281 results about "Ruthenium oxide" patented technology

The invention belongs to the technical field of electrocatalyst material preparation, and discloses a long-range disordered localized CoOOH ultrathin nanosheet electrocatalyst as well as a preparation method and application thereof, fluorine-doped cobalt selenide nanobelts prepared by a low-temperature annealing method are used as a base material, and the CoOOH ultrathin nanosheet electrocatalyst is prepared by in-situ reconstruction under an alkaline electrolyzed water anode oxygen evolution reaction condition. In the preparation process of the CoOOH ultrathin nanosheet provided by the invention, lattice cobalt is stabilized in the water electrolysis anode reconstruction process through fluorine ions with strong bonding action with cobalt ions, so that the long-range disordered structure of amorphous CoOOH generated after reconstruction is limited by localization, and the alkaline water electrolysis anode reaction performance is improved. The catalyst has activity and durability obviously superior to those of a commercial ruthenium oxide catalyst in industrial application of anion exchange membrane water electrolysis hydrogen production.

The invention provides a stable multivalent metal surface doped ruthenium oxide catalyst, a preparation method thereof and application of the stable multivalent metal surface doped ruthenium oxide catalyst in a proton exchange membrane water electrolysis device, and belongs to the technical field of catalysts and preparation thereof. According to the prepared multivalent metal such as molybdenum, niobium, tungsten, tantalum and chromium doped ruthenium oxide catalyst, the active center electronic structure is effectively stabilized due to the flexible valence change of the multivalent metal in the oxygen evolution process, meanwhile, a surface layer can be constructed through surface doping, separation of the active center Ru and lattice oxygen is effectively inhibited, and the stability of the catalyst is improved. The prepared catalyst shows excellent catalytic activity and electrochemical stability in an acidic oxygen evolution reaction, has the advantages of low cost and good catalytic stability, and in addition, can stably operate under relatively high current density as a proton exchange membrane electrolyzed water anode catalyst.

The invention belongs to the field of conductive paste preparation, and particularly discloses conductive paste containing ruthenium oxide and a preparation method of the conductive paste. The conductive paste is prepared from the following components in percentage by mass: 40 percent to 50 percent of ruthenium oxide, 3.8 percent to 5 percent of carbon nano tubes, 5 percent to 10 percent of PbO-B2O3-SiO2, 3 percent to 8 percent of ethyl cellulose, 21 percent to 28 percent of terpilenol, 9 percent to 12 percent of butyl carbitol, 0.7 percent to 1 percent of ammonium polyacrylate and 1 percent to 2 percent of dibutyl phthalate. According to the preparation method, ruthenium oxide is activated in vacuum, a mixed solvent is combined after dispersion, and a ball milling and ultrasonic dispersion synergistic process is adopted, so that the slurry is uniformly dispersed and has excellent stability. According to the invention, a ruthenium oxide-carbon nanotube-frit ternary synergistic system is constructed, and terpilenol and butyl carbitol in a specific mass ratio are taken as a mixed solvent, so that the problems of insufficient conductivity and easy agglomeration of traditional paste are effectively solved, and the method can be widely applied to manufacturing of high-precision electronic devices.

The invention discloses a preparation method of a high-strength molybdenum alloy wire and the high-strength molybdenum alloy wire. The technical problem that in the prior art, a molybdenum alloy wire is small in tensile strength is solved. The preparation method of the high-strength molybdenum alloy wire comprises the following steps that molybdenum oxide, rhenium oxide, ruthenium oxide and tungsten oxide are subjected to ball milling and mixing; adding a mixed solution containing cerium ions, yttrium ions and lanthanum ions into the ball-milled and mixed slurry, and continuing ball-milling and mixing; carrying out spray drying on the slurry to obtain composite powder; performing high-temperature hydrogen reduction treatment to obtain multi-component doped molybdenum powder; and the high-strength molybdenum alloy wire is obtained through compression molding treatment, high-temperature sintering treatment, high-temperature rotary swaging and wire drawing treatment.

The invention relates to the technical field of electrochemical catalysis, in particular to a preparation method and application of a bifunctional Schottky heterojunction type water electrolysis catalyst, the bifunctional Schottky heterojunction type water electrolysis catalyst comprises titanium dioxide nanoparticles and transition metal doped ruthenium oxide nanoparticles, and the titanium dioxide nanoparticles and the transition metal doped ruthenium oxide nanoparticles are connected through a Schottky heterojunction; the content of ruthenium oxide in the catalyst is 1%-20%, and the content of transition metal in the catalyst is 0.1%-5%. Titanium dioxide and transition metal doped ruthenium oxide are compounded by using a sol-gel method to form a catalyst with a unique Schottky heterojunction structure, and a built-in electric field formed by Schottky heterojunction promotes spontaneous transfer of charges, optimizes charge distribution, reduces reaction energy consumption, improves water electrolysis reaction efficiency, and is suitable for industrial production. And meanwhile, the consumption of noble metal ruthenium is reduced, and the production cost is reduced.

The invention provides a preparation method of a catalyst, the catalyst and a diethyltoluenediamine synthesis method based on the catalyst, and belongs to the technical field of chemical synthesis. After the surface of phosphoric acid modified zeolite is coated with aluminum oxide, a layer of quantum dot intercalation metal layered oxide is coated, the surface is modified by polydopamine, citric acid is coupled, cerium oxide and ruthenium oxide are loaded, and the catalyst is prepared. The prepared catalyst can well improve the conversion rate of toluenediamine, inhibit side reactions, improve the anti-coking capability, reduce the generation of carbon deposits, prevent the agglomeration of catalyst particles, prolong the service life, improve the mechanical strength and thermal stability, reduce the activation energy in the synthesis process of diethyltoluenediamine, make the reaction conditions milder, make the yield higher, and reduce the production cost. And the method can be repeatedly used and has a wide application prospect.

The invention relates to the technical field of electrocatalysts, and discloses a heterojunction catalyst composed of cobalt-copper co-doped ruthenium dioxide and metal ruthenium as well as a preparation method and application of the heterojunction catalyst. The preparation method comprises the following steps: carrying out hydrothermal reaction on cobalt salt and trimesic acid in a mixed solvent to prepare a cobalt metal organic framework precursor; a cobalt-copper bimetal organic framework is obtained through ion exchange of a copper salt solution; preparing a ruthenium-cobalt-copper ternary metal organic framework by adopting secondary ion exchange of a ruthenium salt solution; and carrying out air calcination treatment to obtain the cobalt-copper co-doped ruthenium dioxide and metal ruthenium heterojunction catalyst. According to the method, cobalt and copper atoms are uniformly doped in ruthenium dioxide crystal lattices through a step-by-step ion exchange strategy, and metal ruthenium nano-particles are grown on the surface in situ to form a heterogeneous interface. The obtained catalyst shows excellent performance in an acidic electrolyzed water anode oxygen evolution reaction, the overpotential is only 199 mV under the current density of 10 mA. Cm, and the stability can be maintained for 40 hours.

The invention relates to the technical field of electrochemical catalysis, in particular to a superfine nickel-doped ruthenium oxide water electrolysis hydrogen production catalyst prepared through a template method and application of the catalyst, the catalyst comprises a RuO2 matrix and a nickel element evenly doped in the matrix, and the mass of the nickel element accounts for 5%-20% of the total mass of the catalyst. According to the invention, the nickel element is doped into a RuO2 lattice, so that the charge distribution of RuO2 is optimized, the intrinsic activity of a catalytic active site is improved, and the catalytic performance of the oxygen evolution electrocatalyst of the material is improved; and meanwhile, ZIF8 is used as a template sacrificial agent, so that agglomeration among the nano-particles is reduced, and the uniformly dispersed metal nano-particles can be prepared.

The invention relates to a noble metal catalyst derived from a metal organic framework, in particular to a ZIF-8-derived ruthenium elementary substance-ruthenium oxide-loaded catalyst as well as a preparation method and application thereof, and belongs to the technical field of advanced nonferrous metal materials, in particular to the field of noble metal nano catalytic materials. According to the invention, the zinc-based metal organic framework compound ZIF-8 is used as a precursor, the ruthenium-loaded elemental ruthenium-ruthenium oxide catalyst is controllably synthesized, and the catalytic activity and stability of the ruthenium oxide catalyst are effectively improved, so that the ruthenium oxide catalyst can be used as a high-activity and good-stability PEM electrolyzed water cathode / anode catalyst.

The invention discloses a preparation method of carbonyl fluoride, which comprises the following steps: with hexafluoropropylene and oxygen as raw materials, introducing gas into a reactor filled with a catalyst for reaction at high temperature; the catalyst is one of palladium oxide, ruthenium oxide, platinum oxide and molybdenum oxide. According to the scheme, the cost is low, the raw material utilization rate is high, and compared with other carbonyl fluoride synthesis methods, the reaction does not involve phosgene, fluorine and other dangerous chemicals, and reaction by-products are few. In addition, according to the method, the toxicity of raw materials is small, hexafluoropropylene can be completely reacted under the condition of excessive oxygen, the reaction process is environment-friendly and simple, and basically no three wastes are generated. According to the method, hexafluoropropylene and oxygen are adopted as raw materials which are common chemical raw materials and are cheap and easy to obtain, and the method is simple in reaction process, mild in reaction, easy to operate and suitable for industrial production.

The invention discloses a preparation method and application of a rare earth element doped ruthenium oxide catalyst, and the preparation method comprises the following steps: (1) dissolving a rare earth metal salt, a ruthenium metal salt, dopamine hydrochloride and a Tris-HCl buffer agent in water to obtain a mixed solution, and carrying out in-situ polymerization reaction, solid-liquid separation and drying to obtain a powder precursor; and (2) carrying out high-temperature calcination on the powder precursor obtained in the step (1) to obtain the rare earth doped ruthenium oxide catalyst. Rare earth metal salt and ruthenium salt precursors are dispersed on an in-situ constructed porous carbon substrate, and the rare earth element doped ruthenium oxide nanosheet is generated by oxidation under a high-temperature condition through a self-sacrifice template method. The method has the characteristics of high efficiency and no pollution. The rare earth element doped ruthenium oxide disclosed by the invention is used as a catalyst for the anodic reaction of the acidic electrolyzed water, and shows excellent catalytic activity and wide application prospect.

A manganese-doped ruthenium dioxide nanofiber material, a preparation method thereof, and an application thereof in alkaline electrocatalytic hydrogen evolution and oxygen evolution at industrial-level current intensity belong to the technical field of controllable preparation of doped metal oxide nanomaterials. In the present invention, a manganese-doped ruthenium dioxide nanofiber material is prepared by two steps of electrospinning technology and calcination in an air atmosphere. The material exists in a uniform fiber morphology as a whole, and the surface is rough. This method is simple and efficient and can be applied to large-scale industrialization. The manganese-doped ruthenium dioxide nanofiber material prepared in the present invention, as a bifunctional electrocatalyst for electrocatalytic water splitting, exhibits excellent hydrogen evolution and oxygen evolution catalytic activities and stability at industrial-level current density, realizes the efficient and stable preparation of clean and green hydrogen energy, solves the disadvantages of low catalyst activity and poor stability in current industry, and provides an efficient solution to the increasingly serious environmental problems, having high practical application and economic value.

The invention provides an iridium-ruthenium oxide composite catalyst, a preparation method thereof and a proton exchange membrane water electrolysis device, and relates to the field of hydrogen production through water electrolysis. The preparation method of the iridium-ruthenium oxide composite catalyst comprises the following steps: mixing sodium nitrate, ruthenium chloride and water to prepare a mixed solution, and then drying and grinding to obtain a mixture; placing the mixture on the surface of nickel foil, carrying out first heating by using Joule heating equipment, and then cooling to obtain ruthenium oxide; mixing ruthenium oxide, hexadecyl trimethyl ammonium bromide and ethylene glycol, and performing ultrasonic dispersion to obtain a ruthenium oxide solution; and mixing the ruthenium oxide solution, H2IrCl6 and potassium hydroxide, adjusting the pH value of the system to be alkaline, then carrying out second heating until reflux and constant-temperature reaction, carrying out solid-liquid separation on the reaction product, and washing to obtain the iridium-ruthenium oxide composite catalyst. The iridium-ruthenium oxide composite catalyst provided by the invention has high activity, high stability and high water electrolysis efficiency.

The invention belongs to the technical field of water electrolysis hydrogen production catalysis, and particularly relates to a ruthenium molybdenum oxide nanorod electrocatalyst, a preparation method and application. In the electrocatalyst, the molar ratio of Mo to Ru is 1: 1-1: 9, and Mo atoms enter ruthenium oxide crystal lattices in the form of replacing Ru atoms; the method comprises the following steps: adding ammonium-containing molybdenum salt and NaNO3 crystals into a ruthenium salt solution, drying, grinding, calcining in air, cooling, and washing with deionized water to remove the NaNO3 crystals to obtain the electrocatalyst. According to the preparation method of the electrocatalyst, the problems of poor stability, high cost, complicated preparation and the like in the preparation process of an anode end catalyst in a proton exchange membrane water electrolysis hydrogen production technology are solved, the prepared electrocatalyst presents an ultra-small nanorod morphology, and a large number of edge and corner sites are generated for an oxygen production reaction; the Ru-O coordination structure of the electrocatalyst is in an unsaturated state, the Ru-O covalent interaction is significantly weakened, the introduction of Mo with low electronegativity inhibits the excessive oxidation of the electrocatalyst, and the oxygen production stability is high.

The invention belongs to the field of catalytic materials, and discloses yttrium-modified ruthenium oxide as well as a preparation method and application thereof. The method comprises the following steps: dissolving glucose and urea to obtain a solution a; ruCl3 and YCl3. 6H2O are added into the solution a, and a solution b is obtained; treating the solution b at 130-150 DEG C for 4-6 hours to form a porous foamed gel solid precursor; grinding the gel solid precursor into fine powder; and calcining to prepare ruthenium oxide modified by yttrium in different proportions. Yttrium-modified ruthenium oxide is prepared through a sol-gel method, and modification of yttrium not only reduces the loading capacity of precious metal, but also improves the activity and stability of the ruthenium oxide in acidic OER. Ruthenium oxide is modified by rare earth element yttrium, so that the electronic structure of the material is improved, the number of active sites is increased, rapid release of gas is facilitated, and the electrocatalytic activity and stability of the material are synergistically improved.

The invention provides a sulfur-doped ruthenium oxide catalyst as well as a preparation method and application thereof. The sulfur-doped ruthenium oxide catalyst comprises ruthenium oxide and sulfur doped in the ruthenium oxide; the doping rate of sulfur in the sulfur-doped ruthenium oxide catalyst is 0.4 at.%-3 at.%; the sulfur element is introduced into the ruthenium oxide crystal, so that trace ruthenium-oxygen bonds in the ruthenium oxide crystal are substituted by sulfur, and the activity of the ruthenium oxide catalyst is improved; detection shows that the sulfur-doped ruthenium oxide catalyst has excellent performance in an OER reaction, the 10mA cm <-2 > overpotential in an RDE test is 268-322mV, the lowest overpotential is only 268mV, and the sulfur-doped ruthenium oxide catalyst can continuously and stably run for 50 hours. And the preparation method of the sulfur-doped ruthenium oxide catalyst is simple, and the sulfur content in the sulfur-doped ruthenium oxide catalyst can be autonomously regulated and controlled through temperature, so that different properties are obtained.

The invention discloses a ruthenium oxide catalyzed diphenylamine bidirectional stable iodine electrode and application thereof in an aqueous battery, and belongs to the technical field of battery preparation. Loading ruthenium oxide and diphenylamine onto graphene through a physical adsorption method to obtain a RuO2 / DPA / C composite material; and mixing the RuO2 / DPA / C composite material with iodine, and carrying out a heating reaction to obtain the ruthenium oxide catalyzed diphenylamine bidirectional stable iodine electrode. And assembling by taking the ruthenium oxide catalyzed diphenylamine bidirectional stable iodine electrode as a positive electrode material to obtain the aqueous zinc ion battery. The preparation method comprises the following steps: loading ruthenium oxide and diphenylamine on graphene to prepare a bidirectional stable iodine electrode; the aqueous battery constructed by the electrode not only solves the stability problem of iodine positive and negative ions in electrolyte, avoids the use of chloride ions or bromide ions, realizes deep charging and discharging of the iodine electrode, but also avoids non-uniform deposition of intermediate iodine elementary substances through intermolecular compounding, and greatly improves the comprehensive performance of the battery.

According to the preparation method of the high-oxygen-vacancy ruthenium oxide catalyst, the catalyst is nanoparticles, and the chemical formula of the catalyst is ZnxRu1-xO2 (x is more than or equal to 0 and less than or equal to 1); the preparation method adopts a dual regulation and control method, that is, metal Zn doping is performed on RuO2, polyvinylpyrrolidone (PVP) is added as a protective agent, and the doping content, the morphology and the crystallinity of the catalyst are regulated and controlled by adjusting factors such as the amount of a zinc source and the amount of macromolecules and adjusting the reaction time, the reaction temperature and the annealing temperature. The RuO2-based catalyst with high oxygen vacancy, high stability and high catalytic activity is rapidly and efficiently synthesized under the dual action of PVP and metal Zn doping. The method is easy to operate, raw materials are cheap and easy to obtain, batch preparation can be achieved, multi-step preparation treatment does not need to be conducted on a sample, Zn-Ru-O of a nano-particle structure exposes a large active surface area, stability is high, catalytic activity is high, and the method is green and free of pollution.

The invention relates to the technical field of thick-film resistors, and discloses a high-sheet-resistance resistor paste, a preparation method thereof and a thick-film circuit. The resistance paste comprises 6%-24% of a composite conductive phase, 33%-57% of an inorganic binding phase, 2%-6% of a modifier and 22%-38% of an organic carrier. The conductive phase comprises nano-scale / submicron-scale ruthenium dioxide powder and submicron-scale flake silver powder, and the conductivity and the stability are cooperatively guaranteed. According to the preparation method, a secondary dispersing and grinding process is adopted, and a finished product is obtained through coarse grinding, vacuumizing fine grinding and 800-mesh filtering. The thick film circuit adopts an N-group parallel architecture, so that the use amount of conductive phases can be greatly reduced. The problem that traditional slurry is poor in stability under high sheet resistance is solved, TCR is smaller than or equal to 100 ppm / DEG C, resistance precision is within + / -5%, temperature and humidity stability is excellent, cost is low, and the slurry is suitable for high-precision heating scenes such as a new energy automobile heating system.

The invention relates to a cerium-tungsten co-doped ruthenium oxide catalyst capable of balancing lattice oxygen consumption and filling as well as a preparation method and application of the cerium-tungsten co-doped ruthenium oxide catalyst. According to the preparation method, LOM reaction is activated under a W-RuO2 stable framework by simultaneously utilizing a bridging effect of an AEM-OER catalyst and a promoting effect of CeOx on lattice oxygen vacancy filling, so that consumption and filling of lattice oxygen are balanced, dual optimization of stability and high activity of RuO2 in OER can be realized, and the preparation method is suitable for industrial production. The method effectively overcomes the defects that the technology for improving the stability of RuO2 by purely using W doping is at the cost of sacrificing activity and the technology for activating the lattice oxygen of RuO2 by purely using Ce doping is at the cost of sacrificing stability, and realizes dynamic balance of lattice oxygen consumption and supplement, so that the OER reaction of the LOM mechanism is stably operated, and the stability of the RuO2 is improved. The traditional technical bottleneck that activity and stability cannot be considered at the same time is broken through.

The invention discloses a methanol oxidation catalyst and a preparation method thereof, and relates to the field of catalysts. The nano titanium ruthenium oxide prepared by a low-temperature hydrothermal method is used as the carrier, the titanium ruthenium oxide crystal phase is of an anatase structure, the nano titanium ruthenium oxide crystal phase and the deposited nickel cobalt manganese metal form a composite structure, a synergistic effect is achieved, and the catalytic performance on methanol is improved. Titanium oxide ruthenium metal is pretreated and then soaked in a self-made water-phase nanometer nickel solution to form a first nanometer nickel metal layer, then surface modification is conducted through a silane coupling agent, then the first nanometer nickel metal layer is placed in a water-phase nanometer cobalt solution, the steps are repeated, a second nanometer cobalt particle layer and a third nanometer manganese particle layer are deposited, and the nanometer nickel metal layer is obtained. And finally, carrying out reduction treatment to obtain the methanol oxidation catalyst with the nano nickel-cobalt-manganese metal layer deposited by taking the titanium ruthenium oxide as the carrier. The catalyst prepared by the invention and methanol generate efficient chain exothermic reaction, the catalytic oxidation is complete, and the catalytic efficiency is high.

A method includes forming a semiconductor region, forming a gate spacer over the semiconductor region, forming a source / drain region aside of the semiconductor region, wherein the source / drain region is of p-type, and forming a gate dielectric over the semiconductor region. The gate dielectric is formed in a space between opposing portions of the gate spacer. A ruthenium oxide layer is formed over the gate dielectric, and acts as a part of a work-function layer of a gate electrode. The method further includes incorporating silicon into the ruthenium oxide layer.

A mixed metal oxide catalyst, particularly Pt and Ru containing oxide catalysts, based catalysts for polymer electrolyte membrane (PEM) fuel cells, water electrolysis, regenerative fuel cells (RFC) or oxygen generating electrodes in various electrolysis applications.

The application discloses a Ru-RE2O3 catalyst and a preparation method and application thereof, and the Ru-RE2O3 catalyst comprises a rare earth metal oxide RE2O3 shell and Ru inside. The catalyst is prepared from a carbon sphere carrier, a ruthenium salt and a rare earth metal salt through first calcination and second calcination. The first calcination is used for converting the ruthenium salt and the rare earth metal salt into corresponding oxides, and the second calcination is carried out under a reducing protective gas atmosphere, and the ruthenium oxide is selectively reduced, so that the Ru-RE2O3 catalyst with a core-shell structure is finally obtained. Compared with existing catalysts, the catalyst of the application forms a heterojunction between ruthenium and rare earth oxides and is uniformly loaded on the surface of the carbon sphere, the utilization rate of active sites is high, and the catalyst exhibits excellent water electrolysis catalytic activity, good mass transfer efficiency and stable cycle performance.

The invention relates to a method for electrochemically hydrogenating isophorone in a divided cell using H2O as a hydrogen source and in the presence of H2SO4 in anolyte and catholyte, wherein a pure-material electrode made of a material selected from graphite, nickel, and steel is used as the cathode and an electrode selected from solid-body and supported electrodes having an active material selected from platinum, graphite, boron-doped diamond, ruthenium oxide, platinum oxide, and / or iridium oxide is used as the anode.

The present invention discloses a preparation method and application of a ruthenium dioxide nanorod material. The preparation method comprises the following steps: (1) preparing a mixed solution of ammonium metatungstate and hydrated ruthenium trichloride; (2) injecting the mixed solution into an ethanol solution of potassium hydroxide in ultrasound using a microporous membrane syringe to obtain a solid precipitate; (3) rinsing the solid precipitate with ethanol to remove excess potassium hydroxide, separating and drying, and then performing high-temperature oxidation to obtain a tungsten oxide / ruthenium dioxide powder material; (4) adding the tungsten oxide / ruthenium dioxide powder material to deionized water for rinsing, separating and drying, and then performing high-temperature carbonization, and then performing secondary high-temperature oxidation to obtain a ruthenium dioxide nanorod material. The preparation method of the present invention has simple process operation and can effectively prevent nanoparticles from agglomerating. The present invention provides the application of the prepared ruthenium dioxide nanorod material as an electrocatalyst in a hydrogen-oxygen fuel cell, which can significantly improve the catalytic conversion efficiency.

The invention discloses an air electrode with an integrated structure as well as a preparation method and application thereof, and belongs to the technical field of zinc-air batteries. The preparation method comprises the following steps: dissolving polyvinyl alcohol in distilled water to prepare a polyvinyl alcohol aqueous solution; sequentially adding potassium hydroxide and zinc acetate into the polyvinyl alcohol aqueous solution, stirring and dissolving to prepare a gel electrolyte solution; freezing and unfreezing the gel electrolyte solution, and repeating for a plurality of times to prepare a PVA gel electrolyte; adding a carbon nanotube into a polyvinyl alcohol aqueous solution to prepare a carbon nanotube-PVA precursor solution, sucking the carbon nanotube-PVA precursor solution, dropwise adding the carbon nanotube-PVA precursor solution onto the PVA gel electrolyte, freezing and then unfreezing, and repeating for a plurality of times to prepare an integrated air electrode carrier; platinum carbon and ruthenium oxide are wetted with absolute ethyl alcohol, then polytetrafluoroethylene emulsion is added, grinding is performed to form a film, and a transparent film-shaped catalyst is prepared; and coating the transparent film-shaped catalyst on the upper surface of the integrated air electrode carrier to prepare the air electrode with an integrated structure. The technical problems of cathode overflow, catalyst loss and poor interface compatibility existing in an air electrode of an existing zinc-air battery can be solved.

An active cathode material for a chloride-ion battery according to the present invention is a strontium ruthenium oxide with a layered perovskite structure. A process for producing an active cathode material according to the present invention comprises (a) preparing a raw material mixture by mixing strontium carbonate and ruthenium oxide, (b) pelletizing the raw material mixture into pellets, and (c) firing the pellets. A cathode composite material for a chloride-ion battery according to the present invention comprises the active cathode material according to the present invention. The chloride-ion battery according to the present invention comprises a layer of active cathode material, and the layer of active cathode material contains the cathode composite material according to the present invention.

This invention relates to the field of biomass degradation technology, specifically to a ruthenium-based catalyst Ru@RuO2 supported by zirconium phosphate, its preparation method, and its application in catalyzing the hydrogenolysis of lignin. This invention is based on the in-situ reduction of elemental ruthenium to needle-like ruthenium oxide supported by amorphous zirconium phosphate, constructing a RuO2 / zirconium phosphate composite nanomaterial. This material can efficiently catalyze the hydrogenolysis of alkali-degraded lignin and model compounds such as α-O-4 and 4-O-5. Furthermore, the ruthenium nanoparticles generated from the in-situ reduction on ruthenium oxide exhibit high stability and can be reused multiple times.

The present invention discloses a neutral zinc-air fiber battery and a preparation method thereof, belonging to the technical field of batteries. Aiming at the problem in the prior art that due to too large bending stiffness, bending causes poor charge and discharge effects, the present invention provides a neutral zinc-air fiber battery and a preparation method thereof, which are assembled in a coaxial structure by a carbon nanotube / zinc powder composite fiber negative electrode, a double-layer gel electrolyte, and a platinum / ruthenium oxide modified carbon nanotube film positive electrode. The method steps are as follows: preparing a carbon nanotube / zinc powder composite fiber; preparing an organic gel electrolyte; preparing a hydrogel electrolyte precursor, and in-situ gelating the hydrogel electrolyte precursor on the composite fiber after curing with the organic gel electrolyte to obtain a fiber negative electrode wrapped with a double-layer gel; winding the platinum / ruthenium oxide nanoparticle modified carbon nanotube film positive electrode around the fiber negative electrode wrapped with the double-layer gel. It has a small bending stiffness and has a good charge and discharge curve for different degrees of bending.