77 results about "Tungsten Compounds" patented technology

The invention relates to the field of new material development and catalysis, and provides a method for preparing a functionalized triazine covalent organic framework material and application of the functionalized triazine covalent organic framework material in catalyzing cellulose to prepare low-carbon alcohol, and the method comprises the following steps: taking a monomer with at least two nitrile bonds as a raw material, taking tungsten salt as a catalyst, carrying out a reaction by adopting an ionothermal method, and after the reaction is completed, adding water to continue the reaction to obtain the functionalized triazine covalent organic framework material. And collecting a product to obtain the triazine covalent organic framework material loaded with the tungsten-containing compound, namely the functionalized triazine covalent organic framework material. The WOx / CTFs are prepared in one step, the steps are simple, the reaction conditions are relatively mild, the application requirements can be met, and W is tightly loaded on the CTFs. The functionalized covalent triazine framework material prepared by the invention can efficiently catalyze cellulose to prepare low-carbon alcohol.

The invention discloses a flexible self-supported lithium-sulfur battery positive electrode material containing a boron-containing vanadium-tungsten compound and a preparation method of the flexible self-supported lithium-sulfur battery positive electrode material. Flexible carbon cloth (CC) is used as a substrate, and the B-V-WS2 composite material with double doping of negative and positive ions of boron (B) and vanadium (V) is designed. Wherein the three-dimensional sheet structure of the 1T-phase WS2 exposes abundant active sites, so that the conversion efficiency of the polysulfide is further improved; the electronic structure and the catalytic activity of the WS2 are remarkably regulated and controlled by the double-doping advantage of B and V. The co-doping of B and V not only enhances the adsorption capacity of WS2 to polysulfide, but also accelerates the sulfur redox reaction kinetics, thereby effectively inhibiting the shuttle effect and improving the sulfur utilization rate. In addition, B and V doping stabilizes the 1T phase structure and inhibits the 1T phase structure from being converted into a 2H phase with thermodynamic stability in the cycle process, so that the stability of the battery in the cycle process is remarkably improved. By virtue of the advantages, excellent cycling stability and rate capability are realized after the material is applied to the lithium-sulfur battery.

The application discloses a high-nickel positive electrode material and a preparation method and application thereof, and belongs to the technical field of new energy sources. x Co y M z M´ w O2 and a porous base material and a gap-filling substance, wherein 0.80<=x<=0.98, 0.02<=y<=0.20, 0<=z<=0.06, 0<w<=0.02; x+y+z+w=1; M is at least one of Mn and Al, M´ is at least one of Y, Sr, La, B, Mg and Ti; the gap-filling substance exists in the inside of the pores and comprises a sintered product derived from an additive B, the additive B comprises a zirconium-containing compound and at least one of a tungsten-containing compound, an antimony-containing compound and a bismuth-containing compound. The high-nickel positive electrode material has excellent long cycle performance and rate performance. The application further provides a preparation method and application of the high-nickel positive electrode material.

A glass fiber and a method for producing the same are provided. The method includes: dissolving a tungsten compound into a first organic solution to form a tungsten compound sol; adding a sulfur source into the tungsten compound sol and stirring the sulfur source and the tungsten compound sol to form a tungsten sulfide gel; placing the tungsten sulfide gel in an environment having a temperature of between 600° C. and 1,200° C. for 4 hours to 6 hours to form tungsten sulfide powder; covering the tungsten sulfide powder on a plurality of surfaces of inorganic powder to form modified inorganic powder, mixing the modified inorganic powder into a glass raw material that is in a molten state; and drawing the glass raw material mixed with the modified inorganic particles to form into a plurality of glass fibers.

Provided is a method for preparing a diol. In the method, a saccharide and hydrogen as raw materials are contacted with a catalyst in water to prepare the diol. The employed catalyst is a composite catalyst comprised of a main catalyst and a cocatalyst, wherein the main catalyst is a water-insoluble acid-resistant alloy; and the cocatalyst is a soluble tungstate and / or soluble tungsten compound. The method uses an acid-resistant, inexpensive and stable alloy needless of a support as a main catalyst, and can guarantee a high yield of the diol in the case where the production cost is relatively low.

The invention belongs to the technical field of recycling of rare and noble metal secondary resources, and discloses a method for preparing a tungsten compound and chloroplatinate from a waste catalyst and application of the method. The method comprises the following steps: (1) firing and crushing the waste catalyst, (2) reacting the waste catalyst with acid, (3) filtering and discarding filtrate, (4) reacting the precipitate with ammonia water, filtering to obtain an ammonium tungstate solution, and retaining filter residues; (5) concentrating the ammonium tungstate solution, crystallizing, separating and drying to obtain an ammonium paratungstate finished product; and (6) reacting the filter residues retained in the step (4) with aqua regia to prepare chloroplatinate. And (7) firing the ammonium paratungstate at a high temperature to obtain tungsten trioxide. According to the method, tungsten and platinum can be effectively separated from the carrier, and the recovery rate of rare and precious metals is increased.

To provide a coating liquid for a positive electrode active material capable of suppressing elution of lithium contained in the positive electrode active material into the coating liquid and constituting an all-solid-state lithium ion secondary battery having stable battery performance, and to provide a method of manufacturing a positive electrode active material with a coating film.SOLUTION: A coating liquid for a positive electrode active material, which is used for forming a coating film made of a composite compound of lithium and tungsten on a positive electrode active material containing lithium, includes an aqueous solution containing a lithium compound and a tungsten compound, and has a lithium concentration in a range of more than 3. 0mol / L and 5. 3mol / L or less. A method for producing a positive electrode active material with a coating film having a coating film composed of a composite compound of lithium and tungsten on a surface of a positive electrode active material containing lithium includes attaching the above-described coating liquid for a positive electrode active material to the surface of the positive electrode active material, followed by drying.SELECTED DRAWING: None

The invention discloses an O-phase sodium ion battery positive electrode material modified by a sodium tungstate-magnesium tungstate composite coating layer and a preparation method of the O-phase sodium ion battery positive electrode material. Relates to the technical field of sodium-ion battery materials. According to the preparation method, an in-situ coating strategy is adopted, the raw materials capable of reacting with the sodium compound are added, residual alkali on the surface of the material is consumed, meanwhile, a stable and uniform coating layer is formed on the surface of the material, and the prepared O-phase sodium ion battery positive electrode material has excellent electrochemical performance; a tungsten-containing compound and a magnesium-containing compound are added in the secondary sintering process, the tungsten-containing compound and the magnesium-containing compound form magnesium tungstate in the sintering process, and meanwhile, the tungsten-containing compound and a sodium source on the surface of the material form sodium tungstate; a double-coating layer formed by magnesium tungstate and sodium tungstate prevents the material from being in contact with an electrolyte, reduces side reaction and improves the cycling stability, and meanwhile, sodium tungstate is preferentially decomposed in the primary cycle of the battery and serves as a sodium supplementing agent, so that the first effect of the material is remarkably improved.

The invention discloses a supported Ni-based alloy catalyst preparation method, which comprises: S1, dissolving a tungsten compound in water, loading on an Al2O3 carrier through an impregnation method, aging, drying, and roasting in air to obtain an intermediate; and S2, dissolving a nickel compound in water, loading the nickel compound on the intermediate through an impregnation method, aging, drying, roasting in air, and performing reduction treatment in an H2 atmosphere to obtain the catalyst. The catalyst is high in activity, good in selectivity and stability, simple in preparation method and low in cost.

The invention discloses a method for preparing a tungsten compound from artificial tungsten ore, which comprises the following steps: reacting sulfuric acid with the artificial tungsten ore to leach tungsten, and controlling the reaction conditions that the pH is 0.2-4.0, the temperature is 25-100 DEG C, the reaction time is 30 minutes to 6 hours, and the liquid-solid ratio is 1: 1-10: 1. And obtaining a metatungstate leaching solution after the reaction is completed, so that efficient leaching of tungsten is realized. And further performing purification and impurity removal on the solution to obtain a pure metatungstate solution. The pure metatungstate solution can be used for preparing different pure tungsten compound products such as solid metatungstate, phosphotungstic acid, ammonium phosphotungstate, tungsten oxide, ammonium metatungstate, ammonium paratungstate and tungstic acid. According to the technology, efficient leaching of tungsten under the mild condition can be achieved, high acid and high alkali are not needed in the whole process, and energy consumption and emission are greatly reduced; the obtained leachate is easy to purify to obtain a pure metatungstic acid solution, and the pure metatungstic acid solution can be directly used as a platform intermediate to flexibly prepare various tungsten chemicals.

The application discloses a preparation method of DL-tartaric acid, which uses maleic anhydride as raw material, uses WO3-SiO2-ZrO2 solid acid as a catalyst, and is prepared through catalytic oxidation reaction under the condition of an oxidant. The catalyst is prepared through the following steps: mixing and dissolving a tungsten-containing compound and a zirconium-containing compound; adding silica sol, a surfactant and a precipitant to form a gel, and then performing filtration, washing and calcination to obtain the catalyst. Since the active species and the carrier in the catalyst have strong interaction, the recycling rate of the catalyst is high, so that the residual amount of heavy metal tungsten in the prepared tartaric acid crystal is effectively reduced, the DL-tartaric acid yield is still high during recycling, the production cost of the tartaric acid is reduced, and the catalyst is suitable for large-scale production.

The invention relates to tungsten-doped tin dioxide nano-powder, a preparation method thereof and application of the tungsten-doped tin dioxide nano-powder in a semiconductor type gas sensitive element. The preparation method of the tungsten-doped tin dioxide nano-powder comprises the following steps: dissolving a soluble tungsten compound and a soluble tin compound in an aqueous solution containing a surfactant, and adding a complexing agent to obtain a uniform metal ion mixed solution; adding a precipitant into the mixed solution under a stirring condition, and adjusting the pH value to 2-6 to precipitate the metal hydroxide precursor; performing aging, solid-liquid separation, washing and drying on the precipitate to obtain precursor powder; adding a dispersing agent into the precursor powder, and uniformly mixing; and calcining to obtain the tungsten-doped tin dioxide nano powder. The tungsten-doped tin dioxide nano-powder can be used for preparing a semiconductor type gas sensor, an ultraviolet detector, a lithium ion battery negative electrode material, a catalyst or a transparent conductive film.

There is provided particles of an alumina-based thermally conductive oxide obtained by firing a raw material mixture containing an aluminum raw material, the raw material mixture containing no boron compound. The aluminum raw material is at least one selected from the group consisting of boehmite and aluminum hydroxide. The raw material mixture contains a glass frit and may further contain an oxide raw material. The oxide raw material is at least one selected from the group consisting of a boron compound, a titanium compound, a phosphorus compound, a tungsten compound, and a bismuth compound. A content of the glass frit in the raw material mixture is in a range from 0.5 parts by mass to 5 parts by mass, to 100 parts by mass of the aluminum raw material.

The utility model discloses a tungsten compound purification device which comprises a frame body, two ends of the frame body are fixedly connected with fixing rings, the fixing rings are internally provided with limiting grooves, a tank body is arranged between the limiting grooves, the inner wall of one side of the tank body is movably connected with a rotating rod, one end of the rotating rod penetrates through the tank body and is in key connection with a driven belt wheel, and the other end of the rotating rod is connected with the driven belt wheel. A power assembly connected with the driven belt wheel is arranged at the bottom of the frame body, two cross-shaped supports are fixedly connected to the outer side of the rotating rod, a plurality of stirring plates are movably connected between the two cross-shaped supports, and a fixing plate is fixedly connected to the inner wall of the top of the tank body. According to the stirring tank, a mixed solution in the tank body can be stirred in multiple directions through the stirring plates, so that the mixed solution is fully and uniformly mixed, meanwhile, the mixed solution can be further dispersed through the fixing plate, and the tank body can rotate in the fixing ring more smoothly through the rotating column.

Provided is a catheter that is not susceptible to deterioration even if stored for a long period of time. A catheter tip comprising: a resin having an ester bond and / or an amide bond; a tungsten-containing compound; and a hydrolysis inhibitor.

A method of manufacturing a positive electrode active material for a lithium ion secondary battery includes a mixing step of mixing a lithium-nickel composite oxide which is a starting material with a tungsten compound powder without lithium, while being heated, to prepare a tungsten mixture, and a heat treatment step of heat-treating the tungsten mixture. The lithium-nickel composite oxide contains lithium (Li), nickel (Ni), and an element M (M), wherein, the element M is at least one element selected from Mn, V, Mg, Mo, Nb, Ti, Co, and Al, wherein, in the starting material, a ratio of number of tungsten atoms to a total number of nickel atom and the element M atoms contained in the lithium-nickel composite oxide is 0.05 at. % or more and 3.00 at. % or less.

The present application relates to the field of ethylene glycol preparation, and discloses a method for preparing ethylene glycol. The method comprises the following steps: in the presence of water, a polyhydroxy compound and hydrogen are reacted with a catalyst; the catalyst comprises a metal / COFs material and a tungsten-containing compound; wherein the COFs material in the metal / COFs material is selected from at least one of nitrogen-containing organic framework materials; and the metal in the metal / COFs material is selected from at least one of noble metal elements and nickel elements. The method for preparing ethylene glycol has high ethylene glycol selectivity and yield; and the catalyst used in the method has good cycle stability.

The invention relates to the technical field of heavy oil hydrocracking, and particularly discloses a self-sulfuration oil-soluble molybdenum-tungsten composite catalyst and a preparation method and application thereof.The preparation method comprises the following steps that S1, a sulfuration agent is added into a mixture containing a molybdenum-containing compound and a tungsten-containing compound, stirring reaction is conducted at the temperature of 50-120 DEG C, and a thiomolybdate and thiotungstate mixture is obtained; and S2, stirring the mixture of thiomolybdate and thiotungstate prepared in the step S1 and a long-carbon-chain amide compound at 30-150 DEG C to react, and distilling the reaction product to remove water, thereby obtaining the self-sulfuration oil-soluble molybdenum-tungsten composite catalyst. According to the preparation method, crystallization and washing are not needed, the self-vulcanized oil-soluble molybdenum-tungsten composite catalyst is obtained by directly reacting with the long-carbon-chain amide compound, the prepared product is high in yield, and the problem of loss of effective metal components caused by washing can be avoided.

Provided is an alumina-based thermally conductive oxide which has not only an excellent thermal conductivity but also excellent chemical resistance, water-fastness, and electrical insulation property, while exhibiting a satisfactory kneadability (miscibility) into a resin and being capable of producing materials and articles, such as a resin composition, having an excellent shapability. Specifically, the present invention is an alumina-based thermally conductive oxide which is obtained by firing a starting material mixture that contains an aluminum starting material. The aluminum starting material is at least one selected from the group consisting of boehmite, aluminum hydroxide, and alumina; the starting material mixture further contains a boric acid compound and an oxide starting material such as a tungsten compound; and the content of the boric acid compound in the starting material mixture is 0.1 to 5 parts by mass, and the content of the oxide starting material in the starting material mixture is 0.1 to 20 parts by mass each based on 100 parts by mass of the aluminum starting material.

The application discloses a tungsten-boron stainless steel composite material and a preparation method thereof, and relates to the technical field of shielding materials, which comprises a boron-tungsten compound, wherein the boron-tungsten compound particles are dispersed in a stainless steel matrix. The tungsten-boron stainless steel composite material has high density of the dispersed boron-tungsten compound, tungsten is a heavy metal element with stable chemical properties and high gamma shielding efficiency; boron has a high neutron absorption cross section for medium and low energy neutrons, and is a high-efficiency neutron shielding component; the tungsten boride materials of various components have good compatibility with the stainless steel; at the sintering and other hot working temperatures of the stainless steel, the tungsten boride materials do not react with the stainless steel matrix; the boron-tungsten compound is dispersed in the stainless steel matrix, and the composite material prepared by the method has better neutron shielding performance and gamma shielding performance than traditional boron stainless steel.

Manufacturing process for tungsten-doped cobalt tetroxide, comprising the following steps: S1: Dissolving a tungsten-containing compound and a molybdenum-containing compound in an alkaline liquid to obtain a mixed solution; S2: simultaneous addition of the mixed solution, a cobalt salt solution and a complexing agent to an alkaline solution to react until a reaction material reaches a target particle size; followed by aging and carrying out a solid-liquid separation (SLS) to obtain a precipitation, wherein the alkaline solution comprises the mixed solution and ammonia water; S3: Roasting the precipitate in an oxygenated atmosphere to obtain a roasted material; and S4: Soaking the roasted material in a sodium sulfide solution, adjusting the pH of the solution to 7.2 to 8.5, and performing SLS to obtain the tungsten-doped cobalt tetroxide.

A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The positive electrode includes a positive electrode material including particles of a composite oxide containing lithium and a metal Me other than lithium, and a tungsten compound attached to a surface of the particles. The metal Me contains at least nickel. The nonaqueous electrolyte includes an unsaturated sultone compound.

A thermally conductive particle containing at least an aluminum raw material, a zinc raw material, and a fired product obtained by firing other raw materials than the aluminum raw material and the zinc raw material, the content of the zinc raw material being 25-70 parts by mass (inclusive) per 100 parts by mass of the aluminum raw material, and the content of the zinc raw material being 70-90 parts by mass (inclusive) per 100 parts by mass of the aluminum raw material. The other raw material contains at least one compound selected from the group consisting of a boron compound, a tungsten compound, a titanium compound, a bismuth compound and a fluorine compound, the content of the other raw material is 0.05-20 parts by mass per 100 parts by mass of the aluminum raw material, and predetermined conditions are satisfied.

The invention provides a modified evaporation boat and a preparation method thereof, and belongs to the technical field of evaporation boats, the modified evaporation boat comprises a boat body and a modified layer, the boat body is provided with an evaporation tank, and the modified layer is laid at the bottom of the evaporation tank; wherein the raw material of the modified layer comprises a tungsten compound. The preparation method of the modified evaporation boat comprises the following steps: preparing modified slurry containing a tungsten compound; and coating the modified slurry at the bottom of an evaporation tank of a boat body, and drying to form a modified layer, thereby obtaining the modified evaporation boat. According to the modified evaporation boat provided by the embodiment of the invention, the molten liquid can be effectively spread and can be stably evaporated for a long time, so that the performance and the appearance of an evaporation product can be improved.

The present invention discloses a coated steel sheet for hot stamping and an aqueous surface treatment liquid used therein. The coated steel sheet for hot stamping comprises a coated steel sheet and a composite film layer formed by applying the aqueous surface treatment liquid to the coated steel sheet. The coated steel sheet comprises a substrate and an Al or AlSi coating layer disposed on one or both sides of the substrate. The composite film layer contains an aqueous anionic polymer resin A, a tungsten-containing compound B, a zinc-containing compound C, a boron-containing compound D, a water-soluble thickener E, and an aqueous surface improvement additive F. By designing the composition of the aqueous surface treatment liquid and applying it to the surface of the coated steel sheet, the present invention ensures that the coated steel sheet for hot stamping has good high-temperature lubricity during hot stamping processing, improves the processing performance of the coated steel sheet for hot stamping, reduces wear on the die surface of hot stamping dies, reduces the frequency of die repairs, and improves production efficiency.

A lithium secondary battery according to an embodiment of the present invention comprises: a positive electrode containing a first positive electrode active material; the first positive electrode active material includes a lithium-nickel metal oxide particle and a coating layer disposed on a surface of the lithium-nickel metal oxide particle and including at least one selected from the group consisting of a lithium-phosphorus-containing compound, a lithium-sulfur-containing compound, a lithium-tungsten-containing compound, and a lithium-aluminum-containing compound, and the negative electrode includes a silicon-based active material. The lithium secondary battery according to the present invention can improve high-temperature life characteristics and fast charge / discharge life characteristics, and can reduce the amount of gas generated in the battery.

Product containing, on its surface and / or in its core, an additive selected from: - phosphorus compounds other than glasses and glass-ceramics, - tungsten compounds other than glasses and glass-ceramics, molybdenum compounds other than glasses and glass-ceramics, - iron in metallic form, aluminum in metallic form, silicon in metallic form, and mixtures thereof, silicon carbide, - boron carbide, silicon nitride, boron nitride, - glasses containing phosphorus and / or iron and / or tungsten and / or molybdenum, - glass-ceramics containing phosphorus and / or iron and / or tungsten and / or molybdenum, - and mixtures thereof, and having, excluding the additive, the following chemical analysis, in mass percentages based on oxides: - Cr2O3 - 2%, and - Cr2O3 + Al2O3 + CaO + ZrO2 + MgO + Fe2O3 + SiO2 + TiO2 ≥ 90%, and - Cr2O3 + Al2O3 + MgO ≥ 60%.

The positive electrode active material for a lithium secondary battery according to embodiments of the present invention comprises lithium-nickel metal oxide particles, wherein the lithium-nickel metal oxide particles have the form of secondary particles in which a plurality of primary particles are aggregated, and wherein the lithium-nickel metal oxide particles comprise a tungsten compound at the interface between the primary particles, and the tungsten content measured by energy-dispersive X-ray spectroscopy (EDS) satisfies Equation 1, thereby increasing the surface stability of the positive electrode active material and improving high-temperature performance.

The present invention discloses a WO3-SiO2-ZrO2 solid acid catalyst and a preparation method thereof. In this catalyst, the loading amount of WO3 is 5.0-15.0 wt%, the loading amount of SiO2 is 2.5-20.0 wt%, and the balance is ZrO2. The preparation method is as follows: a tungsten-containing compound and a zirconium-containing compound are mixed and dissolved; then silica sol, a surfactant and a precipitant are added to form a gel, which is then obtained through filtration, washing and calcination. Through the gel adsorption effect, the solid acid catalyst enables a strong interaction between the active species and the carrier, thereby improving the recycling utilization rate of the catalyst; it is synthesized in one step by a simple and easy precipitation method, and the raw materials are cheap and easily available; as a heterogeneous catalyst, it is easy to separate, and can effectively reduce the residual amount of heavy metal tungsten in tartaric acid crystallization. It still has a high DL-tartaric acid yield during recycling, reducing the production cost of tartaric acid; it is suitable for large-scale production.

This agricultural heat-shielding film comprises: an intermediate layer 2 that contains first resin; an outer layer 3 that contains second resin and is provided on one surface of the intermediate layer 2; and an inner layer 4 that contains third resin and is provided on the other surface of the intermediate layer 2. Endothermic material 5 containing a tungsten-containing compound is dispersed in the outer layer 3 and the inner layer 4.