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Preparation method of microcrystalline glass applied to 5G communication mobile terminal

A technology for glass-ceramics and mobile terminals, which is applied in the field of glass-ceramics used in 5G communication mobile terminals, can solve problems such as use, poor color balance, and easy breakage, and achieves simple preparation of raw materials, improved mechanical properties, and stable processes. Effect

Inactive Publication Date: 2018-11-16
GLASS TECH RES INST OF SHAHE CITY OF HEBEI PROVINCE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Crystallization heat treatment of aluminosilicate glass can obtain transparent glass-ceramics with spinel and quartz solid solution as the main crystal phase, which has high hardness and strength, but its impact resistance is not strong enough
[0005] In the patent document CN106242299A, a kind of glass-ceramics is disclosed, and the glass-ceramics precipitates MgAl 2 o 4 , MgTi 2 o 4 Isocrystalline phase, the transmittance after crystallization heat treatment is greater than 50%, and its mechanical properties have also been improved to a certain extent, but the production method mentioned is to use a crucible to melt and then pour it into a mold, which is difficult to achieve continuous production in large quantities, and there is no Publish the specific crystallization heat treatment process; and it solves the problem of poor color balance. Although sufficient compressive stress values ​​can be obtained through the ion exchange process, a deep stress layer cannot be formed, resulting in Breaks easily and cannot be used as a phone front or back cover

Method used

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  • Preparation method of microcrystalline glass applied to 5G communication mobile terminal

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] A preparation of transparent glass-ceramics applied to 5G communication mobile terminals, comprising the following steps:

[0043] A. Preparation of raw materials

[0044] In parts by weight, prepare 50 parts of quartz sand, 20 parts of alumina, 15 parts of sodium carbonate, 5 parts of potassium nitrate, 6 parts of lithium carbonate, 15 parts of magnesium carbonate, 5 parts of zirconia, 6 parts of zinc oxide, and 4 parts of titanium oxide. 6 parts, 6 parts of ammonium dihydrogen phosphate, 1 part of antimony oxide, 1 part of yttrium oxide, mixed to obtain batching material;

[0045] B. Glass melting

[0046] Put the above batch materials into the melting furnace, melt at 1500°C, homogenize and clarify at high temperature, and melt the batch materials into a uniform and defect-free glass melt;

[0047] C. Glass forming

[0048] The above-mentioned glass melt goes through the forming process, flows into the tin bath through the runner, starts forming at 1250 ° C, and b...

Embodiment 2

[0057] A dark brown glass-ceramic applied to the back cover of a 5G communication mobile terminal, the preparation process is as follows:

[0058] A. Batch preparation

[0059] In parts by weight, take 50 parts of quartz sand, 20 parts of aluminum oxide, 18 parts of sodium carbonate, 5 parts of potassium nitrate, 6 parts of lithium carbonate, 15 parts of magnesium carbonate, 4 parts of titanium oxide, 1 part of antimony oxide, and 3 parts of iron oxide. Parts, accurately weigh the batch material, place it in the mixer, and enter the next process after mixing evenly;

[0060] B. Glass melting

[0061] Put the above-mentioned batch materials into the electric melting furnace, melt at 1650°C, homogenize and clarify at high temperature, and melt the batch materials into a uniform and defect-free melt;

[0062] C. Glass forming

[0063] The melted glass flows into the tin bath through the flow channel, and begins to form at 1250°C, and becomes a 1.2mm thick glass original sheet ...

Embodiment 3

[0072] A method for preparing a transparent glass-ceramic for a front cover applied to a 5G communication mobile terminal, comprising the following steps:

[0073] A. Preparation of raw materials: by weight, prepare 48.2 parts of quartz sand, 20.6 parts of alumina, 26.7 parts of sodium carbonate, 2.3 parts of potassium nitrate, 7.4 parts of lithium carbonate, 15 parts of magnesium carbonate, 2 parts of zirconia, rubidium oxide 1 part, 3 parts of ammonium dihydrogen phosphate, 1 part of antimony oxide, mixed to obtain batch materials;

[0074] B. Glass melting: Put the above batch materials into the melting furnace, melt them at 1600°C, homogenize and clarify at high temperature, and melt the batch materials into glass melt;

[0075] C. Glass forming: the above-mentioned glass melt is passed through the float forming process, and the above-mentioned glass melt is cooled to 1250°C-1200°C and flowed into a tin bath for forming, and it is flattened and polished at 1193-1127°C. Ul...

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Abstract

The invention provides a preparation method of a microcrystalline glass applied to a 5G communication mobile terminal, and belongs to the technical field of microcrystalline glass. The preparation method comprises following steps: step A, preparing following raw materials in parts by weight: 45 to 75 parts of quartz sand, 10 to 25 parts of aluminum oxide, 14.5 to 39.6 parts of sodium carbonate, 2.3 to 9.2 parts of potassium nitrate, 0 to 12.5 parts of lithium carbonate, 0 to 41 parts of magnesium carbonate, 0 to 8 parts of titanium oxide, 0 to 20 parts of zirconium oxide, 0 to 10 parts of zincoxide, 0 to 3 parts of rubidium oxide, 0 to 5 parts of gallium oxide, 0 to 3 parts of europium oxide, 0 to 9 parts of ammonium dihydrogen phosphate, 0 to 3 parts of antimony oxide, 0 to 3 parts of yttrium oxide, 0 to 3 parts of cerium oxide, 0 to 5 parts of iron oxide, 0 to 2 parts of manganese oxide, 0 to 3 parts of nickel oxide, and mixing all raw materials to obtain a mixture; step B, meltingthe mixture; step C, moulding the melt; and step D, carrying out annealing, nucleation, and crystallization to obtain the microcrystalline glass. By controlling the raw materials and technology, the obtained front cover microcrystalline glass has high transmittance of visible light, high strength, and high hardness, and the obtained rear cover microcrystalline glass has high strength and low magnetic loss.

Description

technical field [0001] The invention belongs to the technical field of glass-ceramics, and relates to glass-ceramic applications applied to 5G communication mobile terminals or other glass applications requiring antimagnetism, light transmittance, strength, etc., and specifically relates to a glass-ceramic applied to 5G communication mobile terminals The preparation method, the preparation method of the present invention is used to prepare the glass-ceramic of the 5G communication mobile terminal, and through the combination control of the raw material and the process, it is possible to obtain a front cover glass with high visible light transmittance and high strength and hardness. Crystal glass material, and back cover glass-ceramic material with high strength and low magnetic loss. Background technique [0002] With the development of modern technology, the update speed of electronic display devices is accelerating. The requirement of portability, the transformation of 5G...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C6/04C03B32/02C03B25/00C03C10/02C03C21/00
CPCC03B25/00C03B32/02C03C1/00C03C10/0018C03C21/002
Inventor 郑伟宏袁坚田培静彭志钢杜晓欧史连莹张茂森刘皓
Owner GLASS TECH RES INST OF SHAHE CITY OF HEBEI PROVINCE
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