A combustible 
cartridge case is provided that includes at least one energetic 
thermoplastic homopolymer or 
copolymer derived from, at least in part, poly(bis-azidomethyloxetane) 
prepolymer blocks terminated with 
isocyanate-reactive groups, such as hydroxyl groups. Chain linking of the 
prepolymer blocks is performed with diisocyanates for end-capping the 
prepolymer blocks, and a difunctional linking compound for linking the end-capped prepolymer blocks. The energetic 
thermoplastic is preferably capable of being pressed, extruded, rotational molded, injection loaded, or otherwise shaped into a desired configuration. Also provided is a chain-extended poly(bis-azidomethyloxetane) homopolymer derived from bis-azidomethyloxetane prepolymer blocks, which are terminated with 
isocyanate-reactive groups and chain extended with at least one diisocyanate end-capping compound and at least one difunctional linking compound.