1110 results about "Neodymium" patented technology

The invention discloses a neodymium-iron-boron magnet with double main phases and light rare earth diffusion based on asymmetric cerium distribution and a preparation method, and relates to the technical field of neodymium-iron-boron magnets. The method comprises the steps that a diffusion matrix is prepared through a double-main-phase technology, in the double-main-phase technology, the components of a main-phase alloy and an auxiliary-phase alloy are RaCebFe100-a-b-c-dMcBd, R is PrNd alloy or Nd metal, M is at least one of Cu, Al, Zr, Co and Ga, the content of Ce in the main-phase alloy is larger than that of Ce in the auxiliary-phase alloy, then the upper surface and the lower surface of the diffusion matrix are coated with a diffusion source solution, and the diffusion matrix is obtained through heat treatment. Carrying out heat treatment and aging treatment to obtain a neodymium-iron-boron magnet; the diffusion source solution is formed by mixing a diffusion source and a solvent, and the diffusion source is (PrmNdn) aAlbCucZrdCoeMgf. The neodymium-iron-boron magnet obtained through the method has high residual magnetism and high coercive force at the same time, the diffusion efficiency of the diffusion source is high, and the rare earth utilization rate is increased.

The invention discloses a rare-earth metal arylamine group compound as well as preparation method and application thereof. The invention discloses the rare-earth metal arylamine group compound which is characterized in that a general formula of the rare-earth metal arylamine group compound is (2,6-R12PhNH)5LnLi2(THF)2, wherein Ln is a rear-earth metal selected from one of neodymium, samarium, ytterbium or yttrium; R1 is selected from one of hydrogen, methyl or isopropyl. The rare-earth metal arylamine group compound has the advantages that the rare-earth metal arylamine group compound has a definite structure; raw materials used in the preparation method are simple, easily obtained and cheap; the reaction process is simple and easily operated; the rare-earth metal arylamine group compound product is conveniently purified and the yield of the product is high; the rare-earth metal arylamine group compound has a high activity when acting as a single component catalyst to catalyze a hydrogen phosphine reaction of aldehyde or ketone and phosphite ester; the use amount of the catalyst is less; the yield is high; a substrate has wide universality; a new and simple method is provided for synthesis of a-hydroxyphosphonate.

The invention discloses an yttrium-rich neodymium-iron-boron magnet and a preparation method thereof, and belongs to the technical field of rare earth permanent magnet material preparation. The preparation method comprises the following steps: mixing yttrium-rich neodymium-iron-boron matrix alloy powder with grain boundary doped alloy powder containing Gd and / or Ho, and carrying out compression molding and sintering tempering treatment to obtain a first yttrium-rich neodymium-iron-boron magnet. According to the invention, the grain boundary doped alloy powder containing Gd and / or Ho is added into the yttrium-rich neodymium iron boron matrix alloy powder and then is sintered, so that a continuous and uniform non-magnetic thin-wall grain boundary phase structure is formed in the grain boundary, and the coercive force of the magnet is enhanced. Dy and / or Tb heavy rare earth element grain boundary diffusion is carried out based on the first yttrium-rich neodymium-iron-boron magnet after grain boundary modification, a second yttrium-rich neodymium-iron-boron magnet is obtained, the diffusion depth of Dy and / or Tb in the magnet can be increased, the utilization rate can be increased, the cost can be reduced, the coercivity of the magnet can be improved, and the adverse effect of Dy and / or Tb on residual magnetism can be reduced.

The invention discloses sintered neodymium-iron-boron magnet grinding machining equipment, and relates to the technical field of neodymium-iron-boron magnet machining, the sintered neodymium-iron-boron magnet grinding machining equipment comprises a machining table, the machining table is provided with a grinding assembly, a clamping assembly, a steering adjusting assembly and a cooling assembly, and the clamping assembly is used for clamping a magnet body; the grinding assembly is used for achieving grinding machining of a magnet body, the steering adjusting assembly is used for achieving rotation of the magnet body and achieving multi-directional machining of the magnet body in a matched mode, and the cooling assembly is used for cooling treatment when the magnet body is machined, so that machining is more stable. A plurality of through grooves are formed in the machining table, and a waste collecting assembly is arranged in the machining table and used for collecting machined waste. The problems that in the prior art, a grinding mechanism is directly driven by a feeding mechanism to conduct grinding, the microstructure of a magnet is easily damaged, and the magnetic performance is reduced are solved.

The present application provides an entropy-regulated composite dielectric film, which comprises a polymer matrix; and fillers dispersed in the polymer matrix, wherein the fillers comprise Bi 4‑a M 1a Ti (3‑3b) M 2b O 12 , wherein M1 comprises at least one of lanthanum, neodymium, samarium and praseodymium, M2 comprises at least one of zirconium, hafnium and tin, 0 The entropy-regulated composite dielectric film has high temperature resistance, high breakdown strength, high polarization strength, high energy storage density and good stability.

Embodiments of the present disclosure include a tacklebox, including a base, a first wall, a second wall, a third wall, and a fourth wall, each of the walls having a bottom end attached to or otherwise affixed to a perimeter of the base and upstanding therefrom. Embodiments may also include a lid connected with a top of the third wall via a hinged connection. The first wall, the second wall, the third wall, and the fourth may have a plurality of magnetics disposed about each wall face. The magnets may be neodymium.

The invention discloses a low-temperature-resistant organic silicon elastic damping body and a preparation method thereof, and belongs to the field of synthesis of organic polymer materials. The invention relates to a high-efficiency photoinitiator, which is prepared from the following ingredients in parts by weight: 95 to 110 parts of fluorosiloxane-phenylsiloxane segmented copolymers, 25 to 35 parts of boric acid ester end-capped polyurethane prepolymers, 10 to 15 parts of neodymium-containing metal organic frameworks, 20 to 40 parts of azobenzene modified CNT / TiO2, 2 to 4 parts of photoinitiators 1173 and 2 to 3 parts of neodymium acetylacetonate. Ultralow-temperature adaptability, self-repairing and high-modulus coexistence and wide-temperature-range damping stability are achieved through fluorosilicone / phenyl block copolymer molecular design, a borate-neodymium coordination double-dynamic network, stress response filler and a light-heat gradient curing process. The low-temperature-resistant organic silicon elastic damping body prepared by the invention provides a new solution idea for an extreme environment damping material, and has a wide application prospect.

The invention discloses a high-temperature-resistant high-performance neodymium-iron-boron permanent magnet material and a preparation method thereof, and belongs to the technical field of neodymium-iron-boron permanent magnet materials. The material is prepared from neodymium iron boron magnetic powder, auxiliary metal, hyperbranched polyimide polymer modified nano zirconium oxide and a silane coupling agent through mixing, smelting, crushing, sintering, tempering, coating and curing. The hyperbranched polyimide polymer modified nano-zirconia is introduced into the components, so that the permanent magnet material has excellent thermal stability, the permanent magnet material can still keep stable magnetic performance and mechanical performance at high temperature, the attenuation resistance is good, the thermal demagnetization is low, and the interface bonding strength is improved after the nano-zirconia is modified by hyperbranched polyimide. The interfacial compatibility between the nano zirconium oxide and the polyimide is enhanced through click chemical reaction, and the interfacial bonding strength of the nano zirconium oxide on a neodymium iron boron matrix is improved. The three-dimensional branched structure of the hyperbranched polyimide can form physical crosslinking points in the material, so that the mechanical strength of the material is enhanced.

The invention discloses a method for improving performance of rare earth permanent magnet sintered neodymium iron boron grain boundary diffusion, and belongs to the technical field of rare earth permanent magnet materials. The method comprises the steps that a low-melting-point metal layer and a diffusion layer containing heavy rare earth elements are sequentially formed on the surface of a clean sintered neodymium-iron-boron magnet, and then vacuum diffusion heat treatment and tempering treatment are conducted. Wherein the low-melting-point metal layer comprises at least one of copper, aluminum, gallium and tin or an alloy of the copper, the aluminum, the gallium and the tin; the heavy rare earth element comprises at least one of dysprosium, terbium, holmium and gadolinium. The low-melting-point metal layer is preferentially diffused and wets the grain boundary in the heat treatment process, heavy rare earth elements are promoted to be deeply and uniformly diffused towards the interior of the magnet along the grain boundary, so that a heavy rare earth-rich shell layer is formed outside main phase grains of the magnet, and the intrinsic coercive force is improved; meanwhile, the low-melting-point metal forms a strengthening phase at the grain boundary, the brittleness of the magnet after diffusion is improved, the surface corrosion phenomenon is restrained, and collaborative optimization of the comprehensive performance of the magnet is achieved.

The invention provides an anodic oxidation passivation method of a neodymium-iron-boron permanent magnet zinc coating, which comprises the following steps of: performing electrochemical anodic oxidation by taking a neodymium-iron-boron permanent magnet with a zinc coating on the surface as an anode, a Pt sheet as a cathode and a passivation solution as an electrolyte, forming a passivation layer on the surface of the neodymium-iron-boron permanent magnet with the zinc coating on the surface, and cleaning and drying to obtain the neodymium-iron-boron permanent magnet with the zinc coating on the surface. A chromium-free passivation film is formed on the neodymium-iron-boron permanent magnet zinc coating, and passivation of the neodymium-iron-boron permanent magnet zinc coating is completed; the passivation solution is prepared from 10 g / L to 20 g / L of molybdate, 10 g / L to 15 g / L of ammonium fluozirconate, 1 g / L to 10 g / L of etidronic acid, 1 g / L to 10 g / L of sodium dihydrogen phosphate, 1 g / L to 10 g / L of nitric acid, 1 g / L to 10 g / L of phosphoric acid and the balance distilled water. According to the method disclosed by the invention, a complete, uniform and compact passivation film is formed on the surface of the zinc coating after passivation, the corrosion potential is improved while the corrosion current is effectively reduced, and the time for generating a rust spot in a salt spray test exceeds 72 hours.

The invention discloses a production method of a sintered neodymium-iron-boron spliced magnet. The method comprises the following steps: processing a magnet to a predetermined size, cleaning and drying; dissolving solid epoxy resin, a solid latent curing agent and an accelerant by using an organic solvent to prepare an impregnating adhesive; gluing the two sides of the glass fiber cloth, and fully volatilizing a solvent to obtain pre-impregnated glass fiber cloth; after being cut, the magnetic blocks are inserted between the to-be-spliced magnets; and after being clamped by a clamp, the insulating adhesive layer is heated and cured to form a compact and pore-free insulating adhesive layer. According to the invention, air holes of the adhesive layer are thoroughly eliminated through a prepreg process, the formed insulating adhesive layer has excellent dielectric strength and insulativity, adjacent magnets can be effectively isolated, an eddy current channel can be effectively cut off, the eddy current heating problem in high-frequency application is remarkably reduced, and meanwhile, high strength and high reliability of the spliced magnet are ensured. The method is particularly suitable for the fields of motors and the like needing to reduce eddy-current loss.

The invention discloses an acid, alkali and salt corrosion resistant high-coercivity grain boundary diffusion neodymium-iron-boron magnet and a preparation method thereof, and the preparation method comprises the following steps: (1) selecting a sintered neodymium-iron-boron magnet as a base material, slicing the magnet, polishing the surface, and ultrasonically cleaning a coating surface; (2) preparing slurry by using absolute ethyl alcohol and PVB (Polyvinyl Butyral) glue by taking the heavy rare earth alloy as a diffusion source; uniformly coating a magnet with the slurry, and drying to obtain a magnet to be subjected to diffusion heat treatment; (3) performing diffusion heat treatment on the magnet to be subjected to diffusion heat treatment under a vacuum condition to obtain a grain boundary diffusion magnet; and (4) plating a layer of compact high-potential metal on the surface layer of the magnet by magnetron sputtering to prepare the high-coercivity grain boundary diffusion neodymium-iron-boron magnet with acid, alkali and salt corrosion resistance. According to the method, the coercive force of the magnet is remarkably improved, the influence on the residual magnetism of the magnet is small, and meanwhile, the negative influence on the corrosion resistance of the magnet after grain boundary diffusion is avoided; the prepared magnet has good acid, alkali and salt corrosion resistance.

The invention provides a neodymium iron boron melt-spinning cooling device based on a double-sided forced cooling device and a refining method. The neodymium iron boron melt-spinning cooling device comprises a copper wheel cooling unit, a liquid argon forced cooling unit, a drum-type cooler and a crusher. Carrying out melt-spinning forming on the neodymium-iron-boron melt through a high-speed rotating copper wheel, and realizing primary cooling through a sticking roller surface; a liquid argon nozzle array is arranged above the free surface of the melt-spinning sheet, liquid argon is sprayed at an angle of 30-60 degrees, and secondary forced cooling is formed; and then entering a drum-type cooler for heat conduction cooling, and finally treating by a crusher. According to the device, a double-face cooling system of the roller pasting face and the free face is constructed, the cooling efficiency is effectively improved, the grain size is refined, the heavy rare earth adding amount is reduced, and the device is suitable for preparing the high-performance neodymium-iron-boron magnet.

The hydrogen transmission pipeline steel comprises the following chemical components in percentage by mass: 0.020%-0.045% of C, 0.11%-0.19% of Si, 1.45%-1.65% of Mn, less than or equal to 0.0010% of S, less than or equal to 0.008% of P, 0.015%-0.045% of Al, 0.040%-0.060% of Nb, 0.020%-0.035% of Ti, 0.30%-0.50% of Cr, 0.0040%-0.0080% of RE, less than or equal to 0.004% of N, less than or equal to 0.0015% of O, less than or equal to 0.0001% of H and the balance of Fe and other inevitable impurities, the conditions that the carbon equivalent Ceq = C + Mn / 6 + (Cr) / 5 is less than or equal to 0.35%, the Nb / Ti = the rare earth element is selected from at least one of lanthanum, cerium and neodymium. The invention aims to solve the technical problems that the existing hydrogen transmission pipeline steel is easy to generate hydrogen embrittlement, short in fatigue life and high in production cost in a high-pressure hydrogen environment, and meets the core requirements of hydrogen energy long-distance transmission pipeline engineering on high strength, high hydrogen embrittlement resistance, high fatigue performance and low cost of materials.

The invention discloses a high-magnetic-performance neodymium-iron-boron magnet and a preparation method thereof, and belongs to the technical field of magnetic materials. The technical problem that an existing magnet is low in magnetic performance is solved. The invention provides a preparation method of a high-magnetic-performance neodymium-iron-boron magnet. The preparation method comprises the following steps: S1, preparing neodymium-iron-boron powder A and neodymium-iron-boron powder B by adopting a vacuum melting method; s2, carrying out powder mixing and orientation compression treatment; s21, powder mixing treatment, wherein the neodymium-iron-boron powder A and the neodymium-iron-boron powder B are mixed, and evenly-mixed neodymium-iron-boron powder is obtained; s22, orientation treatment, wherein the evenly-mixed neodymium iron boron powder is placed in a magnetic field with the magnetic field intensity larger than 2.0 T to be subjected to orientation forming, and a neodymium iron boron blank is obtained; and S3, carrying out sintering treatment and two-stage aging treatment on the prepared neodymium-iron-boron blank to finally obtain the neodymium-iron-boron magnet with high magnetic performance. The residual magnetism of the neodymium-iron-boron magnet prepared by the method disclosed by the invention is 14.21 kGs or above.

The present invention provides a calcium-based thermochemical heat storage material modified with high-entropy fluorite oxide and a preparation method thereof. The material comprises a calcium-based material and a high-entropy fluorite oxide, with the calcium-based material accounting for 70-85% by mass. The calcium-based material is calcium oxide, and the high-entropy fluorite oxide is a fluorite-structured oxide formed by zirconium, cerium, lanthanum, neodymium, and ytterbium, with a molar ratio of 1:1:1:1:1 for the oxides of zirconium, cerium, lanthanum, neodymium, and ytterbium. The invention utilizes the high-entropy fluorite oxide as an anti-sintering component to disperse calcium oxide and prevent its sintering, while simultaneously promoting the adsorption, dissociation, and migration of CO2 on the surface of the material, thereby enhancing the cycling stability and energy density of the heat storage material.

The invention discloses a neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet and a preparation method thereof, and relates to the technical field of neodymium-iron-boron magnet preparation, and the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet comprises the following preparation raw materials: 170-175 kg of PrNd (praseodymium-neodymium alloy), 25-30 kg of BFe (iron white copper), 1-5 kg of Co (cobalt), 0.1-2 kg of Cu (copper), 1-5 kg of Zr (zirconium), 0.1-1 kg of Ga (gallium) and 380-420 kg of Fe (iron). According to the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet and the preparation method thereof, the 54H sintered neodymium-iron-boron magnet is prepared through a double-alloy technology with neodymium, iron and gallium as auxiliary alloy without adding dysprosium, terbium and other scarce type heavy rare earth elements, and performance optimization and cost optimization of the neodymium-iron-gallium double-alloy heavy-rare-earth-free 54H sintered neodymium-iron-boron magnet are achieved.

The invention provides a grain boundary diffusion neodymium iron boron magnet and a preparation method thereof, and relates to the technical field of magnetic materials. The preparation method comprises the steps of surface pretreatment and purification, precise diffusion source construction through magnetron sputtering and diffusion promotion through vacuum heat treatment. The core function of pretreatment is to remove surface impurities and lay a foundation for subsequent deposition of alloy films; the proportion of Tb, Al and Cu in a diffusion source is accurately regulated and controlled in the magnetron sputtering stage, and the synergistic effect is achieved; and the vacuum heat treatment promotes Tb to diffuse into the neodymium iron boron. According to the method, a technical closed loop with pretreatment as a basis, a diffusion source as a core and heat treatment as power is formed, the microstructure of the neodymium-iron-boron magnet is optimized, a complete and continuous shell structure with the moderate thickness is formed, the diffusion depth of heavy rare earth is greatly increased, and the service life of the neodymium-iron-boron magnet is prolonged. Finally, the coercive force of the neodymium-iron-boron magnet is remarkably improved, and the utilization rate of heavy rare earth elements is effectively improved. The problem of low Tb utilization rate in the prior art is solved, and the bottleneck of coercive force improvement is broken through.

The invention relates to the technical field of slurry mixing, and discloses a sintered neodymium-iron-boron grain boundary diffusion slurry mixing mechanism and an automatic dip-coating mechanism, the sintered neodymium-iron-boron grain boundary diffusion slurry mixing mechanism comprises a rack, the lower layer of the rack is connected with a bottom plate, the bottom plate is provided with a machine base, and the machine base is provided with a material supplementing barrel; a first discharging pipe is mounted on the lower side wall of the material supplementing barrel, and a valve is mounted on the first discharging pipe; the first discharge pipe is used for conveying slurry to the immersion barrel; an immersion barrel is mounted on the bottom plate; a first bearing plate is mounted on the top surface of the rack, two first bearing seats are mounted on the first bearing plate, and stirring rods are rotationally connected to the first bearing seats; the stirring rod is connected with a first motor through a worm and gear mechanism; a stirring paddle is mounted at the lower end of the stirring rod; automatic and precise dip-coating is achieved, the solvent volatilization influence is reduced, the service life of equipment is prolonged, and the magnet diffusion effect and the product quality stability are guaranteed.

Disclosed in the present invention are a neodymium-iron-boron magnet, a manufacturing method therefor, and the use thereof. In the neodymium-iron-boron magnet, a first easy-demagnetization zone, a second easy-demagnetization zone, a third easy-demagnetization zone and a fourth easy-demagnetization zone have the same heavy-rare-earth content; a first transition zone, a second transition zone, a third transition zone and a fourth transition zone have the same heavy-rare-earth content; the content ratio of Tb in a non-easy demagnetization zone to that in the first easy-demagnetization zone is (0-0.9):1; the content ratio of Dy in the first easy-demagnetization zone to that in the non-easy demagnetization zone is (0-0.9):1; the content ratio of Tb in the first transition zone to that in the first easy-demagnetization zone is (0.8-1):1. The neodymium-iron-boron magnet of the present invention can reduce the attenuation of a surface magnetic field strength and magnetic flux of the neodymium-iron-boron magnet while ensuring remanence, and has good anti-demagnetization performance.

The invention relates to the technical field of rare earth permanent magnet materials, in particular to a grain boundary diffusion magnet based on a hard magnetic 6: 14 phase and a preparation method of the grain boundary diffusion magnet. Preparing a diffusion source, and loading the diffusion source on the surface of the matrix magnet; carrying out heat preservation diffusion under the environment pressure of which the vacuum degree is less than or equal to 10 <-2 > Pa; and carrying out aging treatment to obtain the grain boundary diffusion magnet based on the hard magnetic 6: 14 phase. The grain boundary phase of the prepared grain boundary diffusion magnet based on the hard magnetism 6: 14 phase is mainly the continuous 6: 14 phase, the hard magnetism is presented, the coercive force is improved, meanwhile, the residual magnetism is prevented from being reduced, the problems that the coercive force of an existing neodymium-iron-boron magnet is improved in a limited mode, and the residual magnetism cannot be prevented from being reduced are solved, and the service life of the neodymium-iron-boron magnet is prolonged. The invention provides a low-cost high-comprehensive-magnetic-performance grain boundary diffusion magnet preparation method.

This application provides a large-size NdFeB magnet and its preparation method. The preparation method includes: mixing a main alloy powder and an auxiliary alloy powder in a ratio of 10:(1-3) to obtain a mixed alloy powder; molding the mixed alloy powder and then isostatically pressing it to obtain a green blank; sintering the green blank using a multi-stage heating method to obtain a sintered magnet; wherein the multi-stage heating includes: heating to 1000-1100℃ at at least three gradually decreasing heating rates and holding at that temperature for 1-6 hours; and cooling the sintered magnet to obtain a NdFeB magnet. This application, through a dual alloying process and gradually reducing the heating rate during sintering, can effectively suppress cracking of the magnet during sintering and obtain a large-size magnet with excellent magnetic properties.

This invention discloses a corrosion-resistant aluminum-based multilayer coating on the surface of a sintered NdFeB magnet and its preparation method, comprising: pretreatment of the magnet; preparation of the aluminum coating: in the presence of an inert gas, after adjusting the pressure of the environment to a first preset value, depositing an aluminum coating on the pretreated sintered NdFeB magnet; preparation of the aluminum-based barrier coating: in the presence of a reactive gas, after adjusting the pressure of the environment to a second preset value, exciting the reactive gas into a high-density plasma, generating an aluminum-based barrier layer on the surface of the sintered NdFeB magnet with the deposited aluminum coating; repeating steps S200 and S300, followed by cooling, to complete the preparation of the corrosion-resistant aluminum-based multilayer coating on the surface of the sintered NdFeB magnet. This invention does not involve reactive sputtering, effectively avoiding the "palladium poisoning" phenomenon during the deposition process, and the prepared multilayer coating has excellent corrosion resistance.

The invention provides a treatment method for synergistically enhancing the comprehensive performance of a neodymium-iron-boron magnet, and belongs to the technical field of magnetic materials. According to the method, a heavy rare earth layer and a corrosion-resistant metal layer such as copper, nickel and cobalt for promoting grain boundary diffusion of heavy rare earth are respectively deposited on the surface of the neodymium-iron-boron magnet by adopting a multi-layer electroplating method, the coercivity of the neodymium-iron-boron magnet is enhanced through grain boundary diffusion, and the corrosion resistance of the magnet is enhanced through a nickel-cobalt coating. The treatment method comprises the following steps: carrying out electrochemical deposition on the neodymium-iron-boron magnet in a heavy rare earth metal plating solution, and then respectively electroplating a copper plating layer and a nickel-cobalt plating layer to obtain a heavy rare earth-containing plating layer with strong corrosion resistance and good plating film binding force; the neodymium-iron-boron magnet containing the heavy rare earth coating is subjected to heat treatment, and the coercive force of the magnet is improved through heavy rare earth grain boundary diffusion. The neodymium iron boron grain boundary diffusion process and the surface corrosion prevention process are subjected to integrated treatment, the technological process of high-performance neodymium iron boron industrial preparation is shortened, and the coercive force and the corrosion resistance of the magnet are comprehensively enhanced.

The invention discloses a cerium-zirconium-based high-entropy oxide as well as a preparation method and application thereof. According to the cerium-zirconium-based high-entropy oxide, cerium and zirconium serve as main bodies, and meanwhile rare earth elements (lanthanum, praseodymium, neodymium and samarium) and transition metal elements (manganese, iron, cobalt, nickel, copper and zinc) are introduced to form a high-entropy solid solution with the equal molar ratio and containing 3-8 kinds of metal. In the cerium-zirconium-based high-entropy oxide, the cerium element and the zirconium element respectively account for 20%-40% of the total amount, and the other elements are respectively 10%-30% in an equimolar ratio. The cerium-zirconium-based high-entropy oxide catalyst prepared by the invention has excellent oxygen storage and release capacity and CO oxidation capacity, and the CO complete conversion temperature is 181 DEG C. The method adopts a simple coprecipitation process, is mild in condition and low in cost, and is suitable for large-scale application in the field of tail gas purification.

The present application relates to the technical field of sintered Nd-Fe-B magnet preparation technology, and particularly relates to a sintered Nd-Fe-B pressure-assisted enhanced grain boundary diffusion method and a magnet thereof, which comprises the following steps: S1, after sintering, the Nd-Fe-B magnet is pre-aged at low temperature and cooled to room temperature; S2, the pre-aged magnet is sliced, diffusion pre-processed, coated with a rare earth diffusion source, pressure-combined with a non-rare earth diffusion source, and diffusion heat treated; the composition of a sintered Nd-Fe-B magnet substrate is RE x M y B z Fe 100‑x‑y‑z , wherein RE comprises at least two elements in Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu; the method increases the strength and toughness of the magnetic steel and reduces the rate of missing corners, meanwhile, pre-aging increases the grain boundary phase width, provides a channel for diffusion, improves the diffusion effect, improves the temperature coefficient of the product, and makes the diffusion source, especially the sprayed or printed diffusion source, better combined with the substrate.

The invention relates to the field of artificial intelligence, and discloses an artificial intelligence assisted neodymium-iron-boron magnet defect detection system which comprises the following steps: acquiring a magnet image and preprocessing process parameters; extracting texture enhancement features through multi-scale texture perception; adaptively generating or adjusting a defect detection model based on the process parameters; and carrying out defect classification positioning, discrimination and optimization. The system comprises an image acquisition module, a process parameter acquisition module, an image preprocessing module, a multi-scale texture perception feature extraction module, an adaptive model generation and selection module, a defect detection module, a discrimination output module and a model optimization module. Defects and background textures can be effectively distinguished, the false detection rate is greatly reduced, the robustness, universality, detection precision and stability of the system are improved, automation and intelligence are achieved, and efficiency and quality consistency are improved.

The invention relates to the technical field of neodymium-iron-boron magnet gluing, in particular to automatic neodymium-iron-boron magnet stacking and gluing integrated equipment which comprises a rack, a support, a first electric guide rail, a second electric guide rail, a frame and the like. A second electric guide rail is installed on a sliding block of the first electric guide rail, and a frame body is connected to a sliding block of the second electric guide rail. Cylindrical magnets can be fed into the material guide rail through the disc vibration feeder, the cylindrical magnets move into the containing block along the material guide rail to be stacked, glue can be sprayed to the cylindrical magnets through the electric glue head, the cylindrical magnets are glued, the two steps of stacking and gluing can be completed through one piece of equipment, the investment cost can be reduced, and the production efficiency is improved. Meanwhile, the production period can be shortened, and the overall machining efficiency is improved.

The utility model relates to a polishing device for processing a neodymium-iron-boron magnet cylinder, which comprises a supporting device, a polishing device, a polishing device, a polishing device, a polishing device, a polishing device and a polishing device, and is characterized in that the supporting device is mounted in the center of the top of a rack; the polishing assemblies are mounted on the front side and the rear side of the rack and used for polishing the neodymium-iron-boron magnet cylinder; the clamping assemblies are arranged on the left side and the right side of the rack and used for centering the neodymium-iron-boron magnet cylinder and enabling the neodymium-iron-boron magnet cylinder to rotate; the clamping assembly is provided with a chamfering assembly used for chamfering the two end faces of the neodymium-iron-boron magnet cylinder, the chamfering assembly comprises a tool base and a chamfering tool capable of rotating and making contact with the end faces of the neodymium-iron-boron magnet cylinder, and the chamfering tool is detachably arranged on the tool base. According to the chamfering device, the chamfering assembly is arranged and comprises the tool base capable of adjusting the angle of the chamfering tool, the angle of the chamfering tool can be adjusted only by rotating the tool base, and then chamfers of different angles can be machined.

The invention relates to the technical field of neodymium-iron-boron magnet production, in particular to a sintered neodymium-iron-boron magnet for preparing lanthanum-cerium-yttrium and a method of the sintered neodymium-iron-boron magnet. In the invention, the cerium element is used for replacing a praseodymium-neodymium alloy, meanwhile, the lanthanum and yttrium elements are introduced according to the proportion to generate a synergistic effect to regulate and control the structure of the high-cerium-content sintered neodymium-iron-boron magnet, the yttrium element is used for inhibiting main phase grain coarsening and improving the coercive force, and the lanthanum and yttrium elements can promote the flow of a rare earth-rich liquid phase in the sintering process and improve the diffusivity, so that the high-cerium-content sintered neodymium-iron-boron magnet is obtained. The density is improved.