306 results about "Oxygen compound" patented technology

Provided is a laminate capable of electrolyzing an oxygen compound gas represented by CO2 with high conversion efficiency and suppressing deterioration in electrolytic performance. In this laminate having a structure in which an electrolyte layer is sandwiched between an anode catalyst layer and a cathode catalyst layer, a perovskite oxide and CuFe2O4 are contained in the cathode catalyst layer, and the content of CuFe2O4 in the cathode catalyst layer is at least 10 mass%.

Electrical power derived from a renewable energy source is used to perform water electrolysis to produce oxygen and hydrogen. A flue gas and heat are produced from combustion of a fuel using at least a portion of the oxygen generated by electrolysis. A feed stream including hydrocarbon oil is hydroprocessed using the generated heat and at least a portion of the hydrogen generated by electrolysis to produce a product including a saturated hydrocarbon. At least a portion of the flue gas is hydrogenated using at least a portion of the hydrogen generated by electrolysis to produce a second product stream including a hydrocarbon, an oxygenate, or both.

The invention discloses an argillaceous sandstone uranium ore leaching method and device based on a recyclable activation material, and relates to the technical field of uranium ore resource development. The preparation method of the recyclable activated material comprises the following steps: adding WS2 and Fe3O4 into an aqueous solution, uniformly stirring, adding a boron-containing compound, a fluorine-containing precursor aqueous solution and a nitrogen-oxygen-containing compound, uniformly stirring, heating, stirring for reaction, filtering, washing and drying to obtain a precursor; and calcining the precursor in a protective atmosphere to obtain F / O co-doped h-BN / WS2 / Fe3O4 which is used as a recoverable activation material. The obtained recoverable activated material has good catalytic performance, can be widely applied to preparation of a catalyst for leaching uranium from argillaceous sandstone uranium ore, and can generate strong turbulence, secondary circulation and near-wall shear force for high-viscosity ore pulp and efficiently excite the catalytic activity of a piezoelectric material in cooperation with the device provided by the invention.

The present invention relates to a process for producing a jet fuel composition (12), the process comprising: a) Processing an oxygenate stream (1) in an Oxygenate-to-Olefin (OtO) unit (2) to produce an olefin stream (3); b) Separating the olefin stream (3) in a fractionation unit (4) into at least a C2-olefin-rich stream (5), a C3-olefin-rich stream (6) and a C4+-olefin-rich stream (7); c) Dimerizing at least a portion of ethylene contained in the C2-olefin-rich stream (5) to C4-olefins in a dimerization unit (20), thereby producing a dimerized product stream (21); d) Processing an oligomerization feed (8) comprising at least a portion of the C4+-olefin-rich stream (7) and at least a portion of the dimerized product stream (21) in an oligomerization unit (9) to produce an oligomerized olefin stream (10); e) Hydrogenating at least a portion of the oligomerized olefin stream (10).

The present invention relates to a process for producing a jet fuel composition (12), the process comprising: a) Processing an oxygenate stream (1) in an Oxygenate-to-Olefin (OtO) unit (2) to produce an olefin stream (3); b) Processing an oligomerization feed (8) comprising at least a portion of the olefin stream (3) in an oligomerization unit (9) to produce an oligomerized olefin stream (10); c) Hydrogenating at least a portion of the oligomerized olefin stream (10); wherein a fraction of the oligomerized olefin stream (10) is withdrawn as a recycle stream (40a, 40b) and passed to a steamcracking unit (41) to produce a steamcracking product stream (42), wherein at least a portion of the steamcracking product stream (42) is included in the oligomerization feed (8).

The present invention relates to a process for producing a jet fuel composition (12), the process comprising: a) Processing an oxygenate stream (1) in an Oxygenate-to-Olefin (OtO) unit (2) to produce an olefin stream (3); b) Providing an oligomerization feed (8) comprising at least a portion of the olefin stream (3) and at least a portion of an external C4+-olefin stream (30) comprising C4+-olefins; c) Processing the oligomerization feed (8) in an oligomerization unit (9) to produce an oligomerized olefin stream (10); d) Hydrogenating at least a portion of the oligomerized olefin stream (10).

The invention provides a catalyst for synthesizing N-methylaniline and a preparation method thereof, the catalyst comprises an active component, a carrier and an auxiliary agent, the active component comprises oxygen-containing compounds of copper, zinc and chromium, the carrier is gamma-alumina subjected to surface hydroxylation treatment, and the auxiliary agent is a cerium-molybdenum bimetallic alloy. The preparation method comprises the following steps: loading the active component on the hydroxylation carrier through ultrasonic impregnation, drying, further loading the cerium-molybdenum auxiliary agent, and carrying out reduction alloying and roasting activation to form the composite catalyst. The catalyst is a regular cylinder, has the diameter of 4-6mm and the length of 4-6mm, has an optimized pore structure and surface properties, and is suitable for methylation reaction of aniline and methanol. According to the method, the dispersity of active components is improved through modified chromic oxide, the mass transfer efficiency is enhanced through a hydroxylation carrier, the synergistic catalysis effect of cerium-molybdenum alloy is combined, the reaction activity and selectivity are remarkably improved, meanwhile, side reactions are inhibited, the stability is enhanced, and the method can be widely applied to industrial production of N-methylaniline.

The invention provides a positive plate, a battery and electronic equipment. The positive plate comprises a positive current collector and a positive active layer positioned on at least one surface of the positive current collector; the positive electrode active layer comprises a first positive electrode active layer and a second positive electrode active layer which are sequentially stacked in a direction far away from the positive electrode current collector; the first positive electrode active layer comprises a first positive electrode active material, and the first positive electrode active material comprises lithium manganese iron phosphate and a lithium oxide compound; the second positive electrode active layer comprises a second positive electrode active material, and the second positive electrode active material comprises a lithium oxide compound and nickel cobalt lithium manganate. When the positive plate is applied to the battery, the battery is not easy to generate gas during high-temperature storage, so that the safety performance of the battery is improved.

The invention discloses a co-catalytic cracking method for biomass oil and heavy oil, which comprises the following steps: firstly, adding alkaline earth metal salt and a ligand compound into water, mixing, heating to 70 DEG C, reacting at a constant temperature, and filtering to obtain an alkaline earth metal complex; adding an alkaline earth metal complex into the biomass oil, stirring and mixing, reacting the alkaline earth metal complex serving as a deoxidizing agent with phenolic substances in the biomass oil to form a metal-phenol complex, adding an extracting agent after the reaction, uniformly mixing, dissolving the metal-phenol complex into the extracting agent, and layering the solution; and uniformly mixing the treated layered solution with heavy oil, and carrying out catalytic cracking under the action of a catalyst. The alkaline earth metal complex not only can remove oxygen-containing compounds in the biomass oil, but also can effectively resist heavy metal pollution of heavy oil and strengthen the activity of the catalyst, so that the light oil yield is remarkably increased, the proportion of coke to dry gas is reduced, the formation of coke is reduced, and the economical efficiency and environmental friendliness of the catalytic cracking process are greatly optimized.

The invention relates to the field of oxygen-containing compound adsorption and removal, and discloses a molecular sieve adsorbent as well as a preparation method and application thereof. The method comprises the following steps: mixing a silicon source and an aluminum source, carrying out preliminary crystallization, aging and crystallizing in a gel-like mother solution containing the silicon source and the aluminum source to obtain an FAU molecular sieve seed crystal, and carrying out mixed crystallization on the FAU molecular sieve seed crystal, various molecular sieves and the aluminum source, forming and roasting the obtained molecular sieve mixed crystal, the sodium metaaluminate modified carbon nanotube, an aluminum source and an auxiliary component; and finally, carrying out surface modification by adopting anhydrous amino acid ionic liquid. The molecular sieve adsorbent has a hierarchical pore structure composed of abundant micropores and mesopores and a relatively high specific surface area, the adsorption performance is improved through modification of the amino acid ionic liquid and addition of the modified carbon nanotubes, and when the molecular sieve adsorbent is used for adsorbing and removing oxygen-containing compounds in olefins, the molecular sieve adsorbent shows a relatively good removal rate and a relatively long adsorption period, and the molecular sieve adsorbent has relatively good application prospects. The production cost can be effectively reduced, and the method has high production and application value.

A silicon composite material and a preparation method, a negative electrode plate, a battery, and an electrical apparatus. The silicon composite material comprises a silicon-based material and a flexible material, wherein the hardness of the flexible material is less than the hardness of the silicon-based material. The silicon-based material comprises at least one of elemental silicon, a silicon-oxygen compound, a silicon-carbon composite, a silicon-nitrogen composite, and a silicon alloy. The flexible material is located on at least part of the surface of the silicon-based material. By means of the combination of the flexible material and the silicon-based material, the risk of a current collector being crushed during the preparation of an electrode plate can be reduced, and the compacted density of the electrode plate can be improved, thus increasing the energy density of a battery.

The invention discloses a closed all-solid-state lithium-oxygen battery, an oxidation composite positive electrode and a preparation method, the closed all-solid-state lithium-oxygen battery comprises an oxygen-containing compound and a catalyst, the oxygen-containing compound comprises one or more of Li2O, Li2O2, KO2, Li2CO3, Li3PO4 and LiNO3, and the catalyst comprises a transition metal oxide, a noble metal and an alloy thereof, a carbon-based material, a metal organic framework and a derivative thereof, a monatomic catalyst and a composite material. The catalyst comprises one or more of oxygen-containing compounds and one or more of non-metal catalysts, the mass ratio of the oxygen-containing compounds is 50%-80%, and the mass ratio of the catalyst is 20%-50%. According to the invention, the oxidation-reduction reaction of oxygen is immobilized, oxygen is not generated, and the problems of complex structure and low actual energy density of an open type lithium air battery are solved; the solid electrolyte is used for replacing electrolyte, so that the potential safety hazard of electrolyte permeation is solved, the electrochemical performance is improved, and a new path is provided for the ultrahigh-specific-energy all-solid-state battery.

The present invention relates to a process for producing a jet fuel composition (12), the process comprising: a) Processing an oxygenate stream (1) in an Oxygenate-to-Olefin (OtO) unit (2) to produce an olefin stream (3); b) Separating the olefin stream (3) in a fractionation unit (4) into at least a C2-olefin-rich stream (5), a C3-olefin-rich stream (6) and a C4+-olefin-rich stream (7); c) Processing an oligomerization feed comprising a first oligomerization feed stream (8a) containing at least a portion of the C3-olefin-rich stream (6) and a second oligomerization feed stream (8b) containing at least a portion of the C4+-olefin-rich stream (7) in an oligomerization unit (9) to produce an oligomerized olefin stream (10); d) Hydrogenating at least a portion of the oligomerized olefin stream (10); wherein the oligomerization unit (9) comprises at least a first reaction zone (9a), and a second reaction zone (9b) downstream of the first reaction zone (9a); wherein the first oligomerization feed stream (8a) is introduced into the oligomerization unit (9) at a position upstream of the first reaction zone (9a), and the second oligomerization feed stream (8b) is introduced into the oligomerization unit (9) at a position downstream of the first reaction zone (9a) and upstream of the second reaction zone (9b).

Processes for dehydrogenating normal paraffins derived from natural oils to olefins are described. The feed stream is passed through an adsorption bed comprising alkaline or alkaline earth cation exchange X-Zeolite to removes essentially all oxygenates and aromatics from the feed stream. One or more additional adsorbent beds having different adsorbents can also be included to remove additional oxygenates and aromatics as well as sulfur compounds, nitrogen compounds, phosphorous compounds, or combinations thereof. The dehydrogenation process can be part of a process for producing alkylbenzenes from natural oils.

The utility model discloses a small nitrogen oxygen compound detection device of gas detection technical field, including mobile detection box, the inside one side of mobile detection box is installed with detection chamber, the outside wall center position of one side of detection chamber is installed with motor, and its structure is reasonable, the utility model discloses the mounting bracket on two groups of purification filter board is by the guiding seat with the sliding mode and is connected in the guiding groove on fixed base, and the mounting plate on fixed base is installed with the exhaust fan of corresponding installation up and down, according to the breather hole on detection chamber, make its air inlet on mobile detection box access to small nitrogen oxygen compound, and the exhaust fan extracts inward, to a certain amount, and the motor controls the baffle and seals the breather hole, reaches the partial small nitrogen oxygen compound existence detection chamber, and can be detected and handled by gas detection sensor, after the small nitrogen oxygen compound of detection is finished, and can be discharged by the exhaust fan to the air outlet.

The invention discloses a catalyst for preparing a C4 + oxygen-containing compound through catalytic conversion of ethanol and a preparation method and application thereof, and belongs to a catalyst technology. The catalyst is composed of a carrier and an active component, the carrier is spinel metal oxide AB2O4, and has high specific surface area, rich pore structure and uniform particle size; the active component is high-dispersion metal M, and the metal M accounts for 0.1-5% of the total mass of the catalyst. The preparation method of the catalyst comprises the following steps: preparing the carrier, and anchoring the active component on the carrier in a highly dispersed manner in a molten salt in-situ loading manner, so that the active component of the catalyst and the carrier form a strong synergistic catalysis effect, and the catalyst has the characteristics of high activity and high stability. Under the reaction conditions that the pressure is 3.0 MPa, the temperature is 250 DEG C and the air speed is 3.0 h <-1 >, the selectivity for preparing the C4 < + > oxygen-containing compound through ethanol conversion is as high as 97.6%, and obvious inactivation can be avoided after 200 hours of stable operation.

The invention refers to the method for producing gasolines or aromatic compound concentrates, where three streams are used as feedstock, one of which includes hydrocarbon fraction, the second stream includes oxygenate, the third stream includes olefin-containing fraction with one or more olefins selected from the group consisting of ethylene, propylene, normal butylenes, isobutylene, in total from 10 to 50 wt %, and where three reaction zones filled with zeolite catalyst are used, with distribution of hydrocarbon fraction and oxygenate to the first reaction zone, and with olefin-containing fraction distributed over the three reaction zones, with the third stream mass fraction distributed to the final reaction zone higher than the mass fraction of the third stream distributed to each of the previous reaction zones. This method allows to increase the yield of C5+ hydrocarbons, enhance n-hexane and n-heptane conversion, reduce benzene content in the product, avoid recycling of gaseous products and decrease consumption of oxygenates. 1 independent claim and 35 dependent claims in the formula, 12 examples, 7 tables.

The application provides a method for removing oxygen-containing compounds from Fischer-Tropsch naphtha, which comprises the following steps: (1) reacting Fischer-Tropsch naphtha, a catalyst, isopropyl alcohol and glycol in a stirring reactor, and then standing and separating; (2) extracting the upper hydrocarbon phase after standing with an extractant to obtain an extraction phase and a raffinate phase; (3) recovering the solvent in a solvent recovery column, obtaining oxygen-containing compounds at the top of the column, and recycling the solvent obtained at the bottom of the column as the extractant; (4) washing the raffinate phase with water to obtain Fischer-Tropsch naphtha from which the oxygen-containing compounds are removed and washed water, recycling the washed water to the water washing column for water washing, and recycling the product at the bottom of the water recovery column as the extractant; the extractant is a mixture of ester compounds and glycol compounds, and the content of the glycol compounds is 40-70%; and the method can reduce the oxygen-containing compounds in the Fischer-Tropsch naphtha to 5 ppm, and the oil recovery rate reaches more than 95%.

A process for producing a sustainable aviation fuel component is described, wherein the process comprises two integrated sub-processes A and B. The sub-processes A comprises providing a renewable feedstock comprising triglycerides, hydrolyzing the triglycerides into free fatty acids which are subjected to a hydrocracking to produce a first hydrocarbon intermediate A. In the sub-processes B of the integrated process, any light hydrocarbons, oxygenates and glycerol released in the sub-processes A are refined into further hydrocarbons, hydrocarbon intermediate B, which together with hydrocarbon intermediate A are isomerized and a sustainable aviation fuel or sustainable aviation fuel component is provided.

The invention relates to the technical field of adsorption materials, in particular to modified adsorption resin for a high-impurity n-heptane raw material and a purification method of the modified adsorption resin. The resin is prepared from the following raw materials: polystyrene-divinylbenzene resin microspheres, chloromethyl ether, 1, 3, 5, 7-tetra (4-chloromethylphenyl) adamantane, 2-methylimidazole and the like. During preparation, polystyrene-divinylbenzene resin microspheres are subjected to chloromethylation to introduce active sites, adamantine crosslinking to construct rigid pore channels, and imidazolyl functionalization to introduce specific adsorption sites. During purification, dynamic adsorption is performed after pretreatment of two stages of adsorption columns, mild regeneration is performed by using an ethanol-acetone mixed solution, isoparaffin, aromatic hydrocarbon and oxygen-containing compounds can be synchronously removed, high-purity n-heptane is obtained, the resin regeneration performance is excellent, and the whole process is easy to industrialize.

A catalyst composition and method for treating a feed including oxygen is provided. The catalyst composition includes a zeolite and a coprocessing material including an oxide of at least one of magnesium (Mg), vanadium (V), and cerium (Ce).

The present application relates to the technical field of Fischer-Tropsch synthesis wax analysis chemistry, and in particular to a method for detecting oxygen-containing compound components in Fischer-Tropsch synthesis wax by using solid-phase microextraction and comprehensive two-dimensional gas chromatography-mass spectrometry. The method comprises the following steps: first, performing solid-phase microextraction on a to-be-tested wax sample to obtain an extract rich in oxygen-containing compound components; and then using comprehensive two-dimensional gas chromatography-mass spectrometry to qualitatively determine the composition of the oxygen-containing compound components contained in the extract. In the method, the content of the oxygen-containing compound components is less than or equal to 7 wt% based on the total weight of the Fischer-Tropsch synthesis wax. The method has the characteristics of high throughput, high sensitivity and high accuracy, and solves the problems of difficult analysis and separation and difficult qualitative determination of alcohol, aldehyde, ketone, acid, ester and other oxygen-containing compound components in Fischer-Tropsch synthesis wax.

The application discloses a deoxygenation method and a deoxygenation adsorbent for Fischer-Tropsch synthesis oil, and relates to the field of Fischer-Tropsch synthesis oil processing.The deoxygenation method comprises the following steps: introducing Fischer-Tropsch synthesis oil into an adsorption tower filled with the deoxygenation adsorbent, and removing oxygen-containing compounds.The deoxygenation adsorbent is prepared by the following method: step S1, adding an aluminum source, a silicon source and a template agent into a lye, and performing first aging at room temperature; continuously adding the aluminum source and the silicon source, and performing second aging at room temperature; performing crystallization at a predetermined temperature; and filtering and washing the product to obtain a molecular sieve; and step S2, immersing the molecular sieve in a lye, adding a template agent into the lye, and then performing crystallization; and filtering, washing, drying and calcining the product after the crystallization to obtain the deoxygenation adsorbent.The deoxygenation method for Fischer-Tropsch synthesis oil provided by the application significantly improves the quality of Fischer-Tropsch synthesis oil and the economic benefits of subsequent processing by preparing a deoxygenation adsorbent with multiple levels of pores and combining the adsorption tower.

The application provides a method for improving the yield of oxygen-containing compounds in low-rank coal-derived soluble matters, and belongs to the technical field of low-rank coal pretreatment, and comprises the following steps: first, performing ozone oxidation pretreatment on low-rank coal to obtain modified low-rank coal; using cobalt acetate, copper acetate and iron acetylacetonate as a cobalt source, a copper source and an iron source respectively, using hydrazine hydrate as a strong reducing agent, and using a one-pot hydrothermal method to obtain magnetic Co-CuFe2O4 nanospheres; and using the prepared Co-CuFe2O4 nanosphere catalyst to perform catalytic ethanolysis reaction on the low-rank coal subjected to ozone oxidation pretreatment. In the application, appropriate ozone oxidation pretreatment can effectively improve the activity of the low-rank coal, and when the magnetic Co-CuFe2O4 nanospheres are applied to catalytic ethanolysis reaction of the low-rank coal subjected to ozone oxidation pretreatment and catalytic ethanolysis reaction of low-rank coal-related model compounds, the magnetic Co-CuFe2O4 nanospheres all exhibit excellent catalytic activity, higher-yield soluble components can be obtained, the yield of oxygen-containing compounds in the derived soluble matters is improved, and efficient and high-value utilization of the low-rank coal is realized.

Electrochemical CO2 upgrading into C2 oxygenates is achieved a membrane electrode assembly (MEA) cell comprising metal plates, an anion exchange membrane (AEM), a cathode and anode, wherein the cathode comprises nanoscale Cu and Ag nanoparticles on a hydrophobic carbon substrate, wherein CO2 is fed to the cathodic side and converted to C2 oxygenates at the electrocatalyst surface.

The application provides a Ce / HZSM-5 catalyst and a preparation method and application thereof, wherein the mass fraction of Ce in the Ce / HZSM-5 catalyst is 1-2 wt% based on 100% of the mass of the Ce / HZSM-5 catalyst. The mass fraction of Ce in the Ce / HZSM-5 catalyst provided in the application is 1-2 wt%, and the Ce loaded on the HZSM-5 can not only adjust the acidity of the Ce / HZSM-5 catalyst, but also can avoid the accumulation of Ce in the zeolite channel of the HZSM-5, so as to reduce the pore volume and pore size of the Ce / HZSM-5 catalyst, so that the Ce / HZSM-5 catalyst has high activity and selectivity to hydrocarbons, and the conversion rate of oxygen-containing compounds in PET cracking oil is improved.

The invention discloses a bird nest type hydrogenation protective agent for a coal-to-oil system as well as a preparation method and application of the bird nest type hydrogenation protective agent, and belongs to the technical field of catalyst protection. The preparation method of the protective agent comprises the following steps: kneading pseudo-boehmite, a binder and a special molecular sieve, then adding an acid solution, polyvinyl alcohol and glycerol, and carrying out wet kneading to obtain mud; after wet kneading is finished, sequentially carrying out vacuum pugging, aging, extrusion molding by adopting a bird nest type mold, pelletizing and roasting to obtain a protective agent carrier; and loading an active metal component on the obtained protective agent carrier, and sintering to obtain the protective agent. According to the protective agent, the pseudo-boehmite with high crystallinity and high pore volume and the special molecular sieve are cooperatively used, and through shaping and roasting crystal transformation, the protective agent has the advantages of high radial strength, high water absorption capacity, high polar oxide adsorption capacity and high deoxidization capacity, and oxygen-containing compounds in coal-to-oil heavy oil can be effectively removed; the service life of the main catalyst is prolonged.

The present application provides a catalyst for preparing oxygen-containing compounds by olefin hydroformylation reaction, and a preparation method and use thereof, the catalyst is Fe x Co y M, the catalyst contains 0.1-15wt% M, 85-99.9wt% Fe and Co, the atomic ratio of x to y is 0.1-10, and M is a metal element. When the catalyst is used for preparing oxygen-containing compounds by olefin hydroformylation reaction, the conversion rate of olefin can reach 93-99.9%, and the selectivity of oxygen-containing compounds can reach 89-98.8%; and the catalyst is in a solid state during the reaction, which is easy to realize solid-liquid separation with the product, and also avoids the loss of the catalyst during the separation process.

A process for producing a jet fuel fraction (41), said process comprising steps of feeding at least one of a biogas stream (1), a carbon dioxide stream (2), or a methane stream (3), and at least a fraction of a tail gas recycle stream (32), to a reformer section (10) to provide a synthesis gas stream (11); feeding said synthesis gas stream (11, 22) to a synthesis section (30) to provide a stabilized condensate stream (31), a liquid wax stream (38), the tail gas recycle stream (32) and a concentrated oxygenate recycle stream (36); refining at said stabilized condensate stream (31) and liquid wax stream (38) in a refinery section (40) to provide a jet fuel fraction stream (41); and recycling said concentrated oxygenate recycle stream (36) to a biogas plant, and a plant for carrying out the process.

The embodiment of the present application provides a solar cell and a forming method thereof. The forming method of the solar cell comprises the following steps: providing a substrate; performing boron diffusion treatment on the substrate to form a boron-doped layer and a borosilicate glass layer which are sequentially stacked on the surface of the substrate, and the borosilicate glass layer has interstitial oxygen atoms; the boron diffusion treatment comprises a deposition stage and a pushing stage, the substrate is provided with a boron source and an oxygen source in the deposition stage; the temperature of a reaction chamber in the deposition stage is greater than that in the pushing stage; after the boron diffusion treatment, a passivation stage is performed, a passivation source is provided to the borosilicate glass layer, and the passivation source and the interstitial oxygen atoms react to form an oxygen-containing compound. The embodiment of the present application is beneficial to improving the performance of the solar cell.