487 results about "Lithium oxide" patented technology

The invention discloses high-purity lithium sulfide as well as a preparation method and application thereof. The preparation method comprises the step that lithium hydride, lithium hydroxide and a sulfur source are subjected to a heating reaction in a dry inert atmosphere, and the high-purity lithium sulfide is obtained. The molar ratio of lithium hydride to lithium hydroxide is X: (10-X), and X is 1-6. The invention also discloses the prepared high-purity lithium sulfide and application of the high-purity lithium sulfide in preparation of sulfide solid electrolyte. Lithium hydroxide and lithium hydride are mixed to serve as a lithium source in lithium sulfide preparation, the lithium hydroxide quickly and uniformly reaches the reaction temperature by means of the characteristic that the lithium hydride reacts with a sulfur source to release heat and produce gas, the lithium hydride reacts to produce gas, meanwhile, discharging of product water vapor is facilitated, and oxygen in the environment is isolated; and hardening and generation of a side reaction product lithium sulfate are prevented, the conversion rate of lithium hydroxide to lithium sulfide is improved, and the raw material and process cost for preparing lithium sulfide is remarkably reduced.

The invention provides a tear-resistant, wear-resistant, low-smoke and non-dripping sheath material as well as a preparation method and application thereof. The tear-resistant wear-resistant low-smoke non-dripping sheath material is prepared from the following components in parts by weight: 25 to 35 parts of metallocene linear low-density polyethylene, 10 to 15 parts of ethylene-vinyl acetate copolymer, 6 to 8 parts of compatilizer, 50 to 60 parts of aluminum hydroxide, 10 to 15 parts of magnesium hydroxide, 3 to 4 parts of microencapsulated red phosphorus, 5 to 8 parts of lithium oxide synergist, 4 to 6 parts of silicone master batch, 0.3 to 0.7 part of carbon black master batch and 1.5 to 2.5 parts of coupling agent. The tear-resistant wear-resistant low-smoke non-dripping sheath material provided by the invention has the characteristics of being halogen-free, flame-retardant, tear-resistant and wear-resistant, and a low-smoke halogen-free flame-retardant power cable prepared from the sheath material has the characteristics of high smoke light transmittance during combustion, no dripping and cracking resistance.

The invention provides a modified lithium metal negative electrode and a preparation method and application thereof, and belongs to the technical field of lithium batteries. The modified lithium metal negative electrode comprises a negative electrode conductive substrate and an interface passivation layer formed on the surface of the negative electrode conductive substrate, and the interface passivation layer comprises lithium oxide, lithium sulfide, lithium nitride, lithium fluoride and a fluorocarbon compound; the interface passivation layer is obtained by putting lithium metal into chloroform for dipping treatment to obtain modified lithium metal and then performing plasma treatment. According to the lithium ion battery, the interface passivation film containing the lithium oxide, the lithium sulfide, the lithium nitride, the lithium fluoride and the fluorocarbon is formed on the negative electrode conductive substrate, and in the repeated charging and discharging process of the lithium ion battery, due to the existence of the interface passivation film, non-uniform deposition of lithium ions can be avoided, so that growth of lithium dendrites is inhibited. Furthermore, the coulombic efficiency and the cycling stability of the charge-discharge cycle of the lithium ion battery can be improved, and the service life of the lithium ion battery is prolonged.

The invention discloses high-toughness ultrathin flexible glass and a preparation method thereof, and relates to the technical field of glass manufacturing. The ultrathin flexible glass is prepared from the following raw materials: silicon dioxide, aluminum oxide, lithium oxide, sodium oxide, magnesium oxide, a modified nano reinforced phase, a high-temperature melting regulator and cerium dioxide. The modified nano reinforced phase is prepared by the following steps: pre-treating silicon carbide and silicon nitride with hydrochloric acid, and mixing with nano zirconium oxide to obtain a mixture; and modifying the mixture with a silane coupling agent to obtain the modified nano reinforced phase. The high-temperature melting regulator is a mixture of lithium borate, sodium sulfate and lithium fluoride. The preparation method of the ultra-thin flexible glass comprises the following steps: preparing the modified nano reinforced phase, melting and homogenizing the glass, forming the glass substrate, and preparing the ultra-thin flexible glass. The ultra-thin flexible glass prepared by the invention has relatively high fracture toughness and structural rigidity, excellent flexibility and bending fatigue durability, and excellent thermal shock resistance.

The invention discloses a method for preparing a lithium-copper composite negative electrode by utilizing lithium slag and application, and the preparation method of the negative electrode comprises the following steps: adding the lithium slag with certain concentration after removing impurities such as Ca < 2 + >, Mg < 2 + > and Fe < 3 + > through acid treatment into metal lithium in a molten state, and fully stirring until the reaction is complete; and coating the molten metal lithium obtained after the reaction on a current collector to obtain the modified lithium metal negative electrode plate. The prepared lithium-copper composite negative electrode has a lithium-loving 3D frame structure, volume expansion in the circulation process can be inhibited, lithium oxide, lithium aluminum alloy and lithium silicon alloy existing on the 3D frame structure can serve as lithium-loving sites for uniform lithium ion deposition, lithium dendrite growth is inhibited, and long-term stable circulation of the lithium metal negative electrode is promoted.

The invention discloses a production process of high-purity lithium oxide, and relates to the technical field of lithium oxide preparation. The production process of the high-purity lithium oxide comprises the following steps: mixing lithium hydroxide and hydrogen peroxide with the mass concentration of 90-99%, and carrying out peroxidation reaction to obtain a mixture containing lithium peroxide and lithium hydroxide; carrying out solid-liquid separation on the mixture containing the lithium peroxide and the lithium hydroxide to obtain a supernatant containing the lithium hydroxide and a solid containing the lithium peroxide; and carrying out drying treatment on the supernatant containing the lithium hydroxide to obtain the recycled lithium hydroxide, and carrying out thermal decomposition on the solid containing lithium peroxide in an inert gas protective atmosphere to obtain the high-purity lithium oxide powder. According to the technical scheme, the high-purity lithium oxide is prepared by adopting a process of peroxidizing lithium hydroxide into lithium peroxide and then carrying out thermal decomposition, the powder can be obtained without grinding, and the method has the advantages of high production efficiency, low energy consumption and high raw material utilization rate.

The invention relates to the technical field of ceramic production, and discloses a high-temperature hard glaze formula for bone china and a bone china production process. 4%-6% of aluminum oxide; 2%-5% of boron oxide; 3%-7% of zinc oxide; 3%-10% of an alkaline earth metal oxide; 7%-13% of alkali metal oxide; 0.5%-2% of zirconium oxide; and 0.5%-1.5% of titanium dioxide. According to the high-temperature hard glaze formula for the bone china and the bone china production process, a proper amount of boric oxide, zinc oxide and lithium oxide are added into the glaze, so that the thermal expansion coefficient of the glaze is effectively reduced, and the thermal stability of the bone china is improved; by adding aluminum oxide, the breaking strength of the bone china can be greatly improved; by adopting a lead-free formula, lead pollution is avoided, and the environment-friendly requirement is met; through the optimized glaze formula and process, the bone china surface has good glossiness and smoothness.

The invention discloses a preparation method of a composite lithium-rich and lithium-supplement additive, which comprises the following steps: taking lithium ferrite as a core, preparing NiO (at) lithium salt by adopting an ALD atomic deposition method, fully and uniformly mixing carbon-coated lithium ferrite and the NiO (at) lithium salt, and sintering to prepare the composite lithium-rich and lithium-supplement additive. According to the invention, the advantages of high lithium supplement capacity of lithium ferrite, less gas production of lithium nickelate and good environmental adaptability are fully exerted, and the lithium supplement agent with high capacity and good stability is obtained; the nanometer nickel protoxide is in full contact with a lithium salt coating layer prepared by an ALD method, subsequent sintering is facilitated, preparation can be performed at a lower temperature, cost reduction is facilitated, meanwhile, the nickel protoxide and the peripheral lithium salt coating layer are subjected to a solid solution reaction, and residual lithium on the surface of lithium ferrite of a nuclear body can be obtained. The'two-channel lithium acquisition mode 'can reduce the overall residual alkali amount of the material, and is beneficial to improving the processing performance of subsequent battery slurry.

Disclosed in the present invention are a 90°C thermoplastic halogen-free low-smoke flame-retardant polyolefin sheath material and a preparation method therefor. The sheath material is prepared from raw materials comprising the following components in parts by mass: 20-40 parts of an ethylene-vinyl acetate copolymer, 20-40 parts of a linear low-density polyethylene, 2-10 parts of a high-density polyethylene, 20-40 parts of a metallocene ethylene-octylene copolymer, 10-15 parts of a maleic-anhydride-grafted metallocene linear low-density polyethylene copolymer, 58-73 parts of aluminum hydroxide, 20-25 parts of modified magnesium hydroxide, 64-84 parts of a synergistic flame retardant, 2-3 parts of a coupling agent, 1-4 parts of a lubricant, 1-3 parts of an antioxidant, and 2-7 parts of a coloring agent, wherein the synergistic flame retardant comprises lithium oxide. A matrix resin has low-temperature performance, mechanical properties and cracking resistance. With regard to flame retardance, a large amount of the synergistic flame retardant, i.e., lithium oxide, is added to a traditional magnesium-aluminum compound flame-retardant system, and therefore an off-white hard shell can be formed during a combustion process while low heat release is ensured, thereby ensuring no dripping during the combustion process.

An ultra-thin flexible glass and its preparation method belong to the technical field of glass manufacturing. The raw materials of the ultra-thin flexible glass are composed of silicon dioxide, aluminum oxide, sodium oxide, boron trioxide, calcium oxide, lithium oxide, a composite toughening agent, a composite flux, and a composite fining agent. The ultra-thin flexible glass prepared by the present invention has an ultimate bending radius of 2-3 mm, a maximum number of bending times of 350,000-360,000 times, a surface compressive stress of 916-937 MPa, a Vickers hardness of 610-623 MPa, and an elastic modulus of 79-82 GPa.

To provide a method which enables inexpensive production with a high yield of lithium hydroxide with a low amount of impurities such as sodium from lithium-containing water including a lithium ion and a chloride ion.SOLUTION: A production method of lithium hydroxide includes: a crystallizing step of crystallizing lithium hydroxide (LiOH) from lithium-containing water including a lithium ion and a chloride ion; a solid-liquid separation step of performing solid-liquid separation treatment of concentrated liquid including the LiOH to obtain the LiOH as a solid product and filtrate; a carbonation step of producing lithium carbonate from the filtrate by carbonation; a lithium carbonate recovery step of evaporating at least a part of ammonia from a mixed liquid obtained in the carbonation step and performing solid-liquid separation treatment of the resultant treated liquid to obtain lithium carbonate as a solid product; a lithium hydroxide production step of converting the obtained lithium carbonate into LiOH followed by solid-liquid separation treatment to obtain an aqueous LiOH solution (1) as a liquid component; and a recrystallizing step of crystallizing LiOH from the aqueous solution (1).SELECTED DRAWING: Figure 2

The invention relates to lithium sulfide and a preparation method thereof.The preparation method includes the following steps that sublimed sulfur powder and a lithium source are mixed and subjected to a heating reaction, and the lithium source comprises at least one of anhydrous lithium hydroxide, lithium hydroxide monohydrate, lithium oxide, lithium hydride and lithium carbonate; a reducing gas is introduced while the heating reaction is performed, or the reducing gas is introduced after the heating reaction is finished, and a reduction reaction is performed; and after the reaction is finished, introducing protective gas for calcining to prepare the lithium sulfide. The preparation method provided by the invention can realize low-cost and high-purity production of lithium sulfide, and ensures the safety and environmental protection of the production process.

The invention belongs to the field of solid-state battery manufacturing, and particularly relates to a low-cost method for synthesizing high-purity lithium sulfide, which comprises the steps of synthesizing high-purity lithium oxide and synthesizing high-purity lithium sulfide. The process for synthesizing Li2O is unique, lithium salt can be chemically reacted into lithium oxide in a plasma environment, and the method has the advantages of high energy efficiency, short process time, good process controllability, high conversion rate, high product purity and the like. According to the method, self-made low-cost high-purity lithium oxide is adopted as a raw material and continuously reacts with hydrogen sulfide gas at a proper temperature (200-400 DEG C) for 20-60 minutes, so that high-purity lithium sulfide can be obtained. According to the process, the synthesis cost is greatly reduced, so that the large-scale commercial production of the sulfide solid electrolyte becomes possible.

The invention relates to a method for simultaneously preparing lithium hydroxide and sulfuric acid. The invention provides a method for simultaneously preparing lithium hydroxide and sulfuric acid, which comprises the following steps: preparing a bipolar membrane electrodialysis device which comprises a first bipolar membrane, an anion exchange membrane, a cation exchange membrane and a second bipolar membrane, and forming an acid chamber between the first bipolar membrane and the anion exchange membrane, a salt chamber is formed between the anion exchange membrane and the cation exchange membrane, and an alkali chamber is formed between the cation exchange membrane and the second bipolar membrane; a lithium sulfate aqueous solution is added into a salt chamber of the bipolar membrane electrodialysis device, a sulfuric acid aqueous solution is added into an acid chamber, and a lithium hydroxide aqueous solution is added into an alkali chamber; and discharging the desalted solution formed in the salt chamber of the bipolar membrane electrodialysis device, discharging the sulfuric acid aqueous solution formed in the acid chamber, and discharging the lithium hydroxide aqueous solution formed in the alkali chamber.

To provide a method for yielding a lithium-containing liquid suitable as a raw material for producing lithium compounds of high purity, from to-be-treated water containing lithium ions, sodium ions, metal ions other than lithium ions and sodium ions, fluoride ions, and anions serving as conjugate bases of acids, and to provide related techniques thereof.SOLUTION: Provided is a method for producing a raw material liquid for a lithium compound, comprising: step 1 of adding a sulfiding agent and a calcium compound to the to-be-treated water, subjecting the to-be-treated water containing the formed solid matter to solid-liquid separation to obtain a treated liquid A; step 2 of adding an oxalate ion source to the treated liquid A, subjecting the treated liquid A containing the formed solid matter to solid-liquid separation to obtain a treated liquid B; and step 3 of subjecting the treated liquid B to bipolar electrodialysis to obtain an alkaline liquid containing lithium ions and sodium ions as a raw material liquid for producing a lithium compound.SELECTED DRAWING: None

The invention discloses a method for converting lithium hydroxide into lithium carbonate. The method comprises the following steps: S1, preparing or taking a lithium hydroxide solution and a carbonate solution; s2, putting the lithium hydroxide solution and the carbonate solution into electrodialysis equipment, and carrying out electrodialysis treatment; and S3, after electrodialysis is finished, collecting a lithium carbonate solution, and sequentially carrying out lithium precipitation and solid-liquid separation on the lithium carbonate solution to obtain the battery-grade lithium carbonate. According to the method for converting lithium hydroxide into lithium carbonate disclosed by the invention, CO2 is replaced by carbonate, so that the generation of lithium bicarbonate is avoided, the lithium carbonate and the byproduct alkali liquor are directly obtained, the raw material source is wide, the preparation condition is mild, the production cost is greatly reduced, and the method has huge potential economic benefits.

The present invention discloses a tellurium-lead-lithium oxide glass powder for BC cell N-region conductive paste and its preparation method, belonging to the field of photovoltaic silver paste. The glass powder adopts components with high Pb, Te, and Li: aTeO2 - bPbO - cLi2O - dBi2O3 - eWO3 - fZnO - gSiO2 - hNa2O; where a + b + c + d + e + f + g + h = 1, 0.2 < a < 0.4, 0.1 < b < 0.4, 0.1 < c < 0.25, 0 < d < 0.1, 0 < e < 0.1, 0 < f < 0.1, 0 < g < 0.1, 0 < h < 0.05, and a + b > 0.5, and the ratio of c to h is (3 - 10):1. By controlling the specific Pb, Te, and Li contents and the specific Li / Na ratio in the present invention, a strong corrosion effect on the poly layer of the cell is achieved, enabling more silver ions dissolved in the glass liquid to recrystallize on the surface of the silicon wafer, thereby achieving good ohmic contact.

The invention belongs to the field of waste resource recovery treatment, and provides a method for combined recovery of lithium iron phosphate and ternary battery powder, which comprises the following steps: mixing and grinding decommissioned lithium iron phosphate and ternary battery powder, partially oxidizing lithium iron phosphate, then carrying out acid leaching, adding an oxidizing agent and a specific oxidation accelerator La2O3-LaF3 in the leaching process, and carrying out acid leaching to obtain lithium iron phosphate and ternary battery powder; carrying out heating reaction on the obtained leached slurry to obtain a lithium extraction solution, and then removing impurities to obtain a pure lithium solution; the impurity removal comprises the following steps: removing fluorine by using lanthanum salt to obtain lanthanum fluoride slag, and recycling the obtained lanthanum fluoride slag as an oxidation accelerant. Lithium iron phosphate is partially oxidized into more stable iron phosphate and lithium oxide by utilizing the oxidability of ternary battery powder, complete oxidation of lithium iron phosphate is effectively promoted by matching with an oxidation accelerator La2O3-LaF3 selected in the acid leaching process, use of hydrogen peroxide is avoided, LaF3 can be regenerated for use through the rear-end comprehensive impurity removal process, the resource utilization rate is increased, and the production cost is reduced. And the economic cost is reduced.

The present invention relates to a method for preparing lithium sulfide, according to the present invention, when preparing lithium sulfide by a reaction between a lithium raw material and hydrogen sulfide, the reaction is carried out under relatively mild conditions compared to the prior art, so that frequent maintenance or replacement due to corrosion and failure of a reactor and various pipes is not required, thereby improving the economical efficiency of the process. Further, by reusing the unreacted hydrogen sulfide from which moisture has been removed and the solvent, process costs can be reduced, and economical efficiency can be ensured during mass production. Furthermore, moisture and water vapor generated in the lithium sulfide generation reaction are effectively removed, thereby preventing a reverse reaction for generating lithium hydroxide, promoting a positive reaction, and producing high-quality lithium sulfide with high purity and high yield. In addition, the particle size can be adjusted in units, and a separate pulverizing space or pulverizing table is not required, so that convenience and mass productivity are excellent.

The invention relates to a lithium ion conductive dense membrane and a preparation method and application thereof. The lithium ion conductive dense membrane comprises a polymer base membrane, ion conductive inorganic particles and a polymer solid electrolyte, the polymer base membrane is of a net structure; the Gurley value of the lithium ion conductive dense film is larger than or equal to 1000, and the porosity is smaller than or equal to 5%. The lithium ion conductive dense membrane provided by the invention has the advantages of high lithium ion conductivity, high transport efficiency and high lithium ion selectivity, and can be applied to electrodialysis lithium extraction. And under the action of external voltage, lithium ions are directionally migrated to the air negative electrode subjected to oxygen reduction reaction through the lithium ion conductive dense membrane to form a lithium hydroxide solution, and other metal hetero-ions are isolated on the positive electrode side by the lithium ion conductive dense membrane, so that lithium enrichment is realized. And meanwhile, transportation of the membrane to lithium ions does not depend on pores in the conductive membrane, so that the service life can be prolonged while the lithium ion separability and the transportation efficiency of the salt lake lithium extraction method are improved.

The present disclosure provides a use of one of oxygen-deficient AlPO4-x, TiP2O7-y, and LiTiOPO4-z in an LATP composite solid-state electrolyte material. The present disclosure specifically uses an oxygen-deficient material for LATP modification, and correspondingly provides an LATP composite solid-state electrolyte material. The lithium oxide solid-state electrolyte provided by the present disclosure, which is capable of conducting both ions and electrons, has the advantages of relatively small particle size, excellent structural chemical stability, good hydrophobicity, and broad applicability. When used in a battery, the solid-state electrolyte can improve the capacities of the positive and negative electrodes, offer improved protection for both electrodes, and improve the charging and discharging capacity and the cycling stability of the battery.

The embodiment of the invention discloses a nano composite material and a preparation method, a use method and a device thereof, and the nano composite material is characterized by comprising a first nano particle and a second nano particle which are combined; the first nano-particles are transition metal nano-particles, and the second nano-particles are one or a combination of the following materials: lithium nitride nano-particles, lithium oxide nano-particles, lithium phosphide nano-particles, lithium selenide nano-particles and lithium sulfide nano-particles. The nano composite material can be subjected to magnetic regulation and control under low voltage, and high-speed and high-density electronic spin information storage is realized.

The invention discloses a toughened glass ceramic and a preparation method thereof, and relates to the technical field of glass ceramics, and the toughened glass ceramic comprises the following components in percentage by weight: 64 to 68 weight percent of silicon dioxide, 22.67 to 26.5 weight percent of lithium oxide, 0.9 to 1.2 weight percent of antibacterial agent, 0.8 to 1.1 weight percent of modified mica powder, 1.98 to 2 weight percent of aluminum oxide, 1.78 to 1.8 weight percent of potassium oxide, 1.68 to 1.7 weight percent of zirconium dioxide, 1.19 to 1.2 weight percent of phosphorus pentoxide and 1 to 3 weight percent of calcium fluoride. According to the toughened glass ceramic and the preparation method thereof, a multi-scale anti-cracking network is formed through macroscopic crack deflection of mica and nanoscale phase change toughening of zirconium oxide, the fracture toughness is remarkably improved, zirconium oxide agglomeration can be reduced through interface optimization of modified mica powder, zirconium oxide is dispersed more uniformly, and the phase change potential is further exerted; due to high-temperature stability of aluminum oxide, antibacterial agent particles can be wrapped, and excessive volatilization or aggregation of the antibacterial agent particles in the sintering process is prevented; aluminum oxide is used as a'protective shell 'to delay the Cu < 2 + > release rate and realize long-acting antibiosis.

The invention discloses a method for selectively extracting magnesium and lithium components in aluminum alloy waste and co-producing graphene, and belongs to the technical field of aluminum alloy waste treatment.The method comprises the steps that the surface of the aluminum waste containing magnesium and lithium is covered with fused salt, and smelting is conducted under the inert atmosphere to obtain a melt; gas containing oxycarbide is introduced into the melt to selectively oxidize magnesium metal and lithium metal to generate a mixed product of magnesium oxide, lithium oxide and graphite carbon, the mixed product is migrated into a molten salt layer on the surface of the melt to form salt slag, the salt slag is subjected to acid leaching and solid-liquid separation, graphene is obtained, and the leaching solution is the magnesium-lithium leaching solution. According to the method, the aluminum alloy waste containing magnesium and lithium serves as the raw material, magnesium and lithium components in the alloy waste are extracted, oxycarbide is converted into high-value graphene in situ, the process technical route is simple and easy to implement, no pollutant or waste is generated, and the requirements of low-carbon development and industrial application are met.

The present invention provides a method for producing lithium hydroxide, comprising the steps of reacting lithium carbonate and calcium hydroxide in a liquid to obtain a solution containing lithium hydroxide, and performing solid-liquid separation on the solution into a liquid component containing lithium hydroxide and a solid component containing lithium derived from the lithium carbonate, and recovering lithium hydroxide from the liquid component.

The invention discloses a method for in-situ lossless repair of an attenuated lithium manganate positive electrode material, which specifically comprises the following steps: adding the attenuated lithium manganate material into a lithium hydroxide solution, supplementing lithium to an original value by a hydrothermal method, repairing the component and structure defects of attenuated LiMn2O4 by combining high-temperature roasting, and recycling and regenerating lithium manganate particles with severely attenuated capacity. The lithium manganate positive electrode material is directly recovered by the lossless method, and the chemical components and crystallinity of the invalid positive electrode material in various health states are reconstructed, so that the invalid positive electrode material can be repeatedly used in the lithium ion battery. Finally, the treated recycled powder material is coated by a metal organic framework (MOFs) self-assembly method, so that the electrochemical performance of the treated powder material is further improved. The method is simple, environmentally friendly and low in energy consumption, has obvious advantages compared with a traditional hydrometallurgy battery recovery method, and lays an important foundation for sustainable manufacturing of energy materials.

In a method for producing a preactivated lithium transition metal oxide (LiTMO) for a lithium ion cycling battery, the LiTMO is immersed in an electrolyte disposed in a reactor comprising a working electrode and a counter electrode ionically connected via the electrolyte. The LiTMO is subjected to an electrochemical delithiation and relithiation cycle comprising an electrochemical delithiation step followed by an electrochemical relithiation step. In the electrochemical delithiation step, an electric current is applied to the working electrode in such a way that the LiTMO is oxidized, lithium ions are released from the LiTMO to form a delithiated LiTMO, and the lithium ions released from the LiTMO dissolve in the electrolyte.In electrochemical relithiation, an electric current is applied to the counter electrode in such a way that the LiTMO is reduced and the lithium ions dissolved in the electrolyte are incorporated into the LiTMO to form a relithiated LiTMO.

The invention belongs to the technical field of glass materials, and particularly relates to black high-hardness heat-resistant microcrystalline glass ware and a preparation method thereof. Silicon dioxide, sodium oxide, aluminum oxide, potassium oxide, boric oxide, magnesium oxide, calcium oxide, zinc oxide, sodium fluosilicate, iron oxide, manganese oxide, fluorite, lithium oxide, metal manganese coated with silicon dioxide and schorlite are used as raw materials, and the black high-hardness heat-resistant microcrystalline glass ware is prepared through the processes of high-temperature melting and mixing, compression molding, annealing and tempering. The black high-hardness heat-resistant microcrystalline glass ware is excellent in performance, high in hardness and good in heat resistance, and has potential market value.

The invention discloses a graphite composite material and a preparation method thereof and a lithium ion battery, and relates to the technical field of battery material preparation, and the preparation method of the graphite composite material comprises the following steps: obtaining amidated graphite, mixing the amidated graphite, lithium peroxide, a hydrogen peroxide solution and an organic acid reagent, and carrying out a cross-linking reaction to obtain an intermediate; and mixing the intermediate with a curing agent and asphalt, and sequentially carrying out curing reaction and carbonization reaction to obtain the graphite composite material. Wherein the amidated graphite is oxidized and crosslinked by two oxidants including lithium peroxide and a hydrogen peroxide solution under an acidic condition, and lithium ions dissociated from the lithium peroxide can enter interlamellar gaps of the graphite; the intermediate and the curing agent are further crosslinked to form a more complex three-dimensional network structure, and the surface of the graphite is coated with soft carbon through carbonization treatment, so that the stability, the first efficiency, the fast charging performance and the high-temperature performance of the graphite material are improved.

The invention provides composite coated high-stability lithium-rich lithium ferrite and a preparation method thereof, and belongs to the field of lithium ion battery positive electrode lithium supplements.The preparation method of the composite coated high-stability lithium-rich lithium ferrite comprises the steps that an iron source and a lithium source are mixed, and a first mixture is obtained; performing first calcining treatment on the first mixture to obtain a calcined product; mixing and dispersing the calcined product and a metal compound to obtain a second mixture; carrying out second calcining treatment on the second mixture to obtain composite coated high-stability lithium-rich lithium ferrite; wherein the ratio of the amount of substance of the lithium element in the lithium source to the amount of substance of the iron element in the iron source is greater than 5. According to the method, excessive lithium sources are introduced, so that a large amount of residual lithium on the surface of Li5FeO4 forms a residual alkali layer, the residual alkali layer is converted into a compact and complete metal lithium oxide coating layer under the action of the metal compound and the second calcination treatment, and the air stability of Li5FeO4 is effectively improved.