The invention relates to a high-heat-conductivity white adhesive composition, a high-heat-conductivity white cover film made from the same and a preparation method thereof. The high-heat-conductivity white adhesive composition comprises flexible saturated polyester, hard saturated polyester, blocked isocyanate curing agent, pigment, high-heat-conductivity filler, fluorescent brightener, defoaming agent and solvent. The high-heat-conductivity white cover film comprises a high-heat-conductivity insulation basal film, a high-heat-conductivity white adhesive composition coating applied onto one side of the high-heat-conductivity insulation basal film, and a high-heat-conductivity insulation adhesive layer applied onto the other side of the high-heat-conductivity insulation basal film. By applying the heat-conduction adhesive layers onto the two sides of the high-heat-conductivity insulation basal film, the high-heat-conductivity white cover film has the advantages of high whiteness and high reflectivity of the cover film surface, low cost, favorable yellowing resistance, excellent folding resistance and high heat conductivity, and can be widely used in the fields of high-power LEDs (Light Emitting Diodes), backlight sources and the like.