This invention discloses a method for synergistic
surface modification of
tungsten-
copper powder to inhibit the
decomposition of
polyoxymethylene (POM), belonging to the field of
polymer material anti-degradation modification technology. This invention addresses the problem that
tungsten-
copper powder easily catalyzes the severe degradation of POM during PIM
tungsten-
copper feedstock mixing and injection molding, leading to poor feedstock flowability, injection
instability, large fluctuations in product size and weight, and low yield. First, the tungsten-copper
powder is activated by low-temperature
plasma etching to construct a
reaction interface. Then, a silica barrier film is prepared using
tetraethyl orthosilicate as the
silicon source and modified with fluorosilicone, loaded with a
metal soap neutralizer, grafted with a hindered
phenolic antioxidant, and simultaneously introduced with
epoxy active groups to construct a multi-component synergistic degradation inhibition
system. This invention, through multi-step synergistic modification, precisely controls the modification process, comprehensively inhibiting POM
decomposition. When the modified powder is blended with POM, a capping reaction occurs, blocking the unzipping
degradation pathway of POM, improving the compatibility of the filler and the matrix, and ensuring the continuous and stable preparation and injection molding of PIM tungsten-copper feedstock.