The present invention relates to the field of 3D printing materials. Disclosed are a lead-free piezoelectric
ceramic slurry for DLP photocuring 3D printing and a preparation method therefor. The components of the lead-free piezoelectric
ceramic slurry comprise a
coupling-agent-modified
potassium sodium niobate
powder, a free-radical-type photosensitive resin, a
diluent, a free-radical-type initiator, a dispersing agent, an anti-
settling agent, a defoaming agent, an adhesion
promoter and a toner, wherein the free-radical-type photosensitive resin comprises
bifunctional, trifunctional and hexafunctional aliphatic
polyurethane acrylates. By selecting a specific free-radical-type photosensitive resin and combining same with a
diluent, the
slurry has a high content of solids with regard to volume, low
viscosity, good fluidity and a fast curing
reaction speed, and meets a requirement for rapid printing; a
coupling agent is used for modifying a
potassium sodium niobate
powder, the modified
powder is coordinated with a dispersing agent and an anti-
settling agent for use, and therefore the
settling rate of the powder is significantly reduced, thereby prolonging the
shelf life of the slurry; moreover, an adhesion
promoter and a toner are also added, and therefore the printing precision is improved, and a sintered product has a
high density and good piezoelectric properties.