the technical field of daily chemical industry, and discloses a moisturizing and soothing composition and application thereof.The moisturizing and soothing composition comprises, by weight, 20-25% of C14-16 sodium olefin sulfonate, 20-25% of C14-16 sodium alkyl sulfonate, 20-25% of C14-16 sodium alkyl sulfonate, 10-20% of C14-16 0.3%-0.7% of a cationic polymer; a litchi pericarp extract; an aloe extract; and a rosemary extract; wherein the total weight percentage of the litchi peel extract, the aloe extract and the rosemary extract is 1.9%-3.3%. The components are compounded, the cationic polymer and the anionic surfactant are utilized to construct a deposition system, and the three plant extracts with specific total content are cooperated, so that the retention rate of active ingredients in scalp is effectively increased, and the problem that moisturizing and soothing ingredients are easy to wash away is solved. The invention also provides a preparation method combining hot preparation and cold preparation, and the stability of the system and the activity of the extract are ensured by homogenizing the phase A at high temperature and adding the phase E at low temperature. The composition can be used for preparing shampoo products for moisturizing or relieving scalp.

The invention relates to a cyclopeptide inhibitor aiming at human STING (stimulating interferon gene) and application of the cyclopeptide inhibitor. The cyclic peptide can specifically bind to and inhibit activation of human STING. The invention also provides a nanoparticle delivery system for loading the cyclopeptide on a cationic polymer PBAE and an amphiphilic polymer pDMA-pEPEMA, and a preparation method of the nanoparticle delivery system. The cyclic peptide and the nanoparticles thereof can be used for preparing medicines for treating autoimmune diseases (such as systemic lupus erythematosus and the like) caused by excessive activation of the cGAS-STING signal pathway. Compared with the existing small molecule STING inhibitor, the cyclopeptide inhibitor provided by the invention has higher specificity, stability and inhibition effect.

The invention discloses a bioprosthetic valve modifier, a polymer-modified bioprosthetic valve and a preparation method, and belongs to the technical field of preparation of medical materials and medical instruments. The bioprosthetic valve modifier is formed by polymerizing a diclofenac monomer containing a thioketal group, a hydrophilic monomer, a cross-linking agent, an active ester monomer and an initiator. The preparation method of the polymer-modified bioprosthetic valve comprises the following steps: sequentially soaking a bioprosthetic valve material in a glutaraldehyde solution, an amino cationic polymer solution and a nanogel solution, and finally soaking the bioprosthetic valve twice with an active ester compound solution to obtain the polymer-modified bioprosthetic valve. According to the polymer-modified bioprosthetic valve prepared by the invention, the nanogel is modified on the surface of the valve in a covalent bond manner, so that the polymer-modified bioprosthetic valve has good stability and long-term effect, has good biocompatibility and anti-inflammatory, anti-coagulation and anti-calcification effects, and has a good medical application prospect.

The invention discloses an ultraviolet multi-curing heat-conducting insulating material which comprises an epoxy resin oligomer, a polyacrylate oligomer, a reactive diluent, a composite photoinitiator and a sulfydryl-containing silane coupling agent modified heat-conducting particle filler. After ultraviolet irradiation, multiple curing reactions, including free radical polymerization, cationic polymerization, sulfydryl-alkene click addition reaction and sulfydryl-epoxy ring-opening reaction, can be rapidly initiated. The heat-conducting insulating material disclosed by the invention has very high crosslinking density and a more continuous heat-conducting network, and is high in curing speed, free of volatile gas and simple and convenient in preparation process.

The present invention discloses a metal porphyrin-based porous ionic polymer and a preparation method and application thereof, and relates to the technical field of polymer compound catalysis. The metal porphyrin-based porous ionic polymer of the present invention is provided with a three-dimensional structure by introducing tetraphenylmethane and its derivatives or halogen-containing phosphonium salts, thereby obtaining a metal porphyrin-based porous ionic polymer rich in mesopores and having a high specific surface area, thereby improving the catalytic performance and achieving efficient and highly selective catalytic reactions. The metal porphyrin-based porous ionic polymer prepared by the present invention is particularly suitable for catalyzing the cycloaddition reaction of carbon dioxide and epoxide, has high selectivity and strong adsorption capacity for carbon dioxide, and can catalyze the generation of cyclic carbonates efficiently and selectively.

The invention relates to a method for preparing polyamide 6 fine denier fibers through anionic polymerization. Caprolactam and a catalyst are added into a drying device A to remove system moisture and then placed in a storage tank A. Caprolactam is added into a drying device B to remove moisture and then placed in a storage tank B together with an initiator and a cyclic oligomer inhibitor. Caprolactam liquid in the storage tank A and the storage tank B is continuously injected into a screw extruder for anionic ring-opening polymerization reaction to prepare a polyamide 6 basic melt, the basic melt is further conveyed to a tandem devolatilization reaction system to remove monomers and part of cyclic oligomers to obtain a polyamide 6 final polymer, and finally, the polyamide 6 final polymer can be directly spun. The polyamide 6 fine denier fiber is obtained.

The invention relates to a method for preparing a solid polymer electrolyte by UV photo-initiated tandem cationic polymerization. The method comprises the following steps: mixing a free radical polymerization monomer, a cationic polymerization monomer, an initiator and a lithium salt, carrying out light free radical polymerization under ultraviolet irradiation to obtain a free radical polymerization prepolymer, carrying out extrusion primary shaping on the free radical polymerization prepolymer, and carrying out series cationic polymerization to prepare the solid electrolyte. The solid electrolyte has the characteristics of environment friendliness, good stability, safety in use and difficulty in liquid leakage, does not use redundant monomers and solvents, and can realize rapid and batch production of the solid electrolyte.