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131 results about "Haloalkane" patented technology

The haloalkanes (also known as halogenoalkanes or alkyl halides) are a group of chemical compounds derived from alkanes containing one or more halogens. They are a subset of the general class of halocarbons, although the distinction is not often made. Haloalkanes are widely used commercially and, consequently, are known under many chemical and commercial names. They are used as flame retardants, fire extinguishants, refrigerants, propellants, solvents, and pharmaceuticals. Subsequent to the widespread use in commerce, many halocarbons have also been shown to be serious pollutants and toxins. For example, the chlorofluorocarbons have been shown to lead to ozone depletion. Methyl bromide is a controversial fumigant. Only haloalkanes which contain chlorine, bromine, and iodine are a threat to the ozone layer, but fluorinated volatile haloalkanes in theory may have activity as greenhouse gases. Methyl iodide, a naturally occurring substance, however, does not have ozone-depleting properties and the United States Environmental Protection Agency has designated the compound a non-ozone layer depleter. For more information, see Halomethane. Haloalkane or alkyl halides are the compounds which have the general formula "RX" where R is an alkyl or substituted alkyl group and X is a halogen (F, Cl, Br, I).

Halogenated alkane dehalogenase mutant and application thereof in degradation of 1, 2, 3-tribromopropane

ActiveCN120272456ABacteriaHydrolasesPropanolHaloalkane dehalogenase
The invention discloses a haloalkane dehalogenase mutant and an application thereof in degradation of 1, 2, 3-tribromopropane, haloalkane dehalogenase DhaA31 coded by dhaA gene of a Rhodococcus rhodococcus NCIMB 13064 strain is modified to obtain the haloalkane dehalogenase mutant F168W / I246C, the haloalkane dehalogenase mutant has high degradation efficiency on haloalkane pollutant 1, 2, 3-tribromopropane, and the haloalkane dehalogenase mutant has high degradation efficiency on haloalkane pollutant 1, 2, 3-tribromopropane under the condition of water phase normal temperature. The degradation rate of the alkyl halide dehalogenase mutant to 10 mM of 1, 2, 3-tribromopropane within 1 h reaches 100%, and the degradation rate of the alkyl halide dehalogenase mutant to 10 mM of 1, 2, 3-tribromopropane reaches 100%. The haloalkane dehalogenase mutant has high stereoselectivity on (R)-2, 3-dibromo-1-propanol, and the e.r. Value of the haloalkane dehalogenase mutant reaches 6: 94. The haloalkane dehalogenase mutant provided by the invention has high catalytic efficiency and high stereoselectivity, is beneficial to recognition and further degradation of downstream enzymes, and has a good application prospect in bioremediation of emerging haloalkane pollutants.
Owner:NANJING UNIV

Preparation method and application of oil-soluble heteropolyacid ionic liquid catalyst

The invention discloses a preparation method and application of an oil-soluble heteropolyacid ionic liquid catalyst. The catalyst is composed of organic cations and inorganic anions, the cations are one of quaternary ammonium, imidazole and pyridine cations containing long-chain alkyl, the anions are heteropolyacid anions, the long-chain alkyl enables the catalyst to have good oil solubility, the catalyst can be efficiently dispersed in the waste grease, heteropolyacid provides active sites, and the catalyst can be used for treating the waste grease. Nano-scale active particles are formed after in-situ vulcanization, and the catalytic hydrogenation effect is achieved. The invention also provides a preparation method of the oil-soluble heteropolyacid ionic liquid catalyst, the catalyst can be prepared from tertiary amine and halogenated hydrocarbon through three-step reaction of alkylation, anion exchange and acid-base neutralization, the preparation process is simple, a highly toxic reagent is avoided, and the cost is low. The catalyst provided by the invention can be used for catalytic hydroisomerization of various waste oils and fats, has the characteristics of high conversion rate, low coking rate and high product calorific value, and has relatively high industrial application potential.
Owner:FUZHOU UNIV

Synthesis method of allyl phosphonic acid diester

The invention discloses a synthesis method of allyl phosphonic acid diester. According to the method, phosphorous acid diester and an allyl chloride compound are used as raw materials and react in the presence of a specific transition metal catalyst and alkali under the conditions of normal pressure and 45-60 DEG C to obtain the allyl phosphonic acid diester. The method has the advantages of mild reaction conditions, simple operation, high product yield (90-99%), no by-product, no generation of halogenated alkane gas and easy industrial production, and is suitable for the fields of polymer flame retardants, electronic materials, pesticide and medicine intermediates and the like.
Owner:SUZHOU LEAD BIOTECH CO LTD

Amphiphilic nitrogen-doped coal-based carbon dots and preparation method thereof

The invention provides an amphiphilic nitrogen-doped coal-based carbon dot and a preparation method thereof, and belongs to the technical field of carbon nanomaterials. The method comprises the following steps: performing oxidation-depolymerization treatment on coal by using a mixed solution of formic acid and hydrogen peroxide to obtain coal-based carbon dots; uniformly dispersing the coal-based carbon dots and polyamine in a solvent 1, and then carrying out hydrothermal reaction 1 to obtain nitrogen-doped coal-based carbon dots; dissolving the nitrogen-doped coal-based carbon dots in a solvent 2, and then adding halogenated alkane for reaction 2 to obtain an intermediate product; the intermediate product is dissolved in a solvent 3, then a catalyst and a sulfonating agent are added for a reaction 3, and the amphiphilic nitrogen-doped coal-based carbon dots are obtained. The coal-based carbon dots have controllable hydrophilic and hydrophobic structures, excellent surface activity and interfacial activity, excellent dispersion stability and ultralow interfacial tension in a high-salinity oil-water system, and can meet the actual application requirements in the fields of oil-water interface regulation and control, solid-liquid interface wetting regulation and control and the like.
Owner:YANGTZE UNIVERSITY

Full-bio-based multifunctional antibacterial nylon material as well as preparation method and application thereof

PendingCN120944103AAlkaneCarboxylic acid
The invention discloses a full-bio-based multifunctional antibacterial nylon material as well as a preparation method and application thereof, relates to the technical field of high-molecular polymers, and solves the problems that the preparation process of a nylon material in the prior art depends on petroleum resources, the function is single and the application scene is limited. The method comprises the following steps: reacting an aminocaprolactam solution with corresponding aldehyde / carboxylic acid / halogenated alkane, and purifying to obtain a cyclic lysine derivative monomer M; the preparation method comprises the following steps: mixing and heating a cyclic lysine derivative monomer M, an initiator and a catalyst, reacting, and purifying to obtain a nylon material PM; and carrying out quaternization reaction on the nylon PM solution and alkyl halide, and purifying to obtain the full-bio-based multifunctional nylon material P. The preparation method completely abandons the use of petroleum-based raw materials, realizes the multifunctional synergistic effect of antibacterial property, biocompatibility, antibacterial biofilm property, thermosensitivity and the like, and can be applied to the fields of antibacterial materials, biomedical materials, antibacterial biofilms and thermosensitivity materials.
Owner:CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES

Trichlorbacterium and application thereof in bioremediation of pollutants

The invention relates to the field of environmental microbial remediation, in particular to a strain of trichlorobacterium and application thereof in bioremediation of pollutants. According to the present invention, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, and the bacillus subtilis is bacillus subtilis. The strain NB-12 obtained by the invention is a strain of self-synthesized cobalamin screened from river bottom sediments, is suitable for extensive industrial production and degrades a plurality of halogenated alkanes in the environment.
Owner:SHENYANG INST OF APPL ECOLOGY CHINESE ACAD OF SCI

Compositions and methods for reducing greenhouse gas

Provided herein are consumable compositions for methane reduction in ruminants comprising a haloalkane and a medium chain triglyceride (MCT). The use of MCT in the consumable compositions has been found to enhance the anti-methanogenic effect of the consumable compositions in ruminants. Also provided herein are methods of preparing the consumable composition and methods of administering the consumable compositions to ruminants.
Owner:RUMIN8 PTY LTD

A method for synthesizing a dialkylphosphinic ester

This invention discloses a method for synthesizing dialkylphosphinates, belonging to the field of organic synthesis technology. The method uses hypophosphite and haloalkanes as starting materials. First, a hypophosphite is generated through a heated and pressurized reaction under the action of a phase transfer catalyst. The obtained hypophosphite does not require complex purification; it is directly reacted with an olefin under heated and pressurized conditions in the presence of a free radical initiator to obtain the target product, dialkylphosphinate. The method of this invention uses inexpensive and readily available raw materials, has a simple process route, includes only two core reactions, operates under mild conditions, is safe and convenient, produces few and easily treatable byproducts, has a high product yield, and is simple to purify. It is very suitable for large-scale industrial production, providing an economical and efficient synthetic route for the preparation of high-performance halogen-free flame retardants.
Owner:ZHEJIANG WANSHENG CO LTD

Purification method for fluoroolefin having structure of =CF2 or =CHF, high-purity fluoroolefin, and production method therefor

ActiveUS12410112B2Halogenated hydrocarbon preparationHaloalkeneAlkane
Impurities are removed from a fluoroolefin having a structure of ═CF2 or ═CHF that has been obtained by a dehydrohalogenation reaction and that contains haloalkene, haloalkane, and / or haloalkyne impurities.Provided are: a method of purifying a fluoroolefin having a structure of ═CF2 or ═CHF, comprising bringing a fluoroolefin having a structure of ═CF2 or ═CHF that has been obtained by a dehydrohalogenation reaction and that contains at least one of haloalkane, haloalkene, and / or haloalkyne impurities into contact with a solid adsorbent to remove the impurities through adsorption; a high-purity fluoroolefin; and a production method therefor.
Owner:KANTO DENKA IND CO LTD

Degradable Gemini morpholine quaternary ammonium salt, and preparation method and application thereof

The application discloses a degradable gemini morpholine quaternary ammonium salt. The application further discloses a preparation method of the degradable gemini morpholine quaternary ammonium salt, comprising the following steps: S1, performing N-alkylation reaction on morpholine and halogenated alkane to obtain N-alkyl morpholine; S2, performing reaction on substance A and halogenated acetyl halide to obtain substance B; S3, continuously performing N-alkylation reaction on the N-alkyl morpholine and the substance B to obtain the degradable gemini morpholine quaternary ammonium salt. The application further discloses application of the degradable gemini morpholine quaternary ammonium salt in a bactericide and in preparation of a medicine for treating helicobacter pylori infection. The gemini morpholine quaternary ammonium salt has a good effect of killing helicobacter pylori; the gemini morpholine quaternary ammonium salt can be degraded in an alkaline environment, can avoid drug resistance of helicobacter pylori to the gemini morpholine quaternary ammonium salt, and can make the degradation product be rapidly discharged out of the body.
Owner:UNIV OF SCI & TECH OF CHINA

Polyethylene catalysts and methods for their preparation and ultra-high molecular weight polyethylene and methods for their preparation

This invention relates to the field of catalysts, specifically to a polyethylene catalyst and its preparation method, as well as ultra-high molecular weight polyethylene and its preparation method. The method includes the following steps: (1) under diluent conditions, a magnesium halide precursor, an alcohol compound, and a first internal electron donor undergo a first contact reaction to obtain a first reaction solution; (2) a second internal electron donor is added to the first reaction solution to undergo a second contact reaction to obtain a second reaction solution; (3) a titanium precursor is added to the second reaction solution to undergo a third contact reaction to obtain a third reaction solution; (4) a haloalkane is added to the third reaction solution, followed by a third internal electron donor to undergo a fourth contact reaction. The catalyst prepared by this invention exhibits good catalytic performance.
Owner:PETROCHINA CO LTD

Method for removing probenecid sodium halogenated alkyl toxic impurities

The invention relates to a method for removing halogenated alkyl toxic impurities in probenecid sodium, which is characterized by comprising the following steps of: 1, heating and hydrolyzing excessive halogenated alkyl under an alkaline condition to remove the halogenated alkyl toxic impurities; 2, organic solvent extraction and removal; 3, adsorption removal by a specific adsorption column; after the treatment by the method, the residue of haloalkane is reduced to be not detected from 15-100ppm, and the limit requirements of related genotoxic impurities in Chinese drug registration regulations and ICH guidance principles are completely met.
Owner:ANHUI KANGZHENG KANGYUAN PHARM CO LTD

A process for the preparation of r-(+)-2,2-dimethyl-1,3-dioxolane-4-carboxaldehyde

The present application relates to a kind of preparation methods of R-(+)-2,2-dimethyl-1,3-dioxolane-4-formaldehyde, belong to the technical field of pharmaceutical intermediates synthesis.In order to solve the existing wastewater pollution and the problem of low selectivity, provide a kind of preparation method of R-(+)-2,2-dimethyl-1,3-dioxolane-4-formaldehyde, the method includes the action of catalytic amount of phase transfer catalyst quaternary ammonium salt and oxidant, the oxidant is selected from PCC or BPCC, in halogenated alkane solvent, substrate formula II compound double ketone-D-mannitol is converted into product formula I compound R-(+)-2,2-dimethyl-1,3-dioxolane-4-formaldehyde by catalytic oxidation reaction.The present application has the effect of high product yield and purity quality, product yield reaches more than 95%, purity reaches more than 99.5%, also greatly reduces the generation of a large amount of wastewater, the advantage of environment-friendly.
Owner:JIANGSU BAJU PHARM CO LTD

Process for the modification of a beta-ketimine ligand precursor and products thereof

This invention relates to a simple method for modifying β-ketoimine ligand precursors, wherein L... Ph The reaction involves a lithium compound with H2 solution; then a haloalkane is added for C-C coupling; followed by the addition of an acid solution to complete the modification of the β-ketoimine ligand precursor, yielding a terminally alkylated ketoimine. This invention relates to a simple method for modifying β-ketoimine ligand precursors, specifically involving the removal of the proton at the α-position of the β-ketoimine ligand precursor from commercially available n-butyllithium to form a deprotonated β-ketoimine lithium compound, followed by C-C coupling to achieve alkylation at the α-position of the ketocarbonyl group, thus providing a convenient modification of the β-ketoimine ligand precursor.
Owner:SUZHOU UNIV

High-stereoselectivity haloalkane dehalogenase mutant and application thereof

ActiveCN120519424ABacteriaHydrolasesHaloalkane dehalogenaseBioremediation
The invention discloses a haloalkane dehalogenase mutant with high stereoselectivity and application thereof.The haloalkane dehalogenase mutant F131M / F168M / I246L is obtained by modifying haloalkane dehalogenase DhaA31 coded by a rhodococcus dhaA gene, the haloalkane dehalogenase mutant has high degradation efficiency on haloalkane pollutants 1, 2, 3-tribromopropane, and the haloalkane dehalogenase mutant has high stereoselectivity on haloalkane pollutants 1, 2, 3-tribromopropane under the water-phase normal-temperature condition. The degradation rate of the alkyl halide dehalogenase mutant to 10 mM of 1, 2, 3-tribromopropane within 60 min reaches 100%, and the degradation rate of the alkyl halide dehalogenase mutant to 10 mM of 1, 2, 3-tribromopropane reaches 100%. The haloalkane dehalogenase mutant has high stereoselectivity on a high-value product (S)-2, 3-dibromo-1-propanol, and the e.r. Value of the haloalkane dehalogenase mutant reaches 98: 2. The haloalkane dehalogenase mutant provided by the invention has high catalytic efficiency and high stereoselectivity, and has a good application prospect in bioremediation and recycling of emerging haloalkane pollutants.
Owner:NANJING UNIV

Halon purification method

There is provided a halon purification method capable of simply, safely, and efficiently removing mixed bromine molecules to obtain high purity halon. The halon purification method is a method for removing bromine molecules from crude halon containing halon and the bromine molecules, and the method includes: a contact step of bringing the crude halon into contact with an absorbing liquid containing an aqueous solution containing metal iodide to obtain a mixed liquid containing the crude halon and the absorbing liquid; and a separation step of separating the halon from the mixed liquid to obtain the halon and the absorbing liquid having absorbed the bromine molecules.
Owner:RESONAC CORP

Method for continuously preparing alkyl phosphonic acid diaryl ester

The invention relates to a method for continuously preparing alkyl diaryl phosphonate, which comprises the following steps of: a, reacting trialkyl phosphite and triaryl phosphite in a high-temperature section filled with a solid catalyst to obtain a reaction product; and b, removing low-fraction byproducts in the reaction product in the step a through reduced pressure distillation or fractionation at the outlet of the high-temperature section, feeding the residual product into a cooling section, collecting a crude product of the alkyl diaryl phosphonate at the outlet of the cooling section, and carrying out post-treatment to obtain the alkyl diaryl phosphonate. A continuous catalytic reaction is carried out through the solid catalyst filled in the tubular reactor, and an intermittent reaction is changed into a continuous reaction, so that the liquid holdup is greatly reduced, and the safety coefficient of production is improved; a traditional halogenated alkane catalyst is not used, so that the risk that the temperature rise is out of control is effectively reduced; according to the method, the reaction time is shortened while the reaction yield is not reduced, and the production efficiency is improved.
Owner:NINGBO PUDUOKIKE TECH DEV CO LTD

A preparation method of a phenylbutyric acid nitrogen mustard NO donor prodrug delivery system and a medicine for treating tumors

This invention provides a chlorambucil NO donor prodrug having the structure shown in Formula (I) or a pharmaceutically acceptable salt thereof: Formula (I). It involves reacting chlorambucil with a dihaloalkane to obtain a halochlorambucil intermediate; reacting the halochlorambucil intermediate with silver nitrate to obtain the chlorambucil NO donor prodrug. This invention applies the chlorambucil NO donor prodrug to the preparation of drugs for treating tumors, such as melanoma, lymphoma, leukemia, or breast cancer. This nanosystem exhibits good NO release levels under light irradiation. Cellular experiments have demonstrated its good antitumor effect, providing a new strategy for multimodal combined antitumor therapy.
Owner:CHINA THREE GORGES UNIV

Haloalkane dehalogenase mutants and their application in the degradation of 1,2,3-tribromopropane

ActiveCN120272456BBacteriaHydrolasesPropanolHaloalkane dehalogenase
The present invention discloses a haloalkane dehalogenase mutant and its application in degrading 1,2,3-tribromopropane. Rhodococcus rhodochrous NCIMB 13064 strain dhaA The genetically encoded haloalkane dehalogenase DhaA31 was modified to obtain a haloalkane dehalogenase mutant F168W / I246C. The haloalkane dehalogenase mutant has a high degradation efficiency for the haloalkane pollutant 1,2,3-tribromopropane. Under normal temperature conditions in an aqueous phase, the haloalkane dehalogenase mutant has a degradation rate of 100% for 10 mM 1,2,3-tribromopropane within 1 hour; the haloalkane dehalogenase mutant has high stereoselectivity for (R)-2,3-dibromo-1-propanol, with an er value of 6:94. The haloalkane dehalogenase mutant provided by the present invention has high catalytic efficiency and high stereoselectivity, which is conducive to the recognition and further degradation of downstream enzymes, and has good application prospects in the bioremediation of emerging haloalkane pollutants.
Owner:NANJING UNIV

Quaternary ammonium salt polymer catalyst as well as preparation method and application thereof

The invention relates to the technical field of water treatment, in particular to a quaternary ammonium salt polymer catalyst and a preparation method and application thereof. The quaternary ammonium salt polymer catalyst provided by the invention is prepared by the following steps: generating water-in-oil liquid drops from a raw material mixed solution comprising a precursor material, water, a photoinitiator and a cross-linking agent through a microfluidic technology, polymerizing under ultraviolet irradiation, and then carrying out anion exchange, the precursor material is prepared by reacting raw materials including acrylate and halogenated alkane. The quaternary ammonium salt polymer catalyst provided by the invention can activate peroxide to generate intermediate active species of ketone peroxide so as to oxidize and degrade organic pollutants, and meanwhile, ketone peroxide further reacts to generate singlet oxygen, so that the degradation of the organic pollutants can be enhanced. The quaternary ammonium salt polymer catalyst provided by the invention has high catalytic efficiency, and can realize efficient removal of organic pollutants in a short time.
Owner:UNIV OF SCI & TECH OF CHINA

Disubstituted 4, 4 '-bipyridine derivative, preparation method thereof and electro-catalytic material

The invention relates to a disubstituted 4, 4 '-bipyridine derivative as well as a preparation method and an electro-catalytic material thereof. The compound has the following structural general formula: in the formula, R1 is C2-6 alkyl, and R2 is C3-6 alkenyl. The preparation method comprises the following steps: mixing halogenated alkane and 4, 4 '-dipyridyl in an organic solvent for reaction, carrying out solid-liquid separation on a reaction system, and precipitating an intermediate compound from filtrate; redissolving the intermediate compound, and adding halogenated olefin for reaction; and collecting a precipitation product, and drying to obtain the 4, 4 '-bipyridine derivative. The electro-catalytic material is used for electro-catalytic oxygen evolution reaction and comprises foamed nickel and a disubstituted 4, 4 '-bipyridine derivative loaded on the foamed nickel. Compared with the prior art, the disubstituted 4, 4 '-bipyridine derivative and the electrocatalytic material prepared by the invention have relatively small overpotential voltage and resistance in an alkaline electrolyte environment, and can be used for an electrocatalytic oxygen evolution process of electrolyzed water.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

A positively charged quaternary ammonium salt polymer catalyst and its preparation method and application

The invention belongs to the field of water treatment, and more particularly to a positively charged quaternary ammonium salt polymer catalyst and its preparation method and application. The catalyst provided by the present invention is made of a positively charged quaternary ammonium salt precursor through polymerization and anion exchange, and the positively charged quaternary ammonium salt precursor is the reaction product of acrylate and halogenated alkane; the acrylate is one or more of dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate and 3 (dimethylamino) ethyl acrylate; the halogenated alkane is one or more of undecane bromide, dodecane bromide, tetradecane bromide, hexadecane bromide, eicosane bromide, dodecane chloride, tetradecane chloride and hexadecane chloride. The catalyst provided by the present invention has good stability and antibacterial properties, can efficiently and selectively catalyze the degradation of organic pollutants by peroxide, has important practical significance for removing wastewater rich in organic pollutants, and has a wide range of applications in water pollution control and water environment restoration.
Owner:UNIV OF SCI & TECH OF CHINA

A catalytic synthesis method of chiral polysubstituted hydrogenated quinolines

The application discloses a catalytic synthesis method of chiral polysubstituted hydrogenated quinoline compounds, and belongs to the field of organic synthesis. The application comprises the following steps: at 0-40 DEG C, alcohol or halogenated alkane is used as a solvent, a copper metal catalyst and a chiral ligand are added, and reaction is carried out under nitrogen protection for 0.5-2 hours; the temperature is lowered to-60-0 DEG C; then, o-aminophenyl nitrone, propargyl alcohol ester and alkali are sequentially added; and reaction is carried out for 6-48 hours, so as to obtain a chiral polysubstituted hydrogenated quinoline compound shown in formula 1 or 2. The application realizes, for the first time, synthesis of chiral polysubstituted hydrogenated quinoline compounds by using o-aminophenyl nitrone and propargyl alcohol ester as reactants, and by using a cheap copper metal catalyst and a chiral ligand, the method is simple in operation, low in cost, and has excellent enantioselectivity and diastereoselectivity.
Owner:OCEAN UNIV OF CHINA

Process for producing hydro(chloro)fluorocarbon compounds

A process is provided which includes contacting a haloalkane reactant with a fluorination agent in the liquid phase, in the presence of a catalyst, under conditions which are free of or substantially free of a superacid, to produce a product stream including a haloalkane product, preferably a hydro(chloro)fluorocarbon.
Owner:THE CHEMOURS CO FC LLC

Preparation method of anion exchange membrane, anion exchange membrane and fuel cell

The invention provides a preparation method of an anion exchange membrane, the anion exchange membrane and a fuel cell. The preparation method comprises the following steps: S1, taking ammonium salt and halogenated alkane, and sequentially carrying out first dispersion, filtration and first drying treatment in a first solvent, so as to obtain white powder; s2, polybenzimidazole, polyvinyl benzyl chloride and white powder are taken and subjected to second dispersion in a second solvent, and a functionalized ion exchange membrane solution is obtained; s3, polyvinyl alcohol and the functionalized ion exchange membrane solution are taken and subjected to third dispersion in a third solvent, and a blended ion exchange membrane solution is obtained; and S4, taking the hydrophilic nano inorganic particles, and sequentially carrying out fourth dispersion, second drying, washing and cooling treatment in the blended ion exchange membrane solution to obtain the anion exchange membrane. The anion exchange membrane obtained by adopting the technical scheme has the advantages of better mechanical property, higher stability, low cost and better comprehensive performance.
Owner:PETROCHINA SHENZHEN NEW ENERGY RESEARCH INSTITUTE CO LTD +1

A preparation method of 1H-imidazole-1-acetic acid alkyl ester

The present invention discloses a method for preparing 1H-imidazole-1-acetic acid hydrocarbon ester, comprising the following steps: using a halogenated alkane as a solvent, reacting imidazole with an alkali metal alcoholate to obtain an imidazole alkali metal salt, and then reacting with an N-alkylating agent to obtain the 1H-imidazole-1-acetic acid hydrocarbon ester. The raw materials used are inexpensive and readily available, the experimental operation is simple and gentle, the yield and purity of the obtained product are high, production costs are significantly reduced, and the method provides good application prospects for the industrial production of zoledronic acid raw materials.
Owner:GUANGZHOU UNIRISE PHARM CO LTD +3

Dispersing agent applied to nanocellulose drying and application method thereof

PendingCN120309920APolymer scienceDesiccant
The invention relates to the field of drying of nano-crystalline cellulose, in particular to a dispersing agent for improving the redispersion efficiency of the dried nano-crystalline cellulose and a preparation method of the dispersing agent. The related drying agent is polyethylene glycol dialkyl ether, that is, two ends of polyethylene glycol are substituted by saturated alkyl chains, and the drying agent is prepared by carrying out nucleophilic substitution reaction on polyethylene glycol and alkyl halide. When the adding amount of the dispersing agent is 1%-50% of the dry weight of the nanocellulose, the redispersion performance of the dry nanocellulose can be remarkably improved. The dried nano cellulose not only can be re-dispersed in water, but also can be re-dispersed in polar aprotic solvents such as dimethyl sulfoxide, tetrahydrofuran and the like; and the re-dispersed nano-crystalline cellulose still keeps a nano-scale structure. The dispersing agent disclosed by the invention is easy to separate from the nanocellulose, is stable in property, does not participate in conventional chemical reaction, and is beneficial to chemical modification of the nanocellulose.
Owner:TIANJIN UNIV OF SCI & TECH

Refrigeration cycle working medium and refrigeration cycle system

A working medium for a refrigeration cycle includes: as a refrigerant component, fluoroolefin that causes a disproportionation reaction; and as a disproportionation inhibitor that suppresses the disproportionation reaction of the fluoroolefin, fluoroalkane (except for difluoromethane) having a boiling point of 0°C or less and a carbon number of 1 to 3. The working medium for the refrigeration cycle may further include difluoromethane (R32) as the refrigerant component. The working medium for the refrigeration cycle may further include, as the disproportionation inhibitor, haloalkane that has the carbon number of 1 or 2 and is not a compound in which all halogen atoms are fluorine. Thus, the combustibility of the working medium for the refrigeration cycle which includes the fluoroolefin as the refrigerant component and also includes the disproportionation inhibitor can be satisfactorily suppressed.
Owner:PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD