The invention relates to the technical field of flexible transparent electrodes, in particular to a Cu / Al laminated
metal grid flexible transparent
electrode and a preparation method thereof. The Cu / Al laminated
metal grid flexible transparent
electrode comprises a flexible substrate, a
copper layer arranged on the flexible substrate and an aluminum layer arranged on the
copper layer, and the aluminum layer located on the outer layer spontaneously forms an Al2O3
passivation layer with the thickness of 2-5 nm in air. The Al2O3
passivation layer can effectively prevent
oxygen and
moisture from permeating inwards, so that oxidation of the
copper layer in a humid or high-temperature environment is fundamentally inhibited, long-term stability of the electrical property of the
electrode is ensured, and meanwhile, due to the fact that the thickness of the copper layer is 150-250 nm, excellent
conductivity is provided, and low square resistance is achieved; the latticed structure maintains high light
transmittance of the electrode while ensuring a high conductive path. Finally, the structure has excellent
oxidation resistance, high light
transmittance, low
sheet resistance and flexible stability under the support of a flexible transparent substrate with the thickness of 50-200 [mu] m, and meets the harsh requirements of a new generation of flexible optoelectronic devices on electrode performance.