335 results about "Dodecane" patented technology

The invention discloses a nano blocking agent for drilling fluid and a preparation method thereof, and belongs to the technical field of blocking agents, the nano blocking agent for drilling fluid is prepared by reaction of a core layer blocking agent and a shell layer blocking agent, the core layer blocking agent is prepared by reacting nano silicon dioxide, gamma-methacryloxypropyltrimethoxysilane and a first part of vinylphosphonic acid, and has secondary blocking capability; and the shell blocking agent is prepared by reacting a second part of vinyl phosphonic acid, styrene and 2-dodecene-1-yl succinic anhydride, and has the characteristic of flexibility. The nano plugging agent has rigid supporting and flexible deformation capabilities, and the high-temperature stability and compressive strength of a plugging layer are remarkably improved. The chemical binding force of the plugging agent and the rock is enhanced; the hydrolysable methoxyl reserved in the core layer provides a secondary plugging function, and the plugging validity period is prolonged. The invention relates to a preparation method of a nano blocking agent for drilling fluid, which is used for preparing the nano blocking agent for drilling fluid.

The invention discloses a method for evaluating the wettability of shale based on alternate spontaneous imbibition, which comprises the following steps: step (1), obtaining the apparent volume of a to-be-tested sample, then smearing sealant on the periphery of the to-be-tested sample, standing, and entering step (2) after the to-be-tested sample is air-dried; step (2), based on a low-field nuclear magnetic resonance method, calibrating a relation between the mass of the imbibition fluid and a nuclear magnetic semaphore; (3) alternately imbibing dodecane and a 8wt% KCl aqueous solution into the to-be-detected sample treated in the step (1), and monitoring the weight change of imbibition fluid imbibed into the to-be-detected sample by using a two-dimensional nuclear magnetic resonance spectrometer in the alternate imbibition process; (4) determining an oil wet pore volume and a water wet pore volume through a fluid calibration relation; and (5) calculating a main pore wettability index according to the content of the imbibition fluid, and then evaluating the wettability of the shale.

The invention provides a dry powder drag reducer for fracturing fluid and a preparation method of the dry powder drag reducer, and belongs to the technical field of fracturing materials for well drilling, and the preparation method comprises the following steps: dissolving 4-bromobutyryl chloride and N-dodecyl methylamine in acetonitrile, heating and stirring for reaction, adding polyethylene glycol monomethyl ether acrylate and dichloromethane, stirring and purifying in a nitrogen atmosphere to obtain a dry powder drag reducer; a double-tailed hydrophobic monomer is obtained; uniformly mixing the core-shell SiO2 / Fe3O4 composite nanoparticles, an ethanol water solution, KH570 and an ammonia solution, stirring, and purifying to obtain modified SiO2 / Fe3O4; the preparation method comprises the following steps: adding acrylamide, acrylic acid, sodium 2-acrylamido-2-methylpropanesulfonate, a double-tailed hydrophobic monomer and modified SiO2 / Fe3O4 into water, uniformly mixing, adjusting the pH value, introducing nitrogen, mixing and stirring, adding an azo initiator, stirring, cooling, purifying, carrying out vacuum drying, and crushing into powder, thereby obtaining the dry powder drag reducer for the fracturing fluid. The drag reducer has certain heat resistance while achieving good drag reduction performance, and can be better applied to fracturing operation in the well drilling process.

The invention relates to a low-cost composite metal catalyst which is a CuO / ZnO / Al2O3 composite metal catalyst, and the molar ratio of CuO to ZnO to Al2O3 is (6-4): (3-4): (0.5-1). The composite catalyst is prepared by the following steps: adding carbonate into a mixed salt aqueous solution of copper salt, zinc salt and aluminum salt for co-precipitation, grinding a filter cake, and roasting at high temperature. According to the catalyst, 1, 12-dodecanedioic acid dimethyl ester which is low in price and easy to obtain can serve as a raw material, 1, 12-dodecanediol is prepared through catalytic hydrogenation under the milder condition compared with the prior art, high yield and low cost are achieved on the premise that the process condition control difficulty is greatly reduced and the process safety is improved, and the problems that in the prior art, 1, 12-dodecanedioic acid dimethyl ester is synthesized, and the cost is low are solved. The technical problems of high energy consumption, expensive catalyst, harsh reaction conditions and difficult realization of industrial production in the reaction process of 1, 12-dodecanediol in the prior art are solved.

The invention relates to the technical field of glass cleaning agents, in particular to an environment-friendly cover plate glass cleaning agent and a preparation method thereof. The environment-friendly cover plate glass cleaning agent comprises the following raw materials in percentage by weight: 12-20% of inorganic base, 8-12% of a surfactant, 5-8% of a chelating agent, 3-5% of a humectant, 1-3% of an adsorbent, 1-3% of a dispersing agent, 0.3-1% of a buffering agent and the balance of deionized water, the surfactant is dodecyl glucoside and dodecyl ethyoxyl sulphobetaine, and the weight range ratio of the dodecyl glucoside to the dodecyl ethyoxyl sulphobetaine is (3-1): 1; the chelating agent is one or more of sodium gluconate, sodium polyaspartate and sodium polyepoxysuccinate. According to the present invention, the degradable surfactant and the degradable chelating agent are adopted, and the dispersant is added to modify the nanometer titanium dioxide, such that the low pollution property is achieved while the high decontamination efficiency and the anti-fingerprint ability are considered.

The invention relates to the technical field of new material application, and discloses a magnetic bead material for enriching a sulfydryl peptide fragment and a preparation method thereof.The magnetic bead material prepared from micron carboxyl magnetic beads, dodecane dicarboxylic acid dihydrazide and SPSP has a long chemical reaction connecting arm, so that a reaction group has the better freedom degree, the reaction with sulfydryl is better facilitated, and the magnetic bead material can be used for enriching the sulfydryl peptide fragment. The enrichment efficiency is relatively high. When the magnetic bead material is prepared, micron carboxyl magnetic beads and dodecane dicarboxylic acid dihydrazide are based on hydrazine group and carboxyl condensation, the condensation reaction is more selective and more stable, the reaction is carried out under a milder condition, the reaction product is stable, and the reaction efficiency is higher at a lower reaction temperature. Dodecane dicarboxylic acid dihydrazide and SPSP are based on a reaction of N-succinimide and hydrazine, N-succinimide has high specificity to amino-containing molecules, side reactions are reduced, the reaction is generally carried out at room temperature, strong acid and alkali conditions are not needed, and protection of other sensitive groups is facilitated.

The invention belongs to the technical field of adhesives, and particularly discloses a single-component silicone sealant for stainless steel bonding and a preparation method thereof, and the single-component silicone sealant comprises the following components by weight: 50-60 parts of alpha, omega-dihydroxy polydimethylsiloxane; 10 to 15 parts of a polydopamine coated silicon carbide nanowire; 5 to 15 parts of modified nano aluminum oxide gel; 5 to 10 parts of methyltris (methylethylketoxime) silane; 1 to 3 parts of dodecyl tris (methylethylketoxime) silane; 0.03 to 0.3 part of a coordination enhanced organic tin catalyst; and 8-14 parts of a plasticizer. According to the single-component silicone sealant for stainless steel bonding and the preparation method of the single-component silicone sealant, the modified nanometer aluminum oxide gel is selected, the bonding performance of stainless steel in a humid and hot environment is promoted and improved, the silicon carbide nanowire is coated with polydopamine, the bonding performance of the stainless steel is effectively improved, and the single-component silicone sealant can be widely applied to various indoor and outdoor scenes.

The invention belongs to the technical field of semipermeable membrane preparation, and particularly relates to a preparation method of a reverse osmosis membrane. The preparation method comprises the following steps: (1) cleaning the supporting layer for later use; blending diamine, a performance additive and water to obtain a water phase for later use; the preparation method comprises the following steps: blending aromatic acyl chloride, a cosolvent and an organic solvent to obtain an oil phase A for later use, and blending a dynamic crosslinking monomer and the organic solvent to obtain an oil phase B for later use; (2) placing a supporting layer at the bottom of a container, uniformly mixing a water phase and a catalyst, and adding the mixture into the container; and adding the oil phase A into a container to carry out primary condensation reaction, adding the oil phase B to carry out secondary condensation reaction after the reaction is finished, and carrying out post-treatment to obtain the reverse osmosis membrane. According to the invention, a Schiff base-benzene ring bridging structure and a dynamic crosslinking imine bond are introduced through a dynamic crosslinking monomer; and dodecyl ethyoxyl sulphobetaine is matched, so that the chlorine resistance and pollution resistance of the reverse osmosis membrane are improved, and meanwhile, the reverse osmosis membrane has good salt rejection rate and water flux.

The invention relates to the technical field of catalysts, and discloses a preparation method and application of a catalyst for preparing olefin through carbon dioxide hydrogenation. The preparation method comprises the following steps: fully dipping graphite in a mixed solution of dodecane and hexadecane, and taking out to obtain a catalyst carrier; and loading the Fe element and the Mg element into the catalyst carrier by adopting a method of co-precipitating and then roasting to obtain the catalyst for preparing olefin by hydrogenation of carbon dioxide. The catalyst prepared by the preparation method has high stability when being used in a reaction for preparing olefin through hydrogenation of carbon dioxide, can maintain high catalytic activity after long-term use, and has high olefin selectivity at the same time.

The invention discloses a continuous preparation method of dodecyl diphenyl ether, and belongs to the technical field of organic synthesis. The continuous preparation method comprises the following steps: respectively injecting diphenyl ether, olefin and a catalyst into a micro-channel through a feeding pump and a gas flowmeter pump for reaction, collecting reaction liquid, and carrying out post-treatment on the reaction liquid to obtain dodecyl diphenyl ether. According to the method, a continuous preparation process is adopted, a gas catalyst is used, the use amount of the catalyst is greatly reduced, post-treatment steps are reduced, the reaction time is greatly shortened, meanwhile, the purity and yield of the product can reach 99% or above, and the reaction raw materials can be recycled and are green and environment-friendly.

The invention belongs to the technical field of oil exploitation, and particularly relates to a foaming agent for nitrogen foam well cementation and a preparation method thereof. The preparation method comprises the following steps: adding tris (hydroxymethyl) aminomethane, ethanol and dodecyl halide into a reactor, uniformly stirring, heating, carrying out a heat preservation reaction, and adjusting the pH value; adding benzyl halide into the reactor, uniformly stirring, heating, preserving heat and reacting, and adjusting the pH value; carrying out reduced pressure distillation to obtain a viscous liquid, adding toluene for dissolving, transferring into a high-pressure reaction kettle, adding a catalyst, closing the reaction kettle, stirring, heating, vacuumizing, introducing ethylene oxide, heating after the introduction is completed, stopping heating when the pressure does not drop any more, and cooling the system; adjusting the pH value, adding sulfamic acid powder, heating while stirring, carrying out heat preservation reaction, and cooling; and filtering and carrying out reduced pressure distillation to obtain a viscous solid, namely the foaming agent product for well cementation. The foaming agent for well cementation has the advantages of large foaming volume and long half-life period.

The invention discloses a method for preparing spermidine. The method comprises the following steps: dissolving oxalyl chloride and a base in a first solvent, slowly adding 4-bromo-1-butylamine hydrobromic acid, and reacting to obtain 2-((4-bromobutyl)amino)-2-oxoacetyl chloride; adding a base to the reaction solvent of the obtained 2-((4-bromobutyl)amino)-2-oxoacetyl chloride, and slowly adding 3-bromo-1-propylamine hydrobromic acid to obtain N 1 ‑(4‑Bromobutyl)‑N 2 ‑(3‑bromopropyl)oxalamide; 1 ‑(4‑Bromobutyl)‑N 2 ‑(3‑bromopropyl)oxalamide, benzylamine and a base are added to a second solvent to react to obtain 8‑benzyl‑1,4,8‑triazacyclododecane‑2,3‑dione; 8‑benzyl‑1,4,8‑triazacyclododecane‑2,3‑dione is added to an acid for hydrolysis to obtain N 1 ‑(3‑Aminopropyl)‑N 1 Benzylbutane-1,4-diamine; N 1 ‑(3‑Aminopropyl)‑N 1 Benzylbutane-1,4-diamine is added to Raney nickel / methanol, and hydrogen is passed through the reaction to obtain crude spermidine, which is then distilled to obtain pure spermidine. The preparation method of the present invention is easy to operate and safe, easy to industrial-scale production, and has a high conversion rate of spermidine and high product purity.

The invention provides a method for detecting an antioxidant in a food contact plastic material or a product thereof and application of the method. The detection method comprises the following steps: mixing a sample to be detected with an organic solvent, filtering, taking filtrate, carrying out gas chromatography-mass spectrometry detection, and calculating the content of the antioxidant in the sample to be detected according to a detection result, the antioxidant comprises any one or a combination of at least two of 2, 4-bis [(dodecylthio) methyl]-6-methylphenol, 2, 6-di-tert-butyl-4-ethylphenol or 2, 2 '-methylenebis [6-(1-methylcyclohexyl)-p-cresol]. The detection method provided by the invention is simple to operate, low in detection limit and quantitation limit, high in accuracy and excellent in repeatability and reproducibility, and can effectively and accurately detect the three phenolic antioxidants at the same time.

The invention discloses a low-rank coal composite flotation reagent and a preparation method and application thereof, and belongs to the technical field of coal flotation of mineral processing. The agent specifically comprises a composite collecting agent and a composite foaming agent, and the composite collecting agent comprises kerosene, n-dodecane, oleic acid, dimer acid, sodium stearate, terpilenol, diethyl phthalate, alkylphenol ethoxylates, span-80, trioctyl phosphate and 2-ethylhexanol. The composite foaming agent is prepared from the following components: terpilenol, terpenic oil, sec-octyl alcohol and sodium alpha-olefin sulfonate. Compared with a traditional single flotation reagent combination, the composite flotation reagent has a remarkable effect in fine coal flotation, and particularly when coal with the particle size smaller than 0.5 mm is treated, the flotation efficiency, the clean coal yield and the combustible body recovery rate can be effectively improved. More importantly, the medicament is stable at normal temperature, the layering phenomenon is avoided, the long-term effectiveness is ensured, and the medicament has extremely high industrial application potential.

The invention discloses an aqueous film-forming foam extinguishing agent based on a short fluorocarbon chain, and relates to the technical field of extinguishing agents. The invention discloses an aqueous film-forming foam extinguishing agent based on a short fluorocarbon chain. The cleaning agent is prepared from the following raw materials in parts by weight: 8 to 12 parts of modified short fluorocarbon chain surfactant, 5 to 8 parts of dodecyl dimethyl betaine, 50 to 60 parts of deionized water, 2 to 4 parts of modified guar gum, 4 to 6 parts of ethylene glycol, 1 to 2 parts of benzotriazole, 0.5 to 1 part of sodium bicarbonate, 0.3 to 0.5 part of polydimethylsiloxane, 3 to 5 parts of decabromodiphenyl ethane and 1 to 2 parts of sodium carboxymethyl cellulose. 0.5 to 1 part of disodium ethylene diamine tetraacetate, 0.2 to 0.4 part of isothiazolinone and 0.5 to 1 part of nano silicon dioxide. According to the aqueous film-forming foam extinguishing agent based on the short fluorocarbon chain, the modified short fluorocarbon chain surfactant and the nano silicon dioxide cooperate, so that a film is formed quickly and compactly, and the extinguishing efficiency is high; the modified guar gum improves the foam stability, and the foam holding time is long; the raw material ratio is scientific, and both equipment protection and fire control are considered; the preparation process is rigorous, the product quality is stable, and various fire extinguishing scenes are adapted.

The invention belongs to the field of petrochemical engineering, and discloses a bimetallic Ni-Pt / RFE hydroisomerization catalyst and a preparation method and application thereof. The preparation method comprises the following steps: dissolving a nickel precursor in water, stirring until clarification, and dropwise adding ammonia water to obtain a mixed solution 1; rFE is added into the mixed solution 1, the pH value is adjusted to be 9-11.5, suction filtration, washing and drying are conducted after stirring, and Ni / RFE is obtained; dissolving a platinum precursor in water, stirring until the solution is clear, and dropwise adding ammonia water to obtain a mixed solution 2; and adding the Ni / RFE into the mixed solution 2, adjusting the pH value to 9-11.5, stirring, and carrying out suction filtration, washing, drying and roasting to obtain the Ni-Pt / RFE. The method is simple and convenient to operate and mild in condition, the catalyst activity and the isomerization efficiency are remarkably improved through the synergistic effect of Ni and Pt, the catalyst preparation cost is greatly reduced while the use amount of precious metal is reduced, efficient conversion of long straight-chain alkane can be achieved, and the isomerization conversion rate of n-dodecane within 60 minutes can reach nearly 90%.

The invention relates to the technical field of organic synthesis, in particular to a synthesis method of ethyoxyl cyclododecyloxymethane, which comprises the following steps: S1, heating and mixing diethoxymethane and cyclododecanol, adding an acid catalyst, and stirring to react; and S2, after the reaction is finished, introducing into a reactor containing a potassium carbonate aqueous solution, taking an upper-layer solution, and carrying out rectification separation, thereby obtaining the product. According to the synthesis method of ethyoxyl cyclododecyloxymethane, provided by the invention, the raw materials can be fully utilized, the single-time yield reaches 80% or above, the yield after recycling reaches 95% or above, meanwhile, continuous reaction can be realized, the production efficiency is high, and the method has relatively high economic value.

The invention discloses a salt-tolerant anti-calcium imbibition-oil displacement system suitable for a low-permeability compact oil reservoir and a preparation method thereof, the imbibition-oil displacement system comprises the following raw materials by weight: 0.05-1.5% of an amphiphilic head-based double hydrophobic chain surfactant, 0.05-1.5% of an amphiphilic head-based single hydrophobic chain surfactant, and the balance of water, wherein the double-hydrophilic-head-group double-hydrophobic-chain surface active agent is didecyl hydroxyl sulfonate, didodecyl hydroxyl sulfonate, ditetradecyl hydroxyl sulfonate or dihexadecyl hydroxyl sulfonate; the amphiphilic water head-based single hydrophobic chain surfactant is dodecyl amino acid salt, tetradecyl amino acid salt, hexadecyl amino acid salt or octadecyl amino acid salt. The imbibition-oil displacement system can be suitable for an oil reservoir formation water environment with low permeability, compactness, high total mineralization degree and high calcium ion content, can effectively reduce interfacial tension, and has imbibition-oil displacement performance.

The invention discloses an alkyl phenolic resin for improving the bonding performance of a GLR rubber adhesive and a preparation method thereof, and relates to the technical field of phenolic resin preparation, the alkyl phenolic resin comprises the following raw materials by weight: 60-70 parts of modified resin, 15-20 parts of modified EPDM, 2-4 parts of carbon fiber, 5-7 parts of naphthenic oil, and 0.8-1.0 part of an anti-aging agent. The modified resin is obtained by carrying out reaction grafting on methyl 3-dodecylthio-propionate, 5-amino-2-hydroxycycloheptyl-2, 4, 6-triene-1-ketone, punicic acid and the like, and then blending with alkyl phenolic resin. The modified EPDM is obtained by grafting a functional monomer and EPDM, wherein the functional monomer contains imidazole, amino, piperazine, phosphamide, hydroxyl and terminal carbon-carbon double bonds. The prepared alkyl phenolic resin has good corrosion resistance, toughness, antibacterial property, adhesion, oil resistance and flame retardance, and is worthy of popularization and application.

The invention provides a fracturing fluid base fluid, a water-based fracturing fluid and a preparation method of the water-based fracturing fluid, and relates to the technical field of oil fields. The fracturing fluid base fluid is prepared from the following components in percentage by mass: 97.3 percent to 98.1 percent of produced water, 0.5 percent to 0.55 percent of hydroxypropyl guar gum, 0.004 percent to 0.005 percent of sodium hypochlorite, 0.015 percent to 0.03 percent of citric acid, 0.1 percent to 0.18 percent of dodecyl dimethyl benzyl ammonium bromide, 0.2 percent to 0.3 percent of ethylenediamine tetraacetic acid disodium salt, 0.3 percent to 0.5 percent of a temperature stabilizer, 0.6 percent to 0.8 percent of a pH value regulator and 0.2 percent to 0.3 percent of a cleanup additive; the pH value of the fracturing fluid base fluid is 7.5. The fracturing fluid base fluid prepared from the produced water has the advantages of rapid adhesion, no precipitation, no weak crosslinking and no floccule phenomenon, so that the guar gum fracturing fluid prepared from the fracturing fluid base fluid has the characteristics of self-adaption to a reservoir, ultralow damage and high performance.

The invention discloses a method for resource utilization of clay vanadium-containing shale, and belongs to the field of solid waste resource utilization. Aiming at the situation that the clay vanadium-containing shale cannot be effectively utilized due to the fact that the vanadium grade is low and cannot meet the development and utilization requirements, so that resources are wasted, the vanadium grade in the clay vanadium-containing shale is improved through pre-enrichment, and the method mainly comprises the following process steps: (1) grading without grinding after crushing: crushing the clay vanadium-containing shale to be-(2-4 mm), and crushing the clay vanadium-containing shale to be-(2-4 mm); grinding is not needed, wet screening and grading are carried out with 25-45 [mu] m as the standard, oversize products and undersize products are obtained, and the undersize products are pre-enriched products I; (2) after-grinding three-section full-open-circuit short-process flotation is conducted on oversize products, the oversize products are ground to-74 microns and account for 50%-85%, then three-section full-open-circuit short-process flotation is conducted in the acid environment that the pH of ore pulp ranges from 3 to 4, and flotation concentrate is a pre-enriched product II; the collecting agent is compounded and assembled autonomously, and the novel combined collecting agent comprises the following components in percentage by mass: 50-75% of dodecyl guanidine hydrochloride and 25-50% of isooctyl alcohol. The combined inhibitor comprises the following components in percentage by mass: 30-50% of water glass and 50-70% of sodium fluosilicate.

This invention provides a dry powder drag-reducing agent for fracturing fluids and its preparation method, belonging to the technical field of fracturing materials for drilling. The method includes the following steps: dissolving 4-bromobutyryl chloride and N-dodecylmethylamine in acetonitrile, heating and stirring to react; adding polyethylene glycol monomethyl ether acrylate and dichloromethane; stirring under a nitrogen atmosphere; purifying to obtain a double-tailed hydrophobic monomer; mixing core-shell Fe3O4 / SiO2 composite nanoparticles, ethanol aqueous solution, KH570, and ammonia solution; stirring; purifying to obtain modified SiO2 / Fe3O4; adding acrylamide, acrylic acid, sodium 2-acrylamido-2-methylpropanesulfonate, the double-tailed hydrophobic monomer, and modified SiO2 / Fe3O4 to water; adjusting the pH value; mixing and stirring with nitrogen gas; adding an azo initiator; stirring; cooling; purifying; vacuum drying; and pulverizing into powder to obtain the dry powder drag-reducing agent for fracturing fluids. This invention achieves good drag-reducing performance while also possessing certain heat resistance, making it better suited for fracturing operations in drilling processes.

The invention provides a collecting agent for flotation of iron lepidolite and a beneficiation method of iron lepidolite, and relates to the field of beneficiation. The collecting agent comprises the following raw materials in parts by weight: 10-30 parts of oleic acid, 5-15 parts of petroleum sodium sulfonate, 5-15 parts of dodecyl primary amine, 7-20 parts of glacial acetic acid and 8-15 parts of ethanol. The collecting agent is easy to dissolve and disperse in ore pulp, selective adsorption of the collecting agent on the surface of lepidolite is achieved, the collecting capacity and selectivity of the collecting agent are improved, and the obvious defects that a large amount of hydrochloric acid needs to be added in the preparation and use process of a traditional amine collecting agent, volatility and corrosivity are high, the requirement for corrosion prevention of equipment is high, and harm to the human body is large are overcome.

The invention relates to high-heat-resistance polypropylene and a preparation method thereof, and belongs to the technical field of high polymer materials. The preparation method comprises the following steps: carrying out Michael addition reaction on 2-sulfydryl-1, 3-propylene glycol and vinyl dibutyl borate to prepare dihydric alcohol containing thioether and phosphate, and carrying out polymerization reaction on 1, 12-dodecanediol, boric acid ester dihydric alcohol and dimethyldichlorosilane to obtain the flame retardant. A polymer containing a borate group, a thioether group, organic silicon and a dodecane glycol ester group is prepared, the polymer is used as a heat-resistant toughening additive of polypropylene, the borate group and the organic silicon can improve the heat resistance and flame retardance of the polypropylene, and the thioether group and the dodecane glycol ester group can provide flexibility; therefore, the polypropylene is ensured to have good mechanical strength, heat resistance and flame retardance at the same time.

The present application belongs to the technical field of silica sol preparation, and particularly relates to a silica sol preparation method using ion exchange method. In the prior art, the silica sol growth time is shortened by optimizing the preparation and impurity removal process, and the silica sol seed mother liquor is prepared under ultrasonic assistance. The organic alkali catalyst maintains the silica sol growth pH and the metal ions in the complex solution, so that the impurities are reduced during the silica sol growth. After the introduction of dodecyltrimethoxysilane, hexadecyltrimethoxysilane and methyltrimethoxysilane as the hydrophobic group surface modification, the impurity metal ions are filtered through the complexing agent and the ammonium type resin. The three ethylene tetramine ethanol solution modifies the ammonium type resin, enhances the selective adsorption of the resin to the metal ions, and the maleic anhydride crosslinking agent and nano silicon dioxide modify the ammonium type resin, increase the service life of the ammonium type resin. The prepared silica sol has high purity, good mechanical properties and dispersibility, and excellent hydrophobic performance.

The invention discloses a preparation method and application of an Al2O3-Pd catalyst, according to the method, pyridine is used as a raw material, n-dodecane is used as an internal standard, alumina supported palladium is used as a catalyst, cyclohexane is used as a solvent, catalytic hydrogenation is carried out under 1.0-3.0 MPa and 100-200 DEG C to obtain piperidine, the conversion rate is up to 99.8%, and the yield is 95% or above. Compared with the traditional rhodium-carbon catalyst, the method has the advantages of low cost and high yield. In addition, the process is mild in reaction condition, high in yield, high in product quality, few in by-product, free of peculiar smell, environmentally friendly and safe.

The invention discloses a preparation method and application of a heterojunction catalyst based on a two-dimensional zinc porphyrin metal organic framework, and belongs to the field of photochemical energy conversion and photocatalytic degradation. The invention aims to solve the technical problems of high-quality preparation of the artificial photosynthetic photocatalytic composite material and how to effectively improve the photochemical energy conversion efficiency. The method comprises the following steps: 1, dissolving bismuth nitrate pentahydrate, sodium tungstate dihydrate and sodium dodecyl dimethyl benzene sulfonate in deionized water, fully stirring, and transferring the solution to a reaction kettle for hydrothermal reaction; cooling to room temperature, washing and drying to obtain bismuth tungstate solid powder; 2, adding bismuth tungstate and meso-tetra (4-carboxyl phenyl) porphin into a mixed solution of N, N-dimethylformamide and ethanol, carrying out ultrasonic treatment, and fully stirring to obtain a solution A; dissolving zinc nitrate hexahydrate, pyrazine and polyvinylpyrrolidone in a mixed solution of N, N-dimethylformamide and ethanol, and fully stirring to obtain a solution B; after the solution is fully dissolved, dropwise adding the solution B into the solution A under ultrasonic and stirring conditions, and then putting the beaker into an oil bath pan for heating; and cooling to room temperature, washing, and storing in an ethanol solution to obtain the Zn-MOF / Bi2WO6 heterojunction composite material.

The present invention relates to a novel polymorph of (1R,2R,3aS,3bR,10aS,10bR,11S,12aS)-5,10b-difluoro-1-(((fluoromethyl)thio)carbonyl)-11-hydroxyl-2,10a,12a-trimethyl-7-phenyl-1,2,3,3a,3b,7,10,10a,10b,11,12,12a-dodecylhydrocyclapenta[5,6]napththo[1,2-F]indazole-1-furan-2-carboxylate ester as shown in formula (I), a preparation method therefor, and a use thereof. The crystal form of the present invention has characteristics such as a significant pharmaceutical effect, good stability, high yield, and high purity, and is beneficial for the selection and design of a drug administration route and the determination of a drug preparation process parameter, thereby improving drug production quality.

The invention discloses a preparation method of an exfoliated zirconium phosphate-based hydrophobic modified nano-composite oil absorption film, which comprises the following steps: carrying out intercalation treatment on alpha-zirconium phosphate by using 3-amino-1-propanol as a guest molecule to obtain hydroxylated intercalated zirconium phosphate; through ring-opening reaction of hydroxyl and epoxy group, grafting dodecyl glycidyl ether on the surface and between layers of intercalated zirconium phosphate to obtain hydrophobic modified exfoliated zirconium phosphate; the preparation method comprises the following steps: adding glutaraldehyde into a hydrophobic modified stripping state zirconium phosphate and polyvinylidene fluoride system, fully stirring, blade-coating to form a film, and immersing into an acid solution for cleaning to obtain the stripping state zirconium phosphate-based hydrophobic modified nano composite oil absorption film. The oil-water separation performance of the zirconium phosphate is effectively improved, and the problem that the zirconium phosphate is difficult to separate and recycle is solved.

The invention discloses an amide chain-bridged bis-tetraphenylethylene fluorescent probe and a synthesis method and application thereof, belonging to the technical field of organic synthesis and analytical chemistry. The fluorescent probe has a structure of an oxalamide-bridged bis-tetraphenylethylene unit and is chemically named 1,2-bis(2-(4-(1-phenyl-2,2-di-dodecylphenyl)vinyl)phenoxyacetyl)ethylenediamine, i.e., Bis-TPE. In the invention, 1,1-di-p-dodecyloxyphenyl-2-phenyl-2-p-hydroxyphenylethylene, 1,2-bis-chloroacetylethylenediamine, and anhydrous potassium carbonate are selected as synthetic raw materials, placed in a dry acetone system for reflux, and after sufficient reaction, the reaction mixture is extracted and distilled under reduced pressure, and the product is separated by silica gel column chromatography, thereby synthesizing the fluorescent probe. The fluorescence intensity of the fluorescent probe of the invention is 1000 nm in Hg 2+ The quenching is obvious in the presence of , and the presence of other ions has little interference with the detection results. The rapid weakening of the fluorescence intensity of the fluorescent probe can be used to detect Hg in the solution. 2+ Highly efficient and selective detection.