The application relates to a novel
lithium ion battery layered
sulfide positive
electrode material, which has a general formula of Li 1.33‑0.33x V x Ti 0.67‑0.67x S2, and 0<=x<=0.5. The positive
electrode material belongs to a hexagonal
crystal structure of O3 type, and a corresponding
space group is P63 / mmc. The micro-morphology of the positive
electrode material is granular, the particle size is about 20-50 mu m, and each element is uniformly distributed on the particle surface and inside. In the positive
electrode material, almost all the capacity comes from the
redox reaction of
sulfur, and the capacity contribution of
vanadium can be ignored. Electrochemical test and
solid-state nuclear magnetic characterization results show that the Li 1.27 V 0.2 Ti 0.53 S2 positive
electrode material has a reversible capacity of up to 308 mAh g ‑1 , and realizes reversible deintercalation of all Li + in the
system. Meanwhile, the material exhibits extremely excellent rate and cycle performance, has a capacity
retention rate of 81.0% after 4300 cycles of long cycle, and has almost no
voltage attenuation in the cycle process.