1211 results about "Oxygen compound" patented technology

A method is for forming a nitride or oxide film by plasma-assisted cyclic deposition, one cycle of which includes: feeding a first reactant, a second reactant, and a precursor to a reaction space where a substrate is placed, wherein the second reactant flows at a first flow ratio wherein a flow ratio is defined as a ratio of a flow rate of the second reactant to a total flow rate of gases flowing in the reaction space; and stopping feeding the precursor while continuously feeding the first and second reactants at a flow ratio which is gradually reduced from the first flow ratio to a second flow ratio while applying RF power to the reaction space to expose the substrate to a plasma. The second reactant is constituted by a hydrogen-containing compound or oxygen-containing compound.

Implementations described herein protect a chamber components from corrosive cleaning gases used at high temperatures. In one embodiment, a chamber component includes at least a bellows that includes a top mounting flange coupled to a bottom mounting flange by a tubular accordion structure. A coating is disposed on an exterior surface of at least the tubular accordion structure. The coating includes of at least one of polytetrafluoroethylene, parylene C, parylene D, diamond-like carbon (DLC), yttria stabilized zirconia, nickel, alumina, or aluminum silicon magnesium yttrium oxygen compound. In one embodiment, the chamber component is a valve having an internal bellows.

A semiconductor structure comprises a substrate comprising a first crystalline semiconductor material, a dielectric layer, above the substrate, defining an opening, a second crystalline semiconductor material at least partially filling the opening, and a crystalline interlayer between the substrate and the second crystalline semiconductor material. The first crystalline semiconductor material and the second crystalline semiconductor material are lattice mismatched, and the crystalline interlayer comprises an oxygen compound. A method for fabricating semiconductor structure comprises the steps of providing a substrate including a first crystalline semiconductor material, patterning an opening in a dielectric layer above the substrate, the opening having a bottom, forming a crystalline interlayer on the substrate at least partially covering the bottom, and growing a second crystalline semiconductor material on the crystalline interlayer thereby at least partially filling the opening. The crystalline semiconductor materials are lattice mismatched, and the crystalline interlayer comprises an oxygen compound.

Memory devices based on tungsten-oxide memory regions are described, along with methods for manufacturing and methods for programming such devices. The tungsten-oxide memory region can be formed by oxidation of tungsten material using a non-critical mask, or even no mask at all in some embodiments. A memory device described herein includes a bottom electrode and a memory element on the bottom electrode. The memory element comprises at least one tungsten-oxygen compound and is programmable to at least two resistance states. A top electrode comprising a barrier material is on the memory element, the barrier material preventing movement of metal-ions from the top electrode into the memory element.

Disclosed herein are fibers comprising an active material that assists in removing contaminants from fluid. The active material, which forms a coating on the fiber, typically comprises a non-fibrous: nanostructured, metal-containing compound, such as a metal-oxygen compound. A filter media made of such fibers, as well as methods of making the fiber and the filter media are also disclosed. Methods of purifying fluids, such as air, water, and fuels, are further disclosed.

Improved processing for the production of light olefins via oxygenate conversion processing is provided. Synthesis gas conversion such as to produce an effluent including at least methanol can be integrated with oxygenate conversion processing such as to produce an oxygenate conversion reactor effluent including at least light olefins and dimethyl ether. At least a portion of the oxygenate conversion reactor effluent can be contacted with such produced methanol to effect recovery of dimethyl ether from the oxygenate conversion reactor effluent.

This invention provides processes for forming light olefins from methanol and / or from syngas through a dimethyl ether intermediate. Specifically, the invention is to converting methanol and / or syngas to dimethyl ether and water in the presence of a first catalyst, preferably comprising γ-alumina, and converting the dimethyl ether to light olefins and water in the presence of a second catalyst, preferably a molecular sieve catalyst composition.

The invention relates to a preparation method for a wax temperature-sensitive medium for a temperature control valve. According to the invention, an F-T synthetic product containing a component selected from C9 to C20 and having more than 80 wt% of n-alkane is used as a raw material, the raw material is subjected to hydro-conversion in the presence of a catalyst, and alkene and an oxygen-containing compound therein are converted into proper components for the temperature-sensitive medium used for the temperature control valve; a product of hydrogenation undergoes sweating and refining so as to prepare a target product. The wax temperature control valve prepared from the target product is capable of temperature control in a range of 5 to 30 DEG C, and travel range values of all degrees are basically consistent. The preparation method provided by the invention is simple and needs low operation cost. The product can be used for automatic wax temperature control devices needing uniform rise, especially for the temperature-sensitive medium for a wax heating temperature control valve.

The invention is directed to a method for producing an oxygenated biochar material possessing a cation-exchanging property, wherein a biochar source is reacted with one or more oxygenating compounds in such a manner that the biochar source homogeneously acquires oxygen-containing cation-exchanging groups in an incomplete combustion process. The invention is also directed to oxygenated biochar compositions and soil formulations containing the oxygenated biochar material.

A process for the non-oxidative conversion of methane simultaneously with the conversion of an organic oxygenate, represented by a general formula: CnH2n+1OCmH2m+1, wherein C, H and O are carbon, hydrogen and oxygen elements, respectively; n is an integer having a value between 1 and 4; and m is an integer having a value between zero and 4, to C2+ hydrocarbons, particularly to gasoline range C6–C10 hydrocarbons and hydrogen, using a bifunctional pentasil zeolite catalyst, having strong acid and dehydrogenation functions, at a temperature below 700° C. is disclosed. In this process the moles of methane converted per mole of oxygenate converted is above 1.0, depending upon the process conditions.

The present invention provides an integrated system for producing ethylene and propylene from an oxygenate to olefin (OTO) reaction system and a steam cracking system. In a preferred embodiment, at least a portion of an effluent stream from a steam cracking furnace is combined with at least a portion of an effluent stream from an OTO reaction system. Preferably the combined effluent stream is processed by one or more quench units, compression units, and / or fractionation columns. By integrating a steam cracking system with an OTO reaction system, equipment count can be reduced at a significant commercial savings. Compressor efficiency per pound of ethylene and propylene can also be advantageously increased over conventional steam cracking systems. Moreover, the amount of pollutants produced per pound of ethylene and propylene produced can be significantly reduced over the amount of pollutants produced per pound of ethylene and propylene produced in a steam cracking system.

The invention includes methods in which silicon is removed from titanium-containing container structures with an etching composition having a phosphorus-and-oxygen-containing compound therein. The etching composition can, for example, include one or both of ammonium hydroxide and tetra-methyl ammonium hydroxide. The invention also includes methods in which titanium-containing whiskers are removed from between titanium-containing capacitor electrodes. Such removal can be, for example, accomplished with an etch utilizing one or more of hydrofluoric acid, ammonium fluoride, nitric acid and hydrogen peroxide.

The average propylene cycle selectivity of an oxygenate to propylene (OTP) process using a dual-function oxygenate conversion catalyst is substantially enhanced by the use of a combination of: 1) moving bed reactor technology in the hydrocarbon synthesis portion of the OTP flow scheme in lieu of the fixed bed technology of the prior art; 2) a hydrothermally stabilized and dual-functional catalyst system comprising a molecular sieve having dual-function capability dispersed in a phosphorus-modified alumina matrix containing labile phosphorus and / or aluminum anions; and 3) a catalyst on-stream cycle time of 400 hours or less. These provisions stabilize the catalyst against hydrothermal deactivation and hold the build-up of coke deposits on the catalyst to a level which does not substantially degrade dual-function catalyst activity, oxygenate conversion and propylene selectivity, thereby enabling maintenance of average propylene cycle yield near or at essentially start-of-cycle levels.

A crystalline material substantially free of framework phosphorus and comprising a CHA framework type molecular sieve with stacking faults or at least one intergrown phase of a CHA framework type molecular sieve and an AEI framework type molecular sieve, wherein said material, in its calcined, anhydrous form, has a composition involving the molar relationship:(n)X2O3:YO2,wherein X is a trivalent element; Y is a tetravalent element; and n is from 0 to about 0.5. The material exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.

The synthesis of a crystalline material, in particular, a high silica zeolite, comprising a chabazite-type framework molecular sieve is conducted in the presence of an organic directing agent having the formula: [R1R2R3N—R4]+Q−wherein R1 and R2 are independently selected from hydrocarbyl groups and hydroxy-substituted hydrocarbyl groups having from 1 to 3 carbon atoms, provided that R1 and R2 may be joined to form a nitrogen-containing heterocyclic structure, R3 is an alkyl group having 2 to 4 carbon atoms and R4 is selected from a 4- to 8-membered cycloalkyl group, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms; and a 4- to 8-membered heterocyclic group having from 1 to 3 heteroatoms, said heterocyclic group being, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms and the or each heteroatom in said heterocyclic group being selected from the group consisting of O, N, and S, or R3 and R4 are hydrocarbyl groups having from 1 to 3 carbon atoms joined to form a nitrogen-containing heterocyclic structure; and Q− is a anion.

A CMP composition having: a fluid comprising water and at least one oxidizing compound that produces free radicals when contacted with an activator; and a plurality of particles having a surface and comprising at least one activator selected from ions or compounds of Cu, Fe, Mn, Ti, or mixtures thereof disposed on said surface, wherein at least a portion of said surface comprises a stabilizer. Preferred activators are selected from inorganic oxygen-containing compounds of B, W, Al, and P, for example borate, tungstate, aluminate, and phosphate. The activators are preferably ions of Cu or Fe. Surprisingly, as little as 0.2 ppm and 12 ppm of activator is useful, if the activator-containing particles are suspended in the fluid as a slurry. Advantageously, certain organic acids, and especially dihydroxy enolic acids, are included in an amount less than about 4000 ppm. Advantageously, activator is coated onto abrasive particles after the particles have been coated with stabilizer.

Adsorbents and methods for removing cations of heavy metals from a medium are provided. The adsorbents comprise a porous media in which at least one oxygen-containing compound of iron, copper, aluminum, zirconium, titanium and combinations thereof is incorporated. The oxygen-containing compound may be incorporated into the porous media by impregnation or dispersion of a suitable precursor of such a compound. The precursor may be further treated to yield the oxygen-containing compound. Such adsorbents are particularly useful for removing lead and / or other metal cations from the environment and may be used in treating drinking water sources.

The present invention provides a process for controlling the ratio of hydrogen to carbon monoxide in feed streams to reactors that convert syngas to hydrocarbon liquids. The process includes primary syngas production process for converting hydrocarbon gas to syngas comprising hydrogen and carbon monoxide. The process further includes introducing a hydrogen rich stream, a carbon monoxide rich stream, or both produced by an auxiliary source to a feed stream being passed to a reactor for converting the syngas to hydrocarbon liquid, thereby adjusting the H2 / CO ratio in the feed stream. Examples of reactors that may be used to convert syngas to hydrocarbon liquids are FT reactors staged in series and oxygenate producing reactors staged in series.

A crystalline material is described that has an AEI framework type, wherein the material, in its calcined, anhydrous form, has a composition involving the molar relationship:(n)X2O3:YO2,wherein X is a trivalent element, Y is a tetravalent element n is from 0 to less than 0.01. The material is normally synthesized in a halide, typically a fluoride, medium and exhibits activity and selectivity in the conversion of methanol to lower olefins, especially ethylene and propylene.

The invention discloses a sodium chloride-free environment-friendly coal-saving combustion improver special for cement, which aims to solve the technical problem of eliminating the damage of sodium chloride to furnaces, kiln bodies and the atmosphere. The combustion improver consists of an industrial grade finished product raw material, industrial residue, and a tailing material, and contains a barium compound, boride, carbonate, a chromium compound, fluoride, a magnesium compound, a manganese compound, nitride, a molybdenum compound II, a zirconium compound, industrial residue or tailings of rare earth, oxide and dicyclopentadienyl iron. Compared with the prior art, the combustion improver completely cancels the sodium chloride, furthest reduces the content of Cl<-> in ingredients, eliminates the damage of the sodium chloride to the furnaces, the kiln bodies and the atmosphere, reduces the damage of causing acid rain to the atmosphere, increases a plurality of metal acids, oxygen compounds and rare earth minerals, contains waste residue, ensures that the combustion is controllably performed, improves combustion environment, improves the combustion efficiency of fire coal, reduces energy consumption, prolongs the service life of equipment, and protects the environment.

The present invention provides a process for producing lower olefins by catalytic cracking a feedstock comprising an olefins-enriched mixture containing C4 or higher olefins and optionally an organic oxygenate compound. The technical problem mainly addressed in the present invention is to overcome the defects presented in the prior art including low yield and selectivity of lower olefins as the target products, and short regeneration period of catalyst. The present process, which is carried out under the conditions of catalytic cracking olefins and adopts as a feedstock an olefins-enriched mixture containing one or more C4 or higher olefins and optionally an organic oxygenate compound, comprises the steps of: a) letting the feedstock firstly enter a first reaction zone to contact with a first crystalline aluminosilicate catalyst having a SiO2 / Al2O3 molar ratio of at least 10, to thereby produce a first reaction effluent containing lower olefins; b) letting the first reaction effluent enter in turn at least one second reaction zone to contact with a second crystalline aluminosilicate catalyst having a SiO2 / Al2O3 molar ratio of at least 10, to thereby produce a second reaction effluent containing lower olefins; and c) separating lower olefins from the second reaction effluent; wherein the reaction temperatures in the first and second reaction zones are controlled. The present process, which desirably solves the above technical problem, can be used in industrial production of lower olefins.

The invention discloses a crosslinking polyolefin microporous membrane and a preparation method thereof. Materials for making the membrane mainly comprise 28.8 to 48.8 parts by weight of polyolefin, 30 to 50 parts by weight of cosolvent, 0.1 to 2 parts by weight of peralcohol, 1 to 5 parts by weight of silane, and 0.1 part by weight of antioxygen, and further comprise 0 to 20 parts by weight of ultrafine filler. By the crosslinking of polyolefin, the mechanical strength, the thermal resistance and the tolerance to strong base and chlorine-oxygen compound and other severe chemical environmentsof the polyolefin microporous membrane can be improved, and in practical application, such as an isolating membrane of a lithium ion battery or a filtering membrane in a membrane bioreactor, the service life of the polyolefin microporous membrane can be greatly prolonged.

Anhydrous processing to convert methane into oxygenates (such as methanol), liquid fuels, or olefins uses an initiator to create methyl radicals. These radicals combine with sulfur trioxide to form methyl-sulfonate radicals. These radicals attack fresh methane, forming stable methane-sulfonic acid (MSA) while creating new methyl radicals to sustain a chain reaction. This system avoids the use or creation of water, and liquid MSA is an amphoteric solvent that increasing the solubility and reactivity of methane and SO3. MSA from this process can be sold or used as a valuable chemical with no mercaptan or halogen impurities, or it can be heated and cracked to release methanol (a clean fuel, gasoline additive, and chemical feedstock) and sulfur dioxide (which can be oxidized to SO3 and recycled back into the reactor). MSA also can be converted into gasoline, olefins, or other valuable chemicals.

A Fischer-Tropsch C3-C4 olefin stream is treated to lower the oxygenate content to below 4000 ppm. Another Fischer-Tropsch fraction is hydrotreated and hydrocracked to provide an isobutane-containing stream. The treated C3-C4 olefin stream is reacted with the isobutane stream in an alkylation reactor to provide a highly branched, high octane isoparaffinic alkylate. The alkylate is useful as a blending component in motor gasoline.

The average cycle propylene selectivity of an oxygenate to propylene (OTP) process using one or more fixed or moving beds of a dual-function oxygenate conversion catalyst with recycle of one or more C4+ olefin-rich fractions is substantially enhanced by the use of selective hydrotreating technology on these C4+ olefin-rich recycle streams to substantially eliminate detrimental coke precursors such as dienes and acetylenic hydrocarbons. This hydrotreating step helps hold the build-up of detrimental coke deposits on the catalyst to a level which does not substantially degrade dual-function catalyst activity, oxygenate conversion and propylene selectivity, thereby enabling a substantial improvement in propylene average cycle yield. The propylene average cycle yield improvement enabled by the present invention over that achieved by the prior art using the same or a similar catalyst system but without the use of the hydrotreating step on the C4+ olefin-rich recycle stream is of the order of about 1.5 to 5.5 wt-% or more.

A process for the preparation of an olefin product comprising ethylene and / or propylene, which process comprises the steps ofa) cracking a paraffin feedstock comprising C2-C5 paraffins under cracking conditions in a cracking zone to obtain a cracker effluent comprising olefins;b) converting an oxygenate feedstock in an oxygenate-to-olefins conversion system, comprising a reaction zone in which an oxygenate feedstock is contacted with an oxygenate conversion catalyst under oxygenate conversion conditions, to obtain a conversion effluent comprising ethylene and / or propylene;c) combining at least part of the cracker effluent and at least part of the conversion effluent to obtain a combined effluent, and separating an olefin product stream comprising ethylene and / or propylene from the combined effluent, wherein the cracker effluent and / or the conversion effluent comprises a C4 portion comprising unsaturates, and wherein the process further comprises at least partially hydrogenating at least part of the C4 portion, to obtain an at least partially hydrogenated C4 feedstock; and recycling at least part of the at least partially hydrogenated C4 feedstock as recycle feedstock to step a) and / or step b), and an integrated system for performing the process.

The present invention provides various processes for producing light olefins from methanol and ethanol, optionally in a mixed alcohol stream. In one embodiment, the invention includes directing a first syngas stream to a methanol synthesis zone to form methanol and directing a second syngas stream and methanol to a homologation zone to form ethanol. The methanol and ethanol are directed to an oxygenate to olefin reaction system for conversion thereof to ethylene and propylene.

This invention provides an integrated system and process for forming light olefins and polymers from oxygenates, and optionally from natural gas. The integrated system includes an air separation unit, which separates air components into an oxygen stream and a nitrogen stream, and which also forms a compressed air stream. According to the present invention, the oxygen stream, the nitrogen stream and / or the compressed air stream from the air separation unit may serve as a reactant in syngas generation, as a regeneration medium in the methanol-to-olefins reaction system, as a fluidizing stream, as a blanketing medium, as a stripping medium, as instrument air, and / or as a reactant in a sulfur removal unit.