The invention discloses a preparation method of micro-nano spherical
nickel powder and a technological method for directly depositing silver on the surface of the micro-nano spherical
nickel powder, and belongs to the field of
metal powder preparation technologies and surface treatment. Mixing and stirring the
nickel ion solution and the complexing agent solution to obtain a nickel
ion complexing
system; the method comprises the following steps: adding a certain amount of an auxiliary agent into a nickel
ion complexing
system, stirring and dissolving to obtain a mixed
reaction system of
nickel salt, then keeping the temperature of the
system constant, slowly adding a
reducing agent solution at a
constant speed, carrying out a reduction reaction to obtain a nickel
particle suspension solution, and then filtering, washing and
drying to obtain the micro-nano spherical nickel powder. And carrying out gradient silver deposition reaction on the nickel
particle suspension solution after the reaction and the silver plating
mixed solution to obtain a suspension solution with silver coated on the surfaces of the nickel particles, and then filtering, washing and
drying to obtain the micro-nano spherical nickel powder with silver coated on the micro surface. According to the method, the
nucleation and growth process of powder particles can be accurately controlled, the prepared nickel powder is high in
sphericity degree, narrow in
particle size distribution and clean in surface, a perfect substrate is provided for subsequent high-quality silver plating, island-shaped growth of a silver layer is avoided through the gradient plating technology, and the
contact resistance is reduced compared with a traditional technology.