1100 results about "Iron oxide" patented technology

The invention belongs to the field of metal materials, and particularly relates to a high-strength hot-rolled pickled steel plate for an automobile chassis and a production method thereof. The steel plate is mainly suitable for manufacturing automobile chassis structural parts. The steel comprises the following chemical components: C, Si, Mn, Al, V, Ni, Cu, Cr, Pt and Y, P is limited to be less than or equal to 0.015%, S is limited to be less than or equal to 0.005%, N is limited to be less than or equal to 0.006%, and the balance is Fe and inevitable impurities. The yield strength of the steel plate ranges from 498 MPa to 552 MPa, the tensile strength ranges from 608 MPa to 643 MPa, the transverse elongation A ranges from 33% to 38%, the steel plate is qualified after transverse cold bending by 180 degrees D = a, the surface quality is good, oxide scale stripes and chromatic aberration defects are avoided, the surface roughness Ra ranges from 1.10 micrometers to 1.35 micrometers, and the steel plate has excellent corrosion resistance.

The invention discloses an enamel ceramic glaze tile with a metal spot bionic effect and a preparation method thereof, and relates to the technical field of ceramics. The enamel porcelain glaze tile comprises a bottom blank, a metal ground glaze layer and a semi-opaque cover glaze layer, the metal ground glaze layer is prepared from a first ground glaze formula or a second ground glaze formula, and the first ground glaze formula comprises, by mass, potassium feldspar, quartz, calcite, kaolin, talc, zinc oxide, ferric oxide and manganese dioxide; the formula of the second ground glaze comprises the following components in percentage by mass: potassium feldspar, quartz, calcite, kaolin, talc, zinc oxide, ferric oxide and chromic oxide; the semi-opaque surface glaze layer is prepared from the following raw materials in percentage by mass: albite, calcite, talc, burnt soil, zircon powder, oriental zirconium, calcined zinc oxide, black clay powder and calcined aluminum oxide. Through a double-layer glaze structure and a black mud powder glaze breaking mechanism, the stereoscopic visual effect that metal spots are randomly generated on an opacifying substrate is achieved, and meanwhile the Moh's hardness of the ceramic tile is improved.

The invention belongs to the field of metal materials, and particularly relates to a high-elongation 288MPa-grade hot-rolled pickled steel plate for an automobile and a production method thereof. The steel plate is mainly suitable for manufacturing automobile chassis structural parts. The steel comprises the chemical components of C, Si, Mn, Al, Ti, Zr, Ni, Pt and Y, P is limited to be smaller than or equal to 0.015%, S is limited to be smaller than or equal to 0.005%, N is limited to be smaller than or equal to 0.003%, and the balance is Fe and inevitable impurities. The steel plate has excellent mechanical properties, the yield strength of the steel plate is larger than or equal to 238 MPa, the tensile strength is larger than or equal to 288 MPa, the transverse elongation A is larger than or equal to 48%, the hole expansion rate is larger than or equal to 132%, transverse cold bending is conducted by 180 degrees, D = a, the steel plate is qualified, the surface quality is good, oxide scale stripes and chromatic aberration defects are avoided, the surface roughness Ra is 1.08-1.48 micrometers, and the steel plate has good corrosion resistance.

The invention discloses a production method of ferrous dihydrogen phosphate, which comprises the following steps of: changing an iron source of iron-process iron phosphate from traditional iron blocks or iron powder into oxide scale, compounding phosphoric acid and sulfuric acid into mixed acid, and controlling the granularity of the oxide scale and the components and acidity of the mixed acid to solve the problems of dissolution and passivation of the oxide scale. According to the method, iron oxide scale can be better dissolved, the residual problem of ferric ions is solved by reducing excessive iron blocks or iron powder, undissolved impurities such as carbon, silicon and iron are removed by filtering, and finally, the stability problem of a reaction system is solved by adjusting the pH value of the system through industrial phosphoric acid and pure water, so that a ferrous dihydrogen phosphate solution required for producing iron phosphate is obtained. The production cost of an iron source required by iron phosphate is greatly reduced, other impurities are not contained, and mixed acid-containing filtrate and washing water generated in the production process can be recycled through an evaporation device.

The invention relates to the field of coating materials, and provides an antiskid coating based on carbon fibers and a preparation method thereof. The coating is composed of a component A and a component B, the component A comprises KH-570 silane coupling agent surface modified carbon fibers, dog bone-shaped nano silicon dioxide, epoxy modified hydroxy acrylic resin, quartz sand antiskid aggregate, propylene glycol methyl ether acetate, iron oxide pigment and other auxiliaries, and the component B is an HDI tripolymer curing agent. The surface modified carbon fiber is prepared through the steps of cleaning and activating, silane coupling agent dipping, drying and curing and the like, and the dog bone-shaped nano silicon dioxide is prepared through a sol-gel method with hexadecyl trimethyl ammonium bromide and polyvinylpyrrolidone as morphology guiding agents. The preparation method comprises the steps of iron oxide color paste preparation, functional component dispersion, quartz sand addition, curing treatment, double-component mixing and curing and the like. The coating has excellent dry skid resistance, wet skid resistance, wear resistance and durability, and is suitable for the field of ground skid resistance coating.

A full-continuous short-process production method for a metal plate strip comprises the steps of smelting, tundish induction heating, thin strip continuous casting, rolling, 1 # flying shearing, cooling after rolling, acid-free descaling, 2 # flying shearing and strip steel coiling, and a steel coil without oxide scale on the surface is obtained. The metal plate strip comprises the following components in percentage by weight: 0.01-0.06% of C, less than or equal to 0.15% of Si, less than or equal to 0.85% of Mn, less than or equal to 0.02% of P, less than or equal to 0.005% of S and Alslt; 0.001%, less than or equal to 0.0050% of Ca, and the balance Fe and other unavoidable impurities. The method comprises the following steps: carrying out on-line hot rolling on a cast strip cast by double rollers through an on-line six-roller mill, and carrying out an acid-free descaling process to obtain a steel coil without oxide scale on the surface. Products produced through the method are high in ductility, good in forming performance and high in surface quality, and the purpose that cold is replaced by hot in the field of high-end products can be truly achieved.

The invention relates to the technical field of cement-based material preparation, and particularly discloses a preparation method of an anti-carbonization all-solid waste slag-sulphoaluminate cementing material, which comprises the following steps: (1) putting a wet material formed by lead-zinc tailing powder and water into a reaction container, sealing, and heating; and mixing the obtained product with iron powder and / or iron oxide powder and water, stirring, separating out a solid product, and heating and drying in an air atmosphere to obtain the anti-carbonization tailing powder. And (2) mixing the anti-carbonization tailing powder with sulphoaluminate cement powder, and carrying out mechanical grinding treatment to obtain the modified sulphoaluminate cement. And (3) uniformly mixing blast furnace slag powder, the modified sulphoaluminate cement, fly ash, waste gypsum powder, an alkali activator, gypsum and a water reducing agent serving as raw materials to obtain the cementing material. According to the invention, the resource utilization of industrial solid waste is realized, the carbonization resistance of the cementing material is effectively improved, and the service durability of the cementing material is improved.

The invention relates to the technical field of steel rolling, and discloses a Q355B steel hot rolling process optimization method based on dynamic temperature control, which comprises the following steps: blank pretreatment, dynamic heating control, high-pressure water descaling, rough rolling process, finish rolling process, laminar cooling and coiling process. According to the method, a collaborative system of multi-section variable-temperature heating and intelligent temperature control is constructed, temperature distribution in a furnace and the heating rate are monitored and dynamically adjusted in real time, it is guaranteed that the core surface temperature of a plate blank is uniform and consistent, thermal stress and the internal crack tendency in the heating process are eliminated, and a high-temperature blank uniform in structure and stable in performance is provided for follow-up rolling; meanwhile, the high-pressure water descaling system optimizes jet flow parameters and introduces chemical additives, so that a protective layer is formed while oxide scales on the surface are removed, the surface cleanliness and quality of the plate blank are improved, and product defects caused by incomplete descaling and surface damage are avoided.

The invention discloses a device and a method for regenerating a powdery iron oxyhydroxide desulfurizer and purifying sulfur, and the device and the method are characterized in that invalid iron oxyhydroxide is completely reduced into a ferrous oxide and ferrous sulfide after sulfide is added, the reaction of an iron compound is enhanced through ultrasound and stirring, and the separation of the iron compound and the sulfur is promoted. Further fully aerating to fully oxidize the ferrous iron to generate new iron oxyhydroxide; at the moment, the iron oxyhydroxide is in a completely dispersed state, the single particle size is not higher than 1 micron, and small flocs with the particle size of 0-5 microns are formed in laminar water; the surface of the sulfur has hydrophobicity, and the sulfur is gathered to generate hydrophobic self-flocculation, so that large flocs with the particle size of 30-300 microns are formed in the laminar water; the mixture is flushed by water flows with different flow speeds, the iron oxyhydroxide with small particle size is flushed out at a certain flow speed, and the sulfur with large particle size is suspended in the grading pipe, so that the regeneration of the iron oxyhydroxide desulfurizer and the purification of the sulfur are realized.

Provided is a hydrogen sulfide removing agent that can be stably used while maintaining hydrogen sulfide removing ability equivalent to that of a hydrogen sulfide removing agent comprising an amorphous iron oxyhydroxide. This iron oxyhydroxide-based hydrogen sulfide removing agent contains amorphous iron oxyhydroxide and a crystalline component. The content of the amorphous iron oxyhydroxide is not less than the content of the crystalline component.

The invention provides a method for preparing high-purity titanium from ferrotitanium complex ore, and relates to the technical field of nonferrous metallurgy. The method comprises the following preparation steps: calculating and adding a carbonaceous reducing agent according to the components of the ferrotitanium complex ore and a specific principle, mixing and pelletizing, and reducing to generate a Fe (alloy)-TiC-MOx mixture; according to the content of TiC and Fe in the mixture, adding metal iron powder and Fe2O3 or iron ore concentrate according to a certain stoichiometric ratio, mixing, pelletizing, and reducing to obtain a titanium-iron alloy; and the obtained ferrotitanium alloy serves as a soluble anode, and high-purity titanium is prepared through electrolysis in halide molten salt containing low-valence titanium salt. According to the method, the reaction characteristic of iron and iron oxide with TiC at high temperature is utilized, the ferrotitanium alloy is generated from the ferrotitanium complex ore to serve as the soluble anode, then the high-purity titanium is prepared through molten salt electrolysis, the adverse effects of component deviation and anode precipitates existing in the soluble anode containing the titanium compound are avoided, and meanwhile casting forming is easy, and the method is more suitable for industrialization.

The invention discloses a high-toughness grouting material and a preparation method thereof, and belongs to the technical field of building materials. The photochromic thermal insulation material is prepared from the following raw materials in percentage by mass: 30 to 36 percent of sulphoaluminate cement, 28 to 32 percent of quartz sand, 0.4 to 0.9 percent of nano graphene / carbon tube hybrid, 12 to 15 percent of superfine composite admixture, 1.0 to 1.8 percent of temperature-sensitive shape memory alloy fiber, 1.5 to 2.0 percent of microbial self-repairing capsule, 15 to 18 percent of photochromic epoxy hybrid emulsion, 0.2 to 0.35 percent of polycarboxylate superplasticizer and 0.8 to 1.2 percent of magnetic iron oxide coated SiO2 expanding agent. According to the invention, the active inhibition that the crack width is less than or equal to 0.05 mm is realized through the shrinkage compensation of the magnetic field oriented expanding agent, the temperature-sensitive fiber phase change toughening and the photochromism-microorganism synergistic repair.

The utility model belongs to the technical field of cleaning of oxide scales on the surfaces of steel billets, and discloses equipment for cleaning and recycling oxide scales of steel-making steel billets, which comprises two side plates, a steel billet roller way is arranged between the two side plates, and a fixed support is fixedly mounted at the top ends of the two side plates. An electric push rod is fixedly installed in the fixed support, the output end of the electric push rod is fixedly connected with a supporting frame, a first steel wire roller is rotationally connected between the inner walls of the supporting frame, movable frames are symmetrically and slidably installed in the two side plates, and steel plates are fixedly connected to the opposite ends of the two movable frames. The first steel wire roller and the second steel wire roller are designed above the steel billet roller way, so that the high-temperature-resistant first steel wire roller and the high-temperature-resistant second steel wire roller are in rolling contact with steel billets in the steel billet conveying process of the steel billet roller way, oxide scales on the steel billets are removed, and the subsequent steel billet machining quality and efficiency are guaranteed.

The application discloses a kind of composite desulfurizer suitable for oxygen-containing condition desulfurization and its preparation method and application, belong to desulfurizer technical field.The composite desulfurizer is double-layer composite structure;Wherein: outer layer is iron oxide hydroxyl layer, including iron oxide hydroxyl and first binder;Inner layer is copper zinc aluminum layer, including copper oxide, zinc oxide, alumina and second binder.The composite desulfurizer obtained in the application significantly improves the service life of desulfurizer under oxygen-containing condition, and the sulfur capacity of desulfurizer can be as high as 10~20%, and the simultaneous removal of organic sulfur and inorganic sulfur can be realized in one step, effectively reducing the desulfurization cost, with important application prospect.In addition, the preparation of double-layer structure composite desulfurizer is realized by double-layer extruding machine in the application, and the process is simple, which is beneficial to industrialized mass production.

A method of remediating wastewater is provided, the method comprising substantially submersing an electrocatalytic reactor in wastewater, the electrocatalytic reactor including an anode, which is mesh and defines a first bore, a filter layer, which is porous glass, carbon fiber or poly-paraphenylene terephthalamide, the filter layer including fibers and interstitial spaces between the fibers, an iron-doped titanium dioxide film on the fibers, the film including a surface that is substantially iron oxide free, the filter layer housed within the first bore and defining a second bore, a cathode, which is housed within the second bore, is mesh and defines an inner bore, and a perforated air tube housed within the inner bore; and providing at least a voltage of at least about 3 volts to the electrocatalytic reactor, in the absence of a light source, thereby remediating wastewater.

A silicone rubber insulator shed material, and a silicone rubber insulator and a preparation method therefor and an application thereof. The components of the silicone rubber insulator shed material comprise silicone rubber, iron oxide, nano-montmorillonite, fumed silica, aluminum hydroxide, a silane coupling agent, a vulcanizing agent, and hydroxy silicone oil, wherein the iron oxide and the nano-montmorillonite can slow down the thermal oxidation decomposition of the silicone rubber, thus improving the hydrophobicity, hydrophobic mobility and hydrophobic recovery of the silicone rubber composite insulator, thereby solving the technical problem in the prior art that the aging decomposition resistance of silicone rubber needs to be improved.

The method for separating the iron powder through Bayer process red mud pretreatment comprises the steps that Bayer process red mud slurry and a liquid medium are mixed, and mixed slurry is formed; adding a pretreatment aid into the mixed slurry, and pretreating the mixed slurry to modify the surface property of the red mud iron powder in the mixed slurry or improve the rheological property of the mixed slurry; the pretreated mixed slurry is subjected to rotational flow separation, the red mud iron powder is enriched in a solid enrichment phase obtained through rotational flow separation, and the solid enrichment phase containing the red mud iron powder and a liquid dispersion phase are obtained; separating the solid enriched phase containing the red mud iron powder to obtain iron oxide powder; and recycling the liquid dispersion phase as a liquid medium mixed with the Bayer process red mud slurry. According to the embodiment of the invention, through the synergistic effect of mixing, pretreatment and cyclone separation, the separation efficiency and grade of the red mud iron powder are effectively improved from multiple aspects of physical property adjustment, surface property modification and the like.

The invention belongs to the technical field of comprehensive utilization of metallurgical and chemical resources, and discloses a method for improving the productivity of magnet powder and sulfuric acid by adding pyrite in copper smelting. According to the method, a heat release rate, SO2 generation kinetics and an iron oxide phase change path are synergistically optimized by constructing a gradient blending mechanism of pyrite and an in-furnace oxygen potential directional oxidation regulation and control system. The method is characterized in that on the basis of real-time feedback of the molten pool temperature, the flue gas SO2 concentration and the slag phase FeO activity, the pyrite blending rate, the granularity and the carrier gas oxygen concentration are dynamically regulated and controlled in a staged mode; a reduction microenvironment in which logpO2 is approximately equal to-11 is created on a slag-sulfonium interface, and growth of Fe3O4 crystal nucleus is promoted; and the flue gas cooling and acid-making gas inlet stability is optimized. According to the method, the capacity of the magnet powder and the capacity of the sulfuric acid are synchronously improved, the stability and the high efficiency of the copper smelting main process are guaranteed, and an engineering-oriented technical path is provided for comprehensive utilization of resources of copper smelting enterprises.

The invention discloses a rare-earth-based soil remediation catalyst as well as a preparation method and application thereof. The catalyst takes a composite oxide of micron-sized aluminum oxide and titanium dioxide as a carrier, a nano-fiber composite oxide of cerium oxide and copper oxide as an active component and a nano-particle composite oxide of iron oxide and manganese dioxide as a cocatalyst; on the basis of the mass of the carrier, the mass percentage of the active component is 5-10%, and the mass percentage of the cocatalyst is 3-6%. The catalyst synthesized through the method has the advantages of being good in soil compatibility, high in catalytic efficiency and the like, and the target of low-energy-consumption remediation of organic pollutant soil can be achieved.

The invention discloses a grinding device for preparing micro-nano reduced iron powder from high-purity iron oxide powder, and relates to the technical field of iron oxide powder preparation. The grinding device for preparing the micro-nano reduced iron powder from the high-purity iron oxide powder comprises a base, a filtering assembly is arranged on the upper surface of the base, a grinding assembly is arranged at the top of the filtering assembly, a disassembling assembly is arranged at the top of the grinding assembly, and a cylinder is fixedly installed on the surface of the grinding assembly and located on the base. The grinding assembly comprises a vertical pipe in threaded connection with the top of the cylinder, and a grinding net is fixedly installed on the inner bottom wall of the vertical pipe. According to the grinding device, the arrangement of the grinding assembly is ensured, the grinding net can be cleaned while grinding is carried out in the using process, raw material residues and blockage can be effectively avoided in the grinding process, and the situation that normal grinding operation cannot be carried out after the grinding net is blocked is avoided, so that normal use of the grinding device is kept while the cleanliness of the grinding net is kept; and the use convenience of the grinding device is improved, and subsequent normal use is facilitated.

A method and equipment for recycling alumina red mud. First, the alumina red mud is added to a mixed acid of hydrochloric acid and sulfuric acid for reaction to dissolve metals such as iron, aluminum, calcium, sodium, and a small amount of zinc, copper, magnesium, etc., and the solid silicon dioxide is left to be separated as building materials or glass raw materials; after the solution is collected, ammonium bicarbonate is added to obtain aluminum, calcium, and some metal precipitates and separated. Iron and sodium remain in the solution and continue to react with sodium hydroxide to obtain iron hydroxide precipitate and separate out sodium salts. After evaporation of the concentrated solution, iron oxide is obtained as a raw material for steel production; the aluminum, calcium, and other metal precipitates are added to sulfuric acid with a concentration of 90-98% for reaction. After all are dissolved, the solution is subjected to membrane separation and then carbonates are added to obtain calcium carbonate precipitate as a raw material for cement production; after evaporation of the concentrated solution, high-purity alumina is obtained and sent to an aluminum processing plant to produce pure aluminum or aluminum alloy products; the separated sodium salt solution is evaporated to be used as industrial and agricultural salt; the acid mist and harmful gases in the reactor process are treated by an absorption tower and then discharged. The present invention can make full use of the iron oxide, alumina, and effective components of alumina red mud, solves the problem of environmental pollution caused by the large amount of piled-up alumina red mud at present, has a low cost, and is suitable for the current alumina production plants.

The invention provides a method for separating and recovering titanium, iron and vanadium from vanadium-titanium-iron concentrate, and relates to the technical field of comprehensive utilization of vanadium-titanium magnetite. Vanadium-titanium-iron concentrate obtained through mineral separation is subjected to grinding treatment and then leached through high-concentration hydrochloric acid, and acid leaching liquid containing ions such as iron and vanadium and acid leaching residues mainly containing oxides such as titanium and silicon are obtained; leaching the acid leaching residues with sodium hydroxide alkali liquor, removing SiO2 impurities in the acid leaching residues to obtain alkali leaching residues, and washing and heating the alkali leaching residues to obtain a high-purity TiO2 product; carrying out high-temperature pyrolysis on the pickle liquor to prepare superfine powder iron oxide red, and absorbing hydrogen chloride gas formed by pyrolysis by water to form hydrochloric acid for recycling; the method comprises the following steps: washing iron red with water to remove chlorine salt impurities in the iron red, leaching vanadium in the iron red by using a carbonate solution, and filtering to obtain a vanadium solution and iron leaching residues.

The invention belongs to the technical field of glass materials, and particularly relates to black high-hardness heat-resistant microcrystalline glass ware and a preparation method thereof. Silicon dioxide, sodium oxide, aluminum oxide, potassium oxide, boric oxide, magnesium oxide, calcium oxide, zinc oxide, sodium fluosilicate, iron oxide, manganese oxide, fluorite, lithium oxide, metal manganese coated with silicon dioxide and schorlite are used as raw materials, and the black high-hardness heat-resistant microcrystalline glass ware is prepared through the processes of high-temperature melting and mixing, compression molding, annealing and tempering. The black high-hardness heat-resistant microcrystalline glass ware is excellent in performance, high in hardness and good in heat resistance, and has potential market value.

The invention discloses an acid regeneration system, a control method thereof and a medium. The acid regeneration system comprises a man-machine operation device, a controller and an acid regeneration unit, and the controller is used for receiving a control instruction sent by the man-machine operation device and sending an execution instruction to the acid regeneration unit according to the control instruction; the execution instruction comprises a steam condensate water amount execution instruction, and the steam condensate water conveying device is used for controlling the water amount of conveyed steam condensate water based on the steam condensate water amount execution instruction; the acid regeneration unit comprises a desilicication unit and a roasting unit; the desiliconization unit is used for desiliconizing the waste acid liquid to obtain purified iron liquid; the desiliconization unit comprises a purified iron liquid buffer tank for storing purified iron liquid and a steam condensate water conveying device for conveying steam condensate water to the purified iron liquid buffer tank, and the steam condensate water is used for diluting the purified iron liquid; and the roasting unit is used for roasting the diluted purified iron liquid to obtain iron oxide powder and regenerated acid. The iron oxide powder obtained by the system is good in quality.

The utility model discloses a novel oxide scale collecting device. Which comprises a hot-rolled rod and wire conveying roller way, and is characterized in that a chain plate type conveyor is arranged below the roller way; a slag collecting hopper is arranged at the tail part of the chain plate type conveyor; and an iron sheet slag collecting box is arranged below the slag collecting hopper. According to the utility model, the oxide scale does not need to be flushed into the rotational flow well or the primary sedimentation tank by using additional slag flushing water and slag flushing runner and then is collected by using a grab bucket type travelling crane, so that energy conservation and emission reduction are realized. Meanwhile, the design of a slag sluice of a furnace discharging table and a slag sluice of a roughing mill unit area is omitted, only the slag sluice with small gradient and depth in the area from an intermediate mill unit to a finishing mill unit is reserved, and a large amount of cooling water doped with only a small amount of oxide scale powder can be recycled.

The invention relates to a low-cobalt-salt adhesion promoter and a preparation method thereof, and relates to the technical field of rubber adhesives, the low-cobalt-salt adhesion promoter is of a core-shell structure and comprises, by mass, 10-15 parts of core metal precursor powder, 15-20 parts of a shell SiO2 shell layer and 5-8 parts of long-chain alkylsilane grafted to the surface of the SiO2 shell layer; the metal precursor powder comprises cobalt hydroxide, manganese hydroxide and ferric hydroxide, and the molar ratio of the cobalt hydroxide to the manganese hydroxide to the ferric hydroxide is 1: (2-3): (1-1.5). According to the invention, the dispersibility of the low-cobalt salt adhesion promoter and the compatibility with rubber can be effectively improved.

The invention discloses a comprehensive utilization method of refining slag, which comprises the following steps: dissolving the refining slag in hydrochloric acid to obtain a refining slag pickle liquor; filtering the refining slag pickle liquor to obtain first filtrate and filter residues, and washing the filter residues to obtain first solid and first washing liquor; combining the first washing liquid and the first filtrate to obtain a second mixed solution; and adding an oxidizing agent into the second mixed solution to obtain a first precipitate. According to the method, the refining slag is subjected to acid leaching with hydrochloric acid, the PH value of the solution is adjusted, silicon dioxide, aluminum hydroxide, ferric hydroxide, calcium chloride or calcium oxide and recycled hydrochloric acid are obtained, the accumulated refining slag is decomposed into various new substances in the process reaction, the method is simple, the substance purity is high, the refining slag is recycled, and large economic value can be created; and meanwhile, mining of various resources is reduced. And a new direction is found for comprehensive utilization of the refining slag.

The invention relates to the technical field of oily sewage treatment, and discloses a flocculant as well as a preparation method and application thereof. The flocculant contains a component A, a component B, a component C and a component D, the component A contains etherified starch and nano magnetic iron oxide, the component B contains sodium bentonite and nano magnetic iron oxide, the component C contains tannin modified chitosan and nano magnetic iron oxide, and the component D contains carbonate, citric acid and auxiliary materials. The flocculant is easy to store, does not need to be compounded on site, flocculates quickly in water, only needs 60-120 seconds in flocculation time, and has an excellent flocculation effect; the emergency requirement of an accident site can be met, and the good popularization value is achieved; the method is suitable for an oil-containing sewage system with coexistence of anions and cations, can also adapt to a wide pH range, is good in salt resistance and has a good dehydration and filtration aiding effect.

Suppressing methane gas emissions from paddy rice cultivation is extremely important as a measure against global warming. The challenge here is to achieve both improved rice productivity and environmental protection. Specifically, this involves developing a device that can generate large quantities of high-concentration ultrafine bubble (UFB) water in a short time, by adding methane gas emission suppression to the UFB water. [Solution] The UFB generating apparatus of the present invention incorporates a variable-speed rotary stirring device into a UFB generation tank, and this tank is filled with sandy material. By supplying gas and water to this tank at high pressure, the sandy material layer of gas, water, and sandy material is liquefied. By rapidly rotating this liquefied layer with the rotary stirring device, the gas is confined in the pore water of the liquefied layer and then finely fragmented. Furthermore, by using sandy steel slag as the sandy material, in addition to the UFB effect, methane generation due to silica, lime, and iron oxide is suppressed and crop yields are improved.

The invention relates to the technical field of anti-corrosion coatings, in particular to a nano modified polysiloxane heavy anti-corrosion coating and a preparation method thereof.The nano modified polysiloxane heavy anti-corrosion coating is prepared from, by weight, 100 parts of polysiloxane resin, 5-15 parts of amino silane coupling agent, 20-40 parts of mica iron oxide, 1-5 parts of auxiliaries, 10-30 parts of solvent, 3-10 parts of biomimetic mineralization enhancer and 1-5 parts of additive; the biomimetic mineralization enhancer is prepared through dopamine modification and tetraethoxysilane mineralization treatment of nano diatomite, the compactness, adhesive force and physical shielding performance of the coating are remarkably improved, corrosion medium permeation can be effectively blocked, the additive is prepared from silver nanowires and polyvinylidene fluoride through electrostatic spinning, the coating is endowed with conductivity, and the corrosion resistance of the coating is improved. According to the invention, damage self-sensing and early warning are realized, so that the prepared coating has excellent salt mist resistance, wear resistance, impact resistance and long-acting corrosion resistance, is suitable for metal protection in a harsh corrosion environment, and has a wide application prospect.