The invention discloses a protective layer for a
lithium sulphur battery, a preparation method thereof and a
lithium sulphur battery using the protective layer, which aim at effectively preventing
polysulfide from shuttling back and forth in
electrolyte and from corroding a
lithium negative
electrode, facilitating uniform deposition of
discharge products on the surface of an
electrode, improving the specific capacity of the lithium sulphur battery and prolonging the service life of the lithium sulphur battery. The technical liquid of the invention is as follows: the protective layer is prepared by
coating slurry on the surface of a diaphragm, wherein the
slurry comprises modified
graphene and an
adhesive with the
mass ratio of (4-9):1; the modified
graphene contains one or more of the following functional groups:
alkyl, alkylene,
aryl,
halogen, -CN, -SCN, -NCO, -OH, -COOH, -NH2, -COX,-NO2, -SO3H, -COOR, -COR, -CONHR, -CONR2, -OR, -NHR and -NR2, wherein X = F, Cl, Br or I, and R =
alkyl, alkylene or
aryl; the
adhesive is one or more of polyoxyethylene,
polyvinylidene fluoride,
polyacrylic acid,
polytetrafluoroethylene,
gelatin,
sodium alginate and beta-
cyclodextrin.