The application provides a preparation method of
rubidium hydroxide monohydrate and belongs to the technical field of
chemical production.
Rubidium carbonate,
calcium oxide and water are mixed to generate transformation, and a transformation liquid and a transformation residue are obtained; the transformation liquid is concentrated, and a concentrated liquid and a
calcium hydroxide residue are obtained through
filtration; the concentrated liquid and an additive are mixed, negative pressure
distillation is carried out, the obtained solution is cooled and kept warm, gradient cooling is carried out,
solid-liquid separation is carried out, and
rubidium hydroxide monohydrate wet material is obtained; the
rubidium hydroxide monohydrate wet material is vacuum dried, and
rubidium hydroxide monohydrate is obtained. When
rubidium hydroxide is prepared, an additive is added in the concentrated liquid, so that the
crystal directional arrangement of
rubidium hydroxide is realized when the rubidium hydroxide is cooled and crystallized, large-particle rubidium hydroxide monohydrate crystals are obtained, the prepared rubidium hydroxide monohydrate is in a granular form, the
crystal shape is regularly and stably arranged, the rubidium hydroxide monohydrate cannot be hydrolyzed and decomposed at high temperature, is not easy to absorb water under
normal conditions, the water-rubidium ratio of the product is 1:1, and the
impurity is less than 0.01%.