1946 results about "Addition reaction" patented technology

The present invention uses commercially available 3-aminopropylsilane coupling agent, diallylamino polyether acrylate, and an alkylating agent, or γ-propanesultone, or γ-butyrolactone as raw materials, and through an aza-Michael addition reaction and a quaternization reaction, a multifunctional silane coupling agent containing one or more quaternary ammonium cations, or sulfobetaine, or carboxybetaine in its molecular structure is prepared, which is used for the surface modification of bioactive glass, and the bioactivity, antibacterial and antifungal properties, and hydrophilicity enhancement effects after the surface modification of bioactive glass are obtained.

The invention belongs to the technical field of flame-retardant materials, and particularly relates to preparation of a phosphorus, nitrogen and silicon macromolecular flame retardant and application of the phosphorus, nitrogen and silicon macromolecular flame retardant in epoxy resin. The preparation method comprises the following steps: firstly, carrying out substitution reaction on chlorosilane and syringaldehyde or vanillic aldehyde to synthesize a silicon-containing intermediate, then carrying out Schiff base reaction on the silicon-containing intermediate and an amine compound, and finally carrying out addition reaction on the silicon-containing intermediate and a phosphorus-containing compound to prepare the phosphorus, nitrogen and silicon macromolecular flame retardant. The flame retardant has a good flame-retardant effect, can be used for preparing flame-retardant epoxy resin, can effectively improve the limit oxygen index and the vertical combustion grade of the epoxy resin, and can endow the epoxy resin with good transparency and molten drop resistance.

A method for visible light-mediated chemical modification of a polypeptide or protein based on cysteine includes the following steps: allowing a cysteine residue on a cysteine-containing oligopeptide, polypeptide, or protein to undergo a reaction with an activating reagent to generate a free radical precursor in situ; and subjecting the free radical precursor to desulfurization under photocatalytic condition, and allowing the generated free radical intermediate to undergo an addition reaction with an olefin or an alkyne, such that sulfhydryl removal and carbon-carbon bond construction are achieved to produce a chemical modification product of the polypeptide and protein. The method cleverly avoids the influence on the chiral center, and thus the chirality of the amino acid residue can be retained. The method is conducive to well avoiding the occurrence of side reactions, and thus the efficiency of the entire conversion is very high.

The invention discloses an adhesive containing epoxy-terminated polyurethane epoxy resin as well as a preparation method and application of the adhesive. The adhesive comprises the following components in parts by weight: 10-15 parts of epoxy resin, 70-75 parts of epoxy-terminated polyurethane epoxy resin, 19-21 parts of an amine curing agent and 8-15 parts of heat-conducting filler, wherein the epoxy-terminated polyurethane epoxy resin is obtained by reacting a polyurethane prepolymer and epoxy resin, NCO of the polyurethane prepolymer and hydroxyl of the epoxy resin are subjected to an addition reaction, and after the reaction is finished, NCO of a system is eliminated by adopting a small-molecule epoxy compound; the polyurethane prepolymer is obtained by reaction of isocyanate and polyether polyol with flexible chain segments. According to the adhesive, the curing heat release peak value is reduced, the toughness is improved, meanwhile, the high strength is kept, the foaming problem is avoided, the defects that a traditional epoxy adhesive is high in heat release and poor in toughness are overcome, and the adhesive is suitable for the fields such as aerospace and electronic and electric appliances which have strict performance requirements.

The present invention provides a multifunctional silane coupling agent, which is prepared from commercially available 3-aminopropylsilane coupling agent, acryloxy polyetheramine, and one of an alkylating agent, polyether sulfonate, γ-propane sultone or γ-butyrolactone through Michael addition reaction and quaternization reaction. The multifunctional silane coupling agent is a new variety carrying zwitterions, quaternary ammonium cations and polyether chains, enriching the functions and application scope of silane coupling agents. It can endow some modified materials with surface hydrophilicity, conductivity, antibacterial, antifogging, antifouling, biocompatibility, anticoagulant and wet lubrication properties, etc. at the same time.

The invention discloses a polyamine type porous polymer as well as a preparation method and application thereof, and belongs to the technical field of synthesis of porous organic polymers. The specific method comprises the following steps: dispersing beta-mercaptoethylamine, a photoinitiator and a porous framework polymer with carbon-carbon double bond connection in a polar organic solvent; under the ultraviolet light initiation condition, the photoinitiator excites beta-mercaptoethylamine to generate sulfydryl free radicals, and the sulfydryl free radicals and the porous framework polymer with carbon-carbon double bond connection are subjected to an addition reaction; and washing and drying the product after the addition reaction to obtain the amino-modified polyamine porous polymer. The preparation method provided by the invention is rapid in reaction, extremely high in reactant utilization rate and simple in post-treatment, and the prepared polyamine type porous polymer has rich adsorption sites, good stability and excellent carbon dioxide adsorption performance, and can be applied to the field of carbon capture and the like.

The invention relates to the technical field of organic polymer adhesives, and particularly discloses a modified castor oil-based polyurethane adhesive as well as a preparation method and application thereof. The adhesive comprises two components, and the component A comprises the following components in parts by weight: 30.0-50.0 parts of modified castor oil and 0.0-30.0 parts of refined castor oil; the component B is prepared from the following components in parts by weight: 30.0 to 50.0 parts of polyisocyanate or a polyisocyanate modifier and 0.00 to 0.05 part of a dewatering agent; the modified castor oil is prepared from refined castor oil and cysteamine through a sulfydryl-alkene addition reaction. Amido of the modified castor oil is alkalescent, and the reaction speed of the modified castor oil and isocyanate groups is high; hydrogen bonds are easily generated between urea bonds generated by the reaction of amino groups and isocyanate groups, so that the adhesive is endowed with thixotropy and high strength. The adhesive disclosed by the invention is simple in composition, high in reaction speed and good in thixotropy and bonding strength.

The invention belongs to the field of flotation, and particularly relates to a lithium-containing china clay ore flotation method which comprises the following steps: carrying out flotation on to-be-separated minerals of lithium-containing china clay ore in a flotation reagent containing a collecting agent to obtain lithium china clay ore concentrate; the collecting agent is characterized in that the collecting agent is a compound shown in the formula 1 # imgabs0 #; and / or a product obtained by carrying out an addition reaction on a formula 2 (R-NH2) and a formula 3 # imgabs1 # in advance and then carrying out a saponification reaction with an alkali. According to the collecting agent for the lithium china clay ore, the component shown in the formula 1 is innovatively adopted as the collecting agent for the lithium china clay ore, in this way, on the basis of intermolecular coupling of beta-NH-and-COOM, the collecting agent can accidentally adapt to the surface characteristics of target minerals of the lithium china clay ore, high-selectivity collecting can be achieved, and effective collecting under the low-temperature and mild conditions can be achieved.

The invention relates to the technical field of in-vitro diagnostic kits, in particular to carboxyl polystyrene microspheres, a preparation method and application of the carboxyl polystyrene microspheres in a kit for quantitatively detecting MxA. The preparation method of the carboxyl polystyrene microspheres comprises the steps that firstly, polystyrene microspheres with the surface rich in aldehyde groups are prepared through a soap-free emulsion polymerization method; then carrying out a Schiff alkali reaction with 2-aminoethyl methacrylate hydrochloride to carry out double bond modification on the surface of the microsphere, and meanwhile, improving the hydrophilicity of the microsphere by an ester group and an imino group; and finally, carrying out sulfydryl-double bond addition reaction on the polystyrene microspheres and mercaptosuccinic acid to generate the polystyrene microspheres rich in carboxyl on the surfaces. The carboxyl polystyrene microspheres prepared by the invention can improve the binding efficiency of latex and an MxA antibody, so that the detection sensitivity is improved, the purpose of high-sensitivity quantitative detection of MxA protein can be achieved, and the detection time is greatly shortened.

The invention relates to the technical field of PC resin flexibilizers, and discloses a shell-core structure styrene-acrylic resin modified organic silicon elastomer flexibilizer as well as a preparation method and application thereof in order to solve the problems that an organic silicon material and PC resin are poor in intersolubility, a traditional flexibilizer is poor in low-temperature toughening performance and the like. Comprising the following steps: uniformly mixing hydrogen-containing silicone oil, vinyl silicone oil, a third alkenyl functional component and a catalyst, and pre-emulsifying under the action of a surfactant and a thickener to obtain an organic silicon pre-emulsion SiE; uniformly mixing an alkenyl phenyl compound, acrylate and / or a cross-linking agent, adding a molecular weight regulator and an oil-soluble initiator, and pre-emulsifying under the action of a surfactant and water to obtain a styrene-acrylic pre-emulsion SAE; the preparation method comprises the following steps: firstly, preparing an organic silicon pre-emulsion, then heating the organic silicon pre-emulsion to carry out a water-phase hydrosilylation addition reaction, then dropwise adding the styrene-acrylic pre-emulsion to carry out suspension emulsion copolymerization, and then demulsifying and drying to obtain the styrene-acrylic resin modified organic silicon elastomer toughening agent with the core-shell structure.

The invention relates to a perovskite photovoltaic cell high-transmittance low-scattering coating material and a preparation method thereof, and belongs to the technical field of photovoltaic cells. The coating material is prepared from the following components in percentage by weight: 7.2 to 8.5 percent of PMMA (Polymethyl Methacrylate) resin, 0.17 to 0.22 percent of modified nano titanium dioxide, 0.09 to 0.11 percent of flatting agent, 0.03 to 0.04 percent of defoaming agent and the balance of solvent, the modified nano titanium dioxide is prepared into an intermediate through addition reaction of triallylamine and mercaptoethanol, and then a modifier with a network molecular structure is formed through substitution reaction of trifluoropropyl trichlorosilane and hydroxyl at the end part of an intermediate molecule; a thioether chain segment in a modifier molecule and similar nitrogen and oxygen elements form a strong chelation effect to coat the nano titanium dioxide; the introduction of the modified nano titanium dioxide makes up the problem of light transmission reduction caused by traditional titanium dioxide reinforcement.

The invention relates to a low-smoke halogen-free flame-retardant plastic and a preparation method thereof, and belongs to the technical field of flame-retardant high polymer materials. The flame-retardant plastic is prepared from the following components: 12 to 17 weight percent of magnesium hydroxide superfine powder, 4.5 to 6.2 weight percent of modified flame retardant, 5 to 7 weight percent of flexibilizer, 0.9 to 1.2 weight percent of lubricant, 0.3 to 0.4 weight percent of antioxidant and the balance of PBT (Polybutylene Terephthalate) resin, the modified flame retardant is prepared by the following steps: reacting pentaerythritol with phosphorus oxychloride to prepare hydroxyl-containing polyhedral oligomeric phosphate, esterifying acryloyl chloride and the hydroxyl of the polyhedral oligomeric phosphate to prepare a monoester intermediate, and finally performing click addition on sulfydryl of pentaerythritol tetramercaptoacetate and double bonds of the monoester intermediate. The modified flame retardant interacts with magnesium hydroxide, a stable hollow carbon net is formed in the flame retardant process, and the hollow carbon net has a multi-layer adsorption and filtration effect on smoke particles, so that the release of smoke is reduced, and the smoke density is greatly reduced.

The invention discloses an electrolyte additive, an electrolyte, a battery and a power utilization device, the electrolyte additive comprises a compound shown in the formula 1 and a protective agent, the protective agent # imgabs0 comprises a chain compound with the unsaturation degree larger than or equal to 3, the protective agent can be subjected to addition reaction with a sulfonate group-containing free radical formed after the ring-opening reaction of the compound as shown in the formula 1. Therefore, when the electrolyte additive is added into the lithium ion battery, the high-temperature cycle performance and the high-temperature storage performance of the battery can be improved.

The invention discloses a preparation method of silane or siloxane containing adamantyl. According to the invention, adamantane carboxylic acid is taken as a starting raw material, an adamantane compound containing double bonds at the tail end is obtained through an esterification reaction, and then the adamantane compound and hydrogen-containing silane or hydrogen-containing siloxane are subjected to a hydrosilylation reaction to prepare adamantyl-containing silane or siloxane. The method is mild in reaction condition, simple, convenient and easy to operate, capable of achieving preparation of adamantyl silane or siloxane of various structures, wide in application range and capable of providing diversified choices for development of novel adamantyl modified organic silicon materials.

The invention provides a pyrrolidone dihydroisoxazole compound as well as a preparation method and application thereof, and belongs to the technical field of organic synthesis. Specifically, under the catalytic action of Lewis base, beta-oxoacrylamide and 4-nitroisoxazole serve as raw materials, and the pyrrolidone dihydroisoxazole compound is synthesized through a one-step method. Beta-oxoacrylamide and 4-nitroisoxazole which are simple and easy to obtain are adopted as starting raw materials, dearomatization [3 + 2]-cycloaddition reaction is carried out under the catalysis of Lewis base, the pyrrolidone dihydroisoxazole compound is synthesized, the method is easy and convenient to operate and mild in reaction condition, the used reagents and raw materials are economical and easy to obtain, and the method is suitable for industrial production. The target product yield is high, the substrate application range is wide, and the in-vitro anti-tumor activity is good.

To provide an antireflection film that has both high antireflection properties and superior scratch resistance, and that is capable of acquiring high antifouling property without relying on fluorine-containing compounds, as well as a method for producing such an antireflection film.SOLUTION: An antireflection film 10 comprises: a base film 12; a hard coat layer 14 formed on a surface of the base film 12; and an optical functional layer 16 formed on a surface of the hard coat layer 14. The optical functional layer 16 is formed from a cured product of an ionizing radiation-curable composition that contains a polyfunctional (meth)acrylate compound having a reactive group, and an amino-modified organopolysiloxane, where at least a part of the polyfunctional (meth)acrylate compound and at least a part of the amino-modified organopolysiloxane form an addition reaction product, and that further contains alumina particles surface-treated with a silane coupling agent having a reactive group capable of forming a bond with the polyfunctional (meth)acrylate compound.SELECTED DRAWING: Figure 1

The invention provides modified polysiloxane and also provides a preparation method of the modified polysiloxane, and the preparation method comprises the following steps: mixing low-hydrogen-content silicone oil with allyl alcohol polyether and allyl glycidyl ether, heating, adding a catalyst, and carrying out an addition reaction to obtain the modified polysiloxane. The invention also provides an application of the modified polysiloxane as a soil loosening agent, and the modified polysiloxane is used for reducing the soil bulk density and / or increasing the soil porosity, and is also used for improving the water absorption and / or water retention of the soil. By applying the modified polysiloxane soil loosening agent disclosed by the invention, the soil bulk density is effectively reduced, the soil compactness is reduced, and the soil porosity is improved, so that the soil hardening is remarkably improved, the crop growth is promoted, and the modified polysiloxane soil loosening agent is green and safe and has important economic value and environmental significance.

The invention discloses an ultraviolet multi-curing heat-conducting insulating material which comprises an epoxy resin oligomer, a polyacrylate oligomer, a reactive diluent, a composite photoinitiator and a sulfydryl-containing silane coupling agent modified heat-conducting particle filler. After ultraviolet irradiation, multiple curing reactions, including free radical polymerization, cationic polymerization, sulfydryl-alkene click addition reaction and sulfydryl-epoxy ring-opening reaction, can be rapidly initiated. The heat-conducting insulating material disclosed by the invention has very high crosslinking density and a more continuous heat-conducting network, and is high in curing speed, free of volatile gas and simple and convenient in preparation process.

The invention belongs to the technical field of flame-retardant materials, and relates to a sulfathiazolyl P / N / S-containing halogen-free flame retardant as well as a preparation method and application thereof. The halogen-free flame retardant containing phosphorus, nitrogen and sulfur elements is obtained by taking diphenyl hypophosphorous chloride as a basis, preparing a flame-retardant intermediate through nucleophilic substitution reaction between diphenyl hypophosphorous chloride and an aldehyde group-containing phenolic compound, then forming a Schiff base structure by the intermediate and sulfathiazole, and finally performing addition reaction with DOPO (9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide). The flame retardant can play a synergistic flame-retardant role of phosphorus-nitrogen-sulfur elements, and has a good flame-retardant effect. When the flame retardant disclosed by the invention is used for modifying epoxy resin, the UL-94V-0 level can be reached when the addition amount is less than 5% of the total mass. The influence on Tg of an epoxy resin cured product is small, and the smoke suppression and char formation performance and the mechanical property of the epoxy resin cured product can be remarkably improved. The prepared flame-retardant epoxy resin has good smoke suppression property and char forming property, has good compatibility with epoxy resin, and improves the stability of cured epoxy resin in processing.

The invention discloses a method for synthesizing a dichloroacetyl compound, which comprises the following steps: tetrachloroethylene and an acid are subjected to an addition reaction at 100-200 DEG C to obtain an adduct, then the adduct is subjected to an acidolysis, hydrolysis or alcoholysis reaction to obtain the dichloroacetyl compound, the acid for the addition reaction is at least one of sulfuric acid, trifluoromethanesulfonic acid, methanesulfonic acid and phosphoric acid, and the acid for the alcoholysis reaction is at least one of sulfuric acid, trifluoromethanesulfonic acid, methanesulfonic acid and phosphoric acid. The molar ratio of the tetrachloroethylene to the acid is 1: (1-10). By controlling the types of acids and increasing the temperature of the addition reaction, the addition reaction of tetrachloroethylene and acids in the absence of a catalyst is realized. Double bonds of tetrachloroethylene and hydrogen protons are subjected to an addition reaction in a strong acid environment to form a cationic intermediate, then the cationic intermediate is combined with acid radical anions to form an adduct, and the adduct intermediate is high in activity, unstable and free of separation and can be directly subjected to a hydrolysis reaction, an acidolysis reaction or an alcoholysis reaction with another substrate (such as water, acid or alcohol) respectively. The synthesis of dichloroacetyl series compounds is realized, and the route has universality and diversity.

The invention discloses a polyurethane coating and a preparation method thereof, and belongs to the technical field of antibacterial coatings. The preparation method of the polyurethane coating comprises the following steps: carrying out acyl chloride substitution reaction on a phenolic substance and a chlorine donor to obtain an intermediate reactant, and carrying out conjugate addition reaction on the intermediate reactant and an amine substance with hydroxyl groups at two ends to obtain antibacterial diol; reacting the antibacterial diol with isocyanate to obtain a polyurethane coating; the phenolic substance is selected from at least one of thymol, carvacrol, paeonol, catechol and theaflavin. The antibacterial coating is applied to the aspect of an antibacterial coating of a food contact part, the problem that the antibacterial property of an existing antibacterial coating is difficult to last is solved, and the antibacterial coating has the synergistic antibacterial effect of killing and defending bacteria.

The invention discloses bio-based polyester and a preparation method thereof, and belongs to the technical field of biomass resource utilization and bio-based polyester, and the bio-based polyester comprises the following components: deacetylated chitosan, aldehyde modified lignin, polybasic organic amine, polybasic aldehyde monomer, a catalyst, 1, 4-dioxane, methanol and deionized water. The method comprises the following steps: extracting chitosan from shrimp / crab shells, and exposing primary amino groups through alkali treatment; the method comprises the following steps: extracting lignin from coffee grounds, and grafting an aldehyde group with a polyaldehyde monomer; the aldehyde modified lignin and chitosan are subjected to Michael addition reaction and then are crosslinked with polyaldehyde monomers and polybasic organic amine to form a net structure, so that the film forming strength is improved. The environment burden caused by the coffee grounds and shrimp shells or crab shells is reduced, and meanwhile, a low-cost and environment-friendly bio-based polyester is provided for the field of coatings.

The invention discloses a high-strength and high-resilience TPE (thermoplastic elastomer) and a preparation method thereof in the technical field of high polymer materials, and the elastomer is prepared by taking a hydrogenated styrene block copolymer as a matrix and matching with a polyolefin rigid phase, plasticizing oil and a specific additive. The method is characterized in that two self-made reaction type modifiers are introduced, wherein one self-made reaction type modifier is a core-shell nano reinforcing agent containing an epoxy functional group and polyhedral oligomeric siloxane, and the other self-made reaction type modifier is a furan maleimide bifunctional dynamic cross-linking agent. The nano reinforcing agent is prepared through silane hydrolysis and amination reaction, and can react with a matrix for grafting, so that the strength and creep resistance of the material are remarkably improved; the dynamic cross-linking agent is synthesized through step-by-step isocyanate addition reaction, a cross-linked network can be reversibly formed in the processing process, and the material is endowed with extremely high rebound resilience and low permanent deformation. The obtained product has high strength, high resilience and excellent processability, and is especially suitable for high-end fitness equipment.

The invention relates to the technical field of organic silica gel adhesives, in particular to a two-component adhesive for bonding cured silica gel and uncured silica gel as well as a preparation method and application of the two-component adhesive. The adhesive is composed of an agent A and an agent B, wherein the agent A comprises base glue, vinyl silicone resin, low-viscosity vinyl silicone oil, a titanium catalyst, a platinum catalyst and a diluent; the agent B comprises base rubber, hydrogen-containing silicone oil, three silane coupling agents, a 2-ethynyl cyclohexanol inhibitor and two intermediates prepared through addition reaction. The agent A and the agent B are used after being mixed according to the mass ratio of 1: 1, can be bonded with unvulcanized silica gel and jointly vulcanized after being pre-cured for 2 hours at normal temperature or subjected to heat treatment for 30 minutes at 70 DEG C, and are high in peel strength, excellent in humidity and heat resistance and suitable for high-reliability silica gel compounding in the fields of electronics, medical treatment and the like.

The invention discloses a method for continuously synthesizing long-chain alkyl modified silicone oil, which belongs to the technical field of organic synthesis, and comprises the following specific steps: quickly mixing hydrogen-containing silicone oil and long-chain olefin in a micro-mixer, carrying out hydrosilylation reaction in a packed tubular reactor, controlling the reaction residence time by using the tube length, and continuously synthesizing the long-chain alkyl modified silicone oil. Controlling the material ratio by utilizing the reaction liquid flow ratio, controlling the reaction temperature by utilizing a water bath, and obtaining a mixed solution containing modified silicone oil after the reaction is completed; and decoloring the mixed solution by using activated carbon, and then carrying out reduced pressure rotary evaporation on the decolored mixed solution to finally obtain a modified silicone oil pure product. The method realizes continuous synthesis of the modified silicone oil, and has the advantages of simple process, short reaction time and high reaction safety.

The invention belongs to the technical field of oilfield chemistry, and particularly relates to application of a hyperbranched zwitterionic polymer in high-temperature and high-salinity drilling fluid. The hyperbranched zwitterionic polymer is prepared by carrying out Michael addition reaction on polyethyleneimine and a monomer which is neutralized by alkali and contains double bonds and sulfonic acid groups; the polymer has a hyperbranched structure, and the amphoteric ion characteristic that an amino group from polyethyleneimine on a molecular chain and a sulfonic acid group from a monomer form an inner salt structure; the hyperbranched zwitterionic polymer is used as an inhibitor and a viscosity reducer of the drilling fluid. According to the hyperbranched zwitterionic polymer provided by the invention, the salt tolerance and high-temperature stability of the polymer are enhanced by introducing a sulfonate group; the polymer is endowed with low viscosity and high adsorption capacity through a hyperbranched structure, the viscosity of the drilling fluid can be effectively reduced, and clay hydration is inhibited; clay particles are stabilized through electrostatic interaction by zwitterionic characteristics, and the rheological property of the drilling fluid is optimized.

The present invention relates to the technical field of structural adhesives, and provides a high-stability low-exothermic structural adhesive system material, a preparation method therefor and a use thereof. The mass ratio of a resin component to a curing agent component in the structural adhesive system material is 10:(4-5). The resin component comprises 60-80 parts of bisphenol-A epoxy resin, 2-15 parts of bisphenol-F epoxy resin, 10-20 parts of an inorganic reinforcing filler, and 3-8 parts of a thickening thixotropic agent. The curing agent component comprises 56-115 parts of an amine curing agent, 5-20 parts of an inorganic reinforcing filler, 5-9 parts of a thickening thixotropic agent, and 4-60 parts of a modified amine-based rheology additive. The modified amine-based rheology additive is obtained by means of a pre-reaction, at a temperature of 25-150ºC, between an amine substance and a substance capable of undergoing an addition reaction with the amine substance. The present invention solves the problems of how to improve the stability of the structural adhesive and ensure smooth and uniform heat release during a curing exothermic process while meeting mechanical performance requirements.

The invention provides a temporary bonding adhesive and a preparation method and application thereof.The temporary bonding adhesive is prepared from organosilicone epoxy resin, a curing agent and an organic solvent, and the organosilicone epoxy resin is obtained after hydrogen-containing silicone oil and an alkenyl-terminated epoxy compound are subjected to an addition reaction and a hydrolytic condensation reaction; the organic silicon epoxy resin is selected as matrix resin, and is matched with the curing agent and the organic solvent, so that the obtained temporary bonding adhesive has high elastic modulus and excellent thermal stability, a wafer can be helped to pass through a multi-section complex manufacturing process, the temporary bonding adhesive can be separated from the wafer in a mechanical mode, and the yield of the wafer is improved. And the coating is very simple to use, has excellent chemical liquid corrosion resistance, and is very suitable for processing and manufacturing wafers.

The invention relates to the technical field of sustained-release microcapsules, and particularly discloses a thermochromic sustained-release microcapsule as well as a preparation method and application thereof. A capsule core of the microcapsule comprises perfume and a thermochromic composite material, a capsule wall is of a double-layer structure, the inner capsule wall is a porous silicon dioxide layer, and the outer capsule wall is a polyurethane layer formed by xylooligosaccharide and isocyanate; the thermochromic composite material is a reversible thermochromic compound comprising a color former, a color developing agent and a solid solvent. According to the invention, a porous silicon dioxide inner shell layer is prepared by a sol-gel method, polyurethane formed by xylooligosaccharide and isocyanate through nucleophilic addition reaction is taken as an outer shell layer, and through the combined action of a double-layer capsule wall structure, the functions of thermochromism and perfume slow release are continuously exerted. In addition, xylooligosaccharide serving as one of raw materials of the outer capsule wall is wide in source, green and environmentally friendly, the biocompatibility of the microcapsule can be effectively improved, and the xylooligosaccharide microcapsule has very important significance in expanding the application field of the microcapsule.

The invention relates to the technical field of functional coatings, in particular to a high-strength rain erosion resistant coating and a preparation method thereof.The high-strength rain erosion resistant coating is composed of polyaspartic acid ester resin (A) and a high-elasticity aliphatic polyurea curing agent (B), 2, 3-bis (aminomethyl) cyclohexane, chain-extended diamine and diethyl maleate are subjected to an addition reaction to prepare the high-molecular polymer; the component B is synthesized from dicyclohexylmethane diisocyanate, isophorone diisocyanate, polycarbonate diol and a hexamethylene diisocyanate tripolymer step by step; the high-strength rain-erosion-resistant coating is obtained by adding the functional filler, the flatting agent, the ultraviolet absorbent and the environment-friendly solvent into the component A and the component B in a stirring reaction kettle and stirring in a heat preservation mode, a coating film of the high-strength rain-erosion-resistant coating has excellent mechanical strength, meanwhile, the high-strength rain-erosion-resistant coating is more resistant to rain erosion, construction is convenient and fast, and the high-strength rain-erosion-resistant coating is remarkably superior to a commercially available optimal protective film; the method can be widely applied to outer surface protection of high-end equipment such as aviation, wind power and high-speed rails.