The application discloses a multilayer composite polarizing film and a preparation method thereof, relates to the technical field of optical films, and comprises three
layers which are composed of a PVA film of a middle layer and TAC films of two inner and outer
layers, wherein the PVA film is prepared by being immersed and stretched in a stretching bath solution, the stretching bath solution comprises, according to
mass ratio, 5% of
boric acid, 0.35% of
cetyltrimethylammonium chloride, 0.05%-0.15% of
cocamide propyl
betaine, 0.05% of
sodium tripolyphosphate and 0.01%-0.05% of
dopamine nanoparticles, and the rest is water; the
cocamide propyl
betaine neutralizes the adsorption capacity of CTAC and releases the crosslinking sites of PVA through atomic-level charge
complementation, molecular-level functional differentiation and submicroscopic
dynamic balance; a stable compound is formed, the re-adsorption of CTAC is prevented through steric hindrance, and the
ion bridging network is constructed in cooperation with
sodium tripolyphosphate, so that the
system stability is improved, and the service life of the polarizing film is prolonged.