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237 results about "Haloalkane" patented technology

The haloalkanes (also known as halogenoalkanes or alkyl halides) are a group of chemical compounds derived from alkanes containing one or more halogens. They are a subset of the general class of halocarbons, although the distinction is not often made. Haloalkanes are widely used commercially and, consequently, are known under many chemical and commercial names. They are used as flame retardants, fire extinguishants, refrigerants, propellants, solvents, and pharmaceuticals. Subsequent to the widespread use in commerce, many halocarbons have also been shown to be serious pollutants and toxins. For example, the chlorofluorocarbons have been shown to lead to ozone depletion. Methyl bromide is a controversial fumigant. Only haloalkanes which contain chlorine, bromine, and iodine are a threat to the ozone layer, but fluorinated volatile haloalkanes in theory may have activity as greenhouse gases. Methyl iodide, a naturally occurring substance, however, does not have ozone-depleting properties and the United States Environmental Protection Agency has designated the compound a non-ozone layer depleter. For more information, see Halomethane. Haloalkane or alkyl halides are the compounds which have the general formula "RX" where R is an alkyl or substituted alkyl group and X is a halogen (F, Cl, Br, I).

Halogenated alkane dehalogenase mutant and application thereof in degradation of 1, 2, 3-tribromopropane

ActiveCN120272456ABacteriaHydrolasesPropanolHaloalkane dehalogenase
The invention discloses a haloalkane dehalogenase mutant and an application thereof in degradation of 1, 2, 3-tribromopropane, haloalkane dehalogenase DhaA31 coded by dhaA gene of a Rhodococcus rhodococcus NCIMB 13064 strain is modified to obtain the haloalkane dehalogenase mutant F168W / I246C, the haloalkane dehalogenase mutant has high degradation efficiency on haloalkane pollutant 1, 2, 3-tribromopropane, and the haloalkane dehalogenase mutant has high degradation efficiency on haloalkane pollutant 1, 2, 3-tribromopropane under the condition of water phase normal temperature. The degradation rate of the alkyl halide dehalogenase mutant to 10 mM of 1, 2, 3-tribromopropane within 1 h reaches 100%, and the degradation rate of the alkyl halide dehalogenase mutant to 10 mM of 1, 2, 3-tribromopropane reaches 100%. The haloalkane dehalogenase mutant has high stereoselectivity on (R)-2, 3-dibromo-1-propanol, and the e.r. Value of the haloalkane dehalogenase mutant reaches 6: 94. The haloalkane dehalogenase mutant provided by the invention has high catalytic efficiency and high stereoselectivity, is beneficial to recognition and further degradation of downstream enzymes, and has a good application prospect in bioremediation of emerging haloalkane pollutants.
Owner:NANJING UNIV

Electrolyte and lithium battery containing same

The invention provides an electrolyte and a lithium battery containing the same. The electrolyte comprises a lithium salt, a solvent and an inducer, the solvent comprises one or more of siloxane compounds as shown in a formula I; the inducer is selected from one or more of C1-C5 halogenated alkanes, C1-C5 halogenated cycloalkanes, C2-C6 halogenated aliphatic ethers and C6-C12 halogenated aromatic compounds. The electrolyte provided by the invention utilizes the intermolecular interaction force between the siloxane compound and the inducer, so that the dissolution of the lithium salt in the solvent is realized, and the electrolyte has high compatibility to a lithium metal negative electrode, has a wide electrochemical window, can be well matched with a high-voltage positive electrode material and a lithium metal negative electrode material, and has a good application prospect. And the cycle life and coulombic efficiency of the battery can be improved.
Owner:BEIJING CHEHEJIA AUTOMOBILE TECH CO LTD

Diester single-tail cationic surfactant as well as preparation method and application thereof

The invention relates to the technical field of oilfield chemistry, in particular to a diester single-tail cationic surfactant, a preparation method and application thereof and a discharge aiding agent for acid fracturing. The diester single-tail cationic surface active agent is prepared from raw materials such as N, N-dimethyl-1, 3amine, methyl acrylate and halogenated alkane. The invention provides a low-cost, green and environment-friendly diester single-tail cationic surface active agent, and the preparation method of the diester single-tail cationic surface active agent is simple and convenient to operate, safe, reliable and beneficial to industrial production, popularization and application, and has a wide market prospect. The acid fracturing discharge aiding agent using the diester single-tailed surfactant as a raw material can effectively reduce the surface and interfacial tension of an aqueous solution, and meets the technical specification of the acid fracturing discharge aiding agent.
Owner:CHINA NAT PETROLEUM CORP +1

Butyl lithium solid-liquid separation continuous reaction device and butyl lithium preparation method

The invention discloses a butyl lithium solid-liquid separation continuous reaction device and a butyl lithium preparation method. According to the reaction device, through double-layer convection stirring and a baffle plate with a pyramid tip, full contact of metal lithium and halogenated alkane is realized on the premise of not dispersing lithium, the problem of excessive consumption of the metal lithium and the halogenated alkane is solved, and the problem of blockage of a filtering device in a traditional process is solved through a top discharging and bottom filtering mode; according to the method, excessive lithium metal and halogenated alkane react in the liquid-phase solvent, so that the yield of halogenated alkane is increased, excessive lithium can continue to participate in the synthesis reaction of the next kettle of butyl lithium, the content of lithium metal in the product discharged from the reactor is greatly reduced in the process on the premise of ensuring the yield of the butyl lithium product, the utilization rate of lithium is increased, and the production cost is reduced. And industrial production is facilitated.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Phosphoric acid doped quaternized poly (alkane biphenyl-imidazole formaldehyde-biphenyl) polymer electrolyte membrane and preparation method thereof

PendingCN119241786AImprove mechanical propertiesThe preparation method is simple and safeFuel cellsAlkanePolymer science
The invention belongs to the technical field of high polymer materials, and particularly relates to a phosphoric acid doped quaternized poly (alkane biphenyl-imidazole formaldehyde-biphenyl) polymer electrolyte membrane and a preparation method thereof. The preparation method comprises the following steps: in a nitrogen environment, adding 2-brominated biphenyl into tetrahydrofuran, uniformly stirring, adding n-butyllithium at-78 DEG C, stirring, adding halogenated alkane, and continuously stirring to obtain 2-alkane biphenyl; the preparation method comprises the following steps: carrying out Friedel-Crafts reaction on 2-alkane biphenyl, biphenyl and 4-imidazole formaldehyde, and carrying out strong acid catalytic polymerization to obtain a poly (alkane biphenyl-imidazole formaldehyde-biphenyl) polymer; carrying out quaternization treatment to obtain a polymer subjected to quaternization treatment; and finally carrying out phosphoric acid doping to obtain the polymer electrolyte membrane. A long alkyl chain is grafted to a main chain to construct microphase separation, more channels are provided for proton transmission, quaternization treatment is adopted, so that the polymer electrolyte membrane has higher acid absorption capacity, and the ether-free main chain can improve the mechanical property of the membrane.
Owner:CHANGZHOU UNIV

Preparation method and application of oil-soluble heteropolyacid ionic liquid catalyst

The invention discloses a preparation method and application of an oil-soluble heteropolyacid ionic liquid catalyst. The catalyst is composed of organic cations and inorganic anions, the cations are one of quaternary ammonium, imidazole and pyridine cations containing long-chain alkyl, the anions are heteropolyacid anions, the long-chain alkyl enables the catalyst to have good oil solubility, the catalyst can be efficiently dispersed in the waste grease, heteropolyacid provides active sites, and the catalyst can be used for treating the waste grease. Nano-scale active particles are formed after in-situ vulcanization, and the catalytic hydrogenation effect is achieved. The invention also provides a preparation method of the oil-soluble heteropolyacid ionic liquid catalyst, the catalyst can be prepared from tertiary amine and halogenated hydrocarbon through three-step reaction of alkylation, anion exchange and acid-base neutralization, the preparation process is simple, a highly toxic reagent is avoided, and the cost is low. The catalyst provided by the invention can be used for catalytic hydroisomerization of various waste oils and fats, has the characteristics of high conversion rate, low coking rate and high product calorific value, and has relatively high industrial application potential.
Owner:FUZHOU UNIV

Synthesis method of allyl phosphonic acid diester

The invention discloses a synthesis method of allyl phosphonic acid diester. According to the method, phosphorous acid diester and an allyl chloride compound are used as raw materials and react in the presence of a specific transition metal catalyst and alkali under the conditions of normal pressure and 45-60 DEG C to obtain the allyl phosphonic acid diester. The method has the advantages of mild reaction conditions, simple operation, high product yield (90-99%), no by-product, no generation of halogenated alkane gas and easy industrial production, and is suitable for the fields of polymer flame retardants, electronic materials, pesticide and medicine intermediates and the like.
Owner:SUZHOU LEAD BIOTECH CO LTD

Amphiphilic nitrogen-doped coal-based carbon dots and preparation method thereof

The invention provides an amphiphilic nitrogen-doped coal-based carbon dot and a preparation method thereof, and belongs to the technical field of carbon nanomaterials. The method comprises the following steps: performing oxidation-depolymerization treatment on coal by using a mixed solution of formic acid and hydrogen peroxide to obtain coal-based carbon dots; uniformly dispersing the coal-based carbon dots and polyamine in a solvent 1, and then carrying out hydrothermal reaction 1 to obtain nitrogen-doped coal-based carbon dots; dissolving the nitrogen-doped coal-based carbon dots in a solvent 2, and then adding halogenated alkane for reaction 2 to obtain an intermediate product; the intermediate product is dissolved in a solvent 3, then a catalyst and a sulfonating agent are added for a reaction 3, and the amphiphilic nitrogen-doped coal-based carbon dots are obtained. The coal-based carbon dots have controllable hydrophilic and hydrophobic structures, excellent surface activity and interfacial activity, excellent dispersion stability and ultralow interfacial tension in a high-salinity oil-water system, and can meet the actual application requirements in the fields of oil-water interface regulation and control, solid-liquid interface wetting regulation and control and the like.
Owner:YANGTZE UNIVERSITY

Full-bio-based multifunctional antibacterial nylon material as well as preparation method and application thereof

PendingCN120944103AAlkaneCarboxylic acid
The invention discloses a full-bio-based multifunctional antibacterial nylon material as well as a preparation method and application thereof, relates to the technical field of high-molecular polymers, and solves the problems that the preparation process of a nylon material in the prior art depends on petroleum resources, the function is single and the application scene is limited. The method comprises the following steps: reacting an aminocaprolactam solution with corresponding aldehyde / carboxylic acid / halogenated alkane, and purifying to obtain a cyclic lysine derivative monomer M; the preparation method comprises the following steps: mixing and heating a cyclic lysine derivative monomer M, an initiator and a catalyst, reacting, and purifying to obtain a nylon material PM; and carrying out quaternization reaction on the nylon PM solution and alkyl halide, and purifying to obtain the full-bio-based multifunctional nylon material P. The preparation method completely abandons the use of petroleum-based raw materials, realizes the multifunctional synergistic effect of antibacterial property, biocompatibility, antibacterial biofilm property, thermosensitivity and the like, and can be applied to the fields of antibacterial materials, biomedical materials, antibacterial biofilms and thermosensitivity materials.
Owner:CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES

Trichlorbacterium and application thereof in bioremediation of pollutants

The invention relates to the field of environmental microbial remediation, in particular to a strain of trichlorobacterium and application thereof in bioremediation of pollutants. According to the present invention, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, and the bacillus subtilis is bacillus subtilis. The strain NB-12 obtained by the invention is a strain of self-synthesized cobalamin screened from river bottom sediments, is suitable for extensive industrial production and degrades a plurality of halogenated alkanes in the environment.
Owner:SHENYANG INST OF APPL ECOLOGY CHINESE ACAD OF SCI

Efficient method for pretreating, degrading and recycling thermosetting epoxy resin based on mixed reaction type solvothermal method

The invention provides an efficient method for pretreating, degrading and recycling thermosetting epoxy resin based on a mixed reaction type solvothermal method. The efficient method comprises the following steps: S1, providing cured epoxy resin; s2, adding the cured epoxy resin into double solvents for pre-soaking so as to provide a pre-treated sample; the double solvent is selected from halogenated alkane and aliphatic amine; and S3, carrying out reflux on the pretreated sample in a low-temperature interval, cooling to room temperature, carrying out first suction filtration to obtain a first filtrate, mixing the first filtrate with water to separate out a precipitate or form a dispersion liquid, carrying out second suction filtration on the precipitate, further separating the dispersion liquid, and recovering to obtain the epoxy resin degradation micromolecules or oligomers. According to the present invention, the halogenated alkane-aliphatic amine mixed reaction type double solvents with different proportions are subjected to pre-soaking and low-temperature interval reflux, and the obtained mixture and the original solvent molecule have the synergistic effect, such that the thermosetting epoxy resin can be efficiently degraded, the environmental protection is achieved, and the cost is low.
Owner:SHANGHAI JIAOTONG UNIV +1

Compositions and methods for reducing greenhouse gas

Provided herein are consumable compositions for methane reduction in ruminants comprising a haloalkane and a medium chain triglyceride (MCT). The use of MCT in the consumable compositions has been found to enhance the anti-methanogenic effect of the consumable compositions in ruminants. Also provided herein are methods of preparing the consumable composition and methods of administering the consumable compositions to ruminants.
Owner:RUMIN8 PTY LTD

Tetrazole alcohol compound as well as preparation method and application thereof

The invention provides a tetrazole alcohol compound as well as a preparation method and application thereof, and belongs to the field of medicines. The tetrazole alcohol compound provided by the invention has the characteristics that the structural formula is as shown in the formula I: # imgabs0 #, in the formula I, R1 represents H or F, R2 represents H or F, R3 is independently selected from any one of C1-C4 alkyl, C1-C4 alkoxy, halogen, halogenated alkane, halogenated alkoxy, cyano, a benzene ring and a substituted benzene ring, R4 represents H or CH3, X represents CH or N, and Y represents CH or N. The azaconazole compound has remarkable in-vitro and in-vivo antifungal activity on human pathogenic fungi such as candida albicans, cryptococcus neoformans and aspergillus fumigatus, and the in-vitro and in-vivo antifungal activity is higher than that of a traditional antifungal drug fluconazole, and meanwhile, the azaconazole compound has a low inhibition effect on human CYP450 enzyme, especially on human liver drug enzyme CYP3A4, and has a good application prospect. Therefore, the compound can be used for preparing antifungal drugs.
Owner:SHANGHAI TENTH PEOPLES HOSPITAL

Method for detecting impurities in trifluoromethanesulfonate

The invention belongs to the field of drug mutagenesis impurity detection and analysis, and relates to a method for detecting impurities of trifluoromethanesulfonate, in particular to a method for detecting impurities of methyl trifluoromethanesulfonate and ethyl trifluoromethanesulfonate. Specifically, according to the detection method disclosed by the invention, tetrabutylammonium bromide is used as a derivatization reagent to derivatize trifluoromethanesulfonate, a corresponding derivative halogenated alkane is detected by GC-MS (Gas Chromatography-Mass Spectrometer), and then the content of trifluoromethanesulfonate is determined. The method provided by the invention solves the problem that the detection result may have false negative in the prior art, and has the advantages of high sensitivity, low detection limit, good repeatability and high accuracy, and all substances can be well separated.
Owner:SUNSHINE LAKE PHARMA CO LTD

Euphausia superba dehalogenase and application thereof in degradation of halogenated alkane compound

The invention provides euphausia superba dehalogenase and application thereof in degradation of halogenated alkane compounds. The amino acid sequence of the provided euphausia superba dehalogenase is SEQ ID NO: 2. The euphausia superba dehalogenase provided by the invention can efficiently degrade bis-2-chloroethyl sulfide under mild conditions to generate chloride ions and non-toxic sulfur diethylene glycol, can replace a traditional chemical decontamination method, and shows huge application potential. In addition, the stability protective agent for the euphausia superba dehalogenase can keep the activity of the dehalogenase at 88% or above all the time.
Owner:YELLOW SEA FISHERIES RES INST CHINESE ACAD OF FISHERIES SCI

Intrinsic flame-retardant bio-based epoxy resin and preparation method thereof

PendingCN119462572Areduced thermal stabilityGuaranteed rigidityOrganic chemistryEpoxyAlkane
The invention relates to intrinsic flame-retardant bio-based epoxy resin and a synthesis method thereof.The intrinsic flame-retardant bio-based epoxy resin takes magnolol as a main raw material, and the molecular structure contains biphenyl units and ester bonds, so that the intrinsic flame-retardant bio-based epoxy resin has excellent flame retardance and thermal performance. The synthesis method comprises the following three steps: firstly, reacting magnolol with halogenated alkane to generate a precursor; secondly, reacting the precursor with acyl chloride to generate an intermediate; finally, oxidizing the intermediate to generate the target epoxy resin. The method does not need to add a large amount of flame retardant, and avoids negative influence on the performance of the epoxy resin. The synthesized epoxy resin shows excellent flame retardance and heat resistance, has high carbon residue rate, glass transition temperature and thermal decomposition temperature, and has the flame retardant level reaching V-0 level which is superior to that of general epoxy resin.
Owner:EAST CHINA UNIV OF SCI & TECH

A method for preparing symmetrical double-terminal piperidinyl alkane

The present invention relates to the technical field of chemical synthesis, and in particular to a method for preparing a symmetrical double-terminal piperidinyl alkane, wherein the preparation method comprises the following steps: under the protection of an inert gas, a double-terminal halogenated alkane reacts with triphenylphosphine to prepare a phosphonium salt, namely an intermediate A, and then the intermediate A reacts with a piperidinone derivative under alkaline conditions to produce an intermediate B by Wittig reaction; the intermediate B is subjected to hydrogenation reduction to obtain the symmetrical double-terminal piperidinyl alkane; the raw materials of the preparation method of the present invention are easily available, the yield is high, and the preparation method is conducive to industrial production. The purity of the symmetrical double-terminal piperidinyl alkane obtained by the preparation method of the present invention is greater than 99%, and the total yield is 75-80%; the yield and purity are relatively high.
Owner:VALIANT CO LTD

A method for synthesizing a dialkylphosphinic ester

This invention discloses a method for synthesizing dialkylphosphinates, belonging to the field of organic synthesis technology. The method uses hypophosphite and haloalkanes as starting materials. First, a hypophosphite is generated through a heated and pressurized reaction under the action of a phase transfer catalyst. The obtained hypophosphite does not require complex purification; it is directly reacted with an olefin under heated and pressurized conditions in the presence of a free radical initiator to obtain the target product, dialkylphosphinate. The method of this invention uses inexpensive and readily available raw materials, has a simple process route, includes only two core reactions, operates under mild conditions, is safe and convenient, produces few and easily treatable byproducts, has a high product yield, and is simple to purify. It is very suitable for large-scale industrial production, providing an economical and efficient synthetic route for the preparation of high-performance halogen-free flame retardants.
Owner:ZHEJIANG WANSHENG CO LTD

Purification method for fluoroolefin having structure of =CF2 or =CHF, high-purity fluoroolefin, and production method therefor

Impurities are removed from a fluoroolefin having a structure of ═CF2 or ═CHF that has been obtained by a dehydrohalogenation reaction and that contains haloalkene, haloalkane, and / or haloalkyne impurities.Provided are: a method of purifying a fluoroolefin having a structure of ═CF2 or ═CHF, comprising bringing a fluoroolefin having a structure of ═CF2 or ═CHF that has been obtained by a dehydrohalogenation reaction and that contains at least one of haloalkane, haloalkene, and / or haloalkyne impurities into contact with a solid adsorbent to remove the impurities through adsorption; a high-purity fluoroolefin; and a production method therefor.
Owner:KANTO DENKA IND CO LTD

Process for the preparation of haloalkanesulfonic acids from sulfur trioxide and a haloalkane at superacidic conditions

The present invention refers to a method for the production of haloalkane sulfonic acid, in which SO3 and an haloalkane are contacted with each other in the presence of a solvent, said solvent does constitute a superacid and the combination of said solvent with one or more of the reactants also gives rise to a superacid.
Owner:GRILLO CHEM GMBH

Degradable Gemini morpholine quaternary ammonium salt, and preparation method and application thereof

The application discloses a degradable gemini morpholine quaternary ammonium salt. The application further discloses a preparation method of the degradable gemini morpholine quaternary ammonium salt, comprising the following steps: S1, performing N-alkylation reaction on morpholine and halogenated alkane to obtain N-alkyl morpholine; S2, performing reaction on substance A and halogenated acetyl halide to obtain substance B; S3, continuously performing N-alkylation reaction on the N-alkyl morpholine and the substance B to obtain the degradable gemini morpholine quaternary ammonium salt. The application further discloses application of the degradable gemini morpholine quaternary ammonium salt in a bactericide and in preparation of a medicine for treating helicobacter pylori infection. The gemini morpholine quaternary ammonium salt has a good effect of killing helicobacter pylori; the gemini morpholine quaternary ammonium salt can be degraded in an alkaline environment, can avoid drug resistance of helicobacter pylori to the gemini morpholine quaternary ammonium salt, and can make the degradation product be rapidly discharged out of the body.
Owner:UNIV OF SCI & TECH OF CHINA

Polyethylene catalysts and methods for their preparation and ultra-high molecular weight polyethylene and methods for their preparation

This invention relates to the field of catalysts, specifically to a polyethylene catalyst and its preparation method, as well as ultra-high molecular weight polyethylene and its preparation method. The method includes the following steps: (1) under diluent conditions, a magnesium halide precursor, an alcohol compound, and a first internal electron donor undergo a first contact reaction to obtain a first reaction solution; (2) a second internal electron donor is added to the first reaction solution to undergo a second contact reaction to obtain a second reaction solution; (3) a titanium precursor is added to the second reaction solution to undergo a third contact reaction to obtain a third reaction solution; (4) a haloalkane is added to the third reaction solution, followed by a third internal electron donor to undergo a fourth contact reaction. The catalyst prepared by this invention exhibits good catalytic performance.
Owner:PETROCHINA CO LTD

Method for removing probenecid sodium halogenated alkyl toxic impurities

The invention relates to a method for removing halogenated alkyl toxic impurities in probenecid sodium, which is characterized by comprising the following steps of: 1, heating and hydrolyzing excessive halogenated alkyl under an alkaline condition to remove the halogenated alkyl toxic impurities; 2, organic solvent extraction and removal; 3, adsorption removal by a specific adsorption column; after the treatment by the method, the residue of haloalkane is reduced to be not detected from 15-100ppm, and the limit requirements of related genotoxic impurities in Chinese drug registration regulations and ICH guidance principles are completely met.
Owner:ANHUI KANGZHENG KANGYUAN PHARM CO LTD

A process for the preparation of r-(+)-2,2-dimethyl-1,3-dioxolane-4-carboxaldehyde

The present application relates to a kind of preparation methods of R-(+)-2,2-dimethyl-1,3-dioxolane-4-formaldehyde, belong to the technical field of pharmaceutical intermediates synthesis.In order to solve the existing wastewater pollution and the problem of low selectivity, provide a kind of preparation method of R-(+)-2,2-dimethyl-1,3-dioxolane-4-formaldehyde, the method includes the action of catalytic amount of phase transfer catalyst quaternary ammonium salt and oxidant, the oxidant is selected from PCC or BPCC, in halogenated alkane solvent, substrate formula II compound double ketone-D-mannitol is converted into product formula I compound R-(+)-2,2-dimethyl-1,3-dioxolane-4-formaldehyde by catalytic oxidation reaction.The present application has the effect of high product yield and purity quality, product yield reaches more than 95%, purity reaches more than 99.5%, also greatly reduces the generation of a large amount of wastewater, the advantage of environment-friendly.
Owner:JIANGSU BAJU PHARM CO LTD

Process for the modification of a beta-ketimine ligand precursor and products thereof

This invention relates to a simple method for modifying β-ketoimine ligand precursors, wherein L... Ph The reaction involves a lithium compound with H2 solution; then a haloalkane is added for C-C coupling; followed by the addition of an acid solution to complete the modification of the β-ketoimine ligand precursor, yielding a terminally alkylated ketoimine. This invention relates to a simple method for modifying β-ketoimine ligand precursors, specifically involving the removal of the proton at the α-position of the β-ketoimine ligand precursor from commercially available n-butyllithium to form a deprotonated β-ketoimine lithium compound, followed by C-C coupling to achieve alkylation at the α-position of the ketocarbonyl group, thus providing a convenient modification of the β-ketoimine ligand precursor.
Owner:SUZHOU UNIV

High-stereoselectivity haloalkane dehalogenase mutant and application thereof

ActiveCN120519424ABacteriaHydrolasesHaloalkane dehalogenaseBioremediation
The invention discloses a haloalkane dehalogenase mutant with high stereoselectivity and application thereof.The haloalkane dehalogenase mutant F131M / F168M / I246L is obtained by modifying haloalkane dehalogenase DhaA31 coded by a rhodococcus dhaA gene, the haloalkane dehalogenase mutant has high degradation efficiency on haloalkane pollutants 1, 2, 3-tribromopropane, and the haloalkane dehalogenase mutant has high stereoselectivity on haloalkane pollutants 1, 2, 3-tribromopropane under the water-phase normal-temperature condition. The degradation rate of the alkyl halide dehalogenase mutant to 10 mM of 1, 2, 3-tribromopropane within 60 min reaches 100%, and the degradation rate of the alkyl halide dehalogenase mutant to 10 mM of 1, 2, 3-tribromopropane reaches 100%. The haloalkane dehalogenase mutant has high stereoselectivity on a high-value product (S)-2, 3-dibromo-1-propanol, and the e.r. Value of the haloalkane dehalogenase mutant reaches 98: 2. The haloalkane dehalogenase mutant provided by the invention has high catalytic efficiency and high stereoselectivity, and has a good application prospect in bioremediation and recycling of emerging haloalkane pollutants.
Owner:NANJING UNIV

Halon purification method

There is provided a halon purification method capable of simply, safely, and efficiently removing mixed bromine molecules to obtain high purity halon. The halon purification method is a method for removing bromine molecules from crude halon containing halon and the bromine molecules, and the method includes: a contact step of bringing the crude halon into contact with an absorbing liquid containing an aqueous solution containing metal iodide to obtain a mixed liquid containing the crude halon and the absorbing liquid; and a separation step of separating the halon from the mixed liquid to obtain the halon and the absorbing liquid having absorbed the bromine molecules.
Owner:RESONAC CORP

A method for preparing perovskite composite materials based on light induction

The present invention relates to a method for preparing a perovskite composite material based on light induction, which comprises the following steps: preparing a mixed precursor solution containing lead oleate and cesium oleate; preparing a mixed precursor powder containing a covalent organic framework material, lead oleate and cesium oleate; adding a halogenated alkane to the mixed precursor solution or the mixed precursor powder, and reacting under the action of invisible light, and after the reaction is completed, post-processing is performed to obtain a perovskite composite material CsPbX3 NCs or CsPbX3@S-COFs. The present invention has the advantages of mild and simple preparation conditions, green and environmental protection, ability to improve the stability of the composite material, and convenience in regulating the size of the perovskite.
Owner:ZHEJIANG UNIV OF TECH

Method for continuously preparing alkyl phosphonic acid diaryl ester

The invention relates to a method for continuously preparing alkyl diaryl phosphonate, which comprises the following steps of: a, reacting trialkyl phosphite and triaryl phosphite in a high-temperature section filled with a solid catalyst to obtain a reaction product; and b, removing low-fraction byproducts in the reaction product in the step a through reduced pressure distillation or fractionation at the outlet of the high-temperature section, feeding the residual product into a cooling section, collecting a crude product of the alkyl diaryl phosphonate at the outlet of the cooling section, and carrying out post-treatment to obtain the alkyl diaryl phosphonate. A continuous catalytic reaction is carried out through the solid catalyst filled in the tubular reactor, and an intermittent reaction is changed into a continuous reaction, so that the liquid holdup is greatly reduced, and the safety coefficient of production is improved; a traditional halogenated alkane catalyst is not used, so that the risk that the temperature rise is out of control is effectively reduced; according to the method, the reaction time is shortened while the reaction yield is not reduced, and the production efficiency is improved.
Owner:NINGBO PUDUOKIKE TECH DEV CO LTD