Rare earth aluminum alloy, and method and device for preparing same

An aluminum alloy and rare earth metal technology, applied in the field of rare earth aluminum alloy and its preparation, can solve the problems of high production cost and risk, difficulty in controlling rare earth content, low rare earth content, etc., so as to reduce the consumption of auxiliary materials, improve the metal yield and Current efficiency and product quality, the effect of stable product quality

Active Publication Date: 2010-06-09
GRIREM ADVANCED MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0015] We collectively refer to the above methods as industrial aluminum electrolysis, that is, in the process of aluminum electrolysis, rare earth compounds or rare earth metals are directly added to prepare aluminum rare earth master alloys, but this type of method has the following problems: 1) Only rare earths with low rare earth content can be prepared Aluminum alloy; 2) As we all know, a 300KA electrolytic cell has nearly 30 tons of molten alu...

Method used

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  • Rare earth aluminum alloy, and method and device for preparing same
  • Rare earth aluminum alloy, and method and device for preparing same
  • Rare earth aluminum alloy, and method and device for preparing same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Φ450mm circular graphite electrolytic cell is used, the anode is composed of 4 graphite plates, the tungsten cathode is Φ55mm, and the electrolyte ratio is YF 3 : nNaF AlF 3 : LiF=80:15:5, n=3, the proportion of raw materials added is Y 2 o 3 : Al 2 o 3 =86:14, the electrolysis temperature is 1000-1050°C, the current intensity is 2400A, and the anode current density is 0.5-0.8A / cm 2 , the cathode current density is 5~6A / cm 2 , electrolysis time 1 hour, the mixture addition is 2.5Kg, obtains alloy 2.05Kg, yttrium content 89.2% in the alloy, current efficiency is 74.5%, metal yttrium yield 90.1%, alloy composition is shown in Table 1.

[0049] Table 1 Alloy Composition Analysis Results / %

[0050]

Embodiment 2

[0052] Φ450mm circular graphite electrolytic cell is used, the anode is composed of 6 graphite plates, the tungsten cathode is Φ30mm, and the electrolyte ratio is YF 3 : nNaF AlF 3 : LiF=90:5:5, n=2.5, the proportion of raw materials added is Y 2 o 3 : Al 2 o 3 =94:6, the electrolysis temperature is 1050-1100°C, the current intensity is 2800A, and the anode current density is 1-1.5A / cm 2 , the cathode current density is 9~10A / cm 2 , electrolysis time 1 hour, the mixture addition is 3.1Kg, obtains alloy 2.2Kg, yttrium content 96.3% in the alloy, current efficiency is 74.2%, metal yttrium yield 92.4%, alloy composition is shown in Table 2.

[0053] Table 2 Alloy Composition Analysis Results / %

[0054]

Embodiment 3

[0056] Φ450mm circular graphite electrolytic cell is used, the anode is composed of 4 graphite plates, the tungsten cathode is Φ45mm, and the electrolyte ratio is ScF 3 : nNaF AlF 3 : LiF=70:20:10, n=2.5, the ratio of raw materials added is Sc 2 o 3 : Al 2 o 3 =89:11, the electrolysis temperature is 1000-1050°C, the current intensity is 2300A, and the anode current density is 0.8-1A / cm 2 , the cathode current density is 6~7A / cm 2 , electrolysis time 1 hour, the mixture addition is 1.55Kg, obtains alloy 0.92Kg, scandium content 93.8% in the alloy, current efficiency is 72%, metal scandium yield 95.9%, alloy composition is shown in Table 3.

[0057] Table 2 Alloy Composition Analysis Results / %

[0058]

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Abstract

The invention discloses a rare earth aluminum alloy, and a method and a device for preparing the same. The alloy contains at least one rare earth metal of lanthanum, cerium, praseodymium, neodymium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, lutetium, scandium and yttrium, the content of raw earth is 5 to 98 weight percent, and the balance is aluminum and inevitable impurities. The device for preparing the rare earth aluminum alloy is characterized in that: a) graphite serves as an electrolysis bath, a graphite plate is an anode, a tungsten bar is a cathode and a molybdenum crucible serves as a rare earth aluminum alloy receiver; b) the diameter of the tungsten bar is 30 to 55 mm; and c) the anode of the graphite consists of a plurality of graphite plates. The rare earth aluminum alloy, and the method and the device for preparing the same have the advantages that: the alloy has uniform components, little segregation and low impurity content; technology for preparing the rare earth aluminum alloy through fusion electrolysis can maximally replace a process for preparing single medium-heavy metal through metallothermic reduction, greatly reduce energy consumption and the emission of fluorine-containing tail gas and solid waste residue, improve current efficiency and metal yield and reduce the consumption of auxiliary materials and the energy consumption; and the rare earth aluminum alloys with different rare earth contents can be obtained by controlling different electrolytic temperatures and different cathode current densities.

Description

technical field [0001] The invention relates to the field of rare earth alloy materials, and belongs to rare earth pyrometallurgy, in particular to a rare earth aluminum alloy and its preparation method and device Background technique [0002] At present, aluminum and aluminum alloys are the second largest metal structural materials after steel, and are widely used in construction, energy, transportation, aerospace and other fields. The application and research of rare earth in aluminum and aluminum alloy materials has also been developed rapidly. Various rare earth aluminum alloys such as high-strength rare earth aluminum alloy wire (Al-Mg-Si-RE), heat-resistant rare earth aluminum alloy wire (Al- Zr-RE), building aluminum alloys (Al-Mg-Si-Fe-RE), high-strength aluminum alloys (Al-Zn-Mg-RE, Al-Si-Cu-RE), etc. have been widely used. Rare earth aluminum alloys that are widely used in high-tech materials include Y-Al alloys, Sc-Al alloys, Er-Al alloys, and Nd-Al alloys. [0...

Claims

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Application Information

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IPC IPC(8): C22C21/00C22C28/00C25C3/06C25C3/34
Inventor 颜世宏李宗安李红卫庞思明于敦波赵斌王志强周林陈博雨栾文洲徐立海贺圣王祥生
Owner GRIREM ADVANCED MATERIALS CO LTD
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