11318 results about "Isocyanate" patented technology

The invention relates to the technical field of polyurethane production, in particular to a polyurethane super-hydrophobic foam composite material for packaging and a preparation method thereof. The polyurethane super-hydrophobic foam composite material for packaging is prepared by reacting a component A and a component B according to a mass ratio of 100: (31.7-46.5), wherein the component A comprises polyether polyol X with high molecular weight and high activity, polymer polyol, a chain extender, a cross-linking agent, an organic metal catalyst, a tertiary amine catalyst, a foam stabilizer, a foaming agent, a flame retardant, inorganic filler and the like, and the component B is isocyanate modified by polyether polyol Y with high functionality. An ester bond, a rigid benzene ring group and a Si-O-Si chain segment are introduced into a polyether polyol molecular chain segment to improve the internal soft segment structure and chemical crosslinking density of the polyurethane foam, and the prepared super-hydrophobic polyurethane foam not only has excellent hydrophobicity and high temperature resistance, but also is low in density and good in mechanical property.

To provide a technique for a polyurethane foam that can contribute to environmental conservation.SOLUTION: The present technique is directed to a polyurethane foam derived from a composition containing a polyol and an isocyanate, where the polyol contains a polyetherpolyol with a weight average molecular weight of 1200 or more and a polyol with a molecular weight of 300 or less. The polyurethane foam according to the present technique may have a silicone content of 0.25 ppm or less as measured in accordance with VDA278-based methods.SELECTED DRAWING: None

The invention relates to an insulating weather-resistant powder coating and a preparation method thereof, and belongs to the technical field of coatings, and the powder coating comprises composite modified resin, a dual curing agent, a functional filler, a polyacrylate leveling agent, fumed silica, a benzotriazole ultraviolet light absorber, polytetrafluoroethylene wax powder and the like. A core-shell structure of the composite modified resin is designed, high insulativity is kept through a silane modified epoxy core layer, a weather-proof barrier is provided through an acrylic acid shell layer, and the phase separation problem is solved through interface chemical bonding; a dual-curing mechanism is designed, and isocyanate and acrylic hydroxyl react to form an interpenetrating network while an epoxy core layer is cured by anhydride; a filler synergistic effect is designed, silane coupling agent modified nano boron nitride forms a three-dimensional heat-conducting insulating network, and rutile type titanium dioxide is coated with silicon dioxide, so that ultraviolet aging is resisted. All the components cooperate with one another, so that the coating has excellent insulativity, weather resistance, adhesiveness and the like at the same time.

The invention discloses a method for preparing a modified PHA composite material by using a twin-screw extruder and application of the modified PHA composite material. The method comprises the following steps: carrying out in-situ melt blending on polyhydroxyalkanoate (PHA), poly (butylene adipate terephthalate)-poly (butylene adipate terephthalate) (PBAT), polyvinyl alcohol (PVOH) and chain extenders in a twin-screw extruder, so that the chain extenders such as polyfunctional group epoxy or isocyanate react with molecular terminal groups of the PHA, the PBAT and the PVOH to form a partially crosslinked or grafted structure; therefore, the compatibility is enhanced, the thermal stability is improved, and the barrier property is remarkably improved. Experiments prove that the obtained modified PHA composite material has the characteristics of high strength, high elongation, excellent water and oxygen resistance and biodegradability, and meets the strict requirements of multiple fields such as food packaging, agricultural plastic mulching films, medical consumables and the like on mechanical properties and barrier properties. The preparation method is simple, convenient and efficient, and large-scale continuous production can be achieved on existing double-screw extrusion equipment.

The invention provides anti-aging polyurethane-zirconium phosphate composite modified asphalt and a preparation method thereof, and belongs to the technical field of building material preparation. The anti-aging polyurethane-zirconium phosphate composite modified asphalt is prepared from the following components in parts by weight: 100 parts of matrix asphalt, 3 to 15 parts of an isocyanate prepolymer, 1 to 8 parts of organic zirconium phosphate, 0.001 to 0.1 part of a catalyst and 2 to 5 parts of a solubilizer, wherein the organic zirconium phosphate is prepared by carrying out ultrasonic intercalation treatment on zirconium phosphate by adopting organic molecules. Compared with the traditional polyurethane modified asphalt, the organic zirconium phosphate in the anti-aging polyurethane-zirconium phosphate composite modified asphalt has a polyurethane cross-linked network structure, can effectively improve the high and low temperature performance of the asphalt, has a layered structure, can absorb ultraviolet rays, and can effectively improve the anti-aging performance of the asphalt. Therefore, organic molecules in the polyurethane asphalt are protected from being oxidized, the anti-aging performance is excellent, and the service life of an asphalt pavement is prolonged.

The invention belongs to the technical field of polyurethane elastomers, and particularly relates to a high-static-rigidity high-damping low-pressure-change polyurethane elastomer and a preparation method thereof. Comprising a polyol component and an isocyanate component, and the polyol component comprises polyol A, a chain extender, a stabilizer, a hydrolysis-resistant agent and a catalyst; the isocyanate component is prepared from isocyanate, polyhydric alcohol B and branched chain unit alcohol; the polyol A comprises amine ether polyol and polytetrahydrofuran ether polyol; the polyhydric alcohol B comprises bio-based hydrolysis-resistant polyhydric alcohol and polytetrahydrofuran ether polyhydric alcohol; the bio-based hydrolysis-resistant polyol is prepared by carrying out a reaction on sebacic acid, 1, 2-propylene glycol and 1, 4-butanediol; the branched-chain unit alcohol is prepared from tetrahydrofuran and isooctanol through a reaction. By introducing the bio-based hydrolysis-resistant polyhydric alcohol and branched chain monohydric alcohol, the damping effect is remarkably enhanced, and on this basis, through formula adjustment and raw material screening, the product toughness is greatly improved, the compression set is reduced, and the performance of the product in heavy haul railway application is effectively optimized.

The invention discloses a photopolymer type holographic recording medium and a preparation method and application thereof.The photopolymer type holographic recording medium comprises a writing monomer, film-forming resin, a photosensitive initiation combination agent and a catalyst, the writing monomer comprises nanoparticles and a polymerizable monomer, and the film-forming resin is prepared from the nanoparticles and the polymerizable monomer; the refractive index of the polymerizable monomer is smaller than that of the nanoparticles, and the difference between the refractive index of the nanoparticles and the refractive index of the polymerizable monomer is larger than 0.5. The film-forming resin includes a polyol compound and an isocyanate-based compound. The catalyst is used for catalyzing a polyol compound and an isocyanate compound to react to form a film. The photosensitive initiation combination agent is used for sensing light and inducing polymerization of the polymerizable monomer. According to the photopolymer type holographic recording medium disclosed by the invention, after exposure, the polymerizable monomers located in the bright area and the nanoparticles extruded to the dark area have relatively large refractive index difference, so that the refractive index modulation degree of the recording grating can be improved; the film-forming resin provides effective support for the nanoparticles, and the nanoparticles are not agglomerated.

The invention provides a PHA dispersion emulsion as well as a preparation method and application thereof, and belongs to the field of high polymer materials. The invention aims to solve the technical problem that the prior art cannot simultaneously meet the requirements of the polyhydroxyalkanoate water dispersion system on extremely low temperature natural film-forming property, excellent comprehensive performance after film formation and long-term storage stability. The method is characterized in that a polyhydroxyalkanoate polymer with specific molecular weight and polydispersity index range, a coalescing agent 2, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate with a specific chemical structure and a specific type of aliphatic polyisocyanate cross-linking agent compatible with water dispersion are strictly limited and combined. Through the synergistic effect generated by the unique ternary combination, the minimum film forming temperature of the prepared emulsion can be reduced to 6-10 DEG C, a film can be naturally formed without hot pressing, and the formed film has excellent mechanical property, water resistance and adhesive force and has excellent storage stability of at least one year.

The invention discloses a bio-based polyurethane coating and a preparation method thereof, and belongs to the technical field of coatings. The bio-based polyurethane coating comprises the following raw materials in parts by weight: 100 parts of vegetable oil polyol, 70-120 parts of isocyanate, 10-25 parts of a flame retardant, 30-40 parts of an organic solvent, 1-5 parts of a catalyst, 10-30 parts of a hydrophilic chain extender, 10-30 parts of a neutralizer and 20-40 parts of deionized water. The preparation method comprises the following steps: adding plant polyol, isocyanate, a flame retardant, an organic solvent and a catalyst into a container, mixing and reacting to obtain a prepolymer mixed solution, then adding a hydrophilic chain extender, mixing and reacting to obtain a polymer mixed solution, cooling, then adding a neutralizer for neutralizing, then adding deionized water for emulsifying to form a polyurethane emulsion, and finally adding a curing agent for curing. And performing reduced pressure distillation to obtain the bio-based polyurethane coating. According to the invention, biomass-sourced acid reacts with the organosilicon compound to generate the flame retardant, and the prepared bio-based polyurethane coating has good flame retardant property.

The invention discloses an easy-to-apply single-component polyurethane waterproof coating and a preparation method thereof, and belongs to the technical field of waterproof coatings. The easy-to-apply single-component polyurethane waterproof coating disclosed by the invention is prepared from the following raw materials: polyol, a plasticizer, a solid filler, isocyanate, a catalyst and a solvent, the polyol comprises polyether glycol and polyether triol; the plasticizer comprises acetyl tributyl citrate; the catalyst comprises a bismuth neodecanoate catalyst and a dimorpholine diethyl ether catalyst. According to the easy-to-apply single-component polyurethane waterproof coating disclosed by the invention, acetyl tributyl citrate is used for replacing traditional plasticizer chlorinated paraffin, and a bismuth neodecanoate catalyst and a dimorpholine diethyl ether (DMDEE) catalyst are compounded, so that the viscosity of the waterproof coating is effectively reduced, and construction is facilitated; meanwhile, the drying speed of the waterproof coating is increased.

An aqueous ultraviolet-absorbing resin emulsion, and an aqueous resin emulsion composition containing the emulsion is provided, wherein the emulsion is excellent in compatibility with a synthetic resin and light resistance. Also, the emulsion improves stability in blending with an aqueous emulsion of the synthetic resin, and prevents bleed out of the ultraviolet-absorbing resin on the surface of a coating film. Further, the aqueous ultraviolet-absorbing resin emulsion imparts excellent alkali or solvent resistance to a synthetic resin poor in alkali or solvent resistance. More specifically, an aqueous resin emulsion composition comprising (I) an aqueous ultraviolet-absorbing resin emulsion and (II) an other aqueous resin emulsion is provided, wherein the emulsion (I) is obtained by urethanizing (A) a polyol component having an ultraviolet-absorbing group {e.g., 1,1-bis[3-(2H-benzotriazol-2-yl)-4-hydroxy-benzeneethanol]methane}, (B) a polyol if necessary, (C) an alkyl or aryl dialkanolamine compound, and (D) an organic polyisocyanate in (E) an organic solvent, diluting the reaction mixture with (F) an organic solvent having a boiling point lower than 100° C. to give a resin solution, neutralizing the resin solution with (G) a neutralizing agent, and dispersing the resultant in water.

The invention discloses a preparation method of a non-additive nitrogen-phosphorus-cerium synergistic flame-retardant polyurethane elastomer, and the polyurethane elastomer is prepared by taking isocyanate as a hard segment and poly (1, 4-butanediol adipate) as a soft segment, and compounding the hard segment and the soft segment with 2-amino-4-hydroxy-6-methylpyrimidine, a phosphorus reactive flame retardant and cerium oxide. The preparation method is simple, the process is easy to control, and the prepared polyurethane elastomer has good tensile strength; besides, the limit oxygen index of the polyurethane elastomer reaches 27.4, the polyurethane elastomer meets commercial standards of flame-retardant materials and UL-94 V-0 flame-retardant grade requirements, the ultraviolet band light transmittance is 0%, ultraviolet rays can be completely isolated, and the polyurethane elastomer has a good anti-oxidation function and can be applied to the industries of wires, cables, pipe profiles, films, general molding and the like.

The invention belongs to the field of preparation of non-isocyanate polyurethane, and particularly relates to a preparation method of an extreme-environment-resistant non-isocyanate polyurethane adhesive, which comprises the following steps: preparing a cyclic carbonate monomer containing a rigid structure, selecting the type of di / polyamine, and adjusting the ratio of a flexible chain segment amine compound to a rigid amine compound, thereby obtaining the extreme-environment-resistant non-isocyanate polyurethane adhesive. A series of non-isocyanate polyurethane adhesives with excellent mechanical properties are prepared, and controllability of bonding strength and extreme environment resistance is realized. The adhesive disclosed by the invention is simple in synthesis method, reaction conditions are easy to control, and the lap joint shear strength of bonded Al can reach 16.7 MPa; the lap joint shear strength at the low temperature of-196 DEG C reaches 15.6 MPa; and the overlapping shear strength at the high temperature of 190 DEG C reaches 15.2 MPa. After a bonded sample is soaked in a solvent for 24 h, the lap shear strength can still be maintained at 15.4 MPa or above and can reach 16.5 MPa, and the adhesive can be widely applied to the fields of aerospace, medical instruments, chemical product packaging and the like and has good market prospects.

The invention relates to the technical field of layered composite fabrics, in particular to an antibacterial breathable bio-based composite fabric and a preparation method thereof. The composite fabric comprises a two-layer structure of an inner-layer fabric and an outer-layer fabric, the inner-layer fabric is prepared from a bio-based material polylactic acid, the outer-layer fabric is prepared from bio-based materials polyamide fibers and polyester fibers, the polylactic acid is subjected to modification treatment, graphene oxide is introduced, quaternary ammonium salt is generated, the composite fabric has excellent antibacterial performance, and the antibacterial performance of the composite fabric is improved. The preparation method of the antibacterial modified polylactic acid comprises the following steps: reacting graphene oxide with 1-dimethoxy (methyl) silicon methyl isocyanate to prepare isocyanate-based graphene oxide; reacting the isocyanate-based graphene oxide with polylactic acid to prepare graphene oxide modified polylactic acid; reacting the graphene oxide modified polylactic acid with epoxidized soybean oil and amino modified graphene oxide to prepare modified polylactic acid; and carrying out quaternization reaction on the modified polylactic acid and bromoethanol to generate the antibacterial modified polylactic acid.

The invention discloses a multifunctional electronic product screen protective film and a preparation method thereof. The protective film comprises a modified base film and a multifunctional composite layer compounded on the surface of the modified base film, the multifunctional composite layer comprises an elastic buffer layer and a self-repairing layer which are sequentially arranged from inside to outside; wherein the elastic buffer layer is an elastic buffer layer with gradient density; the elastic buffer layer comprises the following components in parts by weight: 100 parts of a thermoplastic polyurethane elastomer, 15-25 parts of hollow glass microspheres, 10-15 parts of polyethylene glycol and 3-6 parts of an isocyanate cross-linking agent; the self-repairing layer comprises the following components in parts by weight: 100 parts of a dynamic reversible covalent bond polymer, 30-40 parts of phase change material microcapsules, 10-15 parts of nano cellulose, 5-8 parts of a near-infrared photosensitive initiator and 2-4 parts of an antioxidant. Compared with the prior art, the protective film provided by the invention has excellent scratch self-repairing performance, good adhesion and high anti-explosion screen performance.

The invention relates to a modified polyurethane elastomer and application of the modified polyurethane elastomer in preparation of bimodal cellular structure foam, and belongs to the technical field of foam forming. The invention provides a modified polyurethane elastomer. The modified polyurethane elastomer comprises the following components: a thermoplastic polyurethane elastomer, a polyisocyanate-based chain extender and an antioxidant component, in the modified polyurethane elastomer, the mass ratio of the thermoplastic polyurethane elastomer to the polyisocyanate chain extender to the antioxidant component is 1: (0.01-3): (0.05-1). According to the modified polyurethane elastomer, non-uniform chain extension modification is carried out on the thermoplastic polyurethane elastomer by introducing an insufficient amount of a polyisocyanate group chain extender, and the thermoplastic polyurethane elastomer foam obtained by foaming the modified polyurethane elastomer has a bimodal (big and small holes) foam structure; and the material has various excellent performances of light weight, heat insulation, sound insulation, buffering, high resilience and the like.

The invention relates to the field of polyurethane coating processing, in particular to a waterproof bio-based polyurethane coating and a preparation technology thereof.The waterproof bio-based polyurethane coating is prepared from, by weight, 25%-40% of castor oil polyester polyol, 15%-25% of isocyanate, 5%-10% of bio-based polybasic acid, 0.2%-0.6% of a catalyst, 0.5%-1% of a chain extender, 15%-20% of modified nanofiller, 3%-5% of a wetting agent and 1%-2% of a curing agent. By adopting the formula, the prepared waterproof bio-based polyurethane coating has good weather resistance, high and low temperature resistance, strength and waterproofness, and can be used in Tibet, Xinjiang, Inner Mongolia, Qinghai and other regions for a long time without aging, and the service life of the waterproof coating is prolonged.

The invention relates to a flexible aqueous binder for a lithium battery negative electrode and a preparation method thereof. The preparation method comprises the following steps: firstly, preparing a flexible polyurethane prepolymer containing vinyl by taking hydroxyl-terminated polybutadiene, isocyanate and hydroxyl acrylate as main raw materials; vinyl-containing compounds such as water-soluble acrylic acid (salt) or acrylamide, oil-soluble acrylic ester or acrylonitrile and the like are used as monomers and are combined with a flexible polyurethane prepolymer to prepare the negative water-based binder with flexible cross-linking points through free radical polymerization. The aqueous binder prepared by the technical method provided by the invention can realize point-to-point and point-to-line bonding modes with a pole piece active substance on a microstructure, so that the bonding strength of the active layer material and a copper foil is improved on the premise of not influencing the electrolyte resistance of the binder; and the flexibility of the negative pole piece and the subsequent processing stability are obviously improved.

The invention relates to a biodegradable high-strength medical soft tissue adhesive as well as a preparation method and application thereof. The medical soft tissue adhesive comprises a soft segment, a hard segment and a hard segment chain extender, the soft segment is a polyethylene glycol polymer; the hard segment is isocyanate; the hard segment chain extender comprises a hard segment electrically neutral chain extender and a hard segment ionized chain extender; the molar ratio of the polyethylene glycol polymer to the isocyanate to the hard segment electrically neutral chain extender to the hard segment ionized chain extender is (1-7): (50-95): (14-20): (2-6). The preparation method comprises the following steps: mixing the polyethylene glycol polymer, the hard segment chain extender and the isocyanate, heating and reacting to obtain a mixed reaction system; cooling after the reaction is completed, adding a rheology modifier, a foaming catalyst and a stabilizer into the mixed reaction system, and uniformly mixing to obtain the biodegradable high-strength medical soft tissue adhesive which is suitable for functional composite materials.

The invention discloses an INS film with excellent comprehensive performance, which comprises a surface protection layer, an upper base material layer, a printing ink layer, a bonding glue layer and a lower base material layer which are sequentially superposed from top to bottom, the surface protection layer is prepared from the following raw materials in parts by weight: 75-135 parts of polyester polyol resin, 30-60 parts of hydroxy acrylic resin, 2-25 parts of an isocyanate curing agent, 2-17 parts of a closed curing agent, 2-25 parts of a chain extender, 0.5-8 parts of a catalyst, 0.5-2 parts of an antioxidant and 0.5-3 parts of an ultraviolet light absorber. According to the surface protection layer of the INS film, the high-temperature condition of a high-temperature plastic uptake procedure of the INS film in preparation of INS parts is well utilized, so that the closed curing agent is effectively excited to perform secondary cross-linking curing reaction. The INS film is good in surface chemical reagent resistance, has the characteristics of high heat stretch rate, high hardness and scratch resistance, has excellent ultraviolet irradiation yellowing resistance, and is particularly suitable for the field of in-mold decoration.

The invention discloses a double self-repairing polyurethane coating containing a metal coordination bond and a Diels-Alder bond. The double self-repairing polyurethane coating is prepared from the following raw materials: polyol, an isocyanate derivative, a chain extender containing the metal coordination bond, metal salt and a binary chain extender containing the Diels-Alder bond. According to the double self-repairing polyurethane coating containing the metal coordination bond and the Diels-Alder bond, the repairing efficiency and the mechanical and chemical resistance can be improved.

The invention discloses a dual-curing 3D printing resin, the dual-curing 3D printing resin comprises an acrylate oligomer containing a dynamic covalent bond and a blocked isocyanate cross-linking agent, and the acrylate oligomer containing the dynamic covalent bond is obtained by reacting an isocyanate-terminated oligomer with acetoacetic acid ethylene glycol methacrylate. The internal molecular structure and the crosslinking density of the dual-curing 3D printing resin can be changed through heat treatment after light curing, and the dual-curing 3D printing resin has excellent stability and can be stored and used in a single-component mode.

The invention relates to the technical field of polyurethane foam materials, and provides viscoelastic polyurethane foam and a preparation method and application thereof.The viscoelastic polyurethane foam prepared through the preparation method has the advantages of being rapid in curing and high in production efficiency, meanwhile, the viscoelastic polyurethane foam low in density and good in physical performance can be obtained, and the viscoelastic polyurethane foam is suitable for being used in the field of polyurethane foam materials. The technical requirements of automobile sound insulation pad foam can be met. According to the preparation method, materials comprising an isocyanate reactive component and isocyanate are subjected to a reaction to obtain the viscoelastic polyurethane foam, wherein the isocyanate reactive component comprises a polyether polyol composition and a foaming agent; the polyether polyol composition is prepared from polyether polyol A1 and polyether polyol A2; the use amount of the polyether polyol A1 is 25-65 parts by mass, the use amount of the polyether polyol A2 is 30-70 parts by mass, and the use amount of the foaming agent is 3-6 parts by mass.

The invention relates to the technical field of polyurethane coatings, in particular to a hydrophobic flame-retardant polyurethane coating and a preparation method thereof. The preparation method comprises the following steps: firstly, taking 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and methallyl alcohol as raw materials, and reacting to obtain hydroxyl grafted phosphaphenanthrene; taking 1, 1, 3, 3-tetramethyldisiloxane and methallyl alcohol as raw materials, and reacting according to a molar ratio of 1: 2 to obtain dihydroxy siloxane; then cyanuric chloride, hydroxyl grafted phosphaphenanthrene and dihydroxyl siloxane react according to the molar ratio of 1: 1: (1.5-1.8), and the dihydroxyl-terminated silicon-containing flame retardant is obtained. The preparation method comprises the following steps: mixing a dihydroxyl-terminated silicon-containing flame retardant with polytetrahydrofuran ether glycol to serve as a soft segment, and reacting with isocyanate to obtain a hydrophobic flame-retardant polyurethane emulsion; mixing the hydrophobic flame-retardant polyurethane emulsion, an anti-aging agent, an ultraviolet light absorber, a defoaming agent, kaolin, nano silicon dioxide and talcum powder to obtain the hydrophobic flame-retardant polyurethane coating.

The invention belongs to the technical field of preparation of lithium bis (fluorosulfonyl) imide, and particularly relates to a preparation method of lithium bis (fluorosulfonyl) imide, which comprises the following steps: step 1, reacting chlorosulfonic acid with chlorosulfonyl isocyanate under the action of a first catalyst to generate bis (fluorosulfonyl) imide; 2, hydrogen fluoride gas is introduced into the bis (chlorosulfonyl) imide generated in the step 1, and bis (fluorosulfonyl) imide is obtained under the action of a first catalyst; and 3, adding a first lithium salt into an organic solvent, adding the imidodisulfuryl fluoride obtained in the step 2 in the stirring process, and carrying out ion exchange to obtain the lithium imidodisulfuryl fluoride. According to the invention, the conversion rate is high, the usage amount of the catalyst is reduced, the steps are simplified, and the yield is further improved.

The invention relates to polyurethane resin, synthetic leather and a preparation method and application thereof, and relates to the technical field of polyurethane, the polyurethane resin is prepared from the following raw materials: bio-based polyester polyol, polyolefin polyol, isocyanate, a chain extender, a pore-forming agent and a solvent; the bio-based polyester polyol is prepared from the following raw materials: bio-based dihydric alcohol, bio-based dibasic acid and micromolecular branched chain-containing dihydric alcohol. The polyurethane resin provided by the invention is high in bio-based content, micromolecular branched chain-containing dihydric alcohol is introduced into bio-based polyester polyol, a branched chain structure provides scratch resistance for the synthetic leather taking the polyurethane resin as a coating layer, the crystallinity of the polyurethane resin is reduced by compounding the polyolefin polyol, the synthetic leather is endowed with soft hand feeling, and the synthetic leather has the advantages that the synthetic leather is not prone to being scratched, and the service life of the synthetic leather is prolonged. Due to the addition of the chain extender and the pore-forming agent, the polyurethane has excellent foaming performance, the synthetic leather has excellent water absorption, and the hand feeling of the synthetic leather is further improved.

The invention discloses a lithium battery diaphragm with a self-repairing function and a preparation method thereof, and belongs to the field of lithium battery diaphragms. The lithium battery diaphragm comprises a polymer base membrane and a ceramic coating, the ceramic coating is coated on one side surface, facing the negative electrode, of the polymer base membrane or two side surfaces of the polymer base membrane; the ceramic coating comprises the following raw materials in parts by mass: 40-50 parts of modified ceramic particles, 4-8 parts of self-repairing microcapsules, 0.5-3 parts of a dispersing agent and 50-60 parts of water; the surfaces of the modified ceramic particles are grafted with amino-phenylboronic acid difunctional silane; chitosan / polyurethane is used as a wall material of the self-repairing microcapsule, and polyisocyanate is used as a core material of the self-repairing microcapsule. When the lithium ion diaphragm is stressed or punctured by dendritic crystals, the polyisocyanate can be released to react and crosslink, the generated cracks are closed, and an ion channel is reconstructed. Through the physical barrier of the ceramic coating and the self-repairing effect of the self-repairing microcapsule, the mechanical strength and the ion transmission performance of the lithium battery diaphragm can be effectively maintained.

The invention relates to the technical field of phase change microcapsules, in particular to a polyurea / polyacrylate double-layer shell material phase change microcapsule and a preparation method thereof. The microcapsule sequentially comprises a phase change material core material, a polyacrylate shell material and a polyurea shell material from inside to outside, and is prepared from the following raw materials: a polyisocyanate monomer, an acrylate monomer, an acrylate functional monomer, an acrylate cross-linking agent, a chain extender, an initiator, a surfactant, a phase change material and water. According to the invention, polyurea interfacial polymerization and polyacrylate suspension polymerization are combined to form a double-layer shell material for coating to prepare the phase change microcapsule, so that the phase change microcapsule has excellent sealing property, durability and high enthalpy value performance.

The invention relates to the field of optical protection materials, and provides a transparent film with laser eavesdropping prevention performance and a preparation method thereof.The transparent film is composed of surface-modified doped tungsten oxide nanosheets, amino-isocyanate bifunctional lithium niobate nanowires, urethane acrylate, an ultraviolet light absorber, a silane coupling agent, a dispersing agent and a flatting agent; the molybdenum-doped tungsten oxide nanosheets are obtained through silane coupling modification after hydrothermal synthesis, and the lithium niobate nanowires are prepared through a gradient modification process of hydrothermal synthesis-silane coupling-isocyanate grafting-phenol end capping. A modified nano material is uniformly dispersed in a resin matrix through an ultrasonic dispersion composite technology, and through blade coating forming, ultraviolet curing and constant-temperature and constant-humidity post-treatment, compared with the prior art, the scheme overcomes the problems that a traditional protective film is insufficient in optical transparency, laser eavesdropping prevention function and dynamic viscoelasticity, and is suitable for the field of high-end security and protection.

The invention relates to the technical field of polyurethane adhesives, in particular to a quick-curing two-component hot-pressing adhesive as well as a preparation method and application thereof. Comprising a component A and a component B. The component A comprises, by weight, 20 to 60 parts of castor oil polyol, 40 to 80 parts of a filling material, 0.001 to 0.01 part of a catalyst and 0.001 to 0.006 part of an auxiliary agent, and the catalyst comprises a triethylene diamine-terminated heat-sensitive catalyst; and the component B comprises an isocyanate curing agent. The filler comprises heavy calcium carbonate and calcium oxide, and the weight ratio of the heavy calcium carbonate to the calcium oxide is (25-40): 1, so that not only can the cost be effectively reduced, but also the tensile-shear strength of the hot-pressing adhesive can be improved; and when the particle size of the filler is adjusted to be 500-2000 meshes, the tensile-shear strength after cementing can be effectively maintained within a relatively low curing time (3-5 minutes), and meanwhile, the storage stability of the sizing material is improved.