419 results about "Crystalline materials" patented technology

The invention relates to the technical field of fluorescence sensing development, in particular to a Cd (II)-based metal organic framework crystalline material as well as a preparation method and application thereof. The chemical formula of the Cd (II)-based metal organic framework crystalline material is {[Cd3 (H2O) 2 (DMA) 2 (5-CMOIA) 2]. 6 / 5H2O} n, the organic framework material is characterized by an X-ray single crystal diffractometer, and the result shows that the organic framework material is crystallized in a triclinic system P-1 space group, the asymmetric unit of the organic framework material is composed of three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions and three The complex is composed of two deprotonated (5-CMOIA) 3-ligands, two coordinated DMA solvent molecules, two coordinated water molecules and six fifths of crystal water molecules. The solid fluorescence spectrum of the Cd (II)-based metal organic framework crystalline material is measured, the fluorescence response of the Cd (II)-based metal organic framework crystalline material to metal ions in a solution is explored, and the result shows that the Cd (II)-based metal organic framework crystalline material can effectively recognize Hg < 2 + > from different ions and can be applied to the field of fluorescence sensing.

Crystal growth systems with a baffle are provided. In one example, a crystal growth system for growing crystalline material, the crystalline material including silicon carbide, includes a seed holder configured to hold a silicon carbide seed crystal. The seed crystal provides a growth surface for growth of the silicon carbide crystalline material. The system includes a crucible at least partially defining a crystal growth chamber. The system includes a source material. The system includes one or more baffles within the crystal growth chamber and spaced apart from the source material. The one or more baffles include one or more apertures defined through the one or more baffles. The baffle includes a long dimension that is non-perpendicular to the growth surface of the seed crystal.

The invention relates to the technical field of crystal material preparation, in particular to a ternary layered selenide Ge3Sb4Se7 semiconductor material and a preparation method thereof. The preparation method of the ternary layered selenide Ge3Sb4Se7 semiconductor material comprises the following steps that S001, germanium powder, antimony powder and selenium powder with the molar ratio being 3: 4: 7 serve as raw materials, the temperature is increased to 900-950 DEG C under the vacuum condition, and heat preservation is conducted for 12-24 h at the temperature; s002, after heat preservation is finished, the temperature is reduced to 475-500 DEG C at the cooling rate of 1-5 DEG C / min, and heat preservation is conducted for 3-5 days at the temperature; and after heat preservation is finished, furnace cooling or quenching cooling is performed to reach the room temperature, and the layered ternary selenide single-phase material with the chemical formula being Ge3Sb4Se7 is obtained. The ternary layered selenide Ge3Sb4Se7 semiconductor material prepared by the invention is a single-phase material and has the characteristics of low thermal conductivity and low resistivity, so that the ternary layered selenide Ge3Sb4Se7 semiconductor material has application potential in the fields of thermoelectric devices, photoelectric detection and the like.

A method of manufacturing a battery cathode for a solid state battery is provided. The method includes generating a plasma remote from one or more targets suitable for forming cathodes, such as LiCoO2, exposing the plasma target or targets to the plasma, thereby generating sputtered material from the target or targets, and depositing sputtered material on a first portion of a substrate, thereby forming crystalline material, such as LiCoO2 on the first portion of the substrate.

The invention relates to the technical field of fluorescence sensing, in particular to a preparation method and application of an Nd (III)-based hydrogen bond organic framework crystalline material. According to the Nd (III)-based hydrogen bond organic framework crystalline state material, Nd (III) serves as a central metal ion and is coordinated with 9 oxygen atoms, and adjacent Nd (III) are connected through H2 (4-CPCA) ligands to form a one-dimensional chain structure. One-dimensional chains are bridged through H2 (4-CPCA) ligands to form a two-dimensional double-layer planar structure, and two-dimensional surfaces are further stacked through the interaction of a large number of intermolecular hydrogen bonds to form a three-dimensional supramolecular structure. The Nd (III)-based hydrogen bond organic framework crystalline material has good fluorescent property and stability, and can be applied to the field of fluorescence sensing.

The invention belongs to the technical field of fluorescent active substance development, and particularly relates to a cadmium (II)-based metal organic framework crystalline material as well as a preparation method and application thereof. The molecular formula of the cadmium (II)-based metal organic framework crystalline material is {[Cd3 (Br-BDC) 3 (BMIP) 2]. 2H2O} n, cadmium (II) ions serve as connecting nodes, BMIP and H2 (Br-BDC) ligands serve as bridging ligands to be in mutual bridging to form a three-dimensional space structure, Cd-O secondary structural units are contained in the structure, three Cd atoms form a trinuclear Cd-O cluster structure through the Cd-O secondary structural units, and the Cd (II)-based metal organic framework crystalline material has the structural formula shown in the description. The Cd1 atom and the Cd1 # atom are in mirror symmetry. The divalent cadmium ion fluorescence sensing material can be prepared by adopting a one-pot solvothermal reaction; the preparation method has the advantages of simple process, convenience in operation, high yield, good reproducibility and the like; the cadmium (II) fluorescent sensing material disclosed by the invention is relatively high in fluorescence emission spectrum intensity and can be applied to the fields of molecular fluorescent probes, metal ion detection and the like.

A method for realizing single-crystalline regeneration of a spent positive electrode material by using a vacuum cracking method. The method comprises: fully mixing a spent polycrystalline ternary positive electrode material of a lithium ion battery with nickel stearate and a lithium salt, melting same, and then calcining same in vacuum so as to obtain a regenerated single-crystalline ternary positive electrode material. The present method not only compensates the loss of lithium of a spent single-crystalline ternary positive electrode material, but also converts insoluble residual Ni on the surface of the single-crystalline material during the "cracking" process of nickel stearate into LiNiO2 capable of providing discharge capacity, thus allowing the regenerated positive electrode material to exhibit more excellent electrochemical properties, and further reducing costs. The method is simple and easy to operate, and has modest requirements on regeneration reaction temperature, and while not needing long-time high-temperature calcination, the method can be used for simultaneously carrying out two processes polycrystalline cracking into single crystalline and lithium replenishment, thus involving low energy consumption, and being easy to popularize.

Optical device films and methods of forming optical device films having a RMS surface roughness less than about 2.2 μin and a refractive index greater than 2.0 are provided. In one embodiment, an optical device film is provided and includes a crystalline or nano-crystalline material having a refractive index greater than 2.0. A top surface of the optical device film has a root-mean-square (RMS) surface roughness less than about 2.2 microinches (μin).

A method of analyzing semiconductor wafers includes capturing a first image of a first crystalline material, etching a first surface of the first crystalline material to delineate etch defects in the first crystalline material, and capturing a second image of first crystalline material after etching the first surface of the first crystalline material. Based on the second image, labels of etch defects delineated in the first surface of the first crystalline material are generated. The first image and the labels of etch defects are spatially coordinated to form a defect map identifying one or more defects in the first image based on the delineated etch defects, and based on the defect map and nondestructive data obtained from a second crystalline material, defects in the second crystalline material are identified.

Apparatuses and methods are provided for an optical frequency converter configured to double or have a carrier frequency of an input optical signal. The input optical signal provided to the optical frequency converter is a higher order mode than a mode of the output optical signal. The optical frequency converter comprises a core, cladding material, and a substrate. The core includes a first core portion of non-linear crystalline material which is non-centrosymmetric, and a second core portion and a third core portion of the non-linear crystalline material each of which is centrosymmetric. The first, the second, and the third core portions are coplanar with and adjacent to the first core portion between the second and the third core portions.

Crystal growth systems for growing crystalline material comprising silicon carbide are provided. In one example, the crystal growth system includes a crucible at least partially defining a crystal growth chamber. The crystal growth chamber has a plurality of zones, each zone associated with a different processing profile. The system includes a silicon carbide crystal. The system includes a source material.

The invention discloses self-repairing and rapid-repairing cement-based mortar and a preparation method thereof, and belongs to the technical field of building materials. The self-repairing and rapid-repairing cement-based mortar is prepared from the following raw materials: 5500-6500 parts of a composite cementing material; 200 to 650 parts of an inorganic permeable crystalline material; 1500 to 3500 parts of a filling material; 307 to 510 parts of a rapid hardening component; 2-5 parts of a moisturizing and thickening component; 150 to 250 parts of a toughening and softening component; and 6-10 parts of a water reducing agent. The preparation method of the self-repairing and rapid-repairing cement-based mortar comprises the following steps: preparing the raw materials according to the proportion, uniformly mixing, adding the mixing water, and uniformly mixing to obtain the self-repairing and rapid-repairing cement-based mortar. The self-repairing quick-repairing cement-based mortar is efficient in water resistance and leaking stoppage, quick in setting and hardening and high in hour strength and has the function of silt; and a good self-repairing capability is achieved for microcosmic cracks of 0.1 mm.

The invention relates to the technical field of fluorescence sensing, in particular to a praseodymium (III) metal organic framework crystalline material and a preparation method and application thereof. According to the praseodymium (III) metal organic framework crystalline state material, Pr (III) is used as a central metal ion and forms eight coordination with eight oxygen atoms of six (4-CPCA) 2-ligands. And adjacent Pr (III) are connected through 4-CPCA < 2-> bridging to form a one-dimensional annular chain. And the one-dimensional chains are further bridged and topologically connected through a (4-CPCA) 2-ligand to form a three-dimensional structure. The praseodymium (III) metal organic framework crystalline material has good fluorescent property and stability, and can be applied to the field of fluorescence sensing.

The toner is a toner including a toner particle comprising a binder resin, a crystalline material, wherein, when a ratio of an area occupied by the crystalline material in a toner surface observed with a scanning electron microscope after ruthenium-staining the toner under a specific condition (1) is represented by S1 (%), a ratio of an area occupied by the crystalline material in the toner surface observed with the scanning electron microscope after ruthenium-staining the toner under a condition (2) is represented by S2 (%), and a dispersion diameter of a plurality of domains formed of the crystalline material on the toner surface observed with the scanning electron microscope after the ruthenium-staining the toner under the condition (2) is represented by R2 (nm), the following expressions (1), (2), and (3) are satisfied.0.0≤S1≤0.5(1)1.≤S2≤10.(2)20≤R2≤200(3)

Systems and methods for defect mitigation in silicon carbide crystal growth systems are provided. In an aspect, an example method includes providing a crystalline material in a first zone of the crystal growth chamber. In some implementations, the example method includes providing a silicon carbide vapor source material in a second zone of the crystal growth chamber. The example method includes providing an etching agent in the crystal growth chamber. The example method includes controlling a temperature gradient in the crystal growth chamber such that a first temperature in the first zone is greater than a second temperature in the second zone to implement an etching process on the crystalline material in the crystal growth chamber.

The invention relates to the technical field of fluorescence sensing, in particular to a Zn (II)-based metal organic framework crystalline material as well as a preparation method and application thereof. Zinc chloride and H3 (5-COIA) ligands are added into DMA, pH is adjusted, the Zn (II)-based metal organic framework material with a novel structure is prepared through a solvothermal method, the preparation method has the advantages of being convenient to operate, high in yield, good in reproducibility and the like, and the Zn (II)-based metal organic framework material has very strong fluorescence emission performance and good water stability and can be used for preparing a fluorescent material with a novel structure. It has been studied to selectively and sensitively detect La3 + ions in aqueous solutions, thereby further protecting human health and the environment from these contaminants.

Methods are provided for hydrothermal synthesis of porous crystalline materials. The method generally comprises forming a solution of precursors and reagents in effective ratios for a porous crystalline material including a fluoride-containing mineralizer, and water-soluble oxidized disulfide oil. The solution is hydrothermally treated under effective conditions and for an effective time to synthesize porous crystalline materials.

A lithium tantalate reducing agent and blackening process containing nanomaterials, belonging to the technical field of crystal materials, comprises the following raw materials in weight percentage: FeSiAl micron sheets, carbon nanospheres and Fe-C core-shell nanoparticles are uniformly mixed in a mass ratio of 90:5:5, and stirred by an electric stirrer. The present invention can realize a simple and controllable blackening process of lithium tantalate, and at the same time, by controlling the temperature of the central temperature zone, ensure the effect of different blackening temperatures, and realize the regulation of yellow light transmittance and resistivity of lithium tantalate wafers.

The invention relates to the technical field of metal organic framework materials (MOF) and isotope separation, in particular to a functionalized metal organic framework material for water / heavy water separation and a preparation method and application thereof. The metal organic framework material is a porous crystal material which is formed by coordination self-assembly of metal ions and V-shaped organic ligands and has a periodic network structure; the V-shaped organic ligand is a V-shaped dicarboxylic acid organic ligand modified by an oxygen-containing functional group designed through topological functionalization. According to the metal organic framework material, through topological functional design of a V-shaped organic ligand, a space confinement channel and a high-density oxygen active site are integrated in the same MOF material, and an ideal model system is provided for identification of water isotopes; according to the metal organic framework material, the framework structure flexibility, the pore channel confinement effect and the molecular recognition capability can be synergistically regulated and controlled, so that efficient recognition and separation of water / heavy water are realized.

The invention belongs to the technical field of crystalline materials, and relates to a metal-organic coordination polymer crystal material, in particular to a nickel-based double-ligand coordination polymer crystal material as well as a preparation method and application thereof. The chemical formula of the nickel-based double-ligand coordination polymer crystal material is {[Ni (1, 4-bib) (BDC) (H2O) 2]. (1, 4-bib) 0.5. H2O} n, and the preparation method comprises the following steps: dissolving NiCl2. 6H2O, H2BDC and 1, 4-bib in a DMF / water mixed solution with a volume ratio of 1: 1, sealing, carrying out a solvothermal reaction, heating at a constant temperature of 90.0 DEG C for 3 days, and slowly cooling the system to room temperature to obtain a green bulk crystal G-Ni. The nickel-based double-ligand coordination polymer crystal material can be applied to Ag < + > recognition and antibiotic detection.

To provide improved laser-assisted methods and devices for parting or removing relatively thin layers of crystalline material from a substrate, such as a boule or a wafer.SOLUTION: A crystalline material processing method includes forming subsurface laser damage at a first average depth position to form cracks in a substrate interior propagating outward from at least one subsurface laser damage pattern, followed by imaging the substrate top surface, analyzing the image to identify a condition indicative of presence of uncracked regions within the substrate, and taking one or more actions responsive to the analysis. One potential action includes changing an instruction set for producing subsequent laser damage formation (at second or subsequent average depth positions), without necessarily forming additional damage at the first depth position. Another potential action includes forming additional subsurface laser damage at the first depth position.SELECTED DRAWING: Figure 49A

The invention discloses a polyacid-based metal viologen framework crystalline material as well as a preparation method and application thereof, and belongs to the technical field of heterogeneous catalytic materials. The crystalline material is synthesized in one step through a hydrothermal method, the molecular formula is Cu2 (H2O) 2 (L) 2 [PW12O40] [OH]. 2H2O, the crystalline material belongs to a monoclinic system, the space group is P21, the cell parameters are alpha = 90 degrees, beta = 114.208 (2) degrees and gamma = 90 degrees, and the structure of the crystalline material is determined through X-ray diffraction. According to the material, accurate compounding of polyacid clusters and metal viologen on the molecular level is achieved, an effective electron transmission channel is constructed, separation of photon-generated carriers is remarkably promoted, and excellent photocatalytic activity is shown. At the ambient temperature, the crystalline material can be used as a catalyst to efficiently degrade dye pollutants (such as methylene blue and rhodamine B) in a water body, the degradation rate within 60 minutes exceeds 90%, and the crystalline material has good cycle stability and structural durability.

An array of complementary die sets is attached to a carrier substrate. A continuous complementary-level molding compound layer is formed around the array of complementary die sets. An array of primary semiconductor dies is attached to the array of complementary die sets. A continuous primary-level molding compound layer is formed around the array of primary semiconductor dies. The bonded assembly is diced by cutting along directions that are parallel to edges of the primary semiconductor dies. The sidewalls of the complementary dies are azimuthally tilted relative to sidewalls of the primary semiconductor dies, or major crystallographic directions of a single crystalline material in the carrier substrate are azimuthally tilted relative to sidewalls of the primary semiconductor dies.

The invention discloses a zirconium sulfonate metal organic framework material and a solvent-free preparation method and application thereof, and belongs to the technical field of crystalline materials, the chemical formula is [Zr (OH) 2 (H2O) 3 (NAP (COOH) 2 (SO3) 2], the ligand is 4, 8-disulfonyl naphthalene-2, 6-dicarboxylic acid (NAP (COOH) 2 (SO3H) 2), and the zirconium sulfonate metal organic framework material is prepared by the following steps: grinding and mixing 4, 8-disulfonyl naphthalene-2, 6-dicarboxylic acid and zirconyl nitrate to obtain a premix; and heating the premix to 130-140 DEG C, reacting for 36-48 hours, washing the product with ethanol after the reaction is finished, and centrifugally drying to obtain the zirconium sulfonate metal organic framework material. The zirconium sulfonate metal organic framework material is prepared through a solvent-free mechanical grinding synthesis method, the utilization rate of raw materials is increased through the solvent-free method, the yield of the zirconium sulfonate metal organic framework material is increased, and the obtained zirconium sulfonate metal organic framework material is excellent in proton conductivity.

A method for preparing an ultra-microporous metal-organic framework (MOF) and its application in propylene and propane adsorption separation, belonging to the technical field of crystalline materials, is disclosed. The MOF is derived from the organic ligands D-camphoric acid, 3-amino-1,2,4-triazole, and anhydrous zinc acetate via a solvothermal reaction in N,N-dimethylformamide and tetrafluoroboric acid. Gas adsorption studies have shown that this MOF has the potential to separate propylene and propane gas molecules.

The invention belongs to the technical field of organic light-emitting materials, and particularly relates to a step-by-step stimuli-responsive crystalline light-emitting material and a preparation method and application thereof. The crystalline luminescent material is a crystalline material based on a polysulfide aromatic hydrocarbon type compound, and the polysulfide aromatic hydrocarbon type compound is a compound based on a tetrathiobenzene mother nucleus. The compound does not have a photoluminescence discoloration property in a crystalline state, but has an obvious photoluminescence discoloration property after the crystallinity is reduced through force stimulation; and the wavelength and proportion of fluorescence / phosphorescence of the compound and the molecular orbital of an excited state can be controlled by adjusting related substituents, so that the optical property is adjustable. The high-crystallinity material prepared from the compound has a response effect on step-by-step stimulation of force and light, so that the high-crystallinity material can be applied to encryption anti-counterfeiting, information storage and the like. The application scenarios include currency anti-counterfeiting, certificate anti-counterfeiting, commodity package anti-counterfeiting, bill anti-counterfeiting, artwork anti-counterfeiting, electronic equipment anti-counterfeiting, logistics anti-counterfeiting, supply chain anti-counterfeiting and the like.

The toner contains a toner particle having a core-shell structure including: a core containing a binder resin and a colorant; and a shell, wherein the toner contains a crystalline material, and the shell contains an amorphous thermoplastic resin; and when SP values of the crystalline material and the amorphous thermoplastic resin, which are calculated by the Fedors method, are defined as SPc (J / cm3)0.5 and SPa (J / cm3)0.5, respectively, the SPc and the SPa (J / cm3) satisfy a particular relationship, and when the toner is observed by SEM after the toner has been subjected to ruthenium staining that treats the toner in an atmosphere of RuO4 gas having 500 Pa for 15 minutes, a ratio S2 (%) of an area occupied by the crystalline material per area of the toner satisfies a particular relationship.

The invention belongs to the technical field of fuel cells, and discloses a Preyssler type polyacid crystalline material, the structural formula of the Preyssler type polyacid crystalline material is {[Cd5 (mu2-H2O) (H2O) 14 (H5P5W30O110) (btp) 4]. 8H2O} n, and the asymmetric unit of the Preyssler type polyacid crystalline material comprises 2.5 crystallographically independent Cd (II) ions, a half {P5W30} unit, 2 btp ligands, 8 coordinated water molecules and 4 free water molecules. The powder proton conductivity of the compound reaches 1.70 * 10 <-3 > S cm <-1 > under the conditions of 85 DEG C and 98% RH, the proton conductivity of a composite membrane formed by the compound and Nafion reaches 2.20 * 10 <-2 > S cm <-1 >, and large-scale commercial application of proton exchange membrane fuel cells can be achieved.

This application relates to the field of functional crystalline material preparation and microfluidic application technology, specifically disclosing a method and product for preparing formate crystals using core-shell microcapsules, including the following steps: (1) dissolving a solid alkaline raw material in a formic acid solution to prepare reaction solution a; (2) separately conveying polymer solution A and polymer solution B with phase separation characteristics, and reaction solution a, so that they are mixed at the intersection of microchannels to prepare dispersed phase b, which is then introduced into the assembly zone for phase separation assembly to form core-shell microcapsules; (3) the core-shell microcapsules are crystallized in a continuous temperature-changing crystallization zone to form formate solid; (4) the formate solid is collected, washed and dried sequentially to obtain the target product; (5) the oil layer is continuously extracted and returned to the assembly zone for recycling. The formate crystals prepared in this application not only have a large particle size, but also exhibit good size uniformity and morphological repeatability, and have the advantages of high throughput, green environmental protection, and simple operation.

The invention relates to the technical field of photoelectrocatalysis, in particular to a Mn (II) coordination polymer photoelectrode crystalline material and a preparation method and application thereof. The Mn (II) coordination polymer {[Mn2 (H2O) 6 (DODDA)]. 4H2O} n is obtained from an H4 (DODDA) organic ligand and manganese salt through a solvothermal method, an asymmetric unit comprises two Mn (II) ions in different coordination modes, adjacent Mn2 ions are bridged through carboxyl oxygen of the ligand to form straight chains, and two adjacent Mn2 straight chains are further bridged with Mn1 through the H4 (DODDA) ligand to form a transverse trapezoidal one-dimensional chain. A three-dimensional supramolecular structure is formed among the one-dimensional chains through the interaction of a large number of intermolecular hydrogen bonds. The Mn (II) coordination polymer shows better photoelectric property, has the potential of serving as a photoelectrode material, has good optical and electrical characteristics, can be used for constructing an efficient photoelectrocatalysis water decomposition system, and has application prospects in the aspects of photocatalytic hydrogen production, solar energy conversion and the like.