The invention relates to a disubstituted 4, 4 '-
bipyridine derivative as well as a preparation method and an electro-catalytic material thereof. The compound has the following structural general formula: in the formula, R1 is C2-6
alkyl, and R2 is C3-6 alkenyl. The preparation method comprises the following steps: mixing halogenated
alkane and 4, 4 '-dipyridyl in an
organic solvent for reaction, carrying out
solid-liquid separation on a
reaction system, and precipitating an intermediate compound from filtrate; redissolving the intermediate compound, and adding halogenated olefin for reaction; and collecting a
precipitation product, and
drying to obtain the 4, 4 '-
bipyridine derivative. The electro-catalytic material is used for electro-catalytic
oxygen evolution reaction and comprises foamed
nickel and a disubstituted 4, 4 '-
bipyridine derivative loaded on the foamed
nickel. Compared with the prior art, the disubstituted 4, 4 '-bipyridine derivative and the electrocatalytic material prepared by the invention have relatively small
overpotential voltage and resistance in an alkaline
electrolyte environment, and can be used for an electrocatalytic
oxygen evolution process of electrolyzed water.