611 results about "Lanthanum oxide" patented technology

The invention belongs to the technical field of powder metallurgy, and particularly relates to a high-strength tungsten alloy wire and a preparation method thereof, lanthanum oxide is uniformly doped through a ball-milling mixing and microwave sintering method, the recrystallization temperature of tungsten crystal grains is reduced by coordinating logarithmic strain of a rotary hammer, an annealing process and the like, the tungsten crystal grains uniformly grow, and the high-strength tungsten alloy wire is prepared. The wire diameter of the high-strength tungsten alloy wire is smaller than 30 microns, the tensile strength of the high-strength tungsten alloy wire is larger than or equal to 6200 MPa, and the percent of pass of the high-strength tungsten alloy wire is larger than or equal to 80%.

The invention relates to the technical field of ceramics, in particular to a preparation method of a heat-resistant ceramic marmite. The heat-resistant ceramic marmite is composed of a green body and a glaze surface, and the green body is prepared from, by weight, 30-35 parts of fused quartz, 8-10 parts of petalite, 9-11 parts of kaolin, 19-21 parts of washed illite clay, 5-7 parts of sepiolite, 5-6 parts of andalusite, 7-9 parts of coal gangue, 0.2-0.7 part of zinc spinel and 2-3 parts of talc; the glaze surface is prepared from the following raw materials in parts by weight: 18 to 20 parts of fused quartz, 14 to 16 parts of petalite, 12 to 14 parts of kaolin, 5 to 6 parts of calcium oxide, 1.5 to 2 parts of zinc oxide, 1 to 1.5 parts of strontium oxide, 8 to 10 parts of spodumene, 0.6 to 0.8 part of lanthanum oxide, 8 to 10 parts of ZrSiO4 coated Al2O3 and 1.2 to 1.8 parts of pigment. The prepared ceramic marmite has the advantages of matt appearance, higher thermal stability, low water absorption rate and excellent comprehensive performance, and is not easy to crack and wear.

The invention relates to a method for preparing a pyrochlore oxyfluoride solid electrolyte by a one-step solid phase method, which comprises the following steps: uniformly mixing lithium carbonate (Li2CO3), lanthanum oxide (La2O3), niobium pentoxide (Nb2O5) and lithium fluoride (LiF), and carrying out high-temperature one-time sintering under protective gas to synthesize a Li2-xLa (1 + x) / 3Nb2O6F (LLNOF solid electrolyte material. The synthesis route is optimized, a single fluorine source is used, and the types of raw materials are reduced; according to the method, secondary sintering is not needed, the pure-phase electrolyte powder can be obtained by adopting one-step sintering synthesis, the steps are simple, the efficiency is high, the cost is reduced, and the resource consumption is reduced. According to the obtained LLNOF electrolyte material powder, the synthesis temperature ranges from 900 DEG C to 1100 DEG C, heating to 1100 DEG C or above is not needed, the requirement for heating equipment is low, large-scale mass production can be conducted, the sample yield is large, and energy consumption is low. Required synthesis equipment is simple and easy to obtain, and the ionic conductivity is good. The lithium ion conductor with high conductivity and stability in air is synthesized through a one-step method.

The invention discloses a large-aperture aluminum oxide loaded copper-based catalyst as well as preparation and application thereof. The large-aperture alumina-loaded copper-based catalyst comprises a large-aperture alumina carrier, and copper oxide and lanthanum oxide loaded on the surface of the large-aperture alumina carrier, the large-aperture alumina-loaded copper-based catalyst is granular, the specific surface area is 250-500 m < 2 > / g, the pore volume is 1.0-2.0 cm < 3 > / g, the average aperture is 16-30 nm, and the pore diameter of the large-aperture alumina-loaded copper-based catalyst is 20-30 nm. The large-aperture alumina supported copper-based catalyst comprises the following components in percentage by mass: 79%-98.9% of a large-aperture alumina carrier, 0.1%-6% of copper oxide and 1%-15% of lanthanum oxide. The large-aperture aluminum oxide loaded copper-based catalyst disclosed by the invention shows relatively high catalytic activity and higher alcohol selectivity in a reaction for preparing higher alcohol from ethanol, and particularly has relatively high C6-C10 fatty alcohol selectivity.

The invention relates to the field of anticorrosive paint, in particular to anticorrosive paint containing lanthanum cerium oxide and a preparation method of the anticorrosive paint. The invention relates to an anticorrosive coating containing lanthanum cerium oxide. The anticorrosive coating is prepared from the following raw materials: 28 to 45 parts of ultraviolet stable composite film forming matter, 5 to 10 parts of composite rare earth filler, 6 to 12 parts of supported synergistic antirust agent, 18 to 30 parts of mixed solvent, 0.8 to 2.5 parts of dispersing agent, 2.7 to 5.3 parts of functional additive and 0.5 to 1.2 parts of nano montmorillonite, the composite rare earth filler is lanthanum cerium oxide-hydroxyapatite composite powder with a core-shell structure, wherein lanthanum cerium oxide is used as a core, hydroxyapatite is used as a shell, and the thickness of the shell layer is 10-20 nm; the ultraviolet stable composite film forming substance comprises epoxy resin and ultraviolet grafting modified polyurethane in a weight ratio of 1: (0.6-2.2); the supported synergistic antirust agent is a mixture of mesoporous silica supported benzotriazole and zinc molybdate. And the obtained coating is high in adhesive force and long in service life.

The invention relates to the technical field of biomedical materials, in particular to a titanium implant multifunctional composite coating with anti-active oxygen and anti-inflammatory dual performance and a preparation method of the titanium implant multifunctional composite coating. The coating is composed of a lanthanum oxide (La2O3) nano-particle layer growing on the surface of the titanium implant in situ and queen lily glycoside A (RA) loaded on the lanthanum oxide (La2O3) nano-particle layer and can continuously release La < 3 + > and RA. The preparation method comprises the following steps: performing alkali heat treatment on the titanium substrate; a La (OH) 3 coating is synthesized on the surface in situ through a hydrothermal reaction; the La2O3 nano-particles are calcined and converted into a La2O3 nano-particle layer with a porous structure; and finally loading RA through an impregnation method. The coating can effectively remove ROS, regulate immune inflammatory response, promote osteogenic differentiation and inhibit osteoclast activity, thereby remarkably promoting osseointegration. The problem of osseointegration under the osteoporosis pathological microenvironment is effectively solved, the preparation process is simple and controllable, and the composition is suitable for bone defect repair of osteoporosis patients and has important clinical application value.

The invention relates to the technical field of ceramics, and discloses an aluminum oxide ceramic glaze based on domestic waste ceramics, and a preparation method and application thereof. The aluminum oxide ceramic glaze comprises the following raw materials in parts by weight: 28-42 parts of domestic waste ceramic, 25-30 parts of kaolin, 6-12 parts of calcined talc, 3-7 parts of borax, 6-14 parts of aluminum oxide, 3-5 parts of zirconium oxide, 1-3 parts of lanthanum oxide and 3-6 parts of self-repairing particles. The self-repairing particles comprise mesoporous alumina doped with Si and Zr, and V2O5-B2O3-TeO2 series glass which is filled in pores of the mesoporous alumina and has a softening point of 200-300 DEG C. After the glaze is applied to the surface of the aluminum oxide ceramic to form a glaze layer, the insulativity of the aluminum oxide ceramic can be effectively improved, meanwhile, the high bonding stability between the glaze layer and the aluminum oxide ceramic can be achieved, and the problems that the insulativity is greatly reduced and the glaze layer cracks during heat circulation are solved.

The invention provides a rare earth heat insulation coating and a preparation method thereof. The coating comprises the following components in parts by weight: 50-60 parts of acrylic resin, 10-15 parts of polyurethane modified epoxy resin, 5-8 parts of nano rare earth powder, 3-5 parts of filler, 0.5-1 part of a coalescing agent, 1-2 parts of a defoaming agent, 1-3 parts of a dispersing agent, 0.5-1 part of an ultraviolet light absorber and 1-2 parts of a silane coupling agent. Wherein the nano rare earth powder comprises lanthanum oxide powder, cerium chloride powder and yttrium hexaboride powder, and the filler comprises nano hollow microspheres, nano calcium carbonate and nano aluminum silicate. The rare earth heat insulation coating has excellent heat insulation effect and mechanical property, and can be applied to various scenes.

The invention discloses a corrosion-resistant aluminum alloy profile and a preparation method thereof, and belongs to the technical field of aluminum alloy profiles. By optimizing the components of the corrosion-resistant aluminum alloy, the strength of the aluminum alloy profile can be guaranteed, and the corrosion resistance of the aluminum alloy profile is positively influenced. Besides, the corrosion-resistant coating is formed on the surface of the corrosion-resistant aluminum alloy base material in a laser cladding mode, the corrosion resistance of the aluminum alloy profile can be remarkably improved while the application performance of the aluminum alloy profile is guaranteed, and in the corrosion-resistant coating, nickel powder can enhance pitting corrosion resistance and intergranular corrosion resistance, so that the corrosion resistance of the aluminum alloy profile is improved. The adhesive force with an aluminum alloy base material is improved; the boron nitride can improve the acid resistance and wear resistance of the surface of the aluminum alloy profile and block a corrosion channel; the lanthanum oxide and the cerium dioxide have a synergistic effect, so that surface grains can be refined, air holes generated in the cladding process are reduced, the compactness of the coating is improved, the compatibility with an aluminum alloy base material is promoted, and the apparent quality of the aluminum alloy profile is guaranteed.

The invention provides a preparation method of a lanthanum oxide modified biochar fertilizer, and belongs to the technical field of agricultural fertilizers, and the preparation method comprises the following steps: 1, microwave activation of biochar: placing corn straw biochar in a microwave reactor for radiation to obtain porous activated biochar; 2, potassium ion loading: dipping the porous activated charcoal in a saturated KOH solution to obtain a solid precipitate, and drying the solid precipitate to obtain potassium-loaded charcoal; 3, lanthanum-organic complex preparation: mixing lanthanum oxide with citric acid, adding deionized water to form a suspension, and performing evaporative crystallization to obtain a lanthanum-citric acid complex; 4, compounding modified biochar: mixing the obtained lanthanum-citric acid complex with potassium-loaded biochar to prepare slow-release lanthanum oxide modified biochar; and 5, compounding a phosphate fertilizer to obtain the slow-release composite charcoal fertilizer. According to the method, the charcoal is modified through lanthanum oxide, so that the modified charcoal has a larger specific surface area, the problem of hardening of the saline-alkali soil is better solved, and the oxygen content of the soil is increased.

The invention discloses a blue-and-white glaze and a preparation method and application thereof, and belongs to the technical field of inorganic non-metallic materials (ceramics), the blue-and-white glaze comprises quartz, feldspar, limestone, plant ash and other basic raw materials, zinc oxide, aluminum oxide, lanthanum oxide, cerium oxide and other rare earth elements, and a modified organic additive is introduced. Compared with the prior art, the blue-and-white glaze shows excellent stability in the drying and firing process, the phenomena of cracking and glaze stripping are effectively reduced, the friction coefficient after firing is low, the breaking strength and the breaking modulus are high, the glossiness and transparency of a glaze surface are remarkably improved, and the blue-and-white glaze has important application value.

The invention relates to a deep sewage defluorination method based on NH4F.LaF3 chemical precipitation, which comprises the following specific steps: adding a solution containing NH4 < + > and La < 3 + > into fluorine-containing water, adjusting the pH value of the sewage to 6-8, and carrying out NH4F.LaF3 chemical precipitation reaction; sediment is discharged, crystal particles in supernate are removed, deep defluorination of the sewage is achieved, and the concentration of fluorine ions in the water after defluorination can be stably lower than 1 mg / L. According to the method disclosed by the invention, by utilizing the characteristic that the solubility of double salt NH4F.LaF3 is very low, NH4 < + > ions (ammonium chloride or ammonia water and hydrochloric acid) and La < 3 + > ions (lanthanum chloride or lanthanum oxide and hydrochloric acid) are added into the fluorine-containing wastewater, so that equivalent reaction of fluorine, lanthanum ions, ammonium ions, fluorine ions and the like in the water is removed, and the addition of a medicament does not need to be excessive. The method has the characteristics of high efficiency and low cost, and has the advantages of small dosage of chemicals, high reaction speed, thorough reaction and low concentration of fluorine in effluent.

The invention provides an inorganic mineral fiber based on water-quenched slag and a preparation method thereof, and belongs to the field of inorganic mineral fiber materials. Titanium oxide powder is synthesized through tetrabutyl titanate and compounded with lanthanum oxide, the high temperature resistance and corrosion resistance of the fiber are improved through the synergistic effect, and the thermal stability and structural integrity of the lanthanum oxide-titanium oxide composite powder are improved through calcination treatment. Meanwhile, the dispersity and the interface bonding force of the powder are optimized through plasma treatment and silane coupling agent modification, so that the mechanical property and the heat resistance of the fiber are enhanced. In addition, phosphate and zirconium oxide are introduced to coat zinc oxide, so that the zinc oxide shows better fluidity and dispersity in a high-temperature melting process; the fiber surface is treated through magnesium chloride and cerium chloride, so that the corrosion resistance and high-temperature stability are improved; the microwave heating technology improves the surface treatment efficiency, avoids the thermal degradation problem of a traditional method, and ensures the long-term stability and performance of the fiber in a severe environment.

The invention discloses a catalyst for preparing gamma-butyrolactone through liquid phase dehydrogenation of 1, 4-butanediol as well as a preparation method and application of the catalyst. Belongs to the technical field of catalyst preparation. The catalyst is composed of a carrier, CuO and MOx, the CuO and the MOx are loaded on the carrier, Cu accounts for 10-50% of the total mass of the catalyst, M accounts for 1-25% of the total mass of the catalyst, M is one of Mn, Zn, Co, Ni, Fe, Cr, Ce, Nb, Ru, Pt, Ir and Pd, and the carrier is one of silicon oxide, aluminum oxide, magnesium oxide, lanthanum oxide, hydroxyapatite and magnesium-aluminum hydrotalcite. An oxide-oxide interface is formed between CuO and MOx through roasting and reduction, and relatively strong electron interaction exists between highly dispersed Cu nanoparticles and the oxide-oxide interface, so that the stability of the catalyst can be enhanced.

The invention discloses high-resistance aluminum-magnesium spinel ceramic as well as a preparation method and application thereof, and relates to the technical field of preparation of ceramic materials. The ceramic comprises the following raw materials in parts by weight: 28-32 parts of silicon dioxide, 15-17 parts of magnesium oxide, 38-42 parts of aluminum oxide, 1-3 parts of lanthanum oxide, 2-5 parts of zirconium oxide, 1.5-2.5 parts of calcium oxide, 0.8-1.2 parts of tantalum oxide, 2-4 parts of titanium oxide and 1-3 parts of zinc oxide. The method provided by the invention has the advantages of low energy consumption, high production efficiency, high insulation resistance and the like, and solves the problems of low yield, complex equipment structure, high production cost and the like of the existing preparation method.

The preparation method of the rare earth antibacterial glaze comprises the following steps: mixing 30-48 parts by mass of quartz sand, 20-35 parts by mass of borax, 25-35 parts by mass of feldspar powder and 10-25 parts by mass of zinc oxide into a ball mill for ball milling, sieving the ball-milled material, and drying to obtain powder A; mixing 0.5-3 parts of lanthanum oxide, 0.5-2 parts of cerium oxide and 100 parts of powder A into a ball mill for ball milling, and sieving and drying the ball-milled material to obtain powder B; melting the powder B at 1350-1400 DEG C to obtain a glaze melt, taking out the glaze melt, tabletting, and cooling to obtain a glaze frit; and carrying out ball milling on the glaze frit until the particle size is less than 20 microns, slowly heating to 650-700 DEG C, and carrying out heat preservation for 25-30 minutes to obtain the rare earth antibacterial glaze. The ceramic prepared from the rare earth antibacterial glaze has broad-spectrum antibacterial performance, inhibits the breeding of microorganisms such as bacteria and fungi, and reduces the infection risk.

The invention provides a plasma spraying high-temperature-erosion-resistant coating and a coating preparation method, and relates to the technical field of material surface treatment. Comprising the following components in parts by mass: 30-45 parts of tungsten carbide, 15-25 parts of chromium carbide-nickel-chromium alloy, 15-25 parts of yttria-stabilized zirconia, 5-10 parts of aluminum oxide-titanium dioxide composite ceramic, 10-20 parts of nickel-chromium-aluminum-yttrium alloy, 1-3 parts of nano aluminum oxide and 1-3 parts of lanthanum oxide. Multiphase collaborative design is adopted, tungsten carbide and chromium carbide-nickel-chromium alloy form double hard phases, the hardness is higher, aluminum oxide-titanium dioxide composite ceramic fills pores and improves compactness, rare earth and nanometer are adopted to cooperate, lanthanum oxide and nanometer aluminum oxide react to generate a LaAlO3 protective layer, oxidation weight gain is small, oxygen diffusion is inhibited, nanometer aluminum oxide refines grains, and the hardness is higher. In conclusion, the high-temperature oxidation resistance is high, and the erosion rate is low.

The invention relates to a red fluorescent material excited by blue light, an LED device and fluorescent ceramic. The chemical formula of the red fluorescent material is La (2-x) MgNbO6.5: xEu < 3 + >, wherein x is more than or equal to 0.01 and less than or equal to 0.1. The preparation method comprises the following steps: weighing lanthanum oxide, magnesium oxide, niobium oxide and europium oxide raw materials according to a stoichiometric ratio, grinding and uniformly mixing; sintering the uniformly mixed powder in a muffle furnace at high temperature, and cooling to room temperature to obtain the red fluorescent material. Compared with the prior art, the novel oxide-based red fluorescent powder prepared by the invention can emit positive red light of which the central wavelength is 616nm under the excitation of 465nm blue light, and can be used for white light LED (Light Emitting Diode) luminescent devices and fluorescent ceramics.

The invention provides a novel underwater wet welding flux-cored wire and a preparation method thereof. The flux-cored wire comprises a metal sheath and a flux core, the flux core is prepared by sintering a flux core base material and a flux core additive; the flux core base material comprises the following raw materials in percentage by mass: 20-40% of rutile, 15-35% of fluoride, 2-7% of titanate, 3-10% of aluminum powder, 5-15% of manganese powder and 10-15% of composite nano metal oxide; the composite nano metal oxide at least comprises the following raw materials: nano aluminum oxide, nano zirconium dioxide, nano yttrium oxide, nano cerium oxide and nano lanthanum oxide; and the flux-cored additive is linear aliphatic epoxy resin. The specific mixed nano metal oxide powder is added into the flux-cored wire, grain refinement is achieved, a quenched martensite structure is reduced, the mechanical property of a weld joint is improved, meanwhile, the specific epoxy resin and the flux-cored base material are mixed, filled and sintered, a proper amount of carbon element is introduced while all raw material components of the flux-cored wire are dispersed uniformly and stably, and the welding quality of the flux-cored wire is improved. And metal is prevented from being oxidized in the welding process.

The invention provides a solid electrolyte membrane, a preparation method thereof and a solid-state battery. The solid electrolyte membrane comprises an inorganic filler, a polymer matrix and a lithium salt, wherein the inorganic filler comprises a dielectric conductive ion material and oxide particles; wherein the dielectric conductive ion material comprises a dielectric filler and a silane coupling agent which is coated on the outer surface of the dielectric filler and contains cyano groups, the dielectric filler contains transition metal elements, and the transition metal elements are Nb elements and / or Ta elements; the oxide particles comprise lanthanum oxide particles; the mass ratio of the dielectric conductive ion material to the oxide particles is (1-5): 1, and the ratio of the total mass of the inorganic filler to the mass of the polymer matrix is (10-50): 100. The solid electrolyte membrane provided by the invention has relatively high ionic conductivity, mechanical strength and structural stability, and can effectively improve the comprehensive performance of the solid lithium metal battery.

The invention provides a nano composite tungsten-based alloy. The alloy comprises the following components in parts by weight: 84.0 to 87.0 parts of W powder, 7.0 to 9.0 parts of N powder, 3.0 to 5.0 parts of Fe powder, 0.2 to 0.5 part of Co powder, 1.5 to 2.5 parts of Mo powder, 0.8 to 1.0 part of Zr powder, 0.5 to 0.8 part of Cr powder, 0.3 to 0.5 part of Mn powder, 0.4 to 0.5 part of B powder, 0.2 to 0.4 part of Ta powder, 0.1 to 0.3 part of Hf powder, 0.1 to 0.2 part of V powder, 0.1 to 0.3 part of T powder, 0.1 to 0.2 part of silicon carbide powder, 0.1 to 0.2 part of aluminum nitride powder, 0.3 to 0.5 part of yttrium oxide powder and 0.1 to 0.2 part of lanthanum oxide powder. The yield strength of the nano-composite tungsten-based alloy can reach 1270-1520 MPa, the tensile strength of the nano-composite tungsten-based alloy is 1430-1680 MPa, the ductility of the nano-composite tungsten-based alloy is 6-12%, and the impact toughness of the nano-composite tungsten-based alloy is 130-220 J / cm < 2 >.

The invention is applicable to the technical field of ceramic high-temperature sensors, and provides a high-temperature co-sintered multilayer special-shaped ceramic high-temperature sensor and a preparation method thereof.The ceramic high-temperature sensor sequentially comprises a protective layer, a functional layer, an insulating layer and a supporting layer, and metal electrode networks are printed on the functional layer and the supporting layer; according to the high-temperature co-sintered multilayer special-shaped ceramic high-temperature sensor, zirconium oxide and aluminum oxide are used as matrixes, lanthanum oxide and yttrium oxide are added, the microstructure and performance of ceramic are optimized, the ceramic has higher high-temperature resistance, mechanical strength and stability, the nano Al2O3 is doped with platinum-iridium alloy ink, and the high-temperature co-sintered multilayer special-shaped ceramic high-temperature sensor has the advantages that the high-temperature co-sintered multilayer special-shaped ceramic high-temperature sensor is more stable in performance. The problem of interface failure of metal and ceramic at high temperature is solved, the electrode made of high-temperature-resistant metal ink is printed on the ceramic layer through the 3D printing technology, good binding force and conductivity exist between the electrode and the ceramic layer, and the electrode can stably work in the high-temperature environment.

The invention discloses a cellulose / chitosan / lanthanum oxide composite material for efficiently removing nitrogen and phosphorus from a water body. The composite material is mainly prepared from the following raw materials: bacterial cellulose, chitosan, lanthanum nitrate hexahydrate and sodium hydroxide. By regulating and controlling the dosage of raw materials such as chitosan, lanthanum nitrate hexahydrate, sodium hydroxide and the like in the synthesis process of the material, the process parameters of material preparation are optimized, so that the optimal nitrogen and phosphorus removal performance is achieved. The practical application capability of the material is verified by evaluating the nitrogen and phosphorus removal performance, the application stability and the environmental factor influence of the material. The development of the material solves the problems that an environmental functional material is high in preparation cost, low in adsorption capacity, poor in selectivity and incapable of removing nitrogen and phosphorus at the same time. Theoretical support is provided for preparation of the nitrogen and phosphorus removal adsorption composite material for the water body, and meanwhile, the composite material has a wide practical application prospect.

The invention relates to a dephosphorization material, a preparation method thereof and a dephosphorization method, belongs to the field of water treatment, and solves at least one of the problems of contradiction between adsorption capacity and structural stability, fast capacity fading, short service life, difficult recovery, higher cost and the like of the existing lanthanum-based dephosphorization material. The phosphorus removal material is a nano-porous carbon-supported lanthanum composite material, and comprises an amorphous nano-porous carbon matrix, an amorphous nano-porous carbon carrier, an amorphous nano-porous carbon carrier, and an amorphous nano-porous carbon carrier, and an active component embedded in situ in the nanoporous carbon matrix; wherein the active component comprises lanthanum oxide and / or lanthanum hydroxide. According to the invention, the adsorption capacity is high, the structure is stable, the attenuation of the adsorption capacity is delayed, the service life is prolonged, the cost is reduced, and the adsorbent can be recycled.

The invention discloses a method for producing high-purity metal chromium from waste chromium-containing refractory materials by using a carbon reduction method, belongs to the technical field of general industrial solid waste resource environment-friendly comprehensive utilization and metal smelting, and particularly relates to a method for producing the high-purity metal chromium from the waste chromium-containing refractory materials by performing crushing magnetic separation, acid leaching impurity removal, carbon reduction, slag-metal separation and electroslag refining processes on the waste chromium-containing refractory materials. The purity of the finally produced metal chromium reaches 98.9%-99.4%, and the chromium recovery rate reaches 82.2%-82.5%. Wherein yttria-stabilized zirconia and lanthanum oxyfluoride are selected as additives, it is accidentally found in the research process that the lanthanum oxyfluoride and zirconia are combined for use to have a synergistic effect, and during specific combination, lanthanum oxyfluoride and zirconia can form a La-Zr-O-F composite melt, so that the slag-gold separation efficiency is remarkably improved; and further, the purity of the final product chromium metal is obviously improved.

The invention relates to the technical field of glass, in particular to an alkali-free aluminoborosilicate glass composite clarifying agent and a clarifying method thereof. The alkali-free aluminoborosilicate glass composite clarifying agent is prepared from the following raw materials in percentage by mass on the basis of the total mass of alkali-free aluminoborosilicate glass: 0.4 to 5.5 percent of halogen alkaline earth metal salt, 0.03 to 0.4 percent of lanthanum oxide, 0.01 to 0.4 percent of tin dioxide and 0.01 to 0.3 percent of cerium dioxide. The alkali-free aluminoborosilicate glass composite clarifying agent is applied to alkali-free aluminoborosilicate glass, and the problems that the alkali-free aluminoborosilicate glass is poor in clarifying effect and has many bubble defects are solved; the corrosion of high-temperature molten glass to refractory materials at parts such as a tank furnace and the like is reduced, so that the number of stone defects of the refractory materials in the glass is reduced, and the service life of the refractory materials of the furnace is prolonged.

The invention relates to the technical field of wastewater treatment, in particular to a fluorine removal agent for deep fluorine removal and a preparation method thereof, and the fluorine removal agent for deep fluorine removal comprises the following raw materials by weight: 2-5 parts of chitosan; 65-90 parts of polyaluminum chloride; 5-15 parts of magnesium oxide; 1-5 parts of titanium dioxide; 1-5 parts of manganese oxide; and 1-5 parts of lanthanum oxide. The fluorine removal agent has the beneficial effects that the obtained fluorine removal agent gets rid of the constraint of traditional calcium salt, a key catalyst (such as titanium dioxide, manganese dioxide and other transition metal oxides) is introduced through comparison and selection on the basis of controlling the compatibility material combination and synthesis reaction process, the catalyst has a catalysis function on a complex reaction, the adsorption capacity of the fluorine removal agent can be improved, and the fluorine removal effect is improved. And a micro-flocculation core growth position is provided to generate an adsorption and clamping effect. The fluorine ion content of the pretreated fluorine-containing wastewater (the fluorine ion content is 20 mg / L or below) can be reduced to 2 mg / L or below, and the fluorine ion removal rate reaches 90% or above.

The invention discloses porous chlorine dioxide slow-release preservative paper and a preparation method thereof.The porous chlorine dioxide slow-release preservative paper comprises a paper base, a porous carrier is fixed to the paper base through oxidized starch glue, and sodium chlorite, an activating agent and a stabilizing agent are loaded on the porous carrier; the porous carrier is one of aluminum oxide, titanium oxide, cobalt oxide, zinc oxide, copper oxide, iron oxide, cerium oxide, zirconium oxide, nickel oxide, manganese oxide, praseodymium oxide and lanthanum oxide with a porous structure. The slow release of chlorine dioxide can be stably and effectively realized, the release period of chlorine dioxide is prolonged, and long-acting stable sterilization and disinfection effects are realized.

The invention relates to a nanofiber membrane and a preparation method and application thereof, the preparation method comprises the following steps: (1) mixing polyurethane, nano lanthanum oxide, a waterproof agent and a solvent to obtain a spinning solution; (2) performing electrostatic spinning on the spinning solution to obtain an electrostatic spinning membrane; and (3) spraying the after-finishing liquid on the electrostatic spinning membrane, and then carrying out heating treatment to obtain the nanofiber membrane. Polyurethane is stretched into superfine fibers through an electrostatic spinning technology, an ultrahigh porous membrane similar to a spider web is prepared, billions of nanopores are formed in per square centimeter of the porous membrane, so that the porous membrane has high air permeability and waterproof and moisture-permeable performance, fibers are bound through a fiber bonding point technology, and the fiber bonding point technology is adopted, so that the waterproof and moisture-permeable performance of the membrane is improved. Therefore, the fabric has excellent washing resistance. The nano lanthanum oxide heating functional particles are added, so that the nanofiber membrane is endowed with heating and heat storage functions, and the washing resistance of the fabric is further improved.

The invention relates to the technical field of catalysts, and particularly provides a methane dry reforming catalyst carrier, a catalyst and a preparation method, the carrier is composed of an alumina matrix, a cerium oxide and a lanthanum oxide doped in the alumina matrix, and an anionic surfactant, and the catalyst comprises the carrier and active metal nickel loaded on the surface of the carrier, the problems that a traditional ZrO2 or 3D-Ti-Ce-O carrier is high in cost and complex in process are solved through La / Ce coordinated regulation and control of oxygen vacancy concentration, improvement of metal dispersity by a surfactant and a low-cost coprecipitation process.