The invention discloses small-particle-size low-
oxygen ZrB-SiC complex-phase
powder, a one-step controllable synthesis method thereof and application of the
powder in high-performance ceramics, and belongs to the technical field of ultra-high-temperature
ceramic materials. According to the method, ZrO, BC, elemental Si and
activated carbon are used as raw materials, and the ZrB-SiC complex-phase
powder is prepared through an optimized
boron-carbon thermal reduction method. The core innovation point is that the specific
raw material ratio design is as follows: n (ZrO): n (BC): n (Si): n (C) = 3: (1.65-1.95): (0.5-1.0): (4.95-6.05), the most preferable ratio is 3: 1.8: 1: 5.5, and heat preservation is performed for 60 minutes at 1500 DEG C in an
inert atmosphere. The design effectively compensates volatilization of intermediate phase BO, and ensures complete reaction. The prepared multiphase powder has the prominent advantages of
small particle size (D100lt, 0.71 [mu] m),
low oxygen content, high purity and accurate regulation and control of the ratio of two phases, and ZrB and SiC two-phase interfaces in the powder are in semi-coherent combination. The high-performance ZrB-SiC
composite ceramic can be prepared by using the self-made powder as a
raw material and adopting
spark plasma sintering (SPS), and the
relative density of the high-performance ZrB-SiC
composite ceramic is up to 99.24% or above.