3160 results about "Sulfidation" patented technology

Disclosed in the present invention are a bimetallic-atom-loaded porous carbon framework material, and a preparation method therefor and the use thereof. The preparation method comprises: by taking a metal organic framework as a precursor raw material, and by using the self-polymerization of a high-molecular polymer on the surface of the metal organic framework, forming a polymer-coated metal-based organic framework material (PM@MOF) having a core-shell structure; and then capturing the metal of a metal chloride salt solution by using surface functional groups of the PM@MOF dispersed in n-hexane, so as to obtain a bimetallic element-doped polymer-coated metal-based organic framework material, and subjecting same to a high-temperature treatment in an argon gas atmosphere so as to obtain a bimetallic-atom-loaded porous carbon-based material (MD@PC). In the present invention, by loading bimetallic atoms on a nitrogen-doped porous carbon matrix to form MD-NX coordination sites, which have the dual functions of sulfur fixation and catalysis, the agglomeration degree of intermediate phase lithium sulfide can be reduced, thereby guaranteeing that the lithiation reaction of sulfur is more sufficient, rapid and efficient.

The invention relates to a method for preparing lithium sulfide, which comprises the following steps: respectively dissolving a sulfur source compound and a lithium source compound in alcohol under the protection of inert atmosphere, and then mixing the two alcohol solutions for double decomposition reaction to generate a lithium sulfide suspension; and then carrying out evaporative crystallization, supercritical fluid washing, centrifugal separation and freeze drying treatment to obtain a lithium sulfide product. The purity of the lithium sulfide prepared through the method can reach 99.9% or above, the lithium sulfide can be used as a positive electrode material of a lithium-sulfur battery or a raw material of a sulfide solid electrolyte in an all-solid-state battery, and the method is low in energy consumption, conforms to the concept of green chemistry and is suitable for large-scale industrial production.

The invention relates to the technical field of battery production, and discloses a preparation method of high-purity lithium sulfide, which comprises the following steps: preparing high-purity sulfur powder; pretreating lithium hydride; proportioning and feeding; carrying out high-speed ball milling treatment; cooling at normal temperature; carrying out ball milling detection; and collecting and packaging. According to the preparation method of the high-purity lithium sulfide, the argon is filled in the ball milling tank, so that the reaction between the lithium hydride and the high-purity sulfur powder is always carried out under the protection of the argon, the safety of the reaction can be ensured, and meanwhile, the use of toxic gas in the production process of the lithium sulfide can be reduced; the high efficiency and safety of the lithium sulfide production process are guaranteed, meanwhile, the converter with the rotating structure at the bottom of the ball milling tank drives the ball milling tank to continuously rotate, full heating and heating uniformity of lithium hydride and high-purity sulfur powder are guaranteed, and then the reaction efficiency and safety of the device in the high-purity lithium sulfide preparation process are improved.

The invention provides a method for preparing high-purity and fine-particle-size lithium sulfide based on carbon thermal reduction. The method comprises the following steps: weighing lithium sulfate monohydrate, an insoluble inorganic carbon source and cysteine in a set proportion to form a raw material mixture; mixing the raw material mixture with water according to a set solid-to-liquid ratio, performing ultrasonic dispersion to obtain homogeneous dispersion liquid, and enabling the dispersion liquid to pass through a nitrogen circulating spray dryer to obtain uniform and dry precursor powder; in a vacuum environment, carrying out segmented calcination to obtain a crude product lithium sulfide; and in a dry and anhydrous environment, washing the crude product lithium sulfide for multiple times by using absolute ethyl alcohol according to a set liquid-solid ratio to obtain an alcoholic solution containing lithium sulfide, and then obtaining lithium sulfide fine powder through a nitrogen circulating spray dryer. The invention solves the problems of side reaction, low purity, large product particles, uncontrollable particle size and the like of lithium sulfide prepared by a carbon thermal reduction method in the prior art.

The embodiment of the invention provides a synthesis method and application of lithium sulfide. The synthesis method of the lithium sulfide comprises the following steps: providing a sulfur source and a lithium source; performing first treatment on the sulfur source to obtain sulfur vapor; performing second treatment on the lithium source to obtain molten metal lithium; and in an inert atmosphere, introducing the sulfur vapor into the molten metal lithium, and reacting to generate lithium sulfide. According to the synthesis method and application of the lithium sulfide provided by the embodiment of the invention, the sulfur source is converted into the sulfur vapor, the lithium source is converted into the molten metal lithium, and the gas-liquid out-phase reaction is carried out in the inert atmosphere, so that the reaction efficiency and the purity are improved, the process is simplified, the cost is reduced, and the high-purity requirement can be met; the purity can be improved through raw material pretreatment of sulfur steam and molten metal lithium, and the strict requirement of a solid-state battery for high-purity lithium sulfide is met.

The invention discloses high-purity lithium sulfide as well as a preparation method and application thereof. The preparation method comprises the step that lithium hydride, lithium hydroxide and a sulfur source are subjected to a heating reaction in a dry inert atmosphere, and the high-purity lithium sulfide is obtained. The molar ratio of lithium hydride to lithium hydroxide is X: (10-X), and X is 1-6. The invention also discloses the prepared high-purity lithium sulfide and application of the high-purity lithium sulfide in preparation of sulfide solid electrolyte. Lithium hydroxide and lithium hydride are mixed to serve as a lithium source in lithium sulfide preparation, the lithium hydroxide quickly and uniformly reaches the reaction temperature by means of the characteristic that the lithium hydride reacts with a sulfur source to release heat and produce gas, the lithium hydride reacts to produce gas, meanwhile, discharging of product water vapor is facilitated, and oxygen in the environment is isolated; and hardening and generation of a side reaction product lithium sulfate are prevented, the conversion rate of lithium hydroxide to lithium sulfide is improved, and the raw material and process cost for preparing lithium sulfide is remarkably reduced.

The invention discloses an intelligent gas valve remote control and early warning system based on the Internet of Things, and relates to the technical field of valve monitoring. The valve processing module is used for preparing an intelligent valve through 316N stainless steel subjected to grain boundary processing, and a sealing ring, a fiber grating array and a QCM sensor are arranged on the intelligent valve; and the intelligent control module is used for acquiring the strain size of the fiber bragg grating and vulcanized film data through the fiber bragg grating array and the QCM sensor, and determining the lubricant release amount and the current regulation density. Strain of the valve rod is monitored in real time through the fiber bragg grating array, segmented friction force is obtained, and a nano lubricant is automatically released according to the friction force, so that the friction coefficient can be reduced, flexible opening and closing of the valve are ensured, and meanwhile, the surface density change of a vulcanized film is detected through the QCM sensor; and the valve rod is automatically triggered to rotate for self-cleaning or electrolytic polishing treatment, so that corrosion development can be effectively inhibited.

Preparation of anhydrous lithium sulfide (Li2S) purified suitably for applications in advanced batteries, and, in particular, for synthesis of solid electrolytes based on Li2S, including sulfide solid electrolytes of the type that may be described as crystalline (e.g., polycrystalline), amorphous (e.g., glass) and combinations thereof, such as sulfide glass-ceramic solid electrolyte materials.

The present invention discloses a sulfurized nano zero-valent iron material, its preparation method and application, including: a core-shell structure sulfurized nano zero-valent iron material and a preparation method, the inner core of the sulfurized nano zero-valent iron is zero-valent iron, and the outer shell is Fe9S 10 , calculated by the mass of the sulfurized nano zero-valent iron, the mass percentage of zero-valent iron is 70-80%, and the mass percentage of the iron sulfide is 20-30%; the preparation method includes: placing iron powder in an H2S gas atmosphere for calcination, after the calcination is completed, cooling to room temperature to obtain the sulfurized nano zero-valent iron material. This material can be used for in-situ remediation of chlorinated hydrocarbon organic pollutants in groundwater. Compared with the prior art, the prepared sulfurized nano zero-valent iron is less likely to be oxidized and can overcome the problem of rapid passivation of nano zero-valent iron during the remediation process.

The present application relates to the technical field of catalysts and relates to a non-noble metal cathode hydrogen evolution catalyst for PEM water electrolysis and a use thereof. The present application provides a method for preparing a cathode hydrogen evolution catalyst. A nickel-molybdenum heteropoly acid having a specific structure is generated in situ on the surface of a porous carbon material carrier, and is used as a hydrogen evolution catalyst active component precursor, and an in-situ generated nickel-containing molybdenum sulfide active component is subjected to sulfidation treatment to prepare a non-noble-metal-supported cathode hydrogen evolution catalyst, wherein the in-situ generated nickel-containing molybdenum sulfide active component has a hydrogen adsorption free energy similar to that of Pt and catalytic hydrogen evolution activity, the dispersity is good, and the number of active sites is large, thereby reducing the costs of the catalyst; in addition, during the sulfidation treatment of the nickel-molybdenum heteropoly acid, nitrogen or phosphorus atoms in the carrier can be doped into the lattice of molybdenum disulfide, thereby reducing the hydrogen evolution Gibbs free energy of sulfur atoms on an MoS2 crystal basal surface, and more active sites are formed on a sulfur edge and a molybdenum edge, facilitating a hydrogen evolution reaction.

The invention provides a modified lithium sulfide solid electrolyte, a sulfide solid electrolyte, a preparation method thereof and a battery, and relates to the technical field of solid electrolyte materials. The preparation method of the sulfide solid electrolyte is different from a traditional doping technology, the high-stability sulfide solid electrolyte is prepared mainly through modification of lithium sulfide, the comprehensive performance of the sulfide solid electrolyte is improved, the ionic conductivity and chemical stability of the sulfide solid electrolyte are improved, and the service life of the sulfide solid electrolyte is prolonged. And the mechanical strength and the crack resistance are also obviously enhanced. The preparation method disclosed by the invention is simple, does not need to be carried out at high temperature, and does not need to use expensive raw materials and complex processes, so that the production cost is reduced, the application range of the sulfide solid electrolyte is expanded, and large-scale production and application of the sulfide solid electrolyte are favorably realized.

The invention provides a composite reagent system and a chalcopyrite and sphalerite collecting method, and belongs to the technical field of mineral processing. The composite reagent system comprises a histidine derived functional group collecting agent and a black agent, and the histidine derived functional group collecting agent (containing a total sulfur ester group, a sulfydryl functional group and a side chain imidazole ring) serves as a core and is compounded with the black agent according to a specific proportion to form a target combination-synergistic interaction flotation mechanism. The histidine derivative collecting agent derives high-activity functional groups under the alkaline condition, and after sulfydryl is dissociated, stable chemical bonds are formed by the dissociated sulfydryl and metal ions on the surfaces of the chalcopyrite and the zinc sulfide. The black powder serves as an auxiliary collecting agent, and the collecting capacity of fine-grain or low-activity sulfide minerals is enhanced through chemical adsorption of dithiophosphate radicals and metal ions on the surfaces of the chalcopyrite and the sphalerite. After the two components are compounded, the selective enrichment efficiency of copper-zinc minerals in the flotation process is remarkably improved.

The invention provides a synthesis method of nanoscale lithium sulfide, and relates to the technical field of lithium sulfide synthesis. The synthesis method provided by the invention comprises the following steps: stirring and dissolving a lithium sulfide raw material in an alcohol solvent, and separating to obtain a lithium sulfide alcohol solution; evaporating, crystallizing and drying the lithium sulfide alcohol solution to obtain lithium sulfide crystals; and mixing the lithium sulfide crystals with a sulfur source, and firing at 550-850 DEG C to obtain the nanoscale lithium sulfide. The nanoscale lithium sulfide is directly synthesized in one step through a solid-phase sintering method, the operation method is simple, the cost is low, and large-scale industrial production can be achieved.

The invention discloses an efficient combined regulator for easily-argillized copper oxide cobalt ore and a beneficiation method. The efficient combined regulator comprises the following components in parts by weight: 250-350 parts of sodium citrate and 1100-1200 parts of sodium hydrosulfide. Sodium citrate has high dispersing capacity, and the efficiency of selective adsorption between the argillization copper-cobalt ore and the medicament can be improved; meanwhile, the complexing ability of sodium citrate on ions, such as Fe, Ca and Mg, influencing agent adsorption on the surface of the ore is high, in addition, products obtained after complexing of the Fe, Ca and Mg ions can be dissolved in water, and action sites are provided for selective adsorption of a vulcanizing agent (NaHS) and a collecting agent amyl xanthate (PAX). According to the combined regulator and the beneficiation method provided by the invention, the problem of poor reagent selectivity in the flotation process of the argillization copper-cobalt ore can be obviously improved, the vulcanization effect of a vulcanizing agent is enhanced, and selective adsorption of a collecting agent is promoted, so that the recovery rate of copper and cobalt metals in the copper-cobalt oxide ore under the condition of serious ore argillization is improved.

The invention belongs to the technical field of lithium battery materials, and particularly relates to a preparation method of high-purity lithium sulfide. Comprising the following steps: putting lithium hydroxide and pure water into a reaction kettle, replacing air in the reaction kettle with nitrogen, starting the reaction kettle, and stirring and heating; introducing quantitative hydrogen sulfide gas from the bottom of the reaction kettle, and circulating the gas in the reaction kettle between liquid in the reaction kettle and a gas space through a gas circulating pump; and after the temperature of the reaction liquid in the kettle is reduced to 20-30 DEG C, filtering in a nitrogen atmosphere, washing the residual solid with quantitative ammonia water, transferring the filtered solid into a drying box, and purging and drying with nitrogen until no water exists, thereby obtaining the high-purity lithium sulfide. In the solvent method, water is used for replacing an organic solvent for reaction, the problems of organic solvent separation and recovery, hazardous waste treatment and the like are avoided, the cost is reduced, and the method is environment-friendly.

The invention provides a preparation method of high-purity and low-cost lithium sulfide and lithium sulfide prepared by the preparation method, and relates to the field of lithium sulfide materials. According to the preparation method of the high-purity and low-cost lithium sulfide, on the basis of the characteristics of high-efficiency heat and mass transfer and uniform dispersion of a fluidized bed fluidization technology, lithium source small liquid drops are coated on the surface of a fluidized precursor, then hydrogen sulfide gas is introduced, the lithium source melt liquid drops or the precursor coated with the lithium source solution liquid drops are subjected to a contact reaction with the hydrogen sulfide gas, and the high-purity and low-cost lithium sulfide is obtained. The lithium sulfide is prepared. According to the preparation method of the high-purity and low-cost lithium sulfide, the problems of more reaction byproducts, low hydrogen sulfide gas utilization rate, easiness in product agglomeration and non-uniform particle size distribution in the existing lithium sulfide preparation process can be effectively solved, the reaction temperature is further reduced, and the production safety is improved; and the problem that the product purity and quality are influenced by water vapor in the preparation process is effectively avoided, and stable and efficient lithium sulfide production is realized.

The invention discloses a large-scale preparation method of lithium sulfide, and belongs to the technical field of preparation of battery materials. Lithium sulfate monohydrate is adopted as a reaction raw material and is subjected to dehydration and purification treatment to obtain anhydrous lithium sulfate, and the anhydrous lithium sulfate is calcined in hydrogen and carbon dioxide mixed gas without introducing other impurities; the method has the advantages that safety under high-temperature calcination reaction can be guaranteed, the produced lithium sulfide crude product is dissolved by the methanol / isopropanol mixed solution to directly generate lithium sulfide crystals, redundant impurities can be removed by calcining the generated lithium sulfide crystals, no other by-products are generated in the reaction process, and the purity of lithium sulfide is guaranteed. According to the Li2S preparation method developed by increasing the purification step and exploring the reaction conditions and the impurity removal mode, low-cost, high-purity and large-scale preparation of Li2S can be realized.

The present invention provides a method for preparing a carbon-containing lithium sulfide composite material, the method comprising: in a water-free and oxygen-free environment of a vacuum glove box, weighing a certain amount of lithium source and sulfur source, putting them into a ball mill, and then adding sodium borohydride according to a set ratio to mix evenly; sealing the ball mill, and passing an inert gas after evacuation, and then ball milling for a certain time at a set speed and after the ball milling is completed, taking out the lithium sulfide solid under the protection of the inert gas; dissolving and filtering the obtained lithium sulfide solid in anhydrous ethanol, and adding a certain amount of carbon source to the filtrate, stirring, and ultrasonic treatment; heating and evaporating to remove the solvent, and obtaining a solid Li2S / C precursor; placing the Li2S / C precursor in a vacuum freeze dryer, and freeze-drying to remove residual moisture to obtain a Li2S / C composite material. The present invention solves the problems of high cost and low purity when preparing lithium sulfide in the prior art.

The invention provides a preparation method and application of lithium sulfide. The preparation method comprises the following steps: reacting a lithium source with a sulfur source; the lithium source is a solid lithium-containing substance with the purity of 99% or above and the whiteness of 86 or above; the solid lithium-containing substance is selected from one or more of anhydrous lithium hydroxide, lithium hydroxide monohydrate, lithium carbonate, lithium chloride, lithium bromide and lithium nitrate. According to the method, a solid lithium-containing substance with the purity of 99% or above and the whiteness of 86 or above is used as a lithium source and reacts with a sulfur source, and the ionic conductivity value of the Li6PS5Cl solid electrolyte prepared from the obtained lithium sulfide is stable. Experimental results show that the ionic conductivity can stably reach more than 2mS / cm.

The invention is applicable to the technical field of nano material preparation, and provides a preparation method of a two-dimensional acetylene-rich carbon / molybdenum sulfide heterostructure hydrogen production catalyst, which comprises the following steps: adding molybdenum sulfide into a solution to prepare a suspension A; adding soluble cuprous salt into the turbid liquid A in an inert atmosphere to obtain a mixed liquid B; alkynyl benzene is added into an organic solvent, and a mixed solution C is obtained; dropwise adding the mixed solution C into the mixed solution B under a continuous stirring condition, and reacting to obtain a mixed solution D; centrifuging the mixed solution D to obtain a precursor E; and cleaning the precursor E, and carrying out vacuum drying to obtain the two-dimensional acetylene-enriched carbon / molybdenum sulfide heterostructure hydrogen production catalyst. No additive is needed in the preparation process, and the product purity is high; by constructing a special two-dimensional heterostructure, the problem of molybdenum sulfide is solved, and the intrinsic activity and stability of the material are remarkably improved. The preparation method has the advantages of easily available raw materials, simple process, low cost and environmental protection, and is suitable for industrial production.

The invention relates to a sulfide solid electrolyte and a preparation method and application thereof, and the preparation method comprises the following steps: distributing elemental sulfur powder on the surface of lithium sulfide powder to obtain composite powder; mixing the composite powder with phosphorus sulfide and lithium halide to obtain a precursor; and sintering the precursor to obtain the sulfide solid electrolyte. According to the preparation method disclosed by the invention, the elemental sulfur powder is distributed on the surface of the lithium sulfide powder, so that the elemental sulfur powder can participate in formation of the sulfide solid electrolyte before volatilization in the sintering process, the prepared sulfide solid electrolyte does not have sulfur loss, and no impurity phase is generated in the sulfide solid electrolyte; therefore, the ionic conductivity of the sulfide solid-state electrolyte can be improved, and the electrochemical performance of an all-solid-state battery can be obviously improved when the sulfide solid-state electrolyte is used for assembling the all-solid-state battery; meanwhile, the preparation method is simple and efficient, and the obtained sulfide solid electrolyte is uniform in performance.

The invention provides a method for preparing high-purity lithium sulfide from lithium carbonate, and belongs to the technical field of lithium material preparation, and the method comprises the following steps: heating a ball-milled mixture of industrial-grade lithium carbonate and an alumina additive to 750-900 DEG C, and carrying out heat preservation and calcination to generate lithium oxide; performing hydrolysis reaction on lithium oxide in hot water, and filtering to obtain a high-purity lithium hydroxide solution; mixing the lithium hydroxide solution with the sulfur-containing protein, and performing spray drying to obtain a mixed precursor; calcining the mixed precursor at a low temperature of 210-340 DEG C in an inert atmosphere; and heating to 550-660 DEG C, calcining at a high temperature, introducing hydrogen sulfide gas, reacting lithium hydroxide to generate lithium sulfide, and cooling to obtain the high-purity lithium sulfide. The invention provides the method for preparing the high-purity lithium sulfide, the purity, the production efficiency and the raw material utilization rate of the lithium sulfide are remarkably improved, and the technical defects of low purity, incomplete raw material reaction, non-uniform precursor mixing, complicated process, difficulty in large-scale production and the like in the traditional lithium sulfide preparation method are overcome.

The invention discloses a method for preparing a carbon monoxide oxidation catalyst by using red mud and tungsten-molybdenum smelting slag, which comprises the following steps of: uniformly stirring and mixing the red mud and the tungsten-molybdenum smelting slag at a high speed, mixing with inorganic strong acid, and performing ultrasonic-assisted stirring to obtain acid leaching slag; the acid leaching residues are subjected to low-temperature plasma activating treatment and then microwave activating treatment, and microwave activated plasma residues are obtained; weighing tricalcium phosphate and microwave activated plasma slag, and uniformly stirring to obtain phosphorus-calcium doped activated slag; weighing an ammonium sulfide solution and the phosphorus-calcium doped activated slag, uniformly stirring, transferring the obtained sulfur-phosphorus-calcium doped activated slag into a hydrothermal reaction kettle, carrying out hydrothermal reaction, carrying out compression molding on the obtained hydrothermal composite material, and carrying out pyrolysis carbonization treatment in an inert gas atmosphere to obtain the phosphorus-calcium doped activated slag. The obtained pyrolysis composite material is soaked with a silane coupling agent solution and then roasted again, and the carbon monoxide oxidation catalyst is obtained. The catalyst prepared by the invention can realize efficient oxidation photocatalysis of carbon monoxide under the conditions of normal temperature and normal pressure.

The invention relates to the technical field of preparation of lithium sulfide, in particular to a method for preparing lithium sulfide through hydrogen reduction of lithium sulfate. According to the specific technical scheme, the method for preparing the lithium sulfide by reducing the lithium sulfate through the hydrogen comprises the steps that the lithium sulfate is smashed to be micron-sized and then fed into a fluidized bed reactor, then high-purity hydrogen preheated to 850 DEG C is introduced into the fluidized bed reactor from the bottom of the fluidized bed reactor, the reaction temperature is controlled to be 850 + / -20 DEG C, and the reaction time is controlled to be 5-10 min. The hydrogen reduction method is relatively low in reaction temperature (700-900 DEG C), hydrogen is used as a clean reducing agent, a reaction byproduct is only water, and the problems of insufficient purity, high energy consumption, serious environmental pollution and the like in a traditional lithium sulfide preparation method can be avoided. The introduction of the fluidized bed technology can greatly enhance the gas-solid phase heat and mass transfer efficiency, realizes the continuity and automation of the process, and is an important path for realizing the industrialization of the reaction.

The invention relates to the technical field of stainless steel pneumatic cylinder barrels, and particularly discloses a wear-resistant stainless steel pipe for a pneumatic cylinder barrel and a preparation process thereof.The wear-resistant stainless steel pipe for the pneumatic cylinder barrel comprises the steps that firstly, a powder metallurgy method is adopted, tungsten carbide, cerium oxide, chromium nitride and other components are added into stainless steel powder, and the performance of a steel pipe base body is enhanced; the corrosion-resistant alloy layer is deposited on the surface of the steel pipe, so that the corrosion resistance, wear resistance and other properties of the steel pipe are enhanced, finally, a silicon nitride wear-resistant ceramic layer is sintered on the surface of the corrosion-resistant coating, and two lubricants of graphite and molybdenum sulfide are synthesized in gaps and holes of the wear-resistant ceramic layer. The defects on the ceramic surface are blocked; and the ceramic coating is endowed with a self-lubricating function.

The invention discloses a preparation method of a high-performance lithium-phosphorus-sulfur-chlorine solid electrolyte, and relates to the technical field of solid-state lithium batteries. The method comprises the following steps: in an inert atmosphere environment, selecting lithium sulfide, phosphorus pentasulfide, sulfur and lithium chloride as raw materials, carrying out mechanical alloying treatment through a high-energy ball milling method, then promoting crystallization through heat treatment, and finally optimizing the particle size distribution of the material through powder grading. The method provided by the invention can effectively improve the ionic conductivity of lithium phosphorus sulfur chlorine, and the solid electrolyte with good fluidity and stability is obtained.

The invention relates to the technical field of battery raw materials, in particular to a preparation method of lithium sulfide powder, the lithium sulfide powder and application, and the preparation method comprises the following steps: uniformly mixing lithium sulfate and a carbon source according to a preset proportion to obtain a first mixture; performing first heat treatment on the first mixture in inert gas to obtain a second mixture; and performing second heat treatment on the second mixture in reducing gas to obtain the lithium sulfide powder. The product obtained by the preparation method disclosed by the invention is the lithium sulfide powder, and the obtained lithium sulfide powder has the advantages of less oxygen and carbon impurities, higher purity and high reaction activity, and meets the synthesis requirements of the electrolyte; according to the preparation method, in the process of preparing lithium sulfide, toxic gas and organic solvent are not used, the reaction temperature is low, the energy consumption is low, the requirement on production equipment is low, the process is simple, the cost is low, harmful gas emission is avoided, safety and environment friendliness are achieved, and industrialization is easy to achieve.

The invention discloses a method for recovering metal from high-nickel copper fire refining slag and application of the method, and relates to the technical field of metal metallurgy. Comprising the following steps: carrying out weak acid arsenic leaching on the copper fire refining slag to obtain arsenic-removed leaching slag and arsenic-containing copper liquid; copper removal is carried out on the arsenic-containing copper liquid to obtain a copper-containing material and copper-removed liquid, and arsenic precipitation is carried out on the copper-removed liquid; the arsenic-removed leaching residues are subjected to oxidation copper leaching to obtain copper leaching residues and a copper sulfate solution, and the copper leaching residues are subjected to reduction vulcanization smelting to obtain nickel matte, tin-antimony smoke dust and smelting residues. According to the method, the cost of separation of copper and arsenic in the raw materials can be reduced, the problem of furnace caking caused in the reduction smelting process is avoided, the obtained copper sulfate solution serves as electrolyte replenishing liquid to be applied to the copper electrolysis process, and the influence on the self-purification process of electrolyte is small. According to the method, nickel and copper are enriched in matte nickel through reduction vulcanization smelting, then copper-nickel separation is conducted through the post-treatment process, the post-treatment process is shorter, nickel recovery is achieved while copper recovery is guaranteed, and better economic benefits are achieved.

The present invention proposes a light-absorbing film and a preparation method and application thereof, including a preparation method of a copper-vanadium-sulfur / copper-vanadium-selenium / copper-vanadium-sulfur-selenium light-absorbing film based on a solution method, and an application of the light-absorbing film prepared by the method on a solar cell. The preparation method is simple to operate and low in cost. Thioglycolic acid and ethanolamine are used as ligands, and ethylene glycol methyl ether is used as a solvent to adjust the viscosity to prepare a precursor solution; a copper-vanadium-sulfur / copper-vanadium-selenium / copper-vanadium-sulfur-selenium film is prepared by spin coating-sintering mode and adjusting the feed ratio of elements; high-temperature heat treatment is continued for sulfurization / selenization reaction to obtain a large-grain through-type copper-vanadium-sulfur / copper-vanadium-selenium / copper-vanadium-sulfur-selenium film, which can avoid the generation of impurities in the film, and the prepared light-absorbing film is applied to the light-absorbing layer of a solar cell, which is conducive to assembling a copper-vanadium-sulfur-selenium thin film solar cell with high photoelectric conversion efficiency.

The invention relates to the field of design and preparation of powder metallurgy friction materials, in particular to a copper-based powder metallurgy friction material and a preparation method thereof. Raw materials used in the method comprise, by mass, 45%-55% of copper powder, 8%-20% of iron powder, 6%-15% of ferrochromium, 16%-22% of graphite, 0.5%-4% of molybdenum disulfide, 0.5%-4% of tin sulfide and 0.5%-4% of nickel-coated tungsten disulfide, and the mass ratio of the tin sulfide to the nickel-coated tungsten disulfide is (1-2): (1-2). In the nickel-coated tungsten disulfide, the content of nickel is 5-40%; the sum of the total amount of molybdenum disulfide, nickel-coated tungsten disulfide and tin sulfide is less than or equal to 5%. The preparation method comprises the following steps: weighing raw material powder according to the designed components, mixing, pressing and sintering to obtain the product. The composition design has the characteristics of scientificity, simple and controllable process and the like, and the obtained product has excellent tribological performance and completely meets the friction braking requirement of high-speed heavy-load equipment of 400km / h and above.