The invention provides a fresh and cool oil-control silicon oil-free hair shampoo which is composed of lauroyl collagen amino acid, sodium cocoamphoacetate, cocamidopropyl betaine, decyl glucoside, glyceryl laurate, peg-120 methyl glucose dioleate, stearamide propyl dimethyl ammonium, guar gum hydroxypropyl trimethyl ammonium chloride, polyquaternary ammonium salt-10, peg-7 glyceryl cocoate, hydroxyethylurea, capryloyl glycine, citric acid, allantoin, triethanolamine, hydrolysis avenin, hydrolyzed collagen, ginger root oil, palmitamidopropylamine trimethyl ammonium chloride, hexamidine di(ethylenhydrin-sulfonic acid) salt and a matrix. The invention further discloses a making method of the hair shampoo. The hair shampoo is capable of adjusting hair environments, enabling hair to be at a silicon oil free of small silicon oil deposition state, controlling oil, removing dandruff, making hair fresh and cool, nutrificating scalp and hair, repairing damaged hair, preventing hair dry yellow,hair spitting or hair breakage, and making the hair soft and glary.