1099 results about "Lanthanum" patented technology

The invention relates to the technical field of adsorbents, and particularly discloses an aluminum oxide type adsorbent and a preparation method thereof.The preparation method comprises the following steps that lanthanum salt, cerium salt and a polyethylene glycol aqueous solution are mixed to be uniform, then the mixture is mixed with gamma-Al2O3 to be uniform, pH is adjusted, standing is conducted, solid-liquid separation is conducted, drying and roasting are conducted, and a double-doped carrier is obtained; dispersing the double-doped carrier in a mixed solution containing 2-methylimidazole, ferric salt and zinc salt, adjusting the pH value, carrying out heating reaction, solid-liquid separation and drying in an inert atmosphere, grinding to obtain powder, and carrying out molding treatment on the powder to obtain a composite carrier; uniformly mixing the Ag modified molecular sieve with silica sol, coating the surface of the composite carrier with the mixture, and drying to obtain an adsorbent precursor; dipping an adsorbent precursor in the dispersion liquid, and after dipping, solid-liquid separation and drying, reactivating to obtain the aluminum oxide type adsorbent; the prepared adsorbent can synergistically and efficiently remove multiple impurities and is excellent in corrosion resistance.

The invention relates to the field of anticorrosive paint, in particular to anticorrosive paint containing lanthanum cerium oxide and a preparation method of the anticorrosive paint. The invention relates to an anticorrosive coating containing lanthanum cerium oxide. The anticorrosive coating is prepared from the following raw materials: 28 to 45 parts of ultraviolet stable composite film forming matter, 5 to 10 parts of composite rare earth filler, 6 to 12 parts of supported synergistic antirust agent, 18 to 30 parts of mixed solvent, 0.8 to 2.5 parts of dispersing agent, 2.7 to 5.3 parts of functional additive and 0.5 to 1.2 parts of nano montmorillonite, the composite rare earth filler is lanthanum cerium oxide-hydroxyapatite composite powder with a core-shell structure, wherein lanthanum cerium oxide is used as a core, hydroxyapatite is used as a shell, and the thickness of the shell layer is 10-20 nm; the ultraviolet stable composite film forming substance comprises epoxy resin and ultraviolet grafting modified polyurethane in a weight ratio of 1: (0.6-2.2); the supported synergistic antirust agent is a mixture of mesoporous silica supported benzotriazole and zinc molybdate. And the obtained coating is high in adhesive force and long in service life.

The invention provides an anti-ferroelectric lanthanum ferrite, bismuth ferrite and strontium titanate superlattice film with high energy storage density as well as a preparation method and application thereof. The anti-ferroelectric lanthanum ferrite, bismuth ferrite and strontium titanate superlattice film with high energy storage density comprises a substrate layer, a bottom electrode layer and a plurality of stacked relaxation ferroelectric layers, wherein the bottom electrode layer and the multiple stacked relaxation ferroelectric layers are sequentially arranged on the substrate layer; each relaxor ferroelectric layer sequentially comprises a first functional layer, a second functional layer and a third functional layer from bottom to top; the first functional layer comprises LaFeO3, the second functional layer comprises BiFeO3, and the third functional layer comprises SrTiO3. The anti-ferroelectric lanthanum ferrite, bismuth ferrite and strontium titanate superlattice thin film with the high energy storage density has small electric leakage performance and high polarization value, and more excellent energy storage performance is achieved.

The invention provides a rare earth heat insulation coating and a preparation method thereof. The coating comprises the following components in parts by weight: 50-60 parts of acrylic resin, 10-15 parts of polyurethane modified epoxy resin, 5-8 parts of nano rare earth powder, 3-5 parts of filler, 0.5-1 part of a coalescing agent, 1-2 parts of a defoaming agent, 1-3 parts of a dispersing agent, 0.5-1 part of an ultraviolet light absorber and 1-2 parts of a silane coupling agent. Wherein the nano rare earth powder comprises lanthanum oxide powder, cerium chloride powder and yttrium hexaboride powder, and the filler comprises nano hollow microspheres, nano calcium carbonate and nano aluminum silicate. The rare earth heat insulation coating has excellent heat insulation effect and mechanical property, and can be applied to various scenes.

The invention relates to a composite diaphragm with high ionic conductivity, a composite solid electrolyte and a preparation method thereof. The composite diaphragm is composed of a lithium lanthanum-based fluorine-doped solid electrolyte LLMOF and a base membrane, the chemical general formula of the LLMOF is Li < x > La < y > M < 1 > < z > M < 2 > < w > M < 3 > O < 6 > F, wherein M1 is a tetravalent cation, M2 is a pentavalent cation, and M3 is a hexavalent cation; 1 < x + 3y < 5, 0 < x < = 2, and 1 / 3 < y < 5 / 3; 0 < = z < = 2, 0 < = w < = 2, 0 < = u < = 2, z + w + u = 2; the base membrane is a large-aperture base membrane, and the aperture r is more than or equal to 200nm and less than or equal to 1mu m; the particle size D50 of the LLMOF is 50 nm to 1 [mu] m, and the particle size D50 of the LLMOF is less than or equal to the aperture r of the base film. According to the composite diaphragm disclosed by the invention, the LLMOF solid electrolyte with an ion channel function is introduced, so that efficient conduction of ions is realized; the particle size is matched with that of a large-aperture base membrane, the membrane can be uniformly embedded into membrane holes, a continuous conduction path is constructed, and the ionic conductivity is improved; meanwhile, the composite diaphragm has excellent thermal stability and interface wettability, interface impedance is effectively reduced, and growth of lithium dendrites is inhibited.

The present application provides an entropy-regulated composite dielectric film, which comprises a polymer matrix; and fillers dispersed in the polymer matrix, wherein the fillers comprise Bi 4‑a M 1a Ti (3‑3b) M 2b O 12 , wherein M1 comprises at least one of lanthanum, neodymium, samarium and praseodymium, M2 comprises at least one of zirconium, hafnium and tin, 0 The entropy-regulated composite dielectric film has high temperature resistance, high breakdown strength, high polarization strength, high energy storage density and good stability.

The invention discloses a blue-and-white glaze and a preparation method and application thereof, and belongs to the technical field of inorganic non-metallic materials (ceramics), the blue-and-white glaze comprises quartz, feldspar, limestone, plant ash and other basic raw materials, zinc oxide, aluminum oxide, lanthanum oxide, cerium oxide and other rare earth elements, and a modified organic additive is introduced. Compared with the prior art, the blue-and-white glaze shows excellent stability in the drying and firing process, the phenomena of cracking and glaze stripping are effectively reduced, the friction coefficient after firing is low, the breaking strength and the breaking modulus are high, the glossiness and transparency of a glaze surface are remarkably improved, and the blue-and-white glaze has important application value.

The invention provides a low-cost high-specific-surface-area cerium-aluminum composite oxide, a preparation method and application thereof, and relates to the technical field of catalysts, the preparation method comprises the following steps: step S1, adding 10-40% of cerium salt, 50-90% of aluminum salt and 0-10% of lanthanum source or zirconium source into deionized water, stirring and mixing, filtering, and washing to be neutral to obtain a cerium-containing solution; step S2, impregnating an alumina carrier in the cerium-containing solution prepared in the step S1, and standing to enable the cerium-containing solution to be impregnated on the alumina carrier, so as to obtain impregnated slurry; and S3, drying the dipping slurry, and then roasting in an inert atmosphere to obtain the cerium-aluminum composite oxide. The stable cerium-aluminum composite material is formed by doping one of lanthanum and zirconium with different masses into aluminum oxide or cerium oxide, the problem that the adsorption capacity of a traditional ammonia trapping method is limited is effectively solved, and the adsorption capacity of the material to ammonia is remarkably improved.

The invention discloses a lanthanum-doped CuMgAl catalyst as well as a preparation method and application thereof, and belongs to the technical field of catalysts. The preparation method of the lanthanum-doped CuMgAl catalyst comprises the following steps: adding a copper salt, a magnesium salt, an aluminum salt and a lanthanum salt into water to obtain a first solution; adding a precipitator into water to obtain a second solution; adding the second solution into the first solution to adjust the pH value to 10.5 to obtain a mixed solution, stirring the mixed solution to generate a co-precipitation reaction, after the reaction is completed, carrying out aging treatment to promote growth and structure ordering of layered double hydroxide crystals, and then carrying out calcination treatment to convert a layered double hydroxide precursor into an oxide, thereby obtaining the layered double hydroxide. And the lanthanum-doped CuMgAl catalyst is obtained. The lanthanum-doped CuMgAl catalyst prepared by the preparation method disclosed by the invention has excellent activity and stability.

The method comprises the following steps: weighing an oxide precursor of metal indium, an oxide precursor of metal M, an ammonium salt and a lithium salt according to a chemical formula of indium-based halide, fully mixing, and calcining in an inert atmosphere to obtain the indium-based halide solid electrolyte. Forming an indium-based halide solid electrolyte through a solid-phase reaction; wherein M is selected from at least one of magnesium, calcium, strontium, barium, aluminum, gallium, indium, bismuth, scandium, yttrium, zinc, germanium, tin, lanthanum, cerium, samarium, gadolinium, holmium, erbium and ytterbium. The method can greatly simplify the synthesis process, reduce the raw material cost and realize industrial batch preparation.

A component for use in a semiconductor processing chamber is provided. A metal or metal alloy component body has a process-facing surface. An intermediate aluminum oxide coating is disposed on the process-facing surface, the intermediate aluminum oxide coating being at least 99% pure by weight and having a porosity of less than 0.1% by volume, the intermediate aluminum oxide coating having a first thickness. A process-exposed layer is disposed on the intermediate aluminum oxide coating, the process-exposed layer comprising at least one of yttrium, hafnium, zirconium, lanthanum, magnesium, and a lanthanide, the process-exposed layer being at least 99% pure by weight, having a porosity of less than 0.1%, and having a second thickness, the second thickness being less than or equal to the first thickness.

The invention relates to a surface-coated oxide solid electrolyte and a preparation method thereof, the surface-coated oxide solid electrolyte comprises an oxide electrolyte and a surface coating layer, the chemical formula of the oxide solid electrolyte is Li7-xLa3Zr2MxO12-x (M = Ta, Nb, Hf, Ge, Sc, Ti, Al, Si, Sn, Y, 0 < = x < = 1), the chemical formula of the surface coating layer is LiXON (R = Ta, Nb, Al, Zr, Ga, In, N = F, Cl, Br, I), and a lithium source, a lanthanum source, a zirconium source, an M source, an X source and an N source, or an XN source are connected in series, garnet solid electrolyte powder with a stable surface coating layer is obtained by adopting a solid phase method or a sol-gel method and combining a low-temperature calcination process; and then mixing and reacting with a lithium salt and a polymer electrolyte, and pouring the obtained slurry on a polyfluortetraethylene plate to prepare the composite electrolyte. Compared with the prior art, the high-ion conductor layer formed on the surface of the product in situ constructs a rapid transmission channel for lithium ion transmission in the composite electrolyte, and high ion conductivity is achieved.

The invention belongs to the technical field of catalytic materials and hydrocarbon reforming, and particularly relates to a high-entropy catalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing a metal salt solution containing lanthanum, chromium, copper, zinc, manganese, nickel, iron and cobalt ions with a chelating agent and a dispersing agent for reaction, carrying out ultrasonic cavitation treatment to obtain sol, adjusting the pH value, gelatinizing under an oil bath heating condition to obtain a colloidal precursor, drying, and calcining in an air atmosphere to obtain a perovskite type high-entropy oxide precursor; and then treating in a reducing atmosphere to obtain the FeZnCuNiCo perovskite type high-entropy alloy catalyst which contains metal components of La, Cr, Ni, Mn, Fe, Zn, Cu and Co and takes a multi-metal alloy active center of Fe-Zn-Cu-Ni-Co as a main component. The high-entropy catalyst can meet the harsh requirements of high temperature, strong carbon deposition driving force and long-period operation in a propane dry reforming reaction, and is suitable for industrial application scenarios of continuous production of high-temperature synthesis gas.

The present invention relates to an ammonia decomposition catalyst and a manufacturing method thereof, and more particularly to an ammonia decomposition catalyst containing alumina (Al2O3), cerium (Ce), lanthanum (La), ruthenium (Ru) and potassium (K).

The invention provides an efficient environment-friendly petroleum passivator as well as a preparation method and application thereof, and belongs to the technical field of passivators. The preparation method comprises the following steps: reacting bismuth nitrate with tetra (4-carboxyl phenyl) porphyrin and benzoic acid to prepare a carboxyl phenyl porphyrin bismuth-MOF material, reacting antimony nitrate with tetra (4-pyridyl) porphyrin and benzoic acid to prepare a pyridyl porphyrin antimony-MOF material, and performing sol-gel reaction on lanthanum isopropoxide and cerium isopropoxide to prepare lanthanum-cerium sol; the preparation method comprises the following steps: mixing calcium nitrate, magnesium chloride, organic acid, organic amine and hydrogen peroxide for reaction to prepare a calcium / magnesium organic matter, mixing the calcium / magnesium organic matter with other substances, adding the mixture into an acetonitrile / ethanol mixed solvent, and uniformly stirring and mixing to prepare the efficient environment-friendly petroleum passivator. The high-efficiency environment-friendly petroleum passivator prepared by the invention is green, safe, non-toxic and efficient, has better capturing and passivating effects on metal ions such as nickel and vanadium in the catalytic cracking reaction process of heavy oil, improves the activity of a catalyst, prolongs the service life of the catalyst, and thus, has a wide application prospect.

The invention belongs to the technical field of electrochemistry, and particularly provides a lanthanum-cerium double-doped sodium ferric sulfate positive electrode material and a preparation method thereof. The material is composed of a matrix and a carbon coating layer coating the matrix, the matrix has a chemical expression of Na6Fe4-x-yLaxCey (SO4) 7, x is greater than or equal to 0.01 and less than or equal to 0.1, and y is greater than or equal to 0.01 and less than or equal to 0.1. The material is prepared through spray drying and high-temperature sintering treatment in sequence, the particle morphology is regular, and the particle size distribution is uniform; the electronic conductivity and Na < + > diffusion rate of the material are remarkably improved by rare earth doping, so that the material has more excellent low-temperature cycle performance, sodium storage performance and the like.

The invention discloses a citric acid regulated mesoporous lanthanum manganese perovskite catalyst, a preparation method and application, in the preparation method, lanthanum salt, manganese salt and citric acid are used as raw materials, a one-step fusion pyrolysis method is adopted for preparation, and the molar ratio of the lanthanum salt to the manganese salt to the citric acid is 1: (0.9-1.1): (1-3). The perovskite catalyst can catalytically degrade toluene waste gas with relatively high concentration, and relatively high toluene removal rate and mineralization rate can be obtained under the condition of low-temperature catalytic oxidation.

The invention provides a rare earth silicon germanate scintillating material and a preparation method and application thereof, in particular to a rare earth silicon germanate scintillating material with high thermal stability and strong radiation resistance and a preparation method and application thereof, the general formula of the rare earth silicon germanate scintillating material with high thermal stability and strong radiation resistance is RE2 (1-x-delta / 2) Ce2xGedeltaSi (1-y + delta) Gey-deltaOz, in the formula, 0 lt; x is more than or equal to 0.05, y is more than or equal to 0.15 and less than or equal to 0.5, delta is more than or equal to 0 and less than or equal to 10 <-4 >, z is more than or equal to 4.95 and less than or equal to 5.05, RE represents a rare earth element, and the rare earth element is selected from at least one of lanthanum (La), lutetium (Lu), yttrium (Y) and gadolinium (Gd). The rare earth silicon germanate scintillating material provided by the invention has the characteristics of strong radiation damage resistance, high scintillation light output, low afterglow and the like while greatly improving the thermal stability, and can be used in occasions with extremely high requirements on the thermal stability or radiation resistance of the material, such as high-energy physical experiments, nuclear medicine imaging, oil exploration wells and the like.

The invention discloses a preparation process of a rare earth precipitation resistant electrophoretic coating for an automobile body. The preparation process comprises the following steps: S1, preparing a stable solution; s2, preparing a rare earth chelating solution; adding lanthanum lactate into the stable solution for multiple times, and adding ammonium ceric sulfate for multiple times after the lanthanum lactate is completely dissolved; s3, preparing a resin base solution; s4, preparing mixed slurry; s5, adding a solvent and an auxiliary agent; a five-membered ring chelate with thermodynamic stability is formed by carboxyl, hydroxyl and rare earth elements in sodium citrate, rare earth ions can be tightly wrapped through strong coordination bonds, namely, empty orbits of the rare earth ions and lone pair electrons of a chelating agent form coordination bonds, so that the rare earth ions cannot be dissociated in a system, and the rare earth ions are prevented from being dissociated in the system. And a path of generating hydroxide precipitates by free rare earth ions is thoroughly blocked, so that rare earth elements are effectively ensured to be uniformly distributed in the electrophoretic paint, and the surface of a raw material treated by a subsequent electrophoresis process is more uniform.

The invention relates to a preparation method of a weather-resistant steel plate for a rare earth La photovoltaic support, and belongs to the technical field of weather-resistant steel. The problem that traditional weathering resistant steel lacks price advantage in market competition with hot-dip galvanized steel due to high alloy content and high initial cost is solved. According to the invention, chemical component design is optimized, a rare earth element La is introduced, a Cu-La-Cr ternary corrosion-resistant system is constructed, meanwhile, specific smelting, refining, continuous casting and hot continuous rolling processes are adopted, and key parameters of each step are strictly controlled; according to the method, the economical efficiency and the high performance of the steel for the photovoltaic support are both considered through pre-desulfurization treatment, adding components, adding time and adding amount of the lanthanum-iron alloy, the temperature system of hot continuous rolling, the controlled cooling process and the like. The preparation method has the characteristics of being low in cost, simple in process and high in operability, and the weather resistance and the mechanical property of the steel plate are not reduced while the alloy cost can be remarkably reduced, so that the requirements of low cost, high corrosion resistance and high strength of weather-resistant steel in the photovoltaic field of C1 and C2 low-corrosion areas in the northwest are met.

The invention relates to the technical field of catalysts, and particularly provides a methane dry reforming catalyst carrier, a catalyst and a preparation method, the carrier is composed of an alumina matrix, a cerium oxide and a lanthanum oxide doped in the alumina matrix, and an anionic surfactant, and the catalyst comprises the carrier and active metal nickel loaded on the surface of the carrier, the problems that a traditional ZrO2 or 3D-Ti-Ce-O carrier is high in cost and complex in process are solved through La / Ce coordinated regulation and control of oxygen vacancy concentration, improvement of metal dispersity by a surfactant and a low-cost coprecipitation process.

The hydrogen transmission pipeline steel comprises the following chemical components in percentage by mass: 0.020%-0.045% of C, 0.11%-0.19% of Si, 1.45%-1.65% of Mn, less than or equal to 0.0010% of S, less than or equal to 0.008% of P, 0.015%-0.045% of Al, 0.040%-0.060% of Nb, 0.020%-0.035% of Ti, 0.30%-0.50% of Cr, 0.0040%-0.0080% of RE, less than or equal to 0.004% of N, less than or equal to 0.0015% of O, less than or equal to 0.0001% of H and the balance of Fe and other inevitable impurities, the conditions that the carbon equivalent Ceq = C + Mn / 6 + (Cr) / 5 is less than or equal to 0.35%, the Nb / Ti = the rare earth element is selected from at least one of lanthanum, cerium and neodymium. The invention aims to solve the technical problems that the existing hydrogen transmission pipeline steel is easy to generate hydrogen embrittlement, short in fatigue life and high in production cost in a high-pressure hydrogen environment, and meets the core requirements of hydrogen energy long-distance transmission pipeline engineering on high strength, high hydrogen embrittlement resistance, high fatigue performance and low cost of materials.

The invention belongs to the technical field of tungsten alloy, and particularly discloses a tungsten alloy electrode material and a preparation method thereof.The tungsten alloy electrode material comprises, by weight, 0.1%-0.2% of lanthanum boride, 0.2%-0.5% of zirconium oxide, 0.2%-0.6% of boron carbide, 0.4%-0.8% of cerium oxide, 0.5%-1.2% of tantalum carbide, 1.4%-1.8% of modified carbon nanotubes and the balance tungsten powder. The lanthanum boride, the zirconium oxide, the boron carbide, the cerium oxide, the tantalum carbide and the modified carbon nanotubes are added into the tungsten powder, under the combined action of the lanthanum boride, the zirconium oxide, the boron carbide, the cerium oxide, the tantalum carbide and the modified carbon nanotubes, the tensile strength and the electrical conductivity are effectively improved, and the high-temperature stability tungsten powder has excellent high-temperature stability and wide application prospects.

The invention relates to a nitrogen-tellurium co-doped carbon-loaded cobalt-lanthanum-gallium triatomic oxygen reduction catalyst as well as a preparation method and application thereof. The catalyst comprises a carbon carrier, doped nitrogen atoms, doped tellurium atoms, supported cobalt atoms, supported lanthanum atoms and supported gallium atoms, wherein the doping proportions of nitrogen atoms and tellurium atoms in the carrier are 3.63 wt%-6.96 wt% and 2.11 wt%-3.83 wt% respectively, the loading capacity of cobalt atoms is 0.86 wt%-1.05 wt%, the loading capacity of lanthanum atoms is 0.38 wt%-0.47 wt%, and the loading capacity of gallium atoms is 0.21 wt%-0.47 wt%; in the preparation method, the nitrogen-tellurium co-doped carbon carrier is fully anchored and coordinated to Co and La atoms through a hydrothermal reaction; and through freeze drying, collapse of a carbon skeleton of the catalyst can be effectively avoided. The obtained catalyst shows good oxygen reduction activity in a solid zinc-air battery, and the peak power density of the catalyst reaches up to 1.68 mW cm <-2 >.

The invention discloses a bacterium-enzyme mixed preparation for PET plastic degradation and a preparation method thereof, and belongs to the technical field of enzyme preparations, a lanthanum metal framework is formed, loaded on the surface of titanium dioxide and carbonized to obtain a lanthanum-doped porous carbon layer, and then nitric acid treatment and silane coupling agent treatment are performed to significantly increase the specific surface area and roughness, so that the specific surface area is increased; the calcium-based diatomite is taken as a carrier to form a sodium alginate microcapsule taking an enzyme preparation as an inclusion, and the sodium alginate microcapsule is loaded on the surface of the calcium-based diatomite, so that the situation that titanium dioxide generates hydroxyl free radicals in photocatalysis to directly attack the enzyme preparation is avoided, and the degradation effect on the PET plastic is prolonged; calcium ions in the calcium-based diatomite can increase the crosslinking degree with the sodium alginate, the load rate of the sodium alginate microcapsule is increased, the strength of the microcapsule is improved, and the slow release effect of an enzyme preparation in the microcapsule is further improved.

Lanthanum perovskite oxide coated high nickel ternary positive electrode material and preparation method thereof, wherein the positive electrode material is a spherical particle formed by coating a high nickel ternary positive electrode material with a lanthanum perovskite oxide coating layer at a mass ratio of 0.01 to 0.03:1; the chemical formula of the lanthanum perovskite oxide is La z Ca 1‑z CoO3, where 0 < z ≤ 1; the chemical formula of the high nickel ternary cathode material is LiNi x Co y Mn (1‑x‑y) O2, wherein 0.80≤x≤0.96, 0.01≤y≤0.10, and 1-x-y>0. The preparation method comprises ball-milling a lanthanide perovskite oxide with a high-nickel ternary cathode material, followed by low-temperature sintering under a protective atmosphere. The cathode material of the present invention exhibits high lithium ion and electron conductivity during charge and discharge, is highly reversible, has a stable structure, and exhibits excellent rate capability and cycle stability. The method of the present invention is simple, low-cost, and suitable for industrial production.

The invention belongs to the technical field of aluminum alloy grain refiners, and particularly relates to a grain refiner and a preparation method and application thereof.The preparation method of the grain refiner comprises the following steps that S1, aluminum powder, vanadium powder, boron powder and lanthanum powder are obtained; s2, after uniform mixing, vacuum ball milling is performed to obtain first powder, and the first powder is sieved to obtain second powder; s3, pressing the second powder to obtain a metal cake; s4, sintering the metal cake in an inert gas atmosphere to obtain a grain refiner; the Al-V-B-La refiner is prepared through a sintering method, the distribution condition of a second phase in the grain refiner and the grain refining effect of the grain refiner are improved through the rare earth element La, the VB2 phase in the grain refiner with the La element added is more uniform in distribution, smaller in size and larger in number density, more second phases can play a role in refining, and the grain refining effect of the grain refiner is improved. And the problem that the refining efficiency is low due to the Si poisoning problem of a traditional grain refiner is solved, and therefore the better aluminum alloy grain refining effect is achieved.

The present invention provides a calcium-based thermochemical heat storage material modified with high-entropy fluorite oxide and a preparation method thereof. The material comprises a calcium-based material and a high-entropy fluorite oxide, with the calcium-based material accounting for 70-85% by mass. The calcium-based material is calcium oxide, and the high-entropy fluorite oxide is a fluorite-structured oxide formed by zirconium, cerium, lanthanum, neodymium, and ytterbium, with a molar ratio of 1:1:1:1:1 for the oxides of zirconium, cerium, lanthanum, neodymium, and ytterbium. The invention utilizes the high-entropy fluorite oxide as an anti-sintering component to disperse calcium oxide and prevent its sintering, while simultaneously promoting the adsorption, dissociation, and migration of CO2 on the surface of the material, thereby enhancing the cycling stability and energy density of the heat storage material.

The invention relates to the field of laser cladding powder, in particular to wear-resistant and corrosion-resistant laser cladding powder and a preparation method thereof. The laser cladding powder is used for solving the problem that a cladding layer formed by existing laser cladding powder is poor in abrasion resistance and corrosion resistance. According to the laser cladding powder, the carbon nano tube loaded lanthanum-yttrium oxide powder and the copolymer coated titanium diboride powder are added, and the carbon nano tube and the lanthanum-yttrium oxide have a synergistic effect to refine grains, so that the corrosion resistance of a cladding layer is improved, and the carbon nano tube has good wear resistance; after the surface of the titanium diboride powder is coated with the copolymer, the dispersity of the titanium diboride is improved, a product decomposed by the copolymer reacts with the titanium diboride under the action of laser to generate titanium carbide, and the wear resistance of a cladding layer is enhanced; the laser cladding powder is suitable for prolonging the service cycle of a mold, can be used for surface strengthening of mine equipment parts, enhances the wear resistance and corrosion resistance of the mine equipment parts, reduces the maintenance frequency of the equipment, and can provide an effective solution for surface strengthening of parts in various industrial fields.

The invention discloses a method for preparing fine-grain copper and copper alloy through pulsed magnetic field and rare earth adding composite regulation and control, and belongs to the technical field of copper and copper alloy material preparation. Graphite mold casting is adopted in the method, and the method comprises the specific steps that electrolytic copper with the purity larger than or equal to 99.95 wt% or a copper alloy with specific components is prepared as a matrix raw material; after smelting, adding pure lanthanum blocks and uniformly stirring; after the melt is poured into a preheating mold, a pulsed magnetic field is applied immediately for treatment, and the parameters of the magnetic field are as follows: the pulse voltage is 180-250 V, the frequency is 4.5-6.5 Hz, and the duration time is 15-20 minutes. According to the method, the heterogeneous nucleation effect of rare earth lanthanum is combined with the melt forced convection and dendritic crystal crushing effect caused by the pulsed magnetic field to synergistically refine a solidification structure and promote columnar crystal orientation equiaxed crystal transformation, so that a cast ingot with fine crystal grains is directly obtained in the casting stage, and the possibility is provided for simplifying the subsequent processing technology.