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1336 results about "Ionic polymerization" patented technology

Ionic polymerization is a chain-growth polymerization in which active centers are ions or ion pairs. It can be considered as an alternative to radical polymerization, and may refer to anionic polymerization or cationic polymerization.

Shampoo as well as preparation method and application thereof

The invention relates to the technical field of daily chemicals, and provides shampoo and a preparation method and application thereof.The shampoo is prepared from, by mass, 3%-15% of a sulfate-free anionic surfactant, 8%-20% of an ampholytic surfactant, 0-5% of a nonionic surfactant, 0.3%-1% of a hair cationic conditioner and 0.1%-3% of emulsified silicone oil based on the total mass of the shampoo; the cationic conditioner for hair comprises a polyquaternium cationic polymer and cationic guar gum, and the mass ratio of the polyquaternium cationic polymer to the cationic guar gum is (1: 2)-(2: 1). According to the application, the polyquaternium cationic polymer and the cationic guar gum are selected as the cationic conditioner for hair, and the sulfate-free anionic surfactant and the emulsified silicone oil are matched, so that mild cleaning of scalp can be realized, water-oil balance of the scalp can be maintained, damage to hair scales can be reduced, and the combability and fluffy effect of the hair can be improved.
Owner:GUANGZHOU TINCI MATERIALS TECH

Diffusion plate printing quantum dot ink and preparation method thereof

PendingCN120098484AInksPolymer scienceMeth-
The invention relates to the field of quantum dot ink, and discloses diffusion plate printing quantum dot ink and a preparation method thereof.The diffusion plate printing quantum dot ink comprises acrylic resin, hyperbranched polyester resin, a quantum dot material, modified boron nitride, a reactive diluent, a photoinitiator, a wetting agent and a defoaming agent; the hyperbranched polyester resin is prepared by reacting hyperbranched polyester acrylate and a sulfydryl-terminated silicon-containing reaction monomer, wherein the hyperbranched polyester acrylate is prepared by reacting pentaerythritol with 2, 2-dimethylolpropionic acid and then carrying out esterification reaction with acrylic acid; the sulfydryl-terminated silicon-containing reaction monomer is prepared by reacting eugenol with 1, 1, 3, 3-tetramethyldisiloxane and then carrying out esterification reaction with 3-mercaptopropionic acid; the modified boron nitride is prepared by modifying a cationic polymer which is prepared by carrying out a Mannich reaction on triethylene tetramine, formaldehyde and acetone and then carrying out a condensation polymerization reaction with formaldehyde. After the ink prepared by the invention is cured, a coating film is high in hardness, adhesive force and heat conductivity coefficient, and good in flexibility, heat resistance and migration barrier property.
Owner:SHENZHEN CHENGYUXING PHOTOELECTRICITY CO LTD

Polymer-coated crosslinked alginate gel fiber

There has been demand for an additional method for producing antibodies. The present invention provides: a polymer-coated crosslinked alginate gel fiber in which a core layer containing a crosslinked alginate gel and either antibody-producing cells (e.g., antibody-producing CHO cells) or bioactive-substance-producing cells (e.g., MIN6 cells derived from pancreatic β cells) is coated with a cationic polymer; and a method for producing antibodies, a bioactive substance, etc., using the fiber.
Owner:MOCHIDA PHARM CO LTD

Anti-scale cross-linked polymer fracturing fluid and preparation method thereof

The invention discloses an anti-scale cross-linked polymer fracturing fluid and a preparation method thereof, and relates to the technical field of petroleum fracturing fluids. When the anti-scale cross-linked polymer fracturing fluid is prepared, allylamine hydrochloride and epoxy chloropropane react to prepare a double-bond chlorinated intermediate; reacting the double-bond chlorinated intermediate with lauramidopropyl dimethylamine to prepare a cationic monomer; copolymerizing a cationic monomer and acrylamide to prepare a cationic polymer; the preparation method comprises the following steps: reacting L-lysine with formaldehyde and phosphorous acid to prepare phosphoric acid modified lysine; reacting the phosphoric acid modified lysine with allyl glycidyl ether to prepare a phosphoric acid modified monomer; acrylamide and an anionic monomer are copolymerized to prepare an anionic polymer; the anionic polymer and the cationic polymer are dissolved in water to prepare the anti-scale cross-linked polymer fracturing fluid. The anti-scale cross-linked polymer fracturing fluid prepared by the invention has the advantages of scale prevention, good temperature resistance, good shear resistance and self-crosslinking.
Owner:KARAMAY HAOYUAN TIANCHENG ENERGY TECHNOLOGY CO LTD

High-stability endotoxin-free PHA nano-emulsion and preparation method thereof

ActiveCN120585676ACosmetic preparationsToilet preparationsEndotoxin removalNanoparticle
The invention discloses a high-stability endotoxin-free PHA nano-emulsion and a preparation method thereof, and belongs to the technical field of biodegradable high polymer material compositions and processing thereof. The nano-emulsion is characterized in that the endotoxin content is not higher than 0.10 EU / g, the median particle size d50 is 100-200 nm, and the PDI is not higher than 0.15, and the nano-emulsion is stable in long-term storage. The preparation method is a continuous solvent-free process and comprises the steps of melt extrusion, high-pressure thermal emulsification and deep endotoxin removal. By adopting the specific pH-insensitive cationic polymer emulsifier and the crystallization inhibitor, the chemical contradiction that an efficient alkaline purification process is incompatible with a nano-emulsion stable system is solved, physical aging is inhibited, and an unexpected technical effect is obtained. The invention also discloses an O / W type cream containing the nano emulsion.
Owner:DU BAI CHENG NEW MATERIAL TECH (SHANGHAI) CO LTD +1

Diaphragm, preparation method thereof and lithium ion battery

The invention provides a diaphragm and a preparation method thereof and a lithium ion battery, the diaphragm comprises a base membrane layer and a composite functional layer, the composite functional layer comprises hydrophobic SiO2 aerogel modified by a hydrophobic agent, a conductive ion polymer and a solid electrolyte, and the composite functional layer respectively accounts for 3-12wt%, 0.5-1.0 wt% and 0.5-1.5 wt% of the total mass of the diaphragm; the hydrophobic agent comprises trimethylchlorosilane, hexamethyldisilazane, perfluorooctyltriethoxysilane, polyvinylidene fluoride, polydimethylsiloxane and the like, the conductive ionic polymer comprises polyvinylpyrrolidone, lithium polymethacrylate, lithium polystyrene sulfonate, polyacrylamide and the like, and the solid electrolyte comprises lithium lanthanum titanium oxide, lithium lanthanum zirconium oxide, lithium lanthanum zirconium tantalum oxide and the like. The wettability is improved by the high porosity of the hydrophobic SiO2 aerogel, the stability and strong conductivity of a physical conductive network of the solid electrolyte and the ion affinity and amphoteric binding capacity of the conductive ion polymer are optimized, the electrochemical performance and thermal stability of the interface are optimized, and comprehensive optimization of the thermal-electric-interface performance of the diaphragm is realized through combination.
Owner:JIANGSU RELIANCE ENERGY TECHNOLOGY CO LTD

Zwitterionic polymer filtrate reducer and preparation method thereof

The invention relates to the technical field of oil-gas field development, in particular to a zwitterionic polymer filtrate reducer and a preparation method thereof.The zwitterionic polymer filtrate reducer is prepared from an acrylamide monomer, a hydrophilic monomer, a rigid monomer, a salt-tolerant monomer, a copolymerization adjusting monomer, starch, aluminum oxide powder, KH560 modified nano-silica, a cationic monomer and an anionic monomer; mixing an acrylamide monomer, a hydrophilic monomer, a rigid monomer, a salt-tolerant monomer, a copolymerization adjusting monomer, a cationic monomer, an anionic monomer and a solvent to obtain a monomer mixed solution; introducing nitrogen to remove oxygen; adding an initiator, heating and carrying out copolymerization reaction; adding starch and continuously stirring to obtain a material flow A; uniformly mixing KH560 modified nano silicon dioxide and aluminum oxide powder, and adding the mixture into the material flow A; and drying, crushing and grinding to obtain zwitterionic polymer filtrate reducer powder. When in contact with a well wall, the filtrate reducer can be spread and adhered to the surface of the well wall to form a low-permeability, flexible, thin and compact filter cake, so that the filter loss of a drilling fluid is reduced.
Owner:SNF CHINA FLOCCULANT

Polyelectrolyte multilayer coated proton exchange membrane for electrolysis and fuel cell applications

A new polyelectrolyte multilayer coated proton-exchange membrane for electrolysis and fuel cell applications has been developed for electrolysis and fuel cell applications. The polyelectrolyte multilayer coated proton-exchange membrane comprises: a cation exchange membrane, and a polyelectrolyte multilayer coating on one or both surfaces of the cation exchange membrane. The polyelectrolyte multilayer coating comprises alternating layers of a polycation polymer and a polyanion polymer. The polycation polymer layer is deposited on and is in contact with the cation exchange membrane. The top layer of the polyelectrolyte multilayer coating can be either a polycation polymer layer or a polyanion polymer layer.
Owner:UOP LLC

Double-shell JAK inhibitor nanoparticle, preparation method thereof and targeted delivery eye drops

The invention relates to the technical field of pharmaceutical preparations, and provides double-shell JAK inhibitor nanoparticles, a preparation method thereof and targeted delivery eye drops. The double-shell JAK inhibitor nanoparticle provided by the invention comprises a core, an inner shell and an outer shell, wherein the core comprises a nanostructure lipid carrier and a JAK inhibitor; the inner shell layer is a cationic polymer, and the outer shell layer is hyaluronic acid. Through the design of the positive charge inner shell layer and the negative charge outer shell layer, the dual functions of mucosa adhesion and active targeting are achieved, the surface of the nanoparticle is electronegative finally, cytotoxicity possibly caused by direct exposure of a cationic polymer is reduced, non-specific aggregation of the cationic polymer and electronegative protein in tears is avoided, and the stability of tears is improved. And the stability of the preparation is improved. The eye drops provided by the invention can obviously prolong the residence time of the JAK inhibitor on the ocular surface, enhance the cornea permeability, can actively target to ocular inflammatory cells, and have a wide application prospect.
Owner:SHANDONG INOMIC INST OF PHARM RES CO LTD

Moisturizing and soothing composition and application thereof

The invention relates to the technical field of daily chemical industry, and discloses a moisturizing and soothing composition and application thereof.The moisturizing and soothing composition comprises, by weight, 20-25% of C14-16 sodium olefin sulfonate, 20-25% of C14-16 sodium alkyl sulfonate, 20-25% of C14-16 sodium alkyl sulfonate, 10-20% of C14-16 0.3%-0.7% of a cationic polymer; a litchi pericarp extract; an aloe extract; and a rosemary extract; wherein the total weight percentage of the litchi peel extract, the aloe extract and the rosemary extract is 1.9%-3.3%. The components are compounded, the cationic polymer and the anionic surfactant are utilized to construct a deposition system, and the three plant extracts with specific total content are cooperated, so that the retention rate of active ingredients in scalp is effectively increased, and the problem that moisturizing and soothing ingredients are easy to wash away is solved. The invention also provides a preparation method combining hot preparation and cold preparation, and the stability of the system and the activity of the extract are ensured by homogenizing the phase A at high temperature and adding the phase E at low temperature. The composition can be used for preparing shampoo products for moisturizing or relieving scalp.
Owner:GUANGZHOU DATANG COSMETICS CO LTD

Cyclic peptide inhibitor aiming at human STING (stimulating interferon gene) and application thereof

The invention relates to a cyclopeptide inhibitor aiming at human STING (stimulating interferon gene) and application of the cyclopeptide inhibitor. The cyclic peptide can specifically bind to and inhibit activation of human STING. The invention also provides a nanoparticle delivery system for loading the cyclopeptide on a cationic polymer PBAE and an amphiphilic polymer pDMA-pEPEMA, and a preparation method of the nanoparticle delivery system. The cyclic peptide and the nanoparticles thereof can be used for preparing medicines for treating autoimmune diseases (such as systemic lupus erythematosus and the like) caused by excessive activation of the cGAS-STING signal pathway. Compared with the existing small molecule STING inhibitor, the cyclopeptide inhibitor provided by the invention has higher specificity, stability and inhibition effect.
Owner:SHANDONG UNIV +1

Ultraviolet multi-curing heat-conducting insulating material as well as preparation method and application thereof

The invention discloses an ultraviolet multi-curing heat-conducting insulating material which comprises an epoxy resin oligomer, a polyacrylate oligomer, a reactive diluent, a composite photoinitiator and a sulfydryl-containing silane coupling agent modified heat-conducting particle filler. After ultraviolet irradiation, multiple curing reactions, including free radical polymerization, cationic polymerization, sulfydryl-alkene click addition reaction and sulfydryl-epoxy ring-opening reaction, can be rapidly initiated. The heat-conducting insulating material disclosed by the invention has very high crosslinking density and a more continuous heat-conducting network, and is high in curing speed, free of volatile gas and simple and convenient in preparation process.
Owner:AKM ELECTRONICS INDAL PANYU

Method for preparing polyamide 6 fine denier fiber through anionic polymerization

The invention relates to a method for preparing polyamide 6 fine denier fibers through anionic polymerization. Caprolactam and a catalyst are added into a drying device A to remove system moisture and then placed in a storage tank A. Caprolactam is added into a drying device B to remove moisture and then placed in a storage tank B together with an initiator and a cyclic oligomer inhibitor. Caprolactam liquid in the storage tank A and the storage tank B is continuously injected into a screw extruder for anionic ring-opening polymerization reaction to prepare a polyamide 6 basic melt, the basic melt is further conveyed to a tandem devolatilization reaction system to remove monomers and part of cyclic oligomers to obtain a polyamide 6 final polymer, and finally, the polyamide 6 final polymer can be directly spun. The polyamide 6 fine denier fiber is obtained.
Owner:ZHEJIANG SCI-TECH UNIV

Method for preparing solid polymer electrolyte by UV (ultraviolet) photo-initiated tandem cationic polymerization

The invention relates to a method for preparing a solid polymer electrolyte by UV photo-initiated tandem cationic polymerization. The method comprises the following steps: mixing a free radical polymerization monomer, a cationic polymerization monomer, an initiator and a lithium salt, carrying out light free radical polymerization under ultraviolet irradiation to obtain a free radical polymerization prepolymer, carrying out extrusion primary shaping on the free radical polymerization prepolymer, and carrying out series cationic polymerization to prepare the solid electrolyte. The solid electrolyte has the characteristics of environment friendliness, good stability, safety in use and difficulty in liquid leakage, does not use redundant monomers and solvents, and can realize rapid and batch production of the solid electrolyte.
Owner:HEBEI UNIV OF TECH

Preparation method of cationic polymeric resin capable of regulating and controlling softening point, cationic polymeric resin and application

PendingCN120081970APolymer sciencePtru catalyst
The invention belongs to the technical field of rubber additives, and particularly discloses a preparation method and application of cationic polymerization resin with an adjustable softening point, and the preparation method comprises the following steps: adding a solvent and a catalyst into a reaction kettle, and adding a monomer into a high-position dropwise adding tank; cooling the solvent in the reaction kettle to a specified temperature, setting the dropping speed according to the softening point requirement of the target polymer, and starting to drop the overhead tank monomer; along with continuous dropwise adding of the monomer, the viscosity of the system is gradually increased, the viscosity is monitored on line, when the viscosity of the system reaches 150CP, the monomer is continuously dropwise added, meanwhile, the viscosity of the system is controlled to be 150-400CP, when the viscosity is greater than 400CP, the solvent is automatically replenished in the system to dilute the reaction liquid, the softening point of the resin is regulated and controlled by controlling the viscosity of the system to be 150-400CP, and the temperature fluctuation range in the whole dropwise adding process is + / -5 DEG C; the heat preservation temperature is consistent with the dropwise adding temperature, reacting for 6-10 hours, and then desolventizing and granulating. The regulation and control method and the control mechanism of the softening point of the resin in the polymerization stage are defined, so that the resin with the adjustable and controllable softening point is produced through process control.
Owner:JIANGSU QIXIANG HIGH NEW MATERIAL

Proton exchange membrane and proton exchange membrane coated with catalyst

Proton exchange membranes are described. The proton exchange membrane includes: a reinforcing membrane; a continuous non-porous hydrogen recombination catalyst coating, the continuous non-porous hydrogen recombination catalyst coating comprising a mixture of a hydrogen recombination catalyst and a proton conducting ionomer; and a continuous non-porous cross-linked polyelectrolyte multilayer coating, the continuous non-porous cross-linked polyelectrolyte multilayer coating comprising alternating layers of a polycationic polymer and a polyanionic polymer. Catalyst coated membranes incorporating proton exchange membranes and methods of making proton exchange membranes are also described.
Owner:UOP LLC

A wear-resistant and scratch-resistant printing ink and its preparation method and application

The invention relates to the field of printing inks and discloses a wear-resistant and scratch-resistant printing ink, a preparation method thereof, and an application thereof. The printing ink comprises: a modified aqueous polyurethane emulsion, a modified mica sheet, a pigment, an additive, and deionized water; the modified aqueous polyurethane emulsion is prepared by introducing a double-terminal hydroxyl chain extender into a polymer; the double-terminal hydroxyl chain extender is reacted with a Schiff base intermediate obtained by reacting salicylaldehyde and p-aminobenzyl alcohol and isocyanoethyl methacrylate, and the obtained double-bonded Schiff base intermediate is reacted with 1,1,3,3-tetramethyldisiloxane to prepare the ink; the modified mica sheet is reacted with triethylenetetramine, formaldehyde, and acetone, and then formaldehyde is added under alkaline conditions for polycondensation, the obtained cationic polymer and glutaraldehyde are prepared into the cationic mica sheet, and finally polyaniline is grown on the surface of the mica sheet through interfacial polymerization. The ink prepared by the invention has good adhesion, high hardness, and excellent water resistance, wear resistance, heat resistance, antistatic properties, and antibacterial properties.
Owner:广东好上好科技有限公司

Cationic polymer acid-resistant thickening agent as well as preparation method and application thereof

The invention discloses a cationic polymer acid-resistant thickening agent as well as a preparation method and application thereof, and belongs to the technical field of oil-gas field development. The polymer thickening agent is prepared from the following components in percentage by mass: 65 to 85 weight percent of acrylamide, 15 to 35 weight percent of methacryloyloxyethyl trimethyl ammonium chloride, 0.01 to 0.05 weight percent of dicationic functional monomer and 1 to 8 weight percent of cosolvent, the acid liquor system comprises the following components in percentage by mass: 5wt%-30wt% of solid acid, 0.01 wt%-0.6 wt% of a cationic polymer acid-resistant thickener, 0.5 wt%-5.0 wt% of a corrosion inhibitor, 0.3 wt%-1.0 wt% of an iron ion stabilizer and the balance of water; wherein the solid acid consists of 5wt%-15wt% of a solid metal catalyst and 85wt%-95wt% of solid particle acid; the acid liquid system has excellent slow release performance, is simple in formula, convenient to transport, low in cost and suitable for site construction, and has wide market prospects.
Owner:SOUTHWEST PETROLEUM UNIV +1

Microcapsule material, microcapsule using microcapsule material and preparation method of microcapsule

The invention discloses a microcapsule material, a microcapsule using the microcapsule material and a preparation method of the microcapsule, and relates to the technical field of daily chemical products. The microcapsule material comprises an addition polymer formed by a ring-opening reaction of epoxy resin and bio-based polyamine, poly (beta-amino ester) formed by a Michael addition reaction of acrylate and phenyl polyamine, and at least one cationic polymer containing quaternary ammonium groups. The microcapsule material shows certain biodegradability, the biodegradation rate of the microcapsule material exceeds 20% within 28 days, and the applied microcapsule can effectively meet the friction fragrance release performance requirement required by essence wrapping, so that after the obtained essence-encapsulated microcapsule is stored in a lotion at 45 DEG C for 28 days, the fragrance release performance of the microcapsule material is not influenced by the friction fragrance release performance, and the fragrance release performance of the microcapsule material is not influenced by the friction fragrance release performance. The excellent friction aroma releasing capability and the adhesion capability on the fabric can still be maintained, and the excellent thermal stability is shown.
Owner:GUANGZHOU LIBAI TECH GRP CO LTD

Cationic polymer scale inhibitor as well as preparation method and application thereof

The invention discloses a cationic polymer scale inhibitor as well as a preparation method and application thereof, and relates to the field of scale inhibitors in geothermal pipelines, the scale inhibitor limits easy-to-scale metal from adhering and scaling on a coating through cationic groups on polymer molecule side chains, meanwhile, the surface contact angle of the coating is increased through functional components with low surface energy, and the scale inhibitor can be used for inhibiting scale formation of the coating. The cationic polymer-based scale inhibitor has the advantages that the cationic polymer-based scale inhibitor is added into the geothermal fluid, so that some granular solid components of the geothermal fluid are difficult to accumulate on the coating to form a crystallized nucleation center, the problems of scaling and accumulation are fundamentally solved, in addition, the cationic polymer-based scale inhibitor has excellent adhesive force with the geothermal pipeline, and guarantee is provided for the corrosion resistance and the long-term effect of the coating.
Owner:CHINA THREE GORGES CORPORATION

Enzyme protective agent for continuous glucose sensor and continuous glucose sensor

The invention provides an enzyme protective agent for a continuous glucose sensor and the continuous glucose sensor, the enzyme protective agent comprises the following components: poloxamer and a zwitterionic polymer, and the mass percent concentration of the poloxamer is 0.1%-2%, and the mass percent concentration of the zwitterionic polymer is 0.5%-5%. By adopting the technical scheme provided by the invention, the poloxamer and the zwitterionic polymer are introduced, so that an enzyme layer coating process can be optimized, a coffee ring effect can be inhibited, and the consistency and monitoring accuracy of the sensor can be improved; and on the premise of keeping the signal transmission performance of the sensor unchanged, the activity and long-term stability of the biological enzyme preparation in the production, storage, transportation and use processes are remarkably improved.
Owner:SEAGATE MEDICAL TECH (SHENZHEN) CO LTD

Gadolinium-based cationic polymer contrast agent and preparation method thereof

The gadolinium-based cationic polymer contrast agent is synthesized by chelating a cationic polymer and gadolinium ions, has high biological safety and can be used for cartilage imaging. The prepared contrast agent adopts an articular cavity direct injection method, so that the imaging effect is improved, and the contrast dosage is reduced. When the cartilage activity is normal, the content of glycosaminoglycan in the matrix is rich, and when the cartilage is inactivated or the activity is reduced, the content of glycosaminoglycan in the matrix is obviously reduced. The gadolinium-based cationic polymer contrast agent is combined with negatively charged glycosaminoglycan in a cartilage matrix through the charge effect. The gadolinium-based cationic polymer contrast agent can be used for noninvasive and quantitative evaluation of cartilage activity in nuclear magnetic resonance imaging, especially cartilage activity and stability in transplantation.
Owner:SHANGHAI NAT ENG RES CENT FORNANOTECH

Zwitterionic polymer, composition, and coating

PendingJP2025081041AVinyl etherPolymer science
To provide a zwitterionic polymer having a vinyl ether structure.SOLUTION: A zwitterionic polymer comprises a structural unit (1) and a structural unit (2), with the molar ratio ((1):(2)) ranging from 10:1 to 1:10. (R1 and R2 are monovalent alkyl groups having 1 to 4 carbon atoms; L1 is an alkylene group having 2 to 6 carbon atoms; L2 is an alkylene group having 2 to 4 carbon atoms; the sum of carbon atoms of L1, R1, and R2 is 8 or more; and R3 is an alkyl group having 1 to 9 carbon atoms.)SELECTED DRAWING: None
Owner:UNIVERSITY OF FUKUI +1

Preparation method of water electrolysis hydrogen production composite electrode based on zwitterionic polymer binder

The invention relates to a preparation method of a water electrolysis hydrogen production composite electrode based on a zwitterionic polymer binder. According to the method, a traditional ionic binder Nafion is replaced with a zwitterionic polymer polysulfobetaine methacrylate, an electrode-electrolyte interface is optimized through a unique electrically neutral hydration layer structure, the rapid desorption behavior of bubbles is enhanced, and efficient transmission of reaction ions is also promoted; and regulating and controlling the mass ratio of the PSBMA binder to the catalyst by using a spraying process. The invention aims to overcome the defects of high cost, insufficient mass transfer and poor interface stability of the existing Nafion binder, and provides the composite electrode taking PSBMA as the binder and the preparation method of the composite electrode, and the provided composite electrode is simple in preparation process and controllable in cost, and has good popularization and application prospects.
Owner:HEBEI UNIV OF TECH

Preparation method of semi-solid battery and its application

The present invention provides a method for preparing a semi-solid-state battery and its application. The preparation method comprises the following steps: (1) injecting a polymerizing agent into an assembled battery, aging the battery, and then injecting an electrolyte to obtain a battery that has been injected; (2) allowing the battery that has been injected in step (1) to stand for a gelation reaction, and after the gelation reaction is completed, sequentially performing formation, aging, and volume separation on the battery to obtain the semi-solid-state battery; wherein the polymerizing agent in step (1) includes a solvent with a cationic polymerization function and / or a gelling factor with a cationic polymerization function. The present invention uses an in-situ polymerization method to prepare a semi-solid-state battery. After mixing the polymerizing agent and the liquid electrolyte, the polymerizing agent contains a solvent with a cationic polymerization function and / or a gelling factor with a cationic polymerization function, and a gelation polymerization reaction is initiated in the liquid electrolyte, thereby obtaining a semi-solid-state battery with low impedance, high energy density, and high safety performance.
Owner:SHANGHAI RUIPU ENERGY CO LTD

Anti-acne hydrogel and preparation method thereof

The invention relates to the technical field of biological medicine, in particular to anti-acne hydrogel and a preparation method thereof. The anti-acne hydrogel is prepared from metal-polyphenol network nanoparticles and a hydrogel base material, the metal-polyphenol network nanoparticles comprise a first polyphenol compound, a second polyphenol compound and metal ions, the first polyphenol compound is a tannic acid compound, and the second polyphenol compound is a flavonoid compound; the hydrogel base material comprises a hydrophilic high-molecular polymer and a cationic polymer. The metal-polyphenol network nano-particles are creatively utilized, the anti-inflammatory and anti-oxidation activity of flavonoid compounds, the convergence and protein binding characteristic of tannin and the antibacterial activity of metal ions are integrated at the same time, and the vicious circle of acne can be intervened at the same time from multiple links of antibacterial, anti-inflammatory, anti-oxidation and keratinization adjustment; and the defect of single action target spot of the existing medicine is overcome.
Owner:GUANGDONG PHARMA UNIV

Side chain type polyaryl anion-exchange membrane, preparation method and application thereof and anion-exchange membrane electrolytic cell

The invention relates to a side chain type polyaryl anion-exchange membrane, a preparation method and application thereof and an anion-exchange membrane electrolytic bath, and belongs to the technical field of hydrogen energy. The preparation method of the side chain type polyaryl anion exchange membrane comprises the following steps: reacting a side chain type polyaryl skeleton polymer with a quaternization reagent to obtain a side chain type polyaryl anion polymer; the side-chain type polyaryl anion polymer is subjected to membrane forming, and the side-chain type polyaryl anion exchange membrane is obtained. According to the invention, a heteroatom-free polyaryl structure is selected as a main chain, and a super-acid-catalyzed Friedel-Crafts reaction is adopted for polymerization, so that the high-molecular polymer is obtained; the cationic functional group is a piperidine cationic functional group with excellent alkali stability; the piperidine cation functional group is connected with the polyaryl main chain through a long alkyl chain. According to the invention, a long alkyl chain is adopted to combine a polyaryl skeleton with a piperidine cation functional group, and a hydrophilic / hydrophobic microphase separation structure is constructed in the membrane, so that the conductivity of hydroxyl ions is remarkably improved while the alkali stability and the size stability are improved.
Owner:HYDROGEN ENERGY (SHENZHEN) CO LTD

Cationic polymer coated copper-based catalyst as well as preparation method and application thereof

The invention relates to a cationic polymer coated copper-based catalyst as well as a preparation method and application thereof, and belongs to the technical field of catalysts. The preparation method comprises the following steps: adding copper nanoparticles into a quaternized spiropiperazine solution, uniformly stirring, adjusting the pH value to 9-13, and then adding a 1, 3, 5-benzoyl chloride solution for reaction to obtain the copper-based catalyst coated with the cationic polymer. The copper-based catalyst coated with the cationic polymer shows excellent carbon dioxide electrocatalytic reduction performance in an electrolytic tank under the acidic condition through a three-in-one mechanism of electrostatic enrichment, coordination stabilization and cross-linking strengthening, ethanol can be efficiently prepared, and the Faraday efficiency reaching up to 50% is achieved under the current density of 250 mA / cm < 2 >.
Owner:JIANGNAN UNIV

COMPOSITION FOR TRANSFECTING CELLS WITH NUCLEIC ACID MOLECULES COMPRISING TRIAZOLE COMPOUND GRAFTED TO A CATIONIC POLYMER AND USE THEREOF

The present invention relates to a composition for transfecting a nucleic acid molecule into a cell and its use. The present invention relates to a composition suitable for transfecting a nucleic acid molecule into a cell, preferably a eukaryotic cell, comprising (i) at least one compound of general formula (I), preferably general formula (III), or a tautomer, mesomers, racemates, enantiomers, diastereomers, or mixtures thereof, or an acceptable salt thereof, and (ii) an acceptable excipient, buffer, cell culture medium, or transfection medium, wherein Y 1 , Y 2 , Y 3 , Z 1 , Z 2 , Z 3 , X1, X2, R3, P + , R and V are as defined herein. The present invention also relates to uses of said compositions and to methods for the in vitro or ex vivo transfection of living cells.
Owner:ザルトリウス ポリプラス