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181 results about "Diphenylamine" patented technology

Diphenylamine is an organic compound with the formula (C₆H₅)₂NH. The compound is a derivative of aniline, consisting of an amine bound to two phenyl groups. The compound is a colorless solid, but commercial samples are often yellow due to oxidized impurities. Diphenylamine dissolves well in many common organic solvents, and is moderately soluble in water. It is used mainly for its antioxidant properties. Diphenylamine is widely used as an industrial antioxidant, dye mordant and reagent and is also employed in agriculture as a fungicide and antihelmintic.

Lithium manganate positive electrode material and preparation method thereof, positive electrode plate and battery

The invention relates to the field of lithium manganate positive electrode materials, in particular to a lithium manganate positive electrode material and a preparation method thereof, a positive electrode plate and a battery, which are used for solving the problems of Jahn-Teller distortion of Mn < 3 + >, Mn dissolution and low conductivity in circulation. Lithium carbonate, manganous-manganic oxide, potassium carbonate, aluminum nitrate and absolute ethyl alcohol are subjected to ball milling and then sintered to obtain K / Al co-doped lithium manganate powder, then the K / Al co-doped lithium manganate powder is coated with an acetylferrocene / diphenylamine polymer, finally, the K / Al co-doped lithium manganate powder is coated with an AlF3 (at) CeF3 suspension, and finally the lithium manganate positive electrode material is obtained. According to the lithium manganate positive electrode material, the electronic conductivity is greatly improved, the rate capability is improved, and the cycling stability is improved; and the material has excellent cycling stability and rate capability.
Owner:XIANGTAN ELECTROCHEMICAL SCI CO LTD

High-flux renewable chlorine-resistant reverse osmosis composite membrane and preparation method thereof

The invention belongs to the technical field of reverse osmosis membranes, and particularly relates to a high-flux reproducible chlorine-resistant reverse osmosis composite membrane and a preparation method thereof.Monomer 3, 5-diamino-1, 2, 4-triazole is added into a water-phase solution, functional amino and imino groups of the monomer react with acyl chloride groups, and the high-flux reproducible chlorine-resistant reverse osmosis composite membrane is prepared by adjusting the structure of a polyamide layer; the separation performance of the membrane can be improved while the water flux of the membrane is not obviously reduced. According to the reverse osmosis composite membrane preliminarily obtained through interfacial polymerization reaction, aniline dimer diaminodiphenylamine is adopted as a modification material, and chemical grafting modification of the membrane surface is carried out on a polyamide composite membrane. The characteristic that the redox potential of a secondary amine group on diaminodiphenylamine is lower than that of an amide group on a polyamide polymer is utilized, the secondary amine group can serve as a sacrificial group to react with active chlorine preferentially, protection of a polyamide separation layer is achieved, and therefore the chlorine resistance of the composite membrane is improved. In addition, diaminodiphenylamine has the same reversible redox characteristic as aniline, and reversible regeneration of chlorine resistance of the grafted membrane can be realized through Na2S2O3 reduction; therefore, the high-flux reproducible chlorine-resistant reverse osmosis composite membrane disclosed by the invention is a reverse osmosis composite membrane based on aniline dimer surface modification, and has the characteristics of high flux, reproducibility, excellent chlorine resistance, good water separation performance, better hydrophilicity and salt rejection rate.
Owner:VONTRON TECH CO LTD

Visible light response type covalent organic framework-TiO2 composite material as well as preparation method and application thereof

The invention discloses the technical field of photocatalysis, and particularly discloses a preparation method of a visible-light response type covalent organic frame-TiO2 composite material, which comprises the following steps: adding TiO2 into a mixed solvent, carrying out ultrasonic dispersion, dropwise adding an H2PtCl6 aqueous solution while stirring, reacting under the irradiation of a mercury lamp, centrifuging, washing and drying to obtain a Pt-TiO2 material; the preparation method comprises the following steps: dispersing a Pt-TiO2 material in an organic solvent, adding 2-hydroxybenzene-1, 3, 5-tricarboxaldehyde and 4, 4 '-(benzo [c] [1, 2, 5] thiadiazole-4, 7-diyl) diphenylamine, carrying out ultrasonic treatment for 3-8 minutes, and then adding acetic acid; after 2-4 times of liquid nitrogen freezing-degassing, sealing, and reacting for 2-5 days at the temperature of 110-130 DEG C; and centrifuging, washing and drying to obtain the covalent organic frame-TiO2 composite material. The novel covalent organic frame-TiO2 composite material prepared by the invention effectively expands the visible light absorption range of TiO2, has strong visible light absorption and strong photocatalytic performance, can efficiently catalyze hydrogen evolution, and has excellent light stability and repeatability in photocatalytic hydrogen evolution reaction.
Owner:GUANGXI TEACHERS EDUCATION UNIV

A purification device for diphenylamine production

The application discloses a kind of purification devices for diphenylamine production, it is related to chemical purification technical field, including purification tank body, stirring mixing assembly and lifting mixed flow component are equipped in the purification tank body, stirring mixing assembly and lifting mixed flow component are jointly connected comprehensive drive component;The lifting mixed flow component includes multiple dispersion pipes arranged in the purification tank body, multiple dispersion pipes are evenly distributed in the circumferential of purification tank body, lifting column is slidably connected in each dispersion pipe, the top end of lifting column is fixedly connected with traction rope, the diphenylamine solution in the purification tank body can be mixed as a whole by being equipped with stirring mixing assembly, the diphenylamine solution can be fine flow mixing by being equipped with lifting mixed flow component using pressure-driven mode, stirring mixing assembly and lifting mixed flow component are jointly used to effectively ensure that the diphenylamine solution in the purification tank body is efficiently mixed, so that diphenylamine is more efficiently purified, and the use effect is good.
Owner:NANTONG XINBANG CHEM

Triarylmethane type I photosensitive dye, and synthesis method and application thereof

The invention discloses a triarylmethane type I photosensitive dye as well as a synthesis method and application thereof. The structure of the dye is shown as a general formula I; intramolecular charge separation is optimized by regulating substituent groups, and the generation efficiency of superoxide anions and hydroxyl radicals is remarkably improved. According to the synthesis method, 4-diphenylaminobenzaldehyde or 4-vinyl benzaldehyde is used as a raw material, efficient preparation is achieved through the steps of condensation, oxidation and the like, the raw material is easy to obtain, and operation is easy and convenient. The dye has strong absorption at the wavelength of 600-630 nm, is suitable for red light triggered photodynamic therapy (PDT), especially keeps high reactive oxygen yield under the hypoxic condition, and breaks through the oxygen dependence limitation of traditional PDT. Experiments show that the dye can induce ferroptosis of tumor cells, has the functions of fluorescence imaging and treatment, and has wide application prospects in the fields of antitumor drugs, in-vivo fluorescence labeling, photoresponsive functional preparations and the like.
Owner:DALIAN UNIV OF TECH

Perovskite solar cell device and preparation method thereof

The invention discloses a perovskite solar cell device and a preparation method, and belongs to the technical field of perovskite solar cell preparation, and the perovskite solar cell device comprises a first electrode layer, an electron transport layer, a perovskite light absorption layer, a hole transport layer and a second electrode layer from top to bottom in sequence, a passivation layer is arranged between the electron transport layer and the perovskite light absorption layer; the passivation layer is made of a diphenylamine passivator; the chemical structural formula of the diphenylamine passivator is shown in the specification, and in the formula, R1-R10 are respectively and independently selected from one of hydrogen, C1-C6 alkyl, carboxyl, cyano, trifluoromethyl, halogen, phosphonic acid group, C1-C6 alkyl thioether group and (CF3) 3-C-; at least five substituent groups in R1-R10 are hydrogen at the same time. By adopting the diphenylamine passivator, the stability and efficiency of the perovskite solar cell device are effectively improved. .
Owner:ZHONGMAO LVNENG TECH (XIAN) CO LTD

Gas engine lubricating oil composition and preparation method thereof

PendingCN120924330ALubricant compositionButanedioic acidAlkylphosphate
The invention provides a gas engine lubricating oil composition and a preparation method thereof. The gas engine lubricating oil composition of the present invention comprises: (A) an alkyl phosphate compound; (B) alkylated diphenylamine; (C) a polyisobutylene succinic acid pentaerythritol ester dispersing agent; (D) a salicylate and / or sulfonate; (E) zinc dialkyl dithiophosphate; (F) an oil-soluble organic molybdenum friction modifier; (G) a metal corrosion inhibitor; (H) a pour point depressant; (I) a major amount of a lubricating base oil. The gas engine lubricating oil composition disclosed by the invention has excellent high-temperature oxidation resistance, cleaning performance, extreme pressure anti-wear performance and anti-corrosion performance.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Temperature-resistant and salt-resistant foaming agent for drilling and synthesis method thereof

The application belongs to the technical field of oil and gas field development, and particularly relates to a temperature-resistant and salt-resistant foaming agent for drilling and a synthesis method thereof. The synthesis method is as follows: diphenylamine-4-sodium sulfonate, isopropyl alcohol and 1,3-dibromopropane are added into a four-necked flask, stirred, heated and refluxed to obtain a mixed solution; 90-95wt% of isopropyl alcohol in the mixed solution is distilled off under reduced pressure, distilled water is added, and the whole is transferred into a separatory funnel, fully shaken, separated, and a small amount of oil phase is discarded; the pH is adjusted to 2-3, a precipitate is separated out, suction filtration is performed, and an intermediate is obtained; the intermediate is transferred into a four-necked flask with isopropyl alcohol, sodium bromoethyl sulfonate is added, the pH is adjusted to 7-8, and the product solution is obtained by heating and refluxing; the product is obtained by vacuum distillation, recrystallization and drying. The foaming agent for drilling has the advantages of good temperature resistance, salt resistance and salinity resistance.
Owner:DONGYING SPRING PETROLEUM ENG TECH

Alcohol-soluble host material for carbon dot electroluminescent device and preparation method and application thereof

The invention relates to the technical field of electroluminescent materials and devices, in particular to an alcohol-soluble host material for a carbon dot electroluminescent device as well as a preparation method and application of the alcohol-soluble host material. The alcohol-soluble host material for the carbon dot electroluminescent device has a structure as shown in a formula I. According to the invention, phosphate ester is introduced into the alcohol-soluble host material as a side chain, so that on one hand, the solubility of the host material in ethanol can be effectively improved, and on the other hand, the film-forming ability of the host material can be effectively improved. Diphenylamine, carbazole and carbazole derivatives are used as donors, triazine is used as an acceptor, and the host material can be endowed with the characteristic of bipolar transmission. Test results show that the alcohol-soluble host material provided by the invention has excellent alcohol solubility and film-forming ability comparable to that of a polymer host material, and also has good hole and electron transport ability, so that carrier transport is effectively balanced, and the luminous efficiency of a host-guest doped electroluminescent device is improved.
Owner:BEIJING UNIV OF CHEM TECH

Diphenylamine compounds and use thereof

The present invention belongs to the technical field of pesticides, and specifically relates to diphenylamine compounds and the use thereof. The compounds are as shown in general formula I, wherein R1, R3, X2, X3 and X5 each independently represent hydrogen, halogen, nitro, cyano, etc.; R2 represents haloalkyl; R4 represents nitro or haloalkyl; X1 represents halogen; and X4 represents haloalkyl. The compounds have excellent control effect on pests such as mites.
Owner:QINGDAO KINGAGROOT CHEM COMPOUNDS CO LTD

Hybrid vehicle engine lubricating oil composition and method of making same

The application provides a hybrid vehicle engine lubricating oil composition and a preparation method thereof.The hybrid vehicle engine lubricating oil composition comprises the following components: (A) a benzotriazole derivative; (B) a composite antioxidant comprising an alkylated diphenylamine antioxidant and a sulfide phenolic antioxidant; (C) a polyisobutylene succinimide ashless dispersant; (D) a sulfonate and / or a sulfated alkyl phenate; (E) a zinc dialkyldithiophosphate; (F) a composite friction modifier comprising an oil-soluble organic molybdenum friction modifier and an ashless friction modifier; (G) a phosphite type extreme pressure antiwear agent; and (H) a major amount of a lubricating oil base oil; wherein the structure of the benzotriazole derivative is shown in formula (I): wherein the definitions of the groups are shown in the specification.The hybrid vehicle engine lubricating oil composition has excellent antioxidant performance, corrosion resistance and rust resistance, and good emulsion retention performance and wear resistance.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Corrosion-resistant waterproof aluminum foil glass fabric and preparation method thereof

The invention discloses corrosion-resistant waterproof aluminum foil glass fabric and a preparation method thereof, and belongs to the technical field of aluminum foil composite glass fabric. The corrosion-resistant waterproof aluminum foil glass fabric sequentially comprises a waterproof glass fabric, a high-temperature-resistant adhesive layer and an aluminum foil from bottom to top, the waterproof glass fabric is obtained by padding a waterproof finishing agent; the waterproof finishing agent is mainly prepared from the following raw material components: a silane coupling agent, hydroxyl-terminated fluorine-containing dihydric alcohol, isophorone diisocyanate and polycaprolactone; the high-temperature-resistant adhesive is mainly prepared from the following raw material components: 4, 4 '-oxydiphthalic anhydride, 4, 4-(hexafluoroisopropyl) bis (p-phenoxy) diphenylamine, 3, 3'-diaminodiphenyl sulfone, 1, 3-bis (3-aminopropyl)-1, 1, 3, 3-tetramethyldisiloxane, 4-amino-2-hydroxybenzaldehyde and o-phenylenediamine, and the high-temperature-resistant adhesive is prepared from the following raw material components: 4, 4 '-oxydiphthalic anhydride, 4, 4-(hexafluoroisopropyl) bis (p-phenoxy) diphenylamine, 4, 4-(hexafluoroisopropyl) bis (p-phenoxy) diphenylamine, 3, 3'-diaminodiphenyl sulfone, 1, 3-bis (3-aminopropyl) The corrosion-resistant waterproof aluminum foil glass fiber cloth prepared by the invention is relatively good in high temperature resistance, corrosion resistance and waterproofness.
Owner:JIANGSU QIANTE ENERGY SAVING TECH CO LTD

Long-life creep-resistant lubricating grease for high-precision ball screw and preparation method of long-life creep-resistant lubricating grease

The invention relates to the field of lubrication of ball screws, in particular to long-life creep-resistant lubricating grease for a high-precision ball screw, which comprises the following components in parts by weight: 65 parts of polyolefin, 5-10 parts of pentaerythritol ester, 5-10 parts of isocyanate, 2-5 parts of amine chain extender, 5 parts of PTFE (polytetrafluoroethylene), 1.0-1.5 parts of diphenylamine, 0.1-0.5 part of 2, 4-diphenyl-1, 3-pentanediol monoisobutyrate, 0.1-0.5 part of antioxidant, 0.1-0.5 part of antioxidant and 0.1-0.5 part of lubricant. The composite material is prepared from the following components in parts by weight: 0.5 to 1 part of 2, 6-butylated hydroxytoluene, 1.5 to 2 parts of molybdenum isocaprylate, 0.5 to 1 part of molybdenum bis (2-ethylhexyl) dithiocarbamate, 1 to 2 parts of zinc dialkyl dithiophosphate, 3 parts of calcium petroleum sulfonate, 1 to 1.5 parts of polyisobutene, 0.2 to 0.5 part of benzotriazole and 0.1 to 0.3 part of polymethacrylate. The isocyanate comprises HDI and IPDI, and the amine chain extender comprises TETA and TEPA. According to the invention, isocyanate and the amine chain extender react to form a polyurea macromolecular chain, and a high-energy hydrogen bond network is formed, so that the lubricating grease has relatively high creep resistance; the anti-creep performance is further enhanced through cooperation with the PTFE particles; meanwhile, through cooperation with diphenylamine, the oxidation resistance is promoted, the consumption is reduced, and the service life of the lubricating grease is longer.
Owner:SHENZHEN DERILL TECH CO LTD

A biodegradable hydraulic fluid composition and a method of making the same

The present application relates to a kind of biodegradable hydraulic oil composition and its preparation method, it includes the following weight parts of component: biodegradable base oil 96.0-98.5 parts and composite detergent 1.5-2.5 parts;The base oil is the mixture of pentaerythritol tetraester and trimethylolpropane triester, fatty acid chain is C8-C10 saturated fatty acid, saturation ≥90%, 28 days biodegradability meets the determination of OECD 301B;The composite detergent includes: octylated diphenylamine 0.45-0.90 parts, 2,6-di-tert-butyl-4-methylphenol 0.10-0.25 parts, 2-ethylhexyl acidic phosphate and its ethanolamine salt 0.60-1.20 parts, dodecenyl succinic acid di (2-ethylhexyl ester) 0.15-0.35 parts, and the mass ratio of octylated diphenylamine and 2,6-di-tert-butyl-4-methylphenol is 1.5:1~4:1.
Owner:TONGYI PETROLEUM CHEM CO LTD

Compressor oil composition and preparation method thereof

The invention relates to the field of lubricating oil, in particular to a compressor oil composition which is prepared from the following components in parts by weight: 0.005 to 0.2 part of an anti-rust agent, 0.05 to 1 part of an extreme pressure anti-wear agent, 0.01 to 0.5 part of a friction reducing agent, 3 to 8 parts of synthetic ester, 0.01 to 1 part of an antioxidant, 0.001 to 0.1 part of an anti-foaming agent and 90 to 97 parts of base oil. The anti-friction agent is a trimethylolpropane-triacid ester derivative, the anti-rust agent is formed by mixing an alkenyl succinic acid half-ester derivative and a carboxyl imidazoline derivative, and the anti-wear reagent at extreme pressure is formed by mixing triphenyl phosphate and an alkyl thiophosphate derivative. The antioxidant is formed by mixing any two of alkyl diphenylamine, alkyl phenyl-alpha-naphthylamine and alkyl hindered phenol. The invention further relates to a preparation method of the compressor oil composition. The compressor oil composition provided by the invention has excellent washing resistance and rust resistance.
Owner:PETROCHINA CO LTD

A preparation method of diphenylamine adamantane-type substituent compound

The invention belongs to the technical field of chemical synthesis and specifically discloses a preparation method of a diphenylamine-type adamantane substituent compound. The method comprises the following steps: adding adamantane alcohol and acetanilide to a solvent for reaction to obtain adamantane acetanilide; adding adamantane acetanilide and NBS to the solvent for reaction to obtain bromoadamantanacetanilide; adding bromoadamantanacetanilide, phenylboric acid, a catalyst and an alkali salt to the solvent for reaction to obtain phenyladamantanacetanilide; and adding phenyladamantanacetanilide and hydrochloric acid to the solvent for reaction to obtain adamantane diphenylamine. The method has readily available raw materials and simple operation, has achieved kilogram-level production, and has high product purity, with a liquid phase purity of over 99.9%.
Owner:WEISIPU NEW MATERIAL (SUZHOU) CO LTD

Method for recovering polycarbonate plastic to obtain amine high-temperature antioxidant

PendingCN121801161APlastic recyclingPolycarbonate plasticPtru catalyst
The invention discloses a method for recovering polycarbonate plastic to obtain an amine high-temperature antioxidant, and belongs to the technical field of plastic recovery. Aromatic amine is used as a nitrogen source, hydroboron and formate are used as in-situ hydrogen donors, and in an inert atmosphere and a heating environment, under the synergistic catalysis of a catalyst and a molecular sieve, the amine high-temperature antioxidant is prepared from polycarbonate based on a one-step method. The reaction path is simple, the selectivity is high, the amine high-temperature antioxidant taking diphenylamine and alkyl diphenylamine as main components can be directly obtained without multi-stage separation and intermediate preparation, and the requirements of simple process flow, low energy consumption and the like are met. The invention provides a high-valued way for polycarbonate recovery, also provides a large-scale raw material source for the field of high-temperature-resistant antioxidants for lubricating oil / fuel / rubber and high polymer materials, and has a wide application prospect.
Owner:SOUTHEAST UNIV

Polycarbonate resin composition and article produced therefrom

PCT designated stageWO2026106183A1Polysiloxane polycarbonate copolymerPolymer science
A polycarbonate resin composition of the present invention comprises: about 100 parts by weight of a base resin comprising about 10-90 wt% of a polycarbonate resin and about 10-90 wt% of a polysiloxane-polycarbonate copolymer resin; about 1-10 parts by weight of a diphenylamine-based compound; and about 0.1-2 parts by weight of a polydimethylsiloxane having a terminal reactive group and having a kinematic viscosity, measured at 40 °C according to ASTM D445, of about 5-200 cSt. The polycarbonate resin composition has excellent transparency, chemical resistance, fluidity, thermal stability, balance of these physical properties, and the like.
Owner:LOTTE CHEM CORP

Lubricating oil composition for unmanned aerial vehicle dedicated four-stroke engine and method for producing the same

PendingCN122357199AMethacrylateThiocarbamate
This invention proposes a lubricating oil composition for a four-stroke engine specifically designed for unmanned aerial vehicles (UAVs) and its preparation method. The lubricating oil composition for a four-stroke engine of this invention comprises the following components: (A) a nitrogen-containing organoboron compound; (B) an alkyl diphenylamine; (C) polyisobutylene succinimide; (D) sulfonates and / or sulfurized alkylphenol salts; (E) zinc dialkyl dithiophosphate; (F) dialkyl dithiocarbamate; (G) polymethyl methacrylate; and (H) a base oil in a major amount. The structure of the nitrogen-containing organoboron compound is shown in formula (I) and / or formula (II), with the definitions of each group provided in the specification. The lubricating oil composition for a four-stroke UAV engine of this invention exhibits excellent extreme pressure anti-wear, anti-oxidation, and detergency properties, effectively suppressing the increased wear caused by the high power-to-weight ratio and harsh lubrication conditions of four-stroke UAV engines.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Lubricating oil composition and method for using lubricating oil composition

PCT designated stageWO2026071167A1AdditivesBase-materialsA-NaphthylamineAniline
The present invention addresses the problem of providing a lubricating oil composition that has excellent permeability through water-bearing strata, as well as excellent evaporation-suppressing properties and coking resistance. The problem was solved by a lubricating oil composition that contains a polyalkylene glycol compound (A), a naphthylamine-based antioxidant (B), and a diphenylamine-based antioxidant (C). The molar ratio [(EO) / (RO)] of oxyethylene units (EO) to oxyalkylene units (RO) other than oxyethylene units (EO) in the polyalkylene glycol compound (A) is 1.0 or more, and the content of the polyalkylene glycol compound (A) is more than 50 mass% based on the total amount of the lubricating oil composition.
Owner:IDEMITSU KOSAN CO LTD

Antioxidants with high mono-alkylated diphenylamine content

Lubricating oil composition is provided. The composition includes several components including a major amount of a base oil, a mixture of alkylated diphenylamines having a weight ratio of mono-alkylated diphenylamine to di-alkylated diphenylamine ranging from 0.6 to 4.0, and a molybdenum or sulfur additive that provides synergistic enhancement of oxidation stability in combination with the mixture of alkylated diphenylamines.
Owner:CHEVRON ORONITE CO LLC

Process for the preparation of methylenedianiline and polymethylenepolyphenylamine

PendingCN122374367APolymer sciencePtru catalyst
A mixture of methylene diphenylamine isomers and polymethylene polyaniline is prepared with a controllable ratio of methylene diphenylamine isomers. Aniline and formaldehyde are reacted to produce N,N'-diphenylmethylenediamine (acetalamine), which is then partially rearranged in the presence of a heterogeneous catalyst to a mixture of aminobenzylaniline and methylene diphenylamine isomers. Further rearrangement is performed in the presence of a homogeneous catalyst to convert the remaining aminobenzylaniline isomers to methylene diphenylamine and polymethylene polyaniline.
Owner:DOW GLOBAL TECHNOLOGIES LLC

Lubricating oil composition for corrosion control

A lubricating oil composition is disclosed. The composition includes a major amount of an oil of lubricating viscosity, one or more alkylhydroxy benzoate compound derived from isomerized normal alpha olefins, and oxidation inhibitor system comprising a molybdenum-containing antioxidant and a diphenylamine. The molybdenum-containing antioxidant is present in an amount to provide at least 120 ppm of Mo to the lubricating oil composition. The diphenylamine is present in an amount to provide 0.5 wt. % or more to the lubricating oil composition.
Owner:CHEVRON ORONITE CO LLC

Flavonol-based fluorescent probe for continuously detecting hydrogen sulfide and hypochlorous acid as well as preparation method and application of flavonol-based fluorescent probe

The invention discloses a flavonol-based fluorescent probe for continuously detecting hydrogen sulfide and hypochlorous acid as well as a preparation method and application of the flavonol-based fluorescent probe. The flavonol-based fluorescent probe is 3-(2, 4-dinitrophenoxy)-7-(4-(diphenylamino) phenyl)-2-(4-(thiomorpholinophenyl) chromone, and the structural formula of the flavonol-based fluorescent probe is shown in the specification. According to the invention, 7-(4-(diphenylamino) phenyl)-3-hydroxy-2-(4-thiomorpholinophenyl) chromone is used as an initial raw material, and the 7-(4-(diphenylamino) phenyl)-3-hydroxy-2-(4-thiomorpholinophenyl) chromone and 2, 4-dinitrofluorobenzene are subjected to nucleophilic substitution reaction to obtain the compound 3-(2, 4-dinitrophenoxy)-7-(4-(diphenylamino) phenyl)-2-(4-(thiomorpholinophenyl) chromone. The compound is firstly subjected to selective thiolysis reaction under the action of hydrogen sulfide, the fluorescence color of a solution of the compound is changed from colorless to bright orange under the irradiation of ultraviolet light with the wavelength of 365 nm, then hypochlorous acid is continuously added into the solution, and the compound can be further subjected to specific oxidation reaction with the hypochlorous acid, so that the compound can be obtained. And the fluorescence color of the solution is changed from bright orange to bright cyan. Therefore, the compound can be used as a fluorescent probe for continuously detecting hydrogen sulfide and hypochlorous acid, has the advantages of low detection limit, high response speed, good light stability, wide pH application range and the like, and shows a good application prospect.
Owner:NANJING FORESTRY UNIV

Azaanthracene fluorescent dye and a preparation method thereof

ActiveCN117088813BOrganic chemistryAcridine dyesBenzoic acidGrignard reagent
The embodiment of the present disclosure discloses a kind of azaxanthene fluorescent dyes and preparation method thereof. Among them, azaxanthene fluorescent dyes have the structure shown in general formula (a);The preparation method of azaxanthene fluorescent dyes includes: halogenated benzoic acid and aniline derivative reaction, generate diphenylamine derivative;Diphenylamine derivative is dehydrated and cyclized to generate azaxanthone derivative;The amino group of the azaxanthone derivative is methylated to generate the first nitrogen methyl anthrone derivative;The first nitrogen methyl anthrone derivative is removed from the first protecting group to generate the second nitrogen methyl anthrone derivative;The phenolic hydroxyl group of the second nitrogen methyl anthrone derivative is protected by the second protecting group to obtain the third nitrogen methyl anthrone derivative;The third nitrogen methyl anthrone derivative is reacted with grignard reagent, and the second protecting group is removed under acidic conditions to obtain azaxanthene fluorescent dye.The azaxanthene fluorescent dye can have high luminous efficiency under acidic conditions.
Owner:DINA TECH (BEIJING) CO LTD

Lubricant composition for gas turbines

The present invention relates to a lubricant composition, in particular for a gas or steam turbine, comprising: —at least one base oil; —at least one phenylnaphthylamine (PAN) compound, preferably alkylphenyl-α-naphthylamine (APAN) compound; —at least one diphenylamine (DPA) compound, preferably dialkyl-diphenylamine compound; and —at least one phosphite ester compound, preferably triaryl phosphite ester compound; in which the ratio by weight between said diphenylamine compound(s) and said phosphite ester compound(s) is strictly greater than 1.0.
Owner:TOTALENERGIES ONETECH

Anti-aging agent composition and corresponding polyol or polyurethane composition

ActiveCN120904531APolyolPhenolic antioxidant
The invention relates to an anti-aging agent composition and a corresponding polyol or polyurethane composition. The anti-aging agent composition comprises: i) alkylated diphenylamine, and ii) a hindered phenol antioxidant of formula IV. According to the alkylated diphenylamine, the proportion of low-molecular-weight components is reduced, the proportion of high-molecular-weight components is increased, and the alkylated diphenylamine has more excellent heat weight loss resistance, heat stability and low volatility; the long-term thermal stability of the sponge can be improved, high-temperature degradation is reduced, and high-temperature volatilization of small-molecular-weight components can be reduced, so that the FOG value of the sponge is reduced.
Owner:RIANLON CORPORATION

Use of an antioxidant to reduce and / or prevent the toxicity of a lubricating composition

The present invention relates to the use of at least one antioxidant in a lubricating composition, said at least one antioxidant comprising at least one oligomer and / or polymer comprising at least one diphenylamine repeating unit for reducing and / or preventing the toxicity of said lubricating composition. Figure for abstract: No figure
Owner:NYCO CO LTD

A raw rubber composition and an anti-aging agent composition

The application relates to a raw rubber composition and an anti-aging agent composition, the raw rubber composition comprising: raw rubber, and alkylated diphenylamine of the application. The alkylated diphenylamine contained in the rubber composition of the application comprises a high content of C9 disubstituted diphenylamine, a low proportion of small molecular weight components, good compatibility with rubber, is not easy to precipitate, has better long-term protection effect, even if used alone, has application effect in protecting production and processing of synthetic rubber and long-term storage, and has better effect when used in combination with a phenolic antioxidant such as an antioxidant 1520 analogue (antioxidant 1530).
Owner:RIANLON CORPORATION