152 results about "Sintered magnets" patented technology

The invention discloses a neodymium iron boron magnet with a protective film and a manufacturing method thereof, and the manufacturing method specifically comprises the following steps: S1, pretreating a plurality of raw materials to ensure the purity and cleanliness of the raw materials; s2, the pretreated materials are mixed in proportion and smelted to prepare uniform neodymium-iron-boron alloy; s3, the smelted alloy is crushed, and particle powder meeting the requirement is prepared through jet mill equipment; s4, the powder is put into a mold, forming orientation is conducted through a magnetic field press, and the maximum residual magnetism is obtained; s5, performing high-temperature sintering on the molded magnet to improve the density and the magnetic performance of the molded magnet; s6, the sintered magnet is machined, and the needed size and shape are obtained; s7, carrying out pretreatment on the surface of the magnet, and carrying out aftertreatment after chemical nickel plating to ensure the quality of a plating layer; according to the method, the surface of the neodymium-iron-boron magnet is coated with a high-phosphorus chemical nickel layer in a plating mode, the magnet can be effectively prevented from being corroded by the external environment, and the service life of the magnet is prolonged.

A high-abundance rare earth iron boron regenerated magnet and its preparation method belong to the field of rare earth permanent magnet materials and their recycling technology. After surface treatment, high-abundance Ce / La rare earth iron boron unqualified products and processing waste are subjected to coarse crushing and hydrogen explosion powdering; a Ce, La, Nd, and Pr rare earth alloy is prepared using a rapid solidification belt spinning technology and hydrogen explosion; the above two materials are ball milled, mixed, oriented, and pressed according to a certain proportion, and then sintered and heat treated to obtain a regenerated sintered magnet. The regenerated magnet prepared by the present invention has a waste material utilization rate of up to 95%, a low rare earth addition amount (0 to 5wt.%), and a light rare earth addition ratio (LaCe / NdPr) greater than 50%. The coercive force of the regenerated magnet is significantly improved, and the comprehensive magnetic properties are equivalent to or even higher than those of the original magnet. The present invention can accurately control the cheap light rare earths La and Ce to obtain a high-performance regenerated magnet, thereby realizing the high-value recycling of high-abundance rare earth permanent magnets.

A method for preparing a high-coercivity and high-thickness NdFeB magnet belongs to the technical field of rare earth permanent magnet material preparation and solves the technical problem of preparing high-thickness and high-coercivity NdFeB magnets. The method comprises the following steps: first, sequentially subjecting the NdFeB magnets to rapid solidification strip spinning, hydrogen crushing, airflow milling, magnetic field orientation molding, cold isostatic pressing, and vacuum low-temperature sintering to obtain a thin low-temperature sintered green body; second, subjecting the low-temperature sintered green body to a grain boundary thermal diffusion treatment after preparing a heavy rare earth element layer on the surface of the low-temperature sintered green body; third, subjecting the low-temperature sintered green body after the diffusion heat treatment to mechanical coarse crushing, hydrogen crushing, powder mixing, airflow milling, magnetic field orientation molding, and cold isostatic pressing to obtain a thick, high-thickness compact; finally, subjecting the high-thickness compact to vacuum low-temperature heat treatment, vacuum high-temperature sintering, and two heat treatments to obtain a high-coercivity and high-thickness NdFeB magnet. The method has a simple preparation process, significantly improves the coercivity of bulk NdFeB sintered magnets, and enables the magnets to have a high magnetic energy product.

This application provides a large-size NdFeB magnet and its preparation method. The preparation method includes: mixing a main alloy powder and an auxiliary alloy powder in a ratio of 10:(1-3) to obtain a mixed alloy powder; molding the mixed alloy powder and then isostatically pressing it to obtain a green blank; sintering the green blank using a multi-stage heating method to obtain a sintered magnet; wherein the multi-stage heating includes: heating to 1000-1100℃ at at least three gradually decreasing heating rates and holding at that temperature for 1-6 hours; and cooling the sintered magnet to obtain a NdFeB magnet. This application, through a dual alloying process and gradually reducing the heating rate during sintering, can effectively suppress cracking of the magnet during sintering and obtain a large-size magnet with excellent magnetic properties.

The invention discloses a cerium-containing high-abundance rare earth sintered neodymium iron boron permanent magnet which does not contain heavy rare earth and does not need a grain boundary diffusion process and a preparation method thereof. The magnet is formed by crushing and mixing three alloy casting pieces, the three alloy casting pieces are an Nd / Pr-rich phase, a Ce-La-rich phase and a Y-Nd-rich phase respectively, and Ce accounts for more than or equal to 30wt% of the total amount of all rare earth elements; the trace elements (Al, Cu, Ga, Nb, Zr and the like) are uniformly introduced in the smelting stage of each main phase, and grain boundary reconstruction is induced through in-situ hydrotreating to form a thin and continuous rare earth-rich grain boundary phase; and after orientation compression molding, vacuum sintering and multi-stage heat treatment, a sintered magnet with excellent magnetic performance is obtained. According to the product, the intrinsic coercive force Hcj is larger than or equal to 15 kOe, the residual magnetism Br is larger than or equal to 13.7 kG, and the maximum magnetic energy product (BH) max is larger than or equal to 39 MGOe. The problems that a high-Ce magnet is low in coercive force, discontinuous in grain boundary phase and the like are solved, the method does not need to depend on Dy / Tb heavy rare earth and a grain boundary diffusion technology thereof, the cost is reduced by 30% or above, and the method is suitable for the fields of new energy automobiles, wind power generation and the like and has a good industrialization prospect.

The invention relates to the technical field of release agents, and discloses a silicone-oil-free wet-process magnet profiling release agent and a preparation process thereof, and the silicone-oil-free wet-process magnet profiling release agent comprises a core functional copolymer, a water-based non-silicon defoaming agent and deionized water. The core functional copolymer is prepared from a hydrophilic self-repairing film-forming monomer, a molecular-level flexible lubricating monomer, a powerful mold anchoring monomer and a programmed pyrolysis triggering monomer through free radical copolymerization. According to the technical scheme, the functions of self-repairing film forming, molecular-level lubrication, mold anchoring and programmed pyrolysis are integrated through a single macromolecular structure. A demolding film layer formed by the water-based demolding agent is uniform and compact, mold sticking and blank defects in the profiling process are avoided, the water-based demolding agent can be completely decomposed and volatilized in the magnet sintering process, and solid residues are not generated, so that the high magnetic performance of a sintered magnet is guaranteed, and the problems that an existing water-based demolding agent is prone to generating film layer defects, poor in system stability, residues after sintering and the like are solved.

An Sm-Fe-N-based sintered magnet comprising a sintered body of a magnetic material containing an Sm-Fe-N-based magnetic powder and a Zn-Al alloy powder, wherein the Al content of the Zn-Al alloy powder is 6-84 atom%, and the open porosity of the sintered magnet is not more than 15%.

The invention discloses an ultra-fine grain high-coercivity heavy-rare-earth-free magnet and a preparation method thereof, belongs to the technical field of heavy-rare-earth-free magnets, and solves one of the problems of coarse grains, poor grain uniformity, low coercivity and poor coercivity temperature coefficient of the heavy-rare-earth-free magnet in the prior art. The ultra-fine grain high-coercivity heavy rare earth-free magnet is a sintered magnet with an R2T14B phase as main phase particles; the area ratio of main phase grains with the grain size smaller than 4 microns of the ultra-fine grain high-coercivity heavy-rare-earth-free magnet is larger than or equal to 90%. The single domain crystal grain percentage is not less than 70%; wherein R is light rare earth and is one or more of lanthanum, cerium, praseodymium and neodymium, T is a transition element, and B is boron. The ultra-fine grain high-coercivity heavy rare earth-free magnet disclosed by the invention is high in intrinsic coercivity and high in intrinsic coercivity temperature coefficient.

This invention discloses an R-T-B sintered magnet with reduced eddy current losses, its preparation method, and its application. The magnet has partition grooves on one or two orientation surfaces, where each orientation surface is perpendicular to the orientation direction of the magnet. The partition grooves extend through the magnet in a first extension direction but not in a second extension direction. The first extension direction of the partition grooves is perpendicular to the orientation direction of the magnet, and the second extension direction is parallel to the orientation direction of the magnet. By creating crisscrossing partition grooves on the magnet and filling them with an insulating layer, this invention increases the resistivity of a thin layer on the magnet's surface by a certain thickness, significantly reducing motor power loss due to eddy current effects. The insulating layer filling the grooves increases the resistivity of both the magnet surface and the grooves, effectively preventing conduction due to poor processing or current breakdown when the groove width is narrow. It also compensates for the reduction in mechanical strength caused by the grooving, ultimately resulting in a low-eddy-current, high-strength sintered magnet.

To provide an R-Fe-B sintered magnet that exhibits high coercivity while keeping material costs down. [Solution] The R-Fe-B sintered magnet contains a rare earth element R including Tb, an element T consisting of Fe or a combination of Fe and Co, B, and each of Al, Cu, and Ga, with an element M consisting of a combination of Al, Cu, and Ga, and includes an RTM phase in the grain boundary phase, where the number of atoms of element M in the RTM phase is in the order of Cu > Al > Ga. Furthermore, in the RTM phase, the atomic ratio of the rare earth element R to element M is preferably 6.0 for the rare earth element R and 1.3 or more for element M.

According to the high-squareness heavy-rare-earth-free R-T-B sintered magnet and the preparation method thereof, the jet milling process is optimized, high-rare-earth alloy B coarse powder is supplemented at the later stage of jet milling, jet milling is carried out at the same time, rare earth is timely and accurately supplemented for rear-section powder with large rare earth loss, the difficulty of later-stage material mixing is reduced, and the high-squareness heavy-rare-earth-free R-T-B sintered magnet is obtained. And the rare earth content of the powder in the post-jet milling stage is increased, so that the rare earth content of the powder in the post-jet milling stage is approximately consistent with the rare earth content of the powder in the previous stage. The particle size distribution of the powder in the later stage is further optimized, the microscopic grain size distribution of the magnet is eventually homogenized, so that the high-squareness heavy-rare-earth-free R-T-B sintered magnet is obtained, the squareness SQ of the magnet is larger than or equal to 0.95, and the intrinsic coercive force Hcj is larger than or equal to 16.5 kOe.

An anti-corrosion treatment method for preparing sintered NdFeB magnet includes preparing a sintered NdFeB matrix, and applying a heat treatment to the sintered NdFeB matrix in an oxidizing atmosphere containing at least one of alcohol or organic acid. A ratio of oxygen partial pressure to water vapor partial pressure in the oxidizing atmosphere is in a range from 1:1 to 300:1. A temperature for the heat treatment is equal to or lower than 300° C. A time for the heat treatment is in a range from 10 minutes to 200 minutes.

The present invention discloses a method for manufacturing a heavy rare earth-free high-coercivity R-T-B magnet, which relates to the technical field of magnets. The technical scheme includes raw materials and diffusion materials composed of 27.5-35.0wt% of an R component, 0.8-0.95wt% of a B component, 0-3wt% of an M component and a balance of a T component in percentage by mass; the M component consists of 0-2wt% of M1 and 0-1wt% of M2, and B and M2 satisfy the following formula (1): 0.8>B-M2>0.2 (1); and M1 is at least one of Cu, Al and Ga, and M2 is at least one of Nb, Zr and Ti; wherein the diffusion material is PrX, and X is at least one element; the manufacturing method includes preparing a R-T-B sintered magnet raw material from the raw material, coating the diffusion material on the surface of the magnet raw material, and obtaining the heavy rare earth-free high-coercivity R-T-B magnet after heat treatment and diffusion. The present invention has the effect of obtaining a heavy rare earth-free high-coercivity R-T-B magnet with a coercivity HcJ greater than 23 kOe without adding heavy rare earth.

A rare earth sintered magnet according to the present disclosure includes: a main phase satisfying general formula (Nd, La, Sm)—Fe—B and including crystal grains based on R2Fe14B crystal structures; and a crystalline subphase based on an oxide phase represented by (Nd, La, Sm)—O. The subphase has a higher concentration of Sm than the main phase.

The application discloses a surface-strengthened R-T-B rare earth permanent magnet based on high-melting-point element grain boundary diffusion and a preparation method thereof. The application adopts heavy rare earth elements (at least one of Dy, Tb and Ho), high-melting-point elements (Zr and Ti) and low-melting-point metals (at least one of Al, Ga and Cu) to prepare a diffusion source, and performs grain boundary diffusion treatment on a sintered magnet, thereby obtaining the surface-strengthened R-T-B rare earth permanent magnet. The grain boundary diffusion high-melting-point element precipitates can inhibit the excessive growth of the main phase grains in the grain boundary diffusion process, realize the refinement of the main phase grains and improve the uniformity of the main phase grain size of the whole magnet. The grain boundary diffusion magnet has higher coercivity and squareness, reduces the reduction amount of the remanence of the magnet after the grain boundary diffusion; and can improve the crack propagation resistance of the Nd-rich phase at the grain boundary, thereby improving the fracture toughness of the magnet while improving the strength of the surface layer of the magnet, so that the qualified rate of the product during surface processing is improved.

A magnet preparation method includes coating powder slurry on at least one of a first surface or a second surface of an NdFeB matrix and carrying out a curing reaction, to obtain a coated magnet, and subjecting the coated magnet to a vacuum heat treatment, a grain boundary diffusion treatment, and an aging treatment. The first surface and the second surface are opposite to each other. The powder slurry includes powder containing heavy rare earth element and UV monomer. The UV monomer includes radical-cured UV monomer. A temperature of the vacuum heat treatment is in a range from 250° C. to 600° C.

The invention discloses a method for reducing consumption of rare earth elements and preparing a high-performance sintered Nd-Fe-B magnet through a diffusion process. The method comprises the following steps: preparing a matrix; the preparation method comprises the following steps: coating a layer of film on the surface of a substrate by a spray coating method and a silk-screen printing method, and then coating a layer of Pr70Cu15Al10Ga5at.% film on the magnet substrate coated with the film; and after film coating, placing in a vacuum tube furnace for diffusion. The invention discloses a method for reducing consumption of rare earth elements and preparing a high-performance sintered Nd-Fe-B magnet through a diffusion process. Two-step grain boundary diffusion is formed by NbF5 which is easy to form intergranular precipitates and Pr70Cu15Al10Ga5 grain boundary diffusion which is used for forming high-anisotropy Pr; intergranular precipitates are formed in the magnet before grain boundary diffusion of the rare earth alloy, grain boundary migration which inevitably occurs during Pr grain boundary diffusion is inhibited, and Ta-containing intergranular precipitates and a microstructure which is used for forming a Pr-rich shell and changes Nd are formed; high coercive force can be realized in the Nd-Fe-B sintered magnet without using heavy rare earth, the process cost is low, and the problem of low rare earth diffusion rate is solved.

A rare-earth sintered magnet is provided, characterized in that it comprises R (R is one or more elements selected from rare earth elements, with Nd being essential), T (T is one or more elements selected from iron group elements, with Fe being essential), X (X is one or two elements selected from B and C, with B being essential), and M. 1 (M 1 The rare earth sintered magnet is selected from one or more of Al, Si, Cr, Mn, Cu, Zn, Ga, Ge, Mo, Sn, W, Pb, and Bi, with less than 0.1% O, less than 0.05% N, and less than 0.07% C, and has an average crystal grain size of less than 4.0 μm. Furthermore, when the orientation degree is set to Or [%] and the average crystal grain size is set to D [μm], it satisfies the relationship (1): 0.26×D+97≦Or≦0.26×D+99. Based on this rare earth sintered magnet, it is possible to obtain magnets with both high Br and high H content. cJ It has excellent magnetic properties.

The invention discloses a neodymium-iron-boron magnet and a preparation method thereof. The neodymium-iron-boron magnet is a sintered magnet obtained by modifying an alloy fine powder raw material through a chemical reagent and then carrying out compression, vacuum treatment and sintering; the alloy fine powder comprises 75 wt%-99 wt% of magnetic powder and 1 wt%-25 wt% of metal fine powder, and the metal fine powder is one or more of lanthanum, cerium, praseodymium, neodymium, iron, aluminum, cobalt, copper and titanium. The preparation method comprises the steps of magnetic powder and metal powder mixing, chemical reagent modification treatment, heat treatment, compression molding, sintering and heat treatment, and the neodymium-iron-boron magnet is obtained. A chemical reagent is used for modifying the magnet, so that the microstructure of the magnet is improved, the interaction effect of a main phase and a grain boundary phase of a magnet base material is improved, grain boundary phase distribution is further optimized through grain boundary diffusion, the comprehensive magnetic performance of the magnet is improved, the use amount of heavy rare earth is reduced, and the bottleneck of high-performance magnet preparation is broken through.

Provided is a method for producing an R-T-B sintered magnet, which does not require the preparation of an inert gas atmosphere. This method for producing an R-T-B sintered magnet comprises: a pulverization step for preparing an alloy powder for an R-T-B sintered magnet; a molding step for preparing a powder molded body using the powder; a cutting step for obtaining a molded body sheet by cutting the powder molded body; and a sintering step for preparing a sintered body by sintering the molded body sheet, in the cutting step, the powder molded body immersed in the liquid is cut by the movement of a metal wire, and the metal wire is a metal stranded wire.

The invention describes a sintered rare earth magnet with a concentration of c of 8001,400 ppm, a maximum concentration of o of 1,000 ppm, and a maximum concentration of N of 800 ppm, a maximum average crystal grain size D50 of 4.5 ppm, and an orientation Or (%) determined by the formula: Or ” (Br / 47tfs)*100, in which D50 and Or satisfy the relationship: Or > 0f7*D5O+95. The sintered magnet shows both high values ​​of Br and HCJ.

The present invention relates to a ferrite sintered magnet, a ferrite particle, a bonded magnet, and a rotary electric machine. The magnet is a ferrite sintered magnet containing a ferrite phase having a crystal structure of a magnetoplumbite type, wherein at least Ca, a metal element A, a metal element R, Bi, Fe, and a metal element M are contained, the metal element A is at least one element selected from Sr, Ba, and Pb, the metal element R is at least one element selected from rare earth elements including Y and must contain La, the metal element M is at least one element selected from Co, Ni, Zn, Al, Cu, and Cr and must contain Co, and when atomic ratios of the metal elements are expressed by formula (1), in formula (1), c, a, r, b, f, and m satisfy the following formulae (2) to (8).

A ferrite magnet includes: a hexagonal ferrite main phase; and a second phase. The second phase is an oxide phase containing: an element A which is at least one selected from the group consisting of Ca, Sr, Ba, Bi, and rare earth elements; a transition metal element T including at least Fe; and an element G which is at least one selected from the group consisting of Si, Al, B, F, K, Na, Li, P, and S. When the total number of atoms of the element A, the transition metal element T, and the element G in the second phase is set to 100 at %, the element A occupies 30 to 80 at %, the element G occupies 15 to 40 at %, and the transition metal element T occupies less than 4 at %.

A rare earth sintered magnet is manufactured by preparing a R1-T-X sintered body having a major phase of R12T14X composition wherein R1 is a rare earth element(s) and essentially contains Pr and / or Nd, T is Fe, Co, Al, Ga, and / or Cu, and essentially contains Fe, and X is boron and / or carbon, forming an alloy powder containing 5≤R2≤60, 5≤M≤70, and 20<B≤70, in at %, wherein R2 is a rare earth element(s) and essentially contains Dy and / or Tb, M is Fe, Cu, Al, Co, Mn, Ni, Sn, and / or Si, and B is boron, disposing the alloy powder on the sintered body, and heat treating the alloy-covered sintered body.

The preparation method comprises the steps that alloy raw materials are smelted, sheet throwing is carried out, heat treatment, hydrogen decrepitation, jet milling, magnetic field forming, cold isostatic pressing treatment and sintering are sequentially carried out, and a first sintered neodymium-iron-boron magnet is obtained; depositing a non-rare earth target material on one surface of the sintered neodymium-iron-boron magnet by using a molecular beam epitaxy technology; grain boundary diffusion and heat treatment; and depositing a heavy rare earth target material on the surface of the sintered magnet by using a molecular beam epitaxy technology to obtain a sintered neodymium-iron-boron magnet II, carrying out grain boundary diffusion and heat treatment, and then carrying out a tempering process to obtain the sintered neodymium-iron-boron magnet. According to the method, atomic-scale film layer control is achieved through the molecular beam epitaxy technology, the problem that a uniform thin diffusion layer is difficult to obtain through a traditional coating method is solved, diffusion materials can be efficiently utilized, the uniform diffusion depth of heavy rare earth elements in the magnet is increased, the ultrahigh-coercivity magnet is manufactured, and the industrial requirements of rare earth permanent magnet motors and the like are met.

To provide a rare earth magnet powder capable of sufficiently improving bulk density and suitable for manufacturing an anisotropic magnet.SOLUTION: A rare earth magnet powder has an average sphericity P1 defined by the formula (1) of P1=Ls / Ll of 0.65 or more. In the formula (1), Ll is the length of the long side of the circumscribing rectangle having the smallest area with respect to the rare earth magnet powder in a microscope image, and Ls in the formula (1) is the length of the short side of the circumscribing rectangle having the smallest area with respect to the rare earth magnet powder in the microscope image.SELECTED DRAWING: Figure 1A

Provided are Sm-Fe-N-based magnetic powder having high squareness, a Sm-Fe-N-based sintered magnet, and methods for producing the Sm-Fe-N-based magnetic powder and Sm-Fe-N-based sintered magnet. The Sm-Fe-N-based magnetic powder: contains particles containing samarium, iron, and nitrogen, and does not contain particles of an oxide of samarium having a particle diameter of 0.1 μm or more; or the number ratio of particles of an oxide of samarium having a particle diameter of 0.1 μm or more is 10% or less, and does not contain copper or contains 5 ppm or less of copper.

To achieve both high residual magnetic flux density and high coercive force, which are conventionally considered paradoxical characteristics, an R-Fe-B system sintered magnet is provided, characterized in that it has the following composition: containing R (R is one or more elements selected from rare earth elements, and Nd is essential), B, M (M is at least one of Si, Al, Mn, Ni, Co, Cu, Zn, Ga, Ge, Pd, Ag, Cd, In, Sn, Sb, Pt, Au, Hg, Pb, and Bi), X (X is at least one of Ti, Zr, Hf, Nb, V, and Ta), and C, with the balance being Fe, O, and unavoidable impurities, and having R2Fe 14 A main phase of B and a grain boundary phase containing an R-C phase having a higher R concentration and a higher C concentration than the main phase, wherein the area ratio of the R-C phase in the magnet cross section exceeds 0 and is 0.5% or less.

The invention relates to the technical field of magnetic materials, in particular to a high-performance sintered neodymium-iron-boron magnet and a preparation method thereof.In order to prolong the service life of the magnet, firstly, a magnet material is limited, and the high-performance sintered neodymium-iron-boron magnet is prepared by controlling components of the magnet material and a sintering process and utilizing a gradient heating and heat preservation process; the sintered magnet has more uniform magnet crystal grain distribution, so that the magnetization of the material is more uniform; on the basis, the anticorrosive coating is modified, and the surface of the carboxylated graphene material is modified, so that a silicon element and a long carbon chain structure of an epoxy-terminated group are introduced into the graphene surface, and the corrosion resistance of the coating can be effectively improved by introducing the silicon element; the long carbon chain can effectively relieve the defect that after graphene participates in epoxy resin curing, the coating is high in brittleness and easy to peel off and separate, and the protection function of the coating can be kept for a long time.

This magnetic material is an Sm-Fe-N-based magnetic material having a main phase with a Th2Zn17-type or Th2Ni17-type crystal structure, wherein the main phase has a molar formula (Sm(1-a-b)αaβb)6Fe51N9, where a is 0.01-0.20, and b is 0.01-0.20.