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407results about How to "Inhibition of polymerization" patented technology

Catalyst for high-selectivity preparation of light aromatic hydrocarbon by using synthesis gas and preparation method thereof

The invention provides a catalyst for high-selectivity preparation of light aromatic hydrocarbon by using synthesis gas and a preparation method thereof and belongs to the field of catalysts. The catalyst is prepared from, by mass, 20%-60% of modified zeolite molecular sieve and 40%-80% of zirconium-containing composite oxide. The preparation method comprises the steps that the zirconium-containing composite oxide is added to a solvent, and ultrasonic dispersion is performed to obtain a solution A; the modified zeolite molecular sieve is added into the solution A; the mixture obtained after ultrasonic dispersion is subjected to suction filtration, and the obtained filter cake after washing is dried; the sample obtained after drying is grinded into powder; the powdery sample is calcinated, and the obtained sample is the catalyst for high-selectivity preparation of the light aromatic hydrocarbon by using synthesis gas. The light aromatic hydrocarbon can be prepared in a high-selectivity mode, and the stability is good. The preparation method of the catalyst for high-selectivity preparation of the light aromatic hydrocarbon by using the synthesis gas is simple and low in cost and has good industrial application prospect.
Owner:XIAMEN UNIV

Hydrogenation and epoxidation of polymers made by controlled polymerization

InactiveUS20050256253A1Simple and versatile and highly effectiveInhibition of polymerizationGranular deliveryPolymer sciencePolymer adhesive
The present invention discloses a process for synthesizing a hydrogenated polymer that comprises: (1) preparing a aqueous polymerization medium which is comprised of (a) at least one monomer, (b) a polymerization control agent, and an emulsifier, wherein the emulsifier is prepared in-situ within the aqueous polymerization medium; (2) initiating polymerization of said monomer within the aqueous polymerization medium to produce a latex of an unsaturated polymer; (3) treating the latex of the unsaturated polymer with (a) an oxidant selected from the group consisting of oxygen, air and hydroperoxides; (b) a reducing agent selected from the group consisting of hydrazine and hydrates of hydrazine; and (c) a metal ion activator to produce the hydrogenated polymer. The present invention further discloses a process for synthesizing a hydrogenated polymer that comprises: (1) preparing a monomer solution which is comprised of (a) at least one monomer, (b) a conjugate acid of a surfactant with a pKa of less than about 14, and (c) a controlled free radical polymerization agent; (2) preparing an aqueous medium which is comprised of (a) water, and (b) a conjugate base of a weak acid wherein the pKb of the base is less than about 14; and (3) mixing the monomer solution with the aqueous medium under conditions that result in the in-situ formation of an emulsifier; (4) initiating free radical polymerization to produce a latex of an unsaturated polymer; and (5) treating the latex of the unsaturated polymer with (a) an oxidant selected from the group consisting of oxygen, air and hydroperoxides; (b) a reducing agent selected from the group consisting of hydrazine and hydrates of hydrazine; and (c) a metal ion activator to produce the hydrogenated polymer.
Owner:THE GOODYEAR TIRE & RUBBER CO

Process for inhibiting a polymerization in a vacuum section of an easily polymerizable compound purification system

A process for inhibiting a polymerization of an easily polymerizable compound purification system is disclosed.According to the present invention, the polymerization of the easily polymerizable compound such as (meth)acrylic acid and (meth)acrylate flowed into a vacuum section can be inhibited by contacting a liquid containing a polymerization inhibitor with the compound directly in the vacuum section.When the vacuum section includes a gas and liquid contact chamber (usually a condenser), the liquid containing a polymerization inhibitor may be supplied to the chamber. When the vacuum section includes a liquid ejector and / or a nash pump as a vacuuming device, the liquid containing a polymerization inhibitor may be circulated by the liquid ejector and / or the nash pump for reducing a pressure of a purifying section. Examples of easily polymerizable compounds are (meth)acrylic acid and (meth)acrylates. The process of the invention is capable of inhibiting the polymerization of the easily polymerizable compound such as (meth)acrylic acid and (meth)acrylate in a vacuum section of a purifying system. The system of the invention is suitable for purifying the easily polymerizable compound.
Owner:NIPPON SHOKUBAI CO LTD
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