4296 results about "Isocyanate" patented technology

An aqueous ultraviolet-absorbing resin emulsion, and an aqueous resin emulsion composition containing the emulsion is provided, wherein the emulsion is excellent in compatibility with a synthetic resin and light resistance. Also, the emulsion improves stability in blending with an aqueous emulsion of the synthetic resin, and prevents bleed out of the ultraviolet-absorbing resin on the surface of a coating film. Further, the aqueous ultraviolet-absorbing resin emulsion imparts excellent alkali or solvent resistance to a synthetic resin poor in alkali or solvent resistance. More specifically, an aqueous resin emulsion composition comprising (I) an aqueous ultraviolet-absorbing resin emulsion and (II) an other aqueous resin emulsion is provided, wherein the emulsion (I) is obtained by urethanizing (A) a polyol component having an ultraviolet-absorbing group {e.g., 1,1-bis[3-(2H-benzotriazol-2-yl)-4-hydroxy-benzeneethanol]methane}, (B) a polyol if necessary, (C) an alkyl or aryl dialkanolamine compound, and (D) an organic polyisocyanate in (E) an organic solvent, diluting the reaction mixture with (F) an organic solvent having a boiling point lower than 100° C. to give a resin solution, neutralizing the resin solution with (G) a neutralizing agent, and dispersing the resultant in water.

The invention belongs to the technical field of lithium ion batteries, and particularly relates to a self-repairing type lithium ion battery positive electrode adhesive, a preparation method, positive electrode slurry and a positive electrode plate. The adhesive comprises a mixed solvent, and a first copolymer serving as a main component and a second copolymer serving as a cross-linking agent are dissolved in the mixed solvent; the first copolymer is an acrylate-based multipolymer containing carboxyl or hydroxyl; the second copolymer is isocyanate terminated UPy functional polyurethane; the adhesive is in a liquid state at room temperature, when the adhesive is subjected to vacuum heat treatment at 60-180 DEG C, carboxyl or hydroxyl in main components of the adhesive reacts with isocyanate groups of a cross-linking agent to form amido bonds along with volatilization of a mixed solvent, and UPy groups are associated through quadruple hydrogen bonds to form dual dynamic cross-linking points. The method can effectively adapt to the volume change of the positive electrode material in the lithium removal / insertion process, and maintains the integrity of the electrode structure, thereby improving the cycling stability and rate capability of the lithium ion battery.

The invention relates to a Fenton-like functional filler which is prepared from 10-20% of iron particles coated with a carbonized film, 10-20% of aluminum sulfate modified straw, 20-30% of PBAT-coated calcium peroxide, 20-30% of diatomite and 10-30% of an adhesive. A processing method of a Fenton-like functional filler comprises the following steps: uniformly mixing iron particles coated with a carbonized film, aluminum sulfate modified straws, PBAT-coated calcium peroxide and diatomite, then adding an adhesive, mixing isocyanate serving as the adhesive with polyol according to a volume ratio of 1: 5, and continuously and uniformly mixing; then the mixed raw materials are injected into a mold coated with a release agent in advance, the mold temperature ranges from 40 DEG C to 60 DEG C, the foaming curing time ranges from 15 min to 20 min, and the Fenton-like functional filler can be obtained. The invention relates to an application of a Fenton-like functional filler in constructed wetlands. The method has the beneficial effects that the method is not influenced by temperature, and the removal effect of the constructed wetland on nitrate nitrogen and refractory COD (Chemical Oxygen Demand) can be obviously enhanced.

The invention relates to the field of wear-resistant materials, in particular to a high-melt-strength thermoplastic polyurethane elastomer and a preparation method thereof. The thermoplastic polyurethane elastomer with high melt strength is prepared from the following raw materials in parts by mass: 60 to 80 parts of a polyol agent, 25 to 40 parts of isocyanate, 6 to 12 parts of a chain extender, 5 to 15 parts of a melt reinforced composition, 3 to 6 parts of a polymerization additive, 0.05 to 0.15 part of an organic tin catalyst, 0.2 to 0.4 part of an antioxidant, 0.4 to 0.6 part of a hydrolysis stabilizer and 0.1 to 0.3 part of a coupling agent. The high-melt-strength thermoplastic polyurethane elastomer provided by the invention not only can have high melt strength, processability and mechanical properties, but also can keep good transparency, flexibility and other comprehensive properties, and the performance is prevented from being greatly sacrificed, so that the application environment of the thermoplastic polyurethane elastomer is ensured.

The invention relates to the technical field of organic polymer adhesives, and particularly discloses a modified castor oil-based polyurethane adhesive as well as a preparation method and application thereof. The adhesive comprises two components, and the component A comprises the following components in parts by weight: 30.0-50.0 parts of modified castor oil and 0.0-30.0 parts of refined castor oil; the component B is prepared from the following components in parts by weight: 30.0 to 50.0 parts of polyisocyanate or a polyisocyanate modifier and 0.00 to 0.05 part of a dewatering agent; the modified castor oil is prepared from refined castor oil and cysteamine through a sulfydryl-alkene addition reaction. Amido of the modified castor oil is alkalescent, and the reaction speed of the modified castor oil and isocyanate groups is high; hydrogen bonds are easily generated between urea bonds generated by the reaction of amino groups and isocyanate groups, so that the adhesive is endowed with thixotropy and high strength. The adhesive disclosed by the invention is simple in composition, high in reaction speed and good in thixotropy and bonding strength.

The invention discloses a bio-based flexible cementing material and a cold-mix asphalt mixture, and relates to the field of adhesives. The bio-based flexible cementing material comprises 80-85 wt% of a component A and 15-20 wt% of a component B, the component A comprises bio-based polyol, natural asphalt, natural rubber, a tackifier and a bio-based plasticizer according to a weight ratio of (160-180): (45-55): (75-85): (140-160): (380-410), and the component B is an isocyanate cross-linking agent. The bio-based flexible cementing material is used as a cementing material of a cold-mixed asphalt mixture, can be directly constructed at low temperature or normal temperature, does not need to be heated to improve the flowability, is convenient to construct, can form a stable skeleton structure through crosslinking, and can form a stable structure under the cooperation of natural rubber and natural asphalt. The bio-based flexible cementing material has both high temperature resistance and low temperature resistance, and the stability of a road structure can be improved.

The invention belongs to the technical field of functional finishing of textiles, and particularly relates to microcapsule emulsion with a pH indicating function, preparation of the microcapsule emulsion and application of the microcapsule emulsion in a textile finishing agent. The invention provides a preparation method of a microcapsule emulsion with a pH indication function, which comprises the following steps: reacting isocyanate with polyol to obtain a polyurethane prepolymer, mixing and dissolving the polyurethane prepolymer with a pH indicator solution, an acrylate monomer and an initiator to obtain an oil phase, and taking an aqueous solution of a polymer emulsifier as a water phase; then mixing and emulsifying the oil phase and the water phase, adding a chain extender, heating to carry out chain extension reaction, cross-linking to a certain degree to form a polyurethane-polyurea-polyacrylate hybrid shell layer on an oil-water interface, and coating a core material pH indicator to obtain the microcapsule emulsion with the pH indication function. According to the invention, the pH indicator is coated in the form of microcapsules for the first time, and industrial production and processing can be carried out.

The invention belongs to the technical field of polyurethane resin, and provides polyurethane resin, polyurethane synthetic leather and a preparation method and application thereof. The preparation raw materials of the polyurethane resin comprise the following components: 9%-23% of first bio-based polyol, 3%-18% of a polyurethane intermediate, 0.005%-0.02% of a first antioxidant, 0.001%-0.003% of a first catalyst, 3-6% of first isocyanate, 0.5%-2% of a first chain extender, 0.01%-0.05% of a first terminator, 0.01%-0.05% of a first anti-visbreaking aid, 0.7%-2.2% of an astringent aid, 0.5%-3% of a polyether aid and 50%-70% of a first solvent. The first bio-based polyol includes a bio-based polytrimethylene ether glycol and a bio-based polycarbonate glycol. The preparation raw materials are all derived from bio-based materials, and the polyurethane synthetic leather is soft in texture, good in astringent feeling and excellent in strength and hydrolysis resistance.

The invention discloses a preparation method of an ethyl cellulose and isocyanate cross-linked coated urea slow-release fertilizer, and relates to a preparation method of a urea slow-release fertilizer. The invention aims to solve the problems that the existing nitrogen fertilizer is low in utilization rate and easy to absorb moisture and cake, a polyurethane coating material is non-degradable, and pure ethyl cellulose is insufficient in mechanical strength and limited in water resistance and is not beneficial to being used as a coating matrix of the fertilizer. The method comprises the following steps: 1, preparing an ethyl cellulose cross-linked isocyanate enveloping solution; and 2, preparing the ethyl cellulose and isocyanate cross-linked coated urea slow-release fertilizer. According to the preparation method, etherified derivative ethyl cellulose of cellulose is taken as a raw material, and the defects that a pure ethyl cellulose membrane is insufficient in mechanical strength, limited in water resistance and low in nutrient separation control precision are overcome by utilizing isocyanate crosslinking modification. The prepared slow-release fertilizer has the advantages of being simple in process, low in cost, environmentally friendly, degradable in matrix, capable of effectively preventing urea from absorbing moisture and caking and the like, and is suitable for large-scale preparation and used in agricultural production.

The present invention relates to the field of the preparation of polyurethane elastic fibers, and relates to a preparation method for a bio-based polyurethane elastic fiber, comprising: preparing polyether polyol from sucrose, glycerol, dimethylamine and propylene oxide; adding a solvent, i.e., N,N-dimethylacetamide, and polyether polyol and polyisocyanate into a reaction tank, and adding p-Toluenesulfonyl semicarbazide and aluminum methylenebis(2,4-di-tert-butylphenoxy) phosphate to prepare a spinning solution; and subjecting the spinning solution to spinning and oil application by means of dry spinning technology to obtain the bio-based polyurethane elastic fiber. The present invention ensures that the properties of polyurethane elastic fibers do not deteriorate or are partially enhanced, while the cost and performance advantages are achieved.

The invention relates to the technical field of polyurethane adhesives, in particular to the field of IPC C09J175, and more particularly relates to a small molecule chain extender, a preparation method thereof and red polyurethane adhesive. The small molecule chain extender is prepared from the following raw materials: dichloroanthraquinone and ethanolamine, and the red polyurethane adhesive is prepared from the small molecule chain extender, polyol, isocyanate and a solvent. A red colored group is introduced into a polyurethane molecular chain, and the colored group is used as a part of a chain extender, so that the color migration resistance and the transparency are improved at the same time.

The invention relates to high-strength all-water-blown polyurethane foam and a preparation method thereof. The high-strength all-water-blown polyurethane foam comprises the following components in parts by weight: a polyol composite material: 100 parts of polyether polyol, 2-8 parts of water, 0.5-3 parts of an amine catalyst, 0.2-2 parts of a gel catalyst, 1-5 parts of an organosilicon surfactant, 3-8 parts of a composite filler and 0-10 parts of an auxiliary agent; wherein the composite filler is formed by coating the surfaces of glass beads with porous nano silicon dioxide; the isocyanate material is an MDI (Diphenyl Diisocyanate) or TDI (Toluene Diisocyanate) prepolymer, and the isocyanate index of the MDI or TDI prepolymer is 100 to 120 percent. The surface of the glass bead is coated with a nano silicon dioxide porous shell layer in situ to form a unique'hard core-soft shell 'gradient interface structure, so that the interface bonding force between the filler and a polyurethane matrix is improved, stress transfer is optimized, and the foam material is endowed with excellent comprehensive mechanical properties, especially compressive strength and structural stability.

The invention belongs to the technical field of polyurethane resin, and provides polyurethane resin, polyurethane synthetic leather and a preparation method and application thereof. The preparation raw materials of the polyurethane resin comprise the following components in percentage by mass: 11%-18% of modified polyol, 3%-9% of bio-based polyol A, 0.01%-0.02% of an antioxidant, 0.001%-0.003% of a catalyst, 5%-7% of isocyanate, 0.5%-3% of a chain extender, 0.1%-0.4% of a terminator, 0.02%-0.04% of an anti-visbreaking aid, 0.5%-3% of a polyether aid and 68%-73% of a solvent, wherein the preparation raw materials of the modified polyol comprise bio-based polyol, alcohol amine and binary acid; the bio-based polyol A comprises bio-based polypropylene carbonate dihydric alcohol. The polyurethane synthetic leather prepared by the preparation method disclosed by the invention has good slip resistance, excellent perspiration-resistant color fastness and relatively high blackness, and is suitable for yoga mats.

The invention provides a polyurethane composite material and application thereof, and relates to the technical field of polyurethane materials. The polyurethane composite material consists of a component A and a component B, the component A comprises the following raw material components in parts by weight: 100 parts of polymer dihydric alcohol, 1-8 parts of a chain extender, 1-3 parts of a catalyst, 0-5 parts of a cross-linking agent, 0.1-2 parts of a carbon-based material, 1-10 parts of an anthraquinone compound and 0.5-2 parts of water; and the component B is an isocyanate curing agent and comprises a prepolymer with a plurality of ester bonds and urea bonds. The polyurethane composite material disclosed by the invention has relatively high mechanical strength, wear resistance and the like, and is suitable for treating nitrogen-containing sewage.

The invention belongs to the technical field of membrane separation, and particularly relates to a method for preparing a high-flux hollow fiber nanofiltration membrane based on interfacial polymerization, the obtained membrane and application. The method comprises the following steps: firstly, carrying out pre-adsorption treatment on a polyethersulfone hollow fiber ultrafiltration base membrane through a polyethyleneimine aqueous solution to form a reactive anchoring layer; then sequentially dipping in an aqueous phase solution containing piperazine, sodium phytate and nanoscale cellulose whiskers and an organic phase solution containing trimesoyl chloride and 5-isocyanate isopeptide acyl chloride for interfacial polymerization; and finally, carrying out heat treatment on the obtained primary composite membrane, and completing a gas-phase cross-linking reaction in a glutaraldehyde steam atmosphere. According to the method, the hollow fiber nanofiltration membrane with high flux, high selectivity, excellent chlorine resistance and pollution resistance is successfully prepared through a multi-stage strengthening process, and the hollow fiber nanofiltration membrane is suitable for the fields of drinking water purification, industrial wastewater reuse, material separation and the like.

The invention discloses a preparation method of a sodium-ion battery negative electrode material and a sodium-ion battery, and relates to the technical field of sodium-ion battery negative electrode materials. The invention relates to a sodium ion battery negative electrode material. The negative electrode material comprises a substrate and a coating covering the surface of the substrate, the coating is composed of the following components in parts by mass: 20-40 parts of epoxy resin, 5-10 parts of an isocyanate curing agent, 10-20 parts of an inorganic filler, 2-6 parts of a UV reactive diluent, 5-10 parts of a conductive material, 1-3 parts of a photoinitiator and 0.5-2 parts of a conductive stabilizer. By introducing the novel conductive stabilizer, the electron migration resistance is effectively reduced, and the charge transfer efficiency of a coating and a matrix interface is optimized, so that the conductivity of the negative electrode material is remarkably improved.

The invention provides unsaturated waterborne polyurethane, a polyurethane composite material as well as a preparation method and application of the unsaturated waterborne polyurethane and the polyurethane composite material. According to the preparation method, isocyanate is introduced into a soft segment through a block process, an unsaturated chain extender is added, unsaturated double bonds are introduced, and waterborne polyurethane with excellent performance is prepared. Meanwhile, cellulose nanofibers are added into the unsaturated waterborne polyurethane, so that the interfacial compatibility and mechanical properties of the unsaturated waterborne polyurethane are improved. The unsaturated waterborne polyurethane provided by the invention has excellent film-forming property, stability and mechanical property.

The invention provides a washable stable humidity-sensitive printing paste composition, a humidity-sensitive printing paste and a preparation method and application thereof. The washing-resistant stable humidity-sensitive printing paste composition comprises humidity-sensitive resin, an interface anchoring agent, a rheology modifier, a latent cross-linking agent and water, the humidity-sensitive resin contains amino and / or hydroxyl, and the latent cross-linking agent is selected from oxime-terminated alicyclic polyisocyanates or derivatives thereof. The latent cross-linking agent has chemical inertness at room temperature and can ensure the rheological stability of the slurry in the printing process, in the baking process, an end-capping reagent in the latent cross-linking agent is dissociated, an isocyanate group and amino and / or hydroxyl in the humidity-sensitive resin are subjected to a cross-linking reaction to form a semi-interpenetrating network structure, and the structure allows water molecules to enter and exit, so that the moisture-sensitive printing ink is formed. The fabric has the humidity-sensitive response characteristic, excessive swelling and movement of hydrophilic chain segments can be limited, dissociation or falling of humidity-sensitive resin under the action of washing shearing force is prevented, and the humidity-sensitive characteristic and washing-resistant stability are improved.

The invention relates to the technical field of membrane separation and water treatment, in particular to an anti-pollution polyurea composite reverse osmosis membrane as well as a preparation method and application thereof. According to the preparation method, a polyamine monomer of a water phase solution and an aromatic polyisocyanate monomer of an organic phase solution are used for constructing a polymerization reaction system to form a urea bond structure, and terminal sealing treatment is cooperatively performed on a polyurea selection layer, so that the compact, flat and hydrophilic polyurea selection layer can be prepared. And the preparation method is simple, mild in condition, low in energy consumption, robust in process, wide in parameter window and suitable for large-scale production. The prepared anti-pollution polyurea composite reverse osmosis membrane has excellent anti-pollution performance and separation performance, can achieve excellent balance between maintenance of initial flux and long-term stability, and has excellent anti-pollution performance and separation performance. The reverse osmosis membrane shows low irreversible pollution rate and good cleaning recoverability to organic / inorganic typical sewage plugging substances, can well meet industrial requirements, and has a good application prospect.

The invention relates to the technical field of polyurethane material preparation, in particular to a polyurethane structural adhesive prepolymer online monitoring and quality control method and system.The method comprises the steps that raw material moisture content and feeding quality data are obtained, a raw material feeding threshold value is set, and whether a prepolymerization reaction is conducted or not is judged; collecting temperature data, viscosity data, isocyanate content, pressure data and stirring power data in real time to obtain real-time data flow; inputting the real-time data flow into a preset prepolymerization reaction prediction model for fusion analysis to obtain a reaction prediction result; generating a regulation and control instruction to optimize the prepolymerization reaction; and after the prepolymerization reaction, carrying out quality detection on the polyurethane prepolymer according to a release quality standard, and executing an automatic release decision. According to the invention, the problems of hysteresis quality, dependence on experience and data islanding of production quality control of the polyurethane prepolymer are effectively solved, and full-flow online monitoring and intelligent quality control from raw material feeding judgment to automatic release of product quality are realized.

The invention belongs to the technical field of preparation and surface protection of polyurethane coatings, and particularly relates to weather-resistant polyurethane and a preparation method thereof. The coating provided by the invention is composed of a component A and a component B according to a weight ratio of 1: (0.2-0.4). The component A is prepared from water-based fluorine-containing hydroxy acrylic dispersion resin with a high hydroxyl value, GMA (glycidyl methacrylate) grafted modified water-based acrylic dispersion resin, a benzotriazole ultraviolet light absorber, a light hindered amine stabilizer, rutile titanium dioxide, wet sericite powder, nano zinc oxide and auxiliaries; and the component B comprises an aliphatic isocyanate curing agent and propylene glycol diacetate. By constructing a quadruple synergistic weather-resistant mechanism of ultraviolet absorption, free radical capture, physical shielding and structural densification, the weather resistance and corrosion resistance of the coating are remarkably improved while the coating keeps excellent adhesive force (0-1 level) and hardness (2H-3H), the color change delta E is smaller than or equal to 1.8 after artificial accelerated aging for 1000 hours, the gloss loss rate is smaller than or equal to 23%, and the weather resistance and corrosion resistance of the coating are greatly improved. And the corrosion spreading width of a 600-hour salt spray test lineation is less than or equal to 2.3 mm.

The invention discloses a polyurethane foam composition, polyurethane foam, a preparation method of the polyurethane foam and a refrigeration device.The polyurethane foam composition comprises a component A and a component B. The component A comprises polyol, a foaming agent, modified hollow glass beads, modified nano-silica and an additive, the additive comprises one or more of a catalyst, a stabilizer and an antioxidant, and the component B comprises isocyanate. The polyurethane foam prepared from the polyurethane foam composition disclosed by the invention has relatively good heat insulation property.

The invention relates to the technical field of semiconductor wafer processing, and particularly discloses an adhesive tape for semiconductor wafer thinning and a preparation process thereof. The adhesive tape for semiconductor wafer thinning comprises a base material layer and a bonding layer arranged on the surface of the base material layer, the base material layer is made of polyolefin, and the bonding layer is a modified acrylic acid adhesive layer; the modified acrylic acid adhesive layer is prepared from the following raw materials in parts by weight: 60 to 70 parts of 2-ethylhexyl acrylate, 15 to 25 parts of butyl acrylate, 5 to 10 parts of methyl methacrylate, 2 to 5 parts of hydroxyethyl acrylate, 0.5 to 2 parts of glycidyl methacrylate, 1 to 3 parts of a modifier, 0.8 to 1.2 parts of an isocyanate cross-linking agent, 0.3 to 0.8 part of an epoxy cross-linking agent and 0.3 to 0.8 part of azodiisobutyronitrile. According to the adhesive tape for semiconductor wafer thinning, the fixing and protecting effects on the wafer are improved.

The invention relates to a preparation method and a preparation device of isocyanate, and the preparation method comprises the following steps: carrying out cold reaction on a phosgene solution and an amine solution in a cold reactor to obtain an intermediate mixed solution; separating the intermediate mixed solution by adopting a cyclone, obtaining a carbamoyl chloride mixed solution from an underflow port of the cyclone, and obtaining an amine hydrochloride mixed solution from an overflow port of the cyclone; the carbamyl chloride mixed solution enters a first thermal reactor for thermal reaction to obtain a first reaction product, and the amine hydrochloride mixed solution enters a second thermal reactor for thermal reaction to obtain a second reaction product; mixing the first reaction product and the second reaction product in a staying reactor to obtain an isocyanate reaction solution; and carrying out post-treatment on the isocyanate reaction liquid to obtain the isocyanate. The method can reduce the generation amount of urea by-products, further inhibits the generation of other subsequent by-products, reduces the chromaticity of the product, and improves the quality of isocyanate.

The invention discloses a PVC blue protective film and a preparation method thereof. The PVC blue protective film comprises a release layer, a blue PVC base film, a priming coat and a pressure-sensitive adhesive layer which are sequentially arranged from top to bottom. The release layer and the priming coat are respectively designed on the two surfaces of the blue PVC base film, a direct coating and direct collecting process mode is adopted, an additional release film does not need to be used, the preparation process is simplified, the production cost is reduced, meanwhile, a plasticizer in the blue PVC base film can be sealed, and the plasticizer is effectively prevented from being separated out; a direct coating process instead of a transfer coating process is adopted, and the base coating is used for clamping, so that the binding strength of the pressure-sensitive adhesive layer and the blue PVC base film is better; the pressure-sensitive adhesive layer adopts a slit coating technology, so that the coating thickness is more uniform, rolling is not easy to occur, and the stability of product quality is improved; the resin in the bottom coating can react with the isocyanate curing agent in the pressure-sensitive adhesive layer, and the resin in the pressure-sensitive adhesive layer can also react with the isocyanate curing agent in the bottom coating, so that the bonding force between the layers is enhanced.

The invention belongs to the technical field of polyurethane, and provides polyurethane resin, polyurethane gloves and a preparation method and application thereof. The polyurethane resin is prepared from the following raw materials in percentage by mass: 5%-12.5% of modified organic silicon polyol, 5%-12.5% of bio-based polyol, 5%-8% of isocyanate, 0.01%-0.02% of an antioxidant, 0.001%-0.002% of a catalyst, 1%-2% of a chain extender, 0.1%-0.7% of polyether polyol, 0.02%-0.05% of a terminating agent and 71%-75% of a solvent, the preparation raw materials of the modified organic silicon polyol comprise a dihydroxyl-terminated organic silicon prepolymer and binary acid. The polyurethane glove prepared by compounding two specific polyhydric alcohol modified organic silicon polyhydric alcohol and bio-based polyhydric alcohol as well as other substances has good wear resistance and fingerprint-free characteristic, is easy to demould, and is suitable for the field of automobile film and chip manufacturing.

The invention relates to the technical field of modified polyurethane preparation, in particular to a modified rigid polyurethane foam material and a preparation method thereof.The material is specifically prepared from CO2-based polyol, polyether, deionized water, a foaming agent, a catalyst, a foam stabilizer and isocyanate. Wherein CO2-based polyol is introduced into original polyether polyol, specifically, poly (ethylene carbonate) polyol is added, so that the heat conductivity coefficient of the material can be reduced, the compression strength of the material can be improved, and the low-cost and high-performance polyurethane foam can be prepared. The finally prepared rigid polyurethane foam material has the characteristics of good heat insulation property and high pressure resistance; and the whole preparation process is simple, the whole cost is low, and the market competitiveness is high.

The invention relates to the technical field of thermal insulation materials, in particular to hydrolysis-resistant polyurethane resin aerogel and a preparation method thereof, and the hydrolysis-resistant polyurethane resin aerogel comprises the following components in parts by weight: 60-80 parts of polyether polyol, 30-50 parts of polyester polyol, 10-15 parts of modified silicon dioxide, 20-30 parts of isocyanate, 0.5-2 parts of a dispersing agent and 0.5-1 part of a catalyst. According to the technical scheme, through chemical bonding of amino groups on the surface of modified silicon dioxide and isocyanate, molecular-level combination of filler and a polyurethane matrix is achieved, the comprehensive performance of the material is remarkably improved, and the prepared polyurethane resin aerogel is promoted to have multiple functions of heat insulation, hydrolysis resistance, flame retardance, aging resistance and the like.

The invention relates to the technical field of adhesives, and discloses an anti-aging polyurethane sealant and a preparation method thereof.The polyurethane sealant is prepared by the steps that polyether polyol and binary isocyanate serve as raw materials and react under the action of a catalyst to form a polyurethane prepolymer, then a functional chain extender is used for conducting chain extension on the prepolymer to form polyurethane latex, and then the polyurethane latex is subjected to heat preservation to form the anti-aging polyurethane sealant. The structure of the functional chain extender contains a hindered phenol antioxidant group, and the hindered phenol antioxidant group is introduced into a polyurethane molecular chain by adopting a chemical grafting mode, so that the aging resistance of the polyurethane sealant can be effectively improved, the aging resistance durability of the polyurethane sealant is guaranteed, and the service life of the polyurethane sealant is prolonged. Therefore, the service life and the application value of the polyurethane sealant are effectively improved.

The invention discloses a high-strength and high-resilience TPE (thermoplastic elastomer) and a preparation method thereof in the technical field of high polymer materials, and the elastomer is prepared by taking a hydrogenated styrene block copolymer as a matrix and matching with a polyolefin rigid phase, plasticizing oil and a specific additive. The method is characterized in that two self-made reaction type modifiers are introduced, wherein one self-made reaction type modifier is a core-shell nano reinforcing agent containing an epoxy functional group and polyhedral oligomeric siloxane, and the other self-made reaction type modifier is a furan maleimide bifunctional dynamic cross-linking agent. The nano reinforcing agent is prepared through silane hydrolysis and amination reaction, and can react with a matrix for grafting, so that the strength and creep resistance of the material are remarkably improved; the dynamic cross-linking agent is synthesized through step-by-step isocyanate addition reaction, a cross-linked network can be reversibly formed in the processing process, and the material is endowed with extremely high rebound resilience and low permanent deformation. The obtained product has high strength, high resilience and excellent processability, and is especially suitable for high-end fitness equipment.