7068 results about "Isocyanate" patented technology

The invention relates to an insulating weather-resistant powder coating and a preparation method thereof, and belongs to the technical field of coatings, and the powder coating comprises composite modified resin, a dual curing agent, a functional filler, a polyacrylate leveling agent, fumed silica, a benzotriazole ultraviolet light absorber, polytetrafluoroethylene wax powder and the like. A core-shell structure of the composite modified resin is designed, high insulativity is kept through a silane modified epoxy core layer, a weather-proof barrier is provided through an acrylic acid shell layer, and the phase separation problem is solved through interface chemical bonding; a dual-curing mechanism is designed, and isocyanate and acrylic hydroxyl react to form an interpenetrating network while an epoxy core layer is cured by anhydride; a filler synergistic effect is designed, silane coupling agent modified nano boron nitride forms a three-dimensional heat-conducting insulating network, and rutile type titanium dioxide is coated with silicon dioxide, so that ultraviolet aging is resisted. All the components cooperate with one another, so that the coating has excellent insulativity, weather resistance, adhesiveness and the like at the same time.

The invention discloses a method for preparing a modified PHA composite material by using a twin-screw extruder and application of the modified PHA composite material. The method comprises the following steps: carrying out in-situ melt blending on polyhydroxyalkanoate (PHA), poly (butylene adipate terephthalate)-poly (butylene adipate terephthalate) (PBAT), polyvinyl alcohol (PVOH) and chain extenders in a twin-screw extruder, so that the chain extenders such as polyfunctional group epoxy or isocyanate react with molecular terminal groups of the PHA, the PBAT and the PVOH to form a partially crosslinked or grafted structure; therefore, the compatibility is enhanced, the thermal stability is improved, and the barrier property is remarkably improved. Experiments prove that the obtained modified PHA composite material has the characteristics of high strength, high elongation, excellent water and oxygen resistance and biodegradability, and meets the strict requirements of multiple fields such as food packaging, agricultural plastic mulching films, medical consumables and the like on mechanical properties and barrier properties. The preparation method is simple, convenient and efficient, and large-scale continuous production can be achieved on existing double-screw extrusion equipment.

The invention belongs to the technical field of polyurethane elastomers, and particularly relates to a high-static-rigidity high-damping low-pressure-change polyurethane elastomer and a preparation method thereof. Comprising a polyol component and an isocyanate component, and the polyol component comprises polyol A, a chain extender, a stabilizer, a hydrolysis-resistant agent and a catalyst; the isocyanate component is prepared from isocyanate, polyhydric alcohol B and branched chain unit alcohol; the polyol A comprises amine ether polyol and polytetrahydrofuran ether polyol; the polyhydric alcohol B comprises bio-based hydrolysis-resistant polyhydric alcohol and polytetrahydrofuran ether polyhydric alcohol; the bio-based hydrolysis-resistant polyol is prepared by carrying out a reaction on sebacic acid, 1, 2-propylene glycol and 1, 4-butanediol; the branched-chain unit alcohol is prepared from tetrahydrofuran and isooctanol through a reaction. By introducing the bio-based hydrolysis-resistant polyhydric alcohol and branched chain monohydric alcohol, the damping effect is remarkably enhanced, and on this basis, through formula adjustment and raw material screening, the product toughness is greatly improved, the compression set is reduced, and the performance of the product in heavy haul railway application is effectively optimized.

The invention discloses a photopolymer type holographic recording medium and a preparation method and application thereof.The photopolymer type holographic recording medium comprises a writing monomer, film-forming resin, a photosensitive initiation combination agent and a catalyst, the writing monomer comprises nanoparticles and a polymerizable monomer, and the film-forming resin is prepared from the nanoparticles and the polymerizable monomer; the refractive index of the polymerizable monomer is smaller than that of the nanoparticles, and the difference between the refractive index of the nanoparticles and the refractive index of the polymerizable monomer is larger than 0.5. The film-forming resin includes a polyol compound and an isocyanate-based compound. The catalyst is used for catalyzing a polyol compound and an isocyanate compound to react to form a film. The photosensitive initiation combination agent is used for sensing light and inducing polymerization of the polymerizable monomer. According to the photopolymer type holographic recording medium disclosed by the invention, after exposure, the polymerizable monomers located in the bright area and the nanoparticles extruded to the dark area have relatively large refractive index difference, so that the refractive index modulation degree of the recording grating can be improved; the film-forming resin provides effective support for the nanoparticles, and the nanoparticles are not agglomerated.

The invention provides a PHA dispersion emulsion as well as a preparation method and application thereof, and belongs to the field of high polymer materials. The invention aims to solve the technical problem that the prior art cannot simultaneously meet the requirements of the polyhydroxyalkanoate water dispersion system on extremely low temperature natural film-forming property, excellent comprehensive performance after film formation and long-term storage stability. The method is characterized in that a polyhydroxyalkanoate polymer with specific molecular weight and polydispersity index range, a coalescing agent 2, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate with a specific chemical structure and a specific type of aliphatic polyisocyanate cross-linking agent compatible with water dispersion are strictly limited and combined. Through the synergistic effect generated by the unique ternary combination, the minimum film forming temperature of the prepared emulsion can be reduced to 6-10 DEG C, a film can be naturally formed without hot pressing, and the formed film has excellent mechanical property, water resistance and adhesive force and has excellent storage stability of at least one year.

The invention discloses an easy-to-apply single-component polyurethane waterproof coating and a preparation method thereof, and belongs to the technical field of waterproof coatings. The easy-to-apply single-component polyurethane waterproof coating disclosed by the invention is prepared from the following raw materials: polyol, a plasticizer, a solid filler, isocyanate, a catalyst and a solvent, the polyol comprises polyether glycol and polyether triol; the plasticizer comprises acetyl tributyl citrate; the catalyst comprises a bismuth neodecanoate catalyst and a dimorpholine diethyl ether catalyst. According to the easy-to-apply single-component polyurethane waterproof coating disclosed by the invention, acetyl tributyl citrate is used for replacing traditional plasticizer chlorinated paraffin, and a bismuth neodecanoate catalyst and a dimorpholine diethyl ether (DMDEE) catalyst are compounded, so that the viscosity of the waterproof coating is effectively reduced, and construction is facilitated; meanwhile, the drying speed of the waterproof coating is increased.

An aqueous ultraviolet-absorbing resin emulsion, and an aqueous resin emulsion composition containing the emulsion is provided, wherein the emulsion is excellent in compatibility with a synthetic resin and light resistance. Also, the emulsion improves stability in blending with an aqueous emulsion of the synthetic resin, and prevents bleed out of the ultraviolet-absorbing resin on the surface of a coating film. Further, the aqueous ultraviolet-absorbing resin emulsion imparts excellent alkali or solvent resistance to a synthetic resin poor in alkali or solvent resistance. More specifically, an aqueous resin emulsion composition comprising (I) an aqueous ultraviolet-absorbing resin emulsion and (II) an other aqueous resin emulsion is provided, wherein the emulsion (I) is obtained by urethanizing (A) a polyol component having an ultraviolet-absorbing group {e.g., 1,1-bis[3-(2H-benzotriazol-2-yl)-4-hydroxy-benzeneethanol]methane}, (B) a polyol if necessary, (C) an alkyl or aryl dialkanolamine compound, and (D) an organic polyisocyanate in (E) an organic solvent, diluting the reaction mixture with (F) an organic solvent having a boiling point lower than 100° C. to give a resin solution, neutralizing the resin solution with (G) a neutralizing agent, and dispersing the resultant in water.

The invention relates to a modified polyurethane elastomer and application of the modified polyurethane elastomer in preparation of bimodal cellular structure foam, and belongs to the technical field of foam forming. The invention provides a modified polyurethane elastomer. The modified polyurethane elastomer comprises the following components: a thermoplastic polyurethane elastomer, a polyisocyanate-based chain extender and an antioxidant component, in the modified polyurethane elastomer, the mass ratio of the thermoplastic polyurethane elastomer to the polyisocyanate chain extender to the antioxidant component is 1: (0.01-3): (0.05-1). According to the modified polyurethane elastomer, non-uniform chain extension modification is carried out on the thermoplastic polyurethane elastomer by introducing an insufficient amount of a polyisocyanate group chain extender, and the thermoplastic polyurethane elastomer foam obtained by foaming the modified polyurethane elastomer has a bimodal (big and small holes) foam structure; and the material has various excellent performances of light weight, heat insulation, sound insulation, buffering, high resilience and the like.

The invention relates to a flexible aqueous binder for a lithium battery negative electrode and a preparation method thereof. The preparation method comprises the following steps: firstly, preparing a flexible polyurethane prepolymer containing vinyl by taking hydroxyl-terminated polybutadiene, isocyanate and hydroxyl acrylate as main raw materials; vinyl-containing compounds such as water-soluble acrylic acid (salt) or acrylamide, oil-soluble acrylic ester or acrylonitrile and the like are used as monomers and are combined with a flexible polyurethane prepolymer to prepare the negative water-based binder with flexible cross-linking points through free radical polymerization. The aqueous binder prepared by the technical method provided by the invention can realize point-to-point and point-to-line bonding modes with a pole piece active substance on a microstructure, so that the bonding strength of the active layer material and a copper foil is improved on the premise of not influencing the electrolyte resistance of the binder; and the flexibility of the negative pole piece and the subsequent processing stability are obviously improved.

The invention discloses an INS film with excellent comprehensive performance, which comprises a surface protection layer, an upper base material layer, a printing ink layer, a bonding glue layer and a lower base material layer which are sequentially superposed from top to bottom, the surface protection layer is prepared from the following raw materials in parts by weight: 75-135 parts of polyester polyol resin, 30-60 parts of hydroxy acrylic resin, 2-25 parts of an isocyanate curing agent, 2-17 parts of a closed curing agent, 2-25 parts of a chain extender, 0.5-8 parts of a catalyst, 0.5-2 parts of an antioxidant and 0.5-3 parts of an ultraviolet light absorber. According to the surface protection layer of the INS film, the high-temperature condition of a high-temperature plastic uptake procedure of the INS film in preparation of INS parts is well utilized, so that the closed curing agent is effectively excited to perform secondary cross-linking curing reaction. The INS film is good in surface chemical reagent resistance, has the characteristics of high heat stretch rate, high hardness and scratch resistance, has excellent ultraviolet irradiation yellowing resistance, and is particularly suitable for the field of in-mold decoration.

The invention relates to the technical field of polyurethane coatings, in particular to a hydrophobic flame-retardant polyurethane coating and a preparation method thereof. The preparation method comprises the following steps: firstly, taking 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and methallyl alcohol as raw materials, and reacting to obtain hydroxyl grafted phosphaphenanthrene; taking 1, 1, 3, 3-tetramethyldisiloxane and methallyl alcohol as raw materials, and reacting according to a molar ratio of 1: 2 to obtain dihydroxy siloxane; then cyanuric chloride, hydroxyl grafted phosphaphenanthrene and dihydroxyl siloxane react according to the molar ratio of 1: 1: (1.5-1.8), and the dihydroxyl-terminated silicon-containing flame retardant is obtained. The preparation method comprises the following steps: mixing a dihydroxyl-terminated silicon-containing flame retardant with polytetrahydrofuran ether glycol to serve as a soft segment, and reacting with isocyanate to obtain a hydrophobic flame-retardant polyurethane emulsion; mixing the hydrophobic flame-retardant polyurethane emulsion, an anti-aging agent, an ultraviolet light absorber, a defoaming agent, kaolin, nano silicon dioxide and talcum powder to obtain the hydrophobic flame-retardant polyurethane coating.

The invention relates to polyurethane resin, synthetic leather and a preparation method and application thereof, and relates to the technical field of polyurethane, the polyurethane resin is prepared from the following raw materials: bio-based polyester polyol, polyolefin polyol, isocyanate, a chain extender, a pore-forming agent and a solvent; the bio-based polyester polyol is prepared from the following raw materials: bio-based dihydric alcohol, bio-based dibasic acid and micromolecular branched chain-containing dihydric alcohol. The polyurethane resin provided by the invention is high in bio-based content, micromolecular branched chain-containing dihydric alcohol is introduced into bio-based polyester polyol, a branched chain structure provides scratch resistance for the synthetic leather taking the polyurethane resin as a coating layer, the crystallinity of the polyurethane resin is reduced by compounding the polyolefin polyol, the synthetic leather is endowed with soft hand feeling, and the synthetic leather has the advantages that the synthetic leather is not prone to being scratched, and the service life of the synthetic leather is prolonged. Due to the addition of the chain extender and the pore-forming agent, the polyurethane has excellent foaming performance, the synthetic leather has excellent water absorption, and the hand feeling of the synthetic leather is further improved.

The invention discloses a lithium battery diaphragm with a self-repairing function and a preparation method thereof, and belongs to the field of lithium battery diaphragms. The lithium battery diaphragm comprises a polymer base membrane and a ceramic coating, the ceramic coating is coated on one side surface, facing the negative electrode, of the polymer base membrane or two side surfaces of the polymer base membrane; the ceramic coating comprises the following raw materials in parts by mass: 40-50 parts of modified ceramic particles, 4-8 parts of self-repairing microcapsules, 0.5-3 parts of a dispersing agent and 50-60 parts of water; the surfaces of the modified ceramic particles are grafted with amino-phenylboronic acid difunctional silane; chitosan / polyurethane is used as a wall material of the self-repairing microcapsule, and polyisocyanate is used as a core material of the self-repairing microcapsule. When the lithium ion diaphragm is stressed or punctured by dendritic crystals, the polyisocyanate can be released to react and crosslink, the generated cracks are closed, and an ion channel is reconstructed. Through the physical barrier of the ceramic coating and the self-repairing effect of the self-repairing microcapsule, the mechanical strength and the ion transmission performance of the lithium battery diaphragm can be effectively maintained.

The invention relates to the field of optical protection materials, and provides a transparent film with laser eavesdropping prevention performance and a preparation method thereof.The transparent film is composed of surface-modified doped tungsten oxide nanosheets, amino-isocyanate bifunctional lithium niobate nanowires, urethane acrylate, an ultraviolet light absorber, a silane coupling agent, a dispersing agent and a flatting agent; the molybdenum-doped tungsten oxide nanosheets are obtained through silane coupling modification after hydrothermal synthesis, and the lithium niobate nanowires are prepared through a gradient modification process of hydrothermal synthesis-silane coupling-isocyanate grafting-phenol end capping. A modified nano material is uniformly dispersed in a resin matrix through an ultrasonic dispersion composite technology, and through blade coating forming, ultraviolet curing and constant-temperature and constant-humidity post-treatment, compared with the prior art, the scheme overcomes the problems that a traditional protective film is insufficient in optical transparency, laser eavesdropping prevention function and dynamic viscoelasticity, and is suitable for the field of high-end security and protection.

The invention belongs to the technical field of lithium ion batteries, and particularly relates to a self-repairing type lithium ion battery positive electrode adhesive, a preparation method, positive electrode slurry and a positive electrode plate. The adhesive comprises a mixed solvent, and a first copolymer serving as a main component and a second copolymer serving as a cross-linking agent are dissolved in the mixed solvent; the first copolymer is an acrylate-based multipolymer containing carboxyl or hydroxyl; the second copolymer is isocyanate terminated UPy functional polyurethane; the adhesive is in a liquid state at room temperature, when the adhesive is subjected to vacuum heat treatment at 60-180 DEG C, carboxyl or hydroxyl in main components of the adhesive reacts with isocyanate groups of a cross-linking agent to form amido bonds along with volatilization of a mixed solvent, and UPy groups are associated through quadruple hydrogen bonds to form dual dynamic cross-linking points. The method can effectively adapt to the volume change of the positive electrode material in the lithium removal / insertion process, and maintains the integrity of the electrode structure, thereby improving the cycling stability and rate capability of the lithium ion battery.

The invention provides a polyurethane modified epoxy resin material for a prepreg and a preparation method of the polyurethane modified epoxy resin material. Comprising 10-35 parts by weight of polyester or polyether polyol, 1-10 parts by weight of isocyanate, 40-70 parts by weight of epoxy resin, 1-3 parts by weight of a light stabilizer, 1-2 parts by weight of an antioxidant, 1-2 parts by weight of an ultraviolet absorbent and 5-30 parts by weight of a chain extender and a curing agent. According to the invention, the intrinsic flexible epoxy resin is prepared by grafting modification of the polyurethane prepolymer, and is applied to a prepreg resin system and a medium-temperature cured carbon fiber prepreg, so that the brittleness of the epoxy resin is improved, and the elongation at break of the epoxy resin is improved, thereby realizing a toughening effect and a composite material forming process.

The invention relates to the technical field of coatings, in particular to a modified FEVE fluorocarbon resin coating and a preparation method thereof. The problem that the FEVE fluorocarbon coating is poor in durability is solved. The preparation method comprises the following steps: modifying FEVE fluorocarbon resin with linoleic acid to obtain a granular material; stirring the modified FEVE fluorocarbon resin, polyisocyanate, montmorillonite and a composite solvent to obtain a prepolymer; pre-dispersing and grinding silicon carbide, modified zinc oxide, a dispersing agent and a composite solvent, adding nano composite particles for ultrasonic dispersion, and adding a prepolymer and a flatting agent to obtain the modified FEVE fluorocarbon resin coating. Wherein the FEVE fluorocarbon resin is modified, so that the crosslinking speed, the coating strength and the adhesive force are improved, the stain resistance, the weather resistance and the corrosion resistance are improved through the nano composite particles and the like, and finally the durability of the FEVE fluorocarbon resin coating is improved.

The invention relates to a Fenton-like functional filler which is prepared from 10-20% of iron particles coated with a carbonized film, 10-20% of aluminum sulfate modified straw, 20-30% of PBAT-coated calcium peroxide, 20-30% of diatomite and 10-30% of an adhesive. A processing method of a Fenton-like functional filler comprises the following steps: uniformly mixing iron particles coated with a carbonized film, aluminum sulfate modified straws, PBAT-coated calcium peroxide and diatomite, then adding an adhesive, mixing isocyanate serving as the adhesive with polyol according to a volume ratio of 1: 5, and continuously and uniformly mixing; then the mixed raw materials are injected into a mold coated with a release agent in advance, the mold temperature ranges from 40 DEG C to 60 DEG C, the foaming curing time ranges from 15 min to 20 min, and the Fenton-like functional filler can be obtained. The invention relates to an application of a Fenton-like functional filler in constructed wetlands. The method has the beneficial effects that the method is not influenced by temperature, and the removal effect of the constructed wetland on nitrate nitrogen and refractory COD (Chemical Oxygen Demand) can be obviously enhanced.

The invention discloses an electrolyte additive composition, an electrolyte, a battery and an electric device. The electrolyte additive composition comprises an impedance stabilizing additive and an isocyanate additive in a weight ratio of (0.1-0.8): 1. According to the electrolyte additive composition, the impedance stabilizing additive and the isocyanate additive are compounded, and the content ratio of the impedance stabilizing additive and the isocyanate additive is regulated, so that the stability of the impedance stabilizing additive in the electrolyte can be improved, the DCR of a battery cell is reduced, the stability of the DCR of the battery cell in the charging, discharging and storage processes is improved, and the service life of the battery cell is prolonged. Therefore, the RTE of the battery in the service period is improved. The electrolyte contains the electrolyte additive composition, and the battery contains the electrolyte. The electric device comprises the battery.

The invention discloses a low-temperature-resistant hydrolysis-resistant polyurethane protector material and a preparation method thereof. The low-temperature-resistant hydrolysis-resistant polyurethane protector material is prepared from a component A and a component B through cross-linking and curing, wherein the component A is prepared from polyether polyol, bifunctional hydroxyl-terminated polysiloxane, modified polyborosiloxane, a cross-linking agent, a chain extender, a foaming agent, a foam stabilizer, a catalyst and a pore opening agent, and the component B is isocyanate. The protective clothing prepared from the material has excellent buffer energy absorption performance, low temperature resistance and hydrolysis resistance, and meets the use requirements in extremely cold weather.

The invention discloses a temperature-resistant waterproof polyurethane coating and a preparation method thereof, and belongs to the technical field of polyurethane coatings, the temperature-resistant waterproof polyurethane coating comprises the following components by mass: 80-90 parts of a polyurethane prepolymer, 1-1.5 parts of a reinforcing filler, 2-3 parts of a composite curing agent and 7-9 parts of polyether glycol; the polyurethane prepolymer is prepared by the following steps: stirring and mixing a fluororubber grafted solution and polyester polyol in a reaction kettle, heating to 70-80 DEG C under the protection of nitrogen, adding an isocyanate mixture, and stirring and reacting for 2-3 hours to obtain the polyurethane prepolymer; according to the temperature-resistant waterproof polyurethane coating prepared by the preparation method disclosed by the invention, the-NCO group is terminated, so that the coating has good stability before curing, is not easy to react with moisture in air and has good moisture resistance before curing, and the fluororubber, the reinforcing filler and the polyurethane waterproof coating are mixed, so that a cross-linked network of the cured polyurethane waterproof coating is enhanced; the mechanical property and the temperature resistance of the cured polyurethane waterproof coating are improved.

The invention relates to the technical field of coatings, and discloses a wear-resistant waterborne polyurethane finish paint and a preparation method thereof. The wear-resistant waterborne polyurethane finish paint comprises a component A and a component B in a mass ratio of (4-7): 1, the component A is prepared from the following components in parts by mass: 50 to 60 parts of waterborne polyurethane, 10 to 15 parts of hyperbranched polysiloxane, 2 to 3 parts of polyoxyethylene fatty acid, 0.8 to 1.2 parts of a de-foaming agent, 6 to 8 parts of color paste and 10 to 15 parts of water; and the component B comprises an isocyanate curing agent. The wear-resistant waterborne polyurethane finish paint prepared in the invention has excellent adhesion strength and wear resistance.

The invention discloses a silane cross-linked polyolefin halogen-free flame-retardant cable material and a low-energy-consumption preparation method thereof.The preparation method comprises the steps that EVA / EEA serves as a matrix, silane groups are covalently connected to a polyolefin molecular chain through a free radical grafting reaction, and a grafting material containing an active silane side group is prepared; meanwhile, vinyl isocyanate is adopted to chemically modify hydroxyl on the surface of magnesium hydroxide, vinyl is grafted to the surfaces of particles, the polarity of the particles is reduced, and the dispersity of the particles is enhanced; then carrying out melt blending on the grafted material and modified magnesium hydroxide, constructing an interface bridge by using an anhydride group, and shortening the two-phase distance; finally, through room-temperature natural cross-linking and warm water auxiliary cross-linking, silane groups are promoted to be hydrolyzed into silanol, the silanol is condensed to form a-Si-O-Si-three-dimensional network, meanwhile, vinyl on the surface of magnesium hydroxide and a polyolefin matrix are subjected to free radical copolymerization, and a covalent bond interface layer is formed between inorganic particles and an organic matrix. According to the method, the synergistic improvement of high crosslinking degree, strong stretchability and excellent flame retardance of the cable material is realized through molecular-level interface regulation and cross-linking network optimization.

The present invention relates to a preparation method of a flame-retardant, high-refractive-index, melt-drop resistant waterborne polyurethane coating. A diol, an isocyanate and dibutyltin dilaurate are added to a 500 mL flask, and the temperature is raised to 70-85 °C, and the mixture is stirred and reacted for 1-2 h to obtain a polyurethane prepolymer; then a charring agent is added to the polyurethane prepolymer, and the reaction is continued for 1-2 h; the temperature is lowered to 60 °C, and then 2,2-dimethylolbutyric acid and amino carbon nanotubes are added and reacted for 0.5-1 h; then a high-refractive-index material is added, and the reaction is carried out at 65-70 °C for 1-2 h, the temperature is lowered to 40 °C, and then triethylamine is added and reacted for 0.5-1 h; deionized water is added, and at a rotation speed of 2000 r / min, an ammonium polyphosphate solution is added, and high-speed shear emulsification is carried out for 0.5-1 h to obtain a flame-retardant, high-refractive-index, melt-drop resistant waterborne polyurethane coating. This polyurethane coating has high flame retardancy, high refractive index and no melt-dropping property.

The invention relates to the technical field of waterproof agents for fabrics, and particularly discloses a fluoride-free waterproof agent for fabrics and a preparation method of the fluoride-free waterproof agent. The preparation method specifically comprises the following steps: dehydrating polyol / ester, adding isocyanate, heating to 80-90 DEG C, reacting for 2-3 hours, cooling, dropwise adding a chain extender, reacting for 0.5-1 hour at 45-48 DEG C, adding POSS, stirring for 1-2 hours at 45-48 DEG C, adding an acrylic monomer A for blocking, cooling, dropwise adding acid, stirring and neutralizing to obtain a prepolymer; pouring the prepolymer into water, stirring and emulsifying to obtain a POSS-PU emulsion; quickly stirring the POSS-PU emulsion, an acrylic monomer B, an emulsifier, water, a co-emulsifier, a pH regulator and the like to obtain a composite emulsion; homogenizing the composite emulsion until the composite emulsion has obvious blue light; and adding dodecanethiol and an azo amidine initiator, reacting at 68-70 DEG C for 3-7 hours, cooling, filtering and taking out to obtain the fluoride-free waterproof agent.

The invention discloses an adhesive containing epoxy-terminated polyurethane epoxy resin as well as a preparation method and application of the adhesive. The adhesive comprises the following components in parts by weight: 10-15 parts of epoxy resin, 70-75 parts of epoxy-terminated polyurethane epoxy resin, 19-21 parts of an amine curing agent and 8-15 parts of heat-conducting filler, wherein the epoxy-terminated polyurethane epoxy resin is obtained by reacting a polyurethane prepolymer and epoxy resin, NCO of the polyurethane prepolymer and hydroxyl of the epoxy resin are subjected to an addition reaction, and after the reaction is finished, NCO of a system is eliminated by adopting a small-molecule epoxy compound; the polyurethane prepolymer is obtained by reaction of isocyanate and polyether polyol with flexible chain segments. According to the adhesive, the curing heat release peak value is reduced, the toughness is improved, meanwhile, the high strength is kept, the foaming problem is avoided, the defects that a traditional epoxy adhesive is high in heat release and poor in toughness are overcome, and the adhesive is suitable for the fields such as aerospace and electronic and electric appliances which have strict performance requirements.

The invention relates to a method for producing a polymer composition, in which a silane-modified polymer is polymerized by free-radical chain polymerization with an ethylenically unsaturated monomer and a further ethylenically unsaturated polymer having a free-radical photoinitiator group in a polyol or a prepolymer having terminal isocyanate groups, and to a polymer composition produced by this process. The invention also relates to a method for producing moisture-curable polyurethane hot melt adhesive compositions, 1K polyurethane adhesives and 2K polyurethane adhesives on the basis of the polymer composition according to the invention. The invention also relates to moisture curable polyurethane hot melt adhesive compositions, 1K polyurethane adhesives and 2K polyurethane adhesives produced by these methods.

The invention relates to the technical field of polyurethane adhesives, in particular to an adhesive for tooling polished aluminum and a preparation method thereof. The adhesive comprises a component A and a component B, wherein the raw materials for preparing the component A comprise at least 25-40 parts of a polyol composition, 50-75 parts of a calcium filler, 0.1-0.3 parts of a dispersant, 0.1-0.3 parts of a catalyst, 1-4 parts of a molecular sieve, 0.01-0.2 parts of a defoamer and 0.1-0.5 parts of nano silicon dioxide, and the component B comprises at least isocyanate. By controlling the selection and coordination of the polyol, the dispersant and the catalyst in the system and the addition amount of each raw material, when the provided adhesive is used for bonding the polished aluminum (1-2 mm) to a honeycomb panel, the roller peel strength is ≥60 N*mm / mm, thereby meeting the actual external wall application requirements.

The invention provides highly phase-separated polyurethane as well as a preparation method and application thereof, and belongs to the technical field of high polymer materials. The highly-phase-separated polyurethane is prepared from the following raw materials: hydrophilic modified polyether polyol, an isocyanate monomer, a catalyst and a chain extender, the hydrophilic modified polyether polyol is prepared from the following raw materials: a ring-opening initiator and an epoxy compound; the ring-opening initiator comprises dihydroxy carboxylic acid and / or dihydroxy sulfonate. The highly-phase-separated polyurethane is clear and stable in microphase structure and has excellent mechanical properties and water resistance.

The invention discloses a preparation method of a flame-retardant, light-emitting and recoverable transparent polyurethane material, which comprises the following steps: reacting triethanolamine with diphenylphosphonyl chloride to obtain a light-emitting flame retardant, and polymerizing the light-emitting flame retardant with polyether polyol, isocyanate and a chain extender to obtain the flame-retardant, light-emitting and recoverable transparent polyurethane material, the preparation method is simple, the process is easy to control, the prepared transparent polyurethane material can keep high tensile strength, the limit oxygen index can reach 30.3, the UL-94 grade reaches the V-0 grade, and the flame retardant effect is good; in addition, due to high transparency and fluorescence, the compound can be used as a light conversion film to be applied to a flexible solar cell, so that the photoelectric conversion efficiency of the flexible solar cell is improved.