487 results about "Lanthanum oxide" patented technology

The invention relates to the technical field of ceramics, in particular to a preparation method of a heat-resistant ceramic marmite. The heat-resistant ceramic marmite is composed of a green body and a glaze surface, and the green body is prepared from, by weight, 30-35 parts of fused quartz, 8-10 parts of petalite, 9-11 parts of kaolin, 19-21 parts of washed illite clay, 5-7 parts of sepiolite, 5-6 parts of andalusite, 7-9 parts of coal gangue, 0.2-0.7 part of zinc spinel and 2-3 parts of talc; the glaze surface is prepared from the following raw materials in parts by weight: 18 to 20 parts of fused quartz, 14 to 16 parts of petalite, 12 to 14 parts of kaolin, 5 to 6 parts of calcium oxide, 1.5 to 2 parts of zinc oxide, 1 to 1.5 parts of strontium oxide, 8 to 10 parts of spodumene, 0.6 to 0.8 part of lanthanum oxide, 8 to 10 parts of ZrSiO4 coated Al2O3 and 1.2 to 1.8 parts of pigment. The prepared ceramic marmite has the advantages of matt appearance, higher thermal stability, low water absorption rate and excellent comprehensive performance, and is not easy to crack and wear.

The invention relates to a method for preparing a pyrochlore oxyfluoride solid electrolyte by a one-step solid phase method, which comprises the following steps: uniformly mixing lithium carbonate (Li2CO3), lanthanum oxide (La2O3), niobium pentoxide (Nb2O5) and lithium fluoride (LiF), and carrying out high-temperature one-time sintering under protective gas to synthesize a Li2-xLa (1 + x) / 3Nb2O6F (LLNOF solid electrolyte material. The synthesis route is optimized, a single fluorine source is used, and the types of raw materials are reduced; according to the method, secondary sintering is not needed, the pure-phase electrolyte powder can be obtained by adopting one-step sintering synthesis, the steps are simple, the efficiency is high, the cost is reduced, and the resource consumption is reduced. According to the obtained LLNOF electrolyte material powder, the synthesis temperature ranges from 900 DEG C to 1100 DEG C, heating to 1100 DEG C or above is not needed, the requirement for heating equipment is low, large-scale mass production can be conducted, the sample yield is large, and energy consumption is low. Required synthesis equipment is simple and easy to obtain, and the ionic conductivity is good. The lithium ion conductor with high conductivity and stability in air is synthesized through a one-step method.

The invention relates to the field of anticorrosive paint, in particular to anticorrosive paint containing lanthanum cerium oxide and a preparation method of the anticorrosive paint. The invention relates to an anticorrosive coating containing lanthanum cerium oxide. The anticorrosive coating is prepared from the following raw materials: 28 to 45 parts of ultraviolet stable composite film forming matter, 5 to 10 parts of composite rare earth filler, 6 to 12 parts of supported synergistic antirust agent, 18 to 30 parts of mixed solvent, 0.8 to 2.5 parts of dispersing agent, 2.7 to 5.3 parts of functional additive and 0.5 to 1.2 parts of nano montmorillonite, the composite rare earth filler is lanthanum cerium oxide-hydroxyapatite composite powder with a core-shell structure, wherein lanthanum cerium oxide is used as a core, hydroxyapatite is used as a shell, and the thickness of the shell layer is 10-20 nm; the ultraviolet stable composite film forming substance comprises epoxy resin and ultraviolet grafting modified polyurethane in a weight ratio of 1: (0.6-2.2); the supported synergistic antirust agent is a mixture of mesoporous silica supported benzotriazole and zinc molybdate. And the obtained coating is high in adhesive force and long in service life.

The invention relates to the technical field of biomedical materials, in particular to a titanium implant multifunctional composite coating with anti-active oxygen and anti-inflammatory dual performance and a preparation method of the titanium implant multifunctional composite coating. The coating is composed of a lanthanum oxide (La2O3) nano-particle layer growing on the surface of the titanium implant in situ and queen lily glycoside A (RA) loaded on the lanthanum oxide (La2O3) nano-particle layer and can continuously release La < 3 + > and RA. The preparation method comprises the following steps: performing alkali heat treatment on the titanium substrate; a La (OH) 3 coating is synthesized on the surface in situ through a hydrothermal reaction; the La2O3 nano-particles are calcined and converted into a La2O3 nano-particle layer with a porous structure; and finally loading RA through an impregnation method. The coating can effectively remove ROS, regulate immune inflammatory response, promote osteogenic differentiation and inhibit osteoclast activity, thereby remarkably promoting osseointegration. The problem of osseointegration under the osteoporosis pathological microenvironment is effectively solved, the preparation process is simple and controllable, and the composition is suitable for bone defect repair of osteoporosis patients and has important clinical application value.

The invention relates to the technical field of ceramics, and discloses an aluminum oxide ceramic glaze based on domestic waste ceramics, and a preparation method and application thereof. The aluminum oxide ceramic glaze comprises the following raw materials in parts by weight: 28-42 parts of domestic waste ceramic, 25-30 parts of kaolin, 6-12 parts of calcined talc, 3-7 parts of borax, 6-14 parts of aluminum oxide, 3-5 parts of zirconium oxide, 1-3 parts of lanthanum oxide and 3-6 parts of self-repairing particles. The self-repairing particles comprise mesoporous alumina doped with Si and Zr, and V2O5-B2O3-TeO2 series glass which is filled in pores of the mesoporous alumina and has a softening point of 200-300 DEG C. After the glaze is applied to the surface of the aluminum oxide ceramic to form a glaze layer, the insulativity of the aluminum oxide ceramic can be effectively improved, meanwhile, the high bonding stability between the glaze layer and the aluminum oxide ceramic can be achieved, and the problems that the insulativity is greatly reduced and the glaze layer cracks during heat circulation are solved.

The invention provides a rare earth heat insulation coating and a preparation method thereof. The coating comprises the following components in parts by weight: 50-60 parts of acrylic resin, 10-15 parts of polyurethane modified epoxy resin, 5-8 parts of nano rare earth powder, 3-5 parts of filler, 0.5-1 part of a coalescing agent, 1-2 parts of a defoaming agent, 1-3 parts of a dispersing agent, 0.5-1 part of an ultraviolet light absorber and 1-2 parts of a silane coupling agent. Wherein the nano rare earth powder comprises lanthanum oxide powder, cerium chloride powder and yttrium hexaboride powder, and the filler comprises nano hollow microspheres, nano calcium carbonate and nano aluminum silicate. The rare earth heat insulation coating has excellent heat insulation effect and mechanical property, and can be applied to various scenes.

The invention discloses a corrosion-resistant aluminum alloy profile and a preparation method thereof, and belongs to the technical field of aluminum alloy profiles. By optimizing the components of the corrosion-resistant aluminum alloy, the strength of the aluminum alloy profile can be guaranteed, and the corrosion resistance of the aluminum alloy profile is positively influenced. Besides, the corrosion-resistant coating is formed on the surface of the corrosion-resistant aluminum alloy base material in a laser cladding mode, the corrosion resistance of the aluminum alloy profile can be remarkably improved while the application performance of the aluminum alloy profile is guaranteed, and in the corrosion-resistant coating, nickel powder can enhance pitting corrosion resistance and intergranular corrosion resistance, so that the corrosion resistance of the aluminum alloy profile is improved. The adhesive force with an aluminum alloy base material is improved; the boron nitride can improve the acid resistance and wear resistance of the surface of the aluminum alloy profile and block a corrosion channel; the lanthanum oxide and the cerium dioxide have a synergistic effect, so that surface grains can be refined, air holes generated in the cladding process are reduced, the compactness of the coating is improved, the compatibility with an aluminum alloy base material is promoted, and the apparent quality of the aluminum alloy profile is guaranteed.

The invention provides a preparation method of a lanthanum oxide modified biochar fertilizer, and belongs to the technical field of agricultural fertilizers, and the preparation method comprises the following steps: 1, microwave activation of biochar: placing corn straw biochar in a microwave reactor for radiation to obtain porous activated biochar; 2, potassium ion loading: dipping the porous activated charcoal in a saturated KOH solution to obtain a solid precipitate, and drying the solid precipitate to obtain potassium-loaded charcoal; 3, lanthanum-organic complex preparation: mixing lanthanum oxide with citric acid, adding deionized water to form a suspension, and performing evaporative crystallization to obtain a lanthanum-citric acid complex; 4, compounding modified biochar: mixing the obtained lanthanum-citric acid complex with potassium-loaded biochar to prepare slow-release lanthanum oxide modified biochar; and 5, compounding a phosphate fertilizer to obtain the slow-release composite charcoal fertilizer. According to the method, the charcoal is modified through lanthanum oxide, so that the modified charcoal has a larger specific surface area, the problem of hardening of the saline-alkali soil is better solved, and the oxygen content of the soil is increased.

The invention discloses a blue-and-white glaze and a preparation method and application thereof, and belongs to the technical field of inorganic non-metallic materials (ceramics), the blue-and-white glaze comprises quartz, feldspar, limestone, plant ash and other basic raw materials, zinc oxide, aluminum oxide, lanthanum oxide, cerium oxide and other rare earth elements, and a modified organic additive is introduced. Compared with the prior art, the blue-and-white glaze shows excellent stability in the drying and firing process, the phenomena of cracking and glaze stripping are effectively reduced, the friction coefficient after firing is low, the breaking strength and the breaking modulus are high, the glossiness and transparency of a glaze surface are remarkably improved, and the blue-and-white glaze has important application value.

The invention relates to a red fluorescent material excited by blue light, an LED device and fluorescent ceramic. The chemical formula of the red fluorescent material is La (2-x) MgNbO6.5: xEu < 3 + >, wherein x is more than or equal to 0.01 and less than or equal to 0.1. The preparation method comprises the following steps: weighing lanthanum oxide, magnesium oxide, niobium oxide and europium oxide raw materials according to a stoichiometric ratio, grinding and uniformly mixing; sintering the uniformly mixed powder in a muffle furnace at high temperature, and cooling to room temperature to obtain the red fluorescent material. Compared with the prior art, the novel oxide-based red fluorescent powder prepared by the invention can emit positive red light of which the central wavelength is 616nm under the excitation of 465nm blue light, and can be used for white light LED (Light Emitting Diode) luminescent devices and fluorescent ceramics.

The invention provides a novel underwater wet welding flux-cored wire and a preparation method thereof. The flux-cored wire comprises a metal sheath and a flux core, the flux core is prepared by sintering a flux core base material and a flux core additive; the flux core base material comprises the following raw materials in percentage by mass: 20-40% of rutile, 15-35% of fluoride, 2-7% of titanate, 3-10% of aluminum powder, 5-15% of manganese powder and 10-15% of composite nano metal oxide; the composite nano metal oxide at least comprises the following raw materials: nano aluminum oxide, nano zirconium dioxide, nano yttrium oxide, nano cerium oxide and nano lanthanum oxide; and the flux-cored additive is linear aliphatic epoxy resin. The specific mixed nano metal oxide powder is added into the flux-cored wire, grain refinement is achieved, a quenched martensite structure is reduced, the mechanical property of a weld joint is improved, meanwhile, the specific epoxy resin and the flux-cored base material are mixed, filled and sintered, a proper amount of carbon element is introduced while all raw material components of the flux-cored wire are dispersed uniformly and stably, and the welding quality of the flux-cored wire is improved. And metal is prevented from being oxidized in the welding process.

The invention provides a solid electrolyte membrane, a preparation method thereof and a solid-state battery. The solid electrolyte membrane comprises an inorganic filler, a polymer matrix and a lithium salt, wherein the inorganic filler comprises a dielectric conductive ion material and oxide particles; wherein the dielectric conductive ion material comprises a dielectric filler and a silane coupling agent which is coated on the outer surface of the dielectric filler and contains cyano groups, the dielectric filler contains transition metal elements, and the transition metal elements are Nb elements and / or Ta elements; the oxide particles comprise lanthanum oxide particles; the mass ratio of the dielectric conductive ion material to the oxide particles is (1-5): 1, and the ratio of the total mass of the inorganic filler to the mass of the polymer matrix is (10-50): 100. The solid electrolyte membrane provided by the invention has relatively high ionic conductivity, mechanical strength and structural stability, and can effectively improve the comprehensive performance of the solid lithium metal battery.

The invention relates to a dephosphorization material, a preparation method thereof and a dephosphorization method, belongs to the field of water treatment, and solves at least one of the problems of contradiction between adsorption capacity and structural stability, fast capacity fading, short service life, difficult recovery, higher cost and the like of the existing lanthanum-based dephosphorization material. The phosphorus removal material is a nano-porous carbon-supported lanthanum composite material, and comprises an amorphous nano-porous carbon matrix, an amorphous nano-porous carbon carrier, an amorphous nano-porous carbon carrier, and an amorphous nano-porous carbon carrier, and an active component embedded in situ in the nanoporous carbon matrix; wherein the active component comprises lanthanum oxide and / or lanthanum hydroxide. According to the invention, the adsorption capacity is high, the structure is stable, the attenuation of the adsorption capacity is delayed, the service life is prolonged, the cost is reduced, and the adsorbent can be recycled.

The invention discloses porous chlorine dioxide slow-release preservative paper and a preparation method thereof.The porous chlorine dioxide slow-release preservative paper comprises a paper base, a porous carrier is fixed to the paper base through oxidized starch glue, and sodium chlorite, an activating agent and a stabilizing agent are loaded on the porous carrier; the porous carrier is one of aluminum oxide, titanium oxide, cobalt oxide, zinc oxide, copper oxide, iron oxide, cerium oxide, zirconium oxide, nickel oxide, manganese oxide, praseodymium oxide and lanthanum oxide with a porous structure. The slow release of chlorine dioxide can be stably and effectively realized, the release period of chlorine dioxide is prolonged, and long-acting stable sterilization and disinfection effects are realized.

The invention relates to a nanofiber membrane and a preparation method and application thereof, the preparation method comprises the following steps: (1) mixing polyurethane, nano lanthanum oxide, a waterproof agent and a solvent to obtain a spinning solution; (2) performing electrostatic spinning on the spinning solution to obtain an electrostatic spinning membrane; and (3) spraying the after-finishing liquid on the electrostatic spinning membrane, and then carrying out heating treatment to obtain the nanofiber membrane. Polyurethane is stretched into superfine fibers through an electrostatic spinning technology, an ultrahigh porous membrane similar to a spider web is prepared, billions of nanopores are formed in per square centimeter of the porous membrane, so that the porous membrane has high air permeability and waterproof and moisture-permeable performance, fibers are bound through a fiber bonding point technology, and the fiber bonding point technology is adopted, so that the waterproof and moisture-permeable performance of the membrane is improved. Therefore, the fabric has excellent washing resistance. The nano lanthanum oxide heating functional particles are added, so that the nanofiber membrane is endowed with heating and heat storage functions, and the washing resistance of the fabric is further improved.

The invention relates to the technical field of catalysts, and particularly provides a methane dry reforming catalyst carrier, a catalyst and a preparation method, the carrier is composed of an alumina matrix, a cerium oxide and a lanthanum oxide doped in the alumina matrix, and an anionic surfactant, and the catalyst comprises the carrier and active metal nickel loaded on the surface of the carrier, the problems that a traditional ZrO2 or 3D-Ti-Ce-O carrier is high in cost and complex in process are solved through La / Ce coordinated regulation and control of oxygen vacancy concentration, improvement of metal dispersity by a surfactant and a low-cost coprecipitation process.

The application discloses a kind of corrosion-resistant aluminum alloy profiles and preparation method thereof, belong to aluminum alloy profile technical field.The application can ensure the strength of aluminum alloy profile by optimizing the composition of corrosion-resistant aluminum alloy, and has a positive effect on the corrosion resistance of aluminum alloy profile.In addition, the application forms a corrosion-resistant coating on the surface of the corrosion-resistant aluminum alloy substrate by laser cladding, which can significantly improve the corrosion resistance of the aluminum alloy profile while ensuring the application performance of the aluminum alloy profile.In the corrosion-resistant coating, nickel powder can enhance the resistance to pitting and intergranular corrosion, and improve the adhesion to the aluminum alloy substrate.Boron nitride can improve the surface acid resistance and wear resistance of the aluminum alloy profile, and block the corrosion channel.Lanthanum oxide and cerium dioxide have a synergistic effect, which can refine the surface grains, reduce the pores generated during the cladding process, improve the compactness of the coating, promote the compatibility with the aluminum alloy substrate, and ensure the appearance quality of the aluminum alloy profile.

The invention discloses a magnesium oxide supported catalyst, a preparation method and application in VOCs (volatile organic compounds) purification, and belongs to the field of volatile organic compound catalytic purification. Magnesium oxide is used as a carrier of the catalyst, and two modified materials are supported, one is a double-active-center material anchoring nickel single atoms and ruthenium clusters in a porous carbon-nitrogen framework, and the other is a double-active-center material anchoring nickel single atoms and ruthenium clusters in a porous carbon-nitrogen framework; and the other one is a defective carbonitride MXene intercalated hydroxyapatite nanosheet, and lanthanum oxide can be added as a cocatalyst. The preparation method comprises the following steps: sequentially loading the two modified materials on the magnesium oxide carrier, and carrying out ultrasonic dispersion, stirring, centrifuging, drying, calcining and the like, so that the active component and the carrier form strong interaction. According to the catalyst, through the synergistic effect of double active centers and the structural advantages of the modified material, the catalytic oxidation efficiency and stability of VOCs are remarkably improved, and the catalyst is suitable for purification treatment of industrial waste gas and volatile organic compounds in indoor air.

The invention relates to the field of laser cladding powder, in particular to wear-resistant and corrosion-resistant laser cladding powder and a preparation method thereof. The laser cladding powder is used for solving the problem that a cladding layer formed by existing laser cladding powder is poor in abrasion resistance and corrosion resistance. According to the laser cladding powder, the carbon nano tube loaded lanthanum-yttrium oxide powder and the copolymer coated titanium diboride powder are added, and the carbon nano tube and the lanthanum-yttrium oxide have a synergistic effect to refine grains, so that the corrosion resistance of a cladding layer is improved, and the carbon nano tube has good wear resistance; after the surface of the titanium diboride powder is coated with the copolymer, the dispersity of the titanium diboride is improved, a product decomposed by the copolymer reacts with the titanium diboride under the action of laser to generate titanium carbide, and the wear resistance of a cladding layer is enhanced; the laser cladding powder is suitable for prolonging the service cycle of a mold, can be used for surface strengthening of mine equipment parts, enhances the wear resistance and corrosion resistance of the mine equipment parts, reduces the maintenance frequency of the equipment, and can provide an effective solution for surface strengthening of parts in various industrial fields.

The present invention generally relates to a lanthanum oxide (La2O3)-reduced graphene oxide (rGO) nanocomposite-based humidity sensor device designed for high-performance detection across a wide relative humidity range of 11-95%. The sensor comprises an interdigitated electrode (IDE) substrate featuring a plurality of electrodes patterned on an insulating base. A sensing layer composed of a nanocomposite of La2O3 and rGO in the ratio of (x)La2O3+(1−x)rGO, where x ranges from 0.1 to 0.3, is deposited on the IDE using a drop-casting method. The slurry used for deposition includes ethanol as a solvent, and the coated substrate is subjected to mild heating at 60° C. to 80° C. for 1 to 2 hours to enhance adhesion and uniformity. The IDEs, made of gold, silver, or their composition, are connected to external leads interfaced with a measurement unit that enables real-time monitoring and quantification of humidity changes in the surrounding environment.

The invention relates to the field of photovoltaic technology, in particular to a solar cell and a preparation process thereof, a laminated cell and a photovoltaic module. The preparation process comprises the following steps: providing a silicon substrate, and preparing a passivation layer on the surface of the silicon substrate; printing a conductive material on the passivation layer; sintering and curing the conductive material to form an initial grid line; performing laser processing on the initial grid line; wherein the conductive material comprises metal powder, glass powder, an organic carrier, iridium oxide, lanthanum oxide and titanium dioxide; the metal powder comprises at least one of silver powder, nickel powder, copper powder, silver coated copper, silver coated nickel and aluminum powder. The iridium oxide, the lanthanum oxide and the titanium dioxide are simultaneously added into the conductive material adopted in the preparation process, so that the power attenuation of the module is reduced.

The invention belongs to the technical field of environmental barrier coatings, and particularly relates to an environmental barrier coating for an outer ring block of an engine and a preparation method of the environmental barrier coating. The environmental barrier coating sequentially comprises a silicon layer, a double-ytterbium silicate layer, a single-ytterbium silicate layer, a transition layer and an abradable layer from inside to outside, and each of the transition layer and the abradable layer comprises a mixed oxide containing aluminum oxide, lanthanum oxide, magnesium oxide and neodymium oxide. The mass ratio of aluminum oxide to lanthanum oxide to magnesium oxide to neodymium oxide in the transition layer is (50-70): (15-25): (10-15): (8-10), and the mass ratio of lanthanum oxide to magnesium oxide to neodymium oxide in the abradable layer is (40-60): (20-30): (15-20): (5-8). The environmental barrier coating has significantly improved abradability, corrosion resistance, life in high temperature service environments.

The invention discloses a PTC ceramic material and a preparation method thereof, and relates to the technical field of PTC, and the PTC ceramic material is prepared from the following components: 50-65 parts of barium titanate, 12-16 parts of lead tetraoxide, 0.1-0.3 part of yttrium oxide, 0.1-0.3 part of lanthanum oxide, 6-15 parts of modified silicon boride, 4-10 parts of aluminum oxide, 1-3 parts of ammonium polyacrylate, and 3-6 parts of polyvinyl alcohol. Through synergistic cooperation of a barium titanate main body and functional fillers such as modified silicon boride, leap-type improvement of the comprehensive performance of the PTC ceramic material is realized, on the basis of maintaining excellent PTC characteristics, the heat conductivity coefficient and the breaking strength of the material are effectively improved, the thermal shock resistance and the mechanical reliability are remarkably enhanced, and the PTC ceramic material has good application prospects. The method is especially suitable for the high-end application fields of automotive electronics, industrial control, high-power LED driving and the like.

Provided here are methods for producing a shaped metal-supported catalyst. One such method includes the steps of mixing a support hydroxide with an aqueous mixture of an active metal compound to form a malleable mixture of an active metal incorporated support hydroxide, passing the malleable mixture through a molding device to produce a shaped metal-supported wet catalyst; and drying and calcining the shaped metal-supported wet catalyst. The support hydroxide contains one or more of aluminium hydroxide, silica hydroxide, zirconia hydroxide, cerium hydroxide, titanium hydroxide, lanthanum hydroxide, gallium hydroxide, or niobium hydroxide. The active metal compound can be one or more of vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, technetium, and rhenium.

The invention discloses a copper-zinc-aluminum hydrogen production catalyst and a preparation method thereof, and relates to the technical field of hydrogen production catalysts, the copper-zinc-aluminum hydrogen production catalyst comprises the following components by weight: 30-35% of copper oxide, 12-15% of zinc oxide, 2-3% of nickel oxide, 5-7% of cerium dioxide, 3-4% of lanthanum oxide, 8-10% of alumina, and 25-40% of SBA-15 and MCM-41 composite mesoporous silicon carrier; wherein the SBA-15 and MCM-41 composite mesoporous silicon carrier has a hierarchical pore structure in which micropores and mesopores and macropores are combined, the pore diameter of the micropores is less than 2nm, the pore diameter of the mesopores is 2-50nm, and the pore diameter of the macropores is 50-100nm; the specific surface area of the catalyst is 300-500m / g. The catalyst has the effects of improving the activity and stability of the catalyst and prolonging the cycle life.

A method for dry reforming of methane (DRM) includes introducing and passing a hydrogen (H2)-containing feed gas stream through a reactor to contact the H2-containing feed gas stream with particles of a catalyst at a temperature of from 500° C. to 900° C. to form a reduced catalyst; introducing and passing a mixed feed gas stream comprising methane (CH4) and carbon dioxide (CO2) through the reactor to contact the mixed feed gas stream with the reduced catalyst at a temperature of from 500° C. to 1000° C. thereby converting at least a portion of the CH4 and CO2 to H2 / CO and regenerating the catalyst particles to form a regenerated catalyst and producing a residue gas stream leaving the reactor. The catalyst may be a fibrous silica lanthanum oxide (FSL) catalyst, and / or a nickel-containing FSL (Ni / FSL) catalyst.

A method for processing a plastic-derived oil may comprise contacting the plastic-derived oil with a catalyst to crack the plastic-derived oil to form a hydrocarbon product. The catalyst may comprise a metal oxide-loaded ZSM-5 zeolite comprising: ZSM-5 particles having a size of less than 100 nm, and one or more metal oxides chosen from iron oxide, lanthanum oxide, and cerium oxide. The one or more metal oxides may be disposed on the ZSM-5 particles.

The application discloses porous chlorine dioxide slow-release preservative paper and a preparation method thereof. The paper comprises a paper base, a porous carrier is fixed on the paper base through oxidized starch glue, sodium chlorite, an activator and a stabilizer are loaded on the porous carrier, and the porous carrier is one of porous structures of aluminum oxide, titanium oxide, cobalt oxide, zinc oxide, copper oxide, iron oxide, cerium oxide, zirconium oxide, nickel oxide, manganese oxide, praseodymium oxide and lanthanum oxide. The application can stably and effectively realize slow release of chlorine dioxide, prolong the release period of chlorine dioxide, and realize long-acting and stable sterilization and disinfection.

The invention discloses a copper-cobalt alloy / lanthanum hydroxide heterojunction catalyst and a preparation method and application thereof.The preparation method includes the steps that lanthanum-based perovskite oxide LaCu (1-x) CoxO3 is prepared through a sol-gel method, and x is equal to 0.1-0.5; laCu1-xCoxO3 is placed in hydrogen and argon mixed gas for reduction treatment, and the copper-cobalt alloy / lanthanum hydroxide heterojunction catalyst is obtained and used for preparing ammonia through electro-catalysis nitrate radical reduction. According to the preparation method, an in-situ dissolution strategy is adopted, a copper-cobalt alloy / lanthanum hydroxide strong interface coupled heterostructure is constructed, CuCo alloy nanoparticles provide high conductivity and rich active sites and form a heterostructure with La (OH) 3, the d-band center of the active sites is optimized through interaction of strong electrons, NO3 <-> adsorption and reaction intermediate stability are promoted, and the stability of the reaction intermediate is improved. The excellent electro-catalytic performance is realized.

The invention provides a dielectric filler-doped solid electrolyte, a lithium metal battery and a preparation method, the dielectric filler-doped solid electrolyte comprises a polyether matrix, and the polyether matrix is formed by dispersing a lithium salt and a dielectric filler, the dielectric filler is two or more of barium titanate (BaTiO3), strontium titanate (SrTiO3), zirconium oxide (ZrO2), hafnium oxide (HfO2), titanium oxide (TiO2), cerium oxide (CeO2), zinc oxide (ZnO), lanthanum oxide (La2O3), aluminum oxide (Al2O3), tantalum oxide (Ta2O5) and yttrium oxide (Y2O3).