651 results about "Polycaprolactone" patented technology

The invention relates to the technical field of medical dressings, in particular to a perianal drug dressing of a multi-layer flow guide composite fabric and a preparation method and application of the perianal drug dressing of the multi-layer flow guide composite fabric. The perianal drug dressing is of a four-layer structure, a wet tissue adhesion layer is made of polydopamine modified chitosan / oxidized hyaluronic acid hydrogel, and wet-state adhesion is achieved; the drug sustained-release layer is used for dispersing mesoporous silica loaded with ciprofloxacin hydrochloride / defensin and chitosan microspheres loaded with epidermal growth factors / lonicera japonica into a polycaprolactone fiber membrane to achieve synergistic antibacterial and healing promotion; the directional flow guide layer is of a gradient wettability sandwich structure with a bionic micro-channel, and one-way rapid drainage can be achieved; the high-absorption outer layer is carboxymethyl cellulose / sodium polyacrylate composite sponge, liquid is locked efficiently, the wound surface is kept dry and comfortable, the clinical problem in perianal infection wound treatment can be effectively solved, and the treatment effect and the patient comfort are remarkably improved.

The invention discloses a biodegradable polylactic acid composite material and a preparation method thereof, and relates to the technical field of polylactic acid materials. The method comprises the steps that firstly, chitosan activated through hydrochloric acid is subjected to graft modification through a KH550 silane coupling agent, meanwhile, nano-zinc oxide is subjected to surface modification through stearic acid, the chitosan and the nano-zinc oxide are mixed, spray drying is conducted, and antibacterial composite powder is prepared; the preparation method comprises the following steps: performing hydrochloric acid activation and KH570 silane coupling agent modification on nano silicon dioxide, performing hydroxypropylation modification on alkali lignin, and performing reflux crosslinking reaction on the modified alkali lignin, KH570 modified nano silicon dioxide, polycaprolactone, methyl methacrylate and azodiisobutyronitrile to prepare a heat-resistant reinforcer; uniformly mixing polylactic acid, poly (butylene succinate), the antibacterial composite powder, the heat-resistant reinforcer, tributyl citrate, polyethylene glycol and talcum powder, and extruding and granulating by using a twin-screw extruder to obtain the heat-resistant antibacterial material. The composite material prepared by the invention has excellent antibacterial property, heat resistance and biodegradability.

The invention relates to the technical field of functional materials, in particular to a polyvinyl butyral flexible material as well as a preparation method and application thereof. The molecular chain regularity is destroyed through an isobutyraldehyde branched chain, the crystallinity is reduced, and the flexibility is improved; cesium-tin co-doped tungsten oxide has high infrared rejection rate and good dispersity, and the influence on the flexibility of the material is reduced; magnesium salicylate and magnesium formate are compounded, so that the reaction activity with resin is reduced, and the bonding stability in the bending process is ensured; the flexibility and migration resistance of the material are synergistically improved through the flexible plasticizer, and the interlayer sheet is prevented from being sticky; the flexible reinforcing agent polycaprolactone micro powder is used for forming an elastic node, bending stress is absorbed, and the recovery performance is improved. The polyvinyl butyral flexible material provided by the invention has flexible bending performance, an efficient infrared barrier function and stable bonding performance, is suitable for scenes such as curved building curtain walls, special-shaped automobile sunroofs or arc-shaped rail traffic windows, and has a wide application prospect.

The invention discloses injection type facial filler composition gel for medical beauty as well as a preparation method and application of the injection type facial filler composition gel, and belongs to the technical field of biomedical materials. The composition gel comprises a combined gel matrix and polycaprolactone microspheres, wherein the combined gel matrix comprises an aqueous solution for injection, sodium carboxymethyl cellulose and human recombinant collagen; according to the composition gel, a combined gel matrix and polycaprolactone microspheres are mixed according to a specific proportion, amino acid residues of human-derived recombinant collagen in the combined gel matrix serve as binding sites of cell surface receptors to improve the cell recognition and attachment capacity of the polycaprolactone microspheres, and the amino acid residues are organically combined with sodium carboxymethyl cellulose to improve the cell recognition and attachment capacity of the polycaprolactone microspheres. The durability and biocompatibility of the shaping effect of the human-derived recombinant collagen at the injection site are improved; the composition prepared by the invention is good in gel fluidity, high in elastic modulus and high in dynamic viscosity, and can meet the expected mechanical and rheological properties of a facial filling agent for cosmetic and plastic surgery.

The invention relates to the technical field of sewage treatment, in particular to a preparation method of a degradable bactericide for an oil field. According to the invention, a hydroxypropyl guanidine gum-polycaprolactone-ethylenediamine fragment copolymer is taken as a carrier, a methylisothiazolinone quaternary ammonium salt (Q-MIT) bactericide is loaded, and the degradable bactericide for the oil field is obtained by cooperating with a dodecyl ethyl sulfide (TC-SE) bactericide and combining with sodium polyaspartate. A carrier forms a hydrogen bond with a polar group on the surface of a biological membrane through a hydroxypropyl guanidine gum main chain to realize targeted anchoring, a polycaprolactone branched chain encapsulates Q-MIT through a hydrophobic effect, primary amino groups of ethylenediamine are introduced to form a pH sensitive Schiff base bond with Q-MIT, and the primary amino groups and adipic dihydrazide form a thermal response hydrazide bond to construct a dual dynamic covalent bond, so that controlled release of Q-MIT is realized, and the biomembrane is prepared. And moreover, the components of the whole system are connected through degradable chemical bonds, so that the environmental protection property and sustainability of oil field operation are guaranteed.

The application belongs to the technical field of plastics, and particularly relates to a degradable antibacterial plastic packaging bag and a preparation method thereof. The degradable antibacterial plastic packaging bag comprises the following raw materials in parts by weight: polycaprolactone 70-90 parts; polybutylene adipate terephthalate 20-40 parts; Cr and Cu co-modified ZIF-8 5-20 parts; and cerium oxide tannic acid material 2-6 parts. The Cr and Cu co-modified ZIF-8 synergistically improves the antibacterial performance of the packaging bag, and the addition of the cerium oxide tannic acid material further improves the antibacterial performance of the packaging bag. Moreover, the degradable antibacterial plastic packaging bag prepared by the application has excellent mechanical properties.

The application discloses a degradable cotton soft towel and a preparation method thereof, relates to the technical field of fiber composite materials, and belongs to the patent classification D01F8 / 02. The preparation method comprises the following steps: performing alkali treatment and enzymolysis on Egyptian long-staple cotton fibers to obtain pretreated cotton fibers, and preheating, stretching and setting poly-caprolactone fibers to obtain pretreated poly-caprolactone fibers; mixing and opening the two kinds of fibers, and then air-laying to form a fiber web; constructing a super water-absorbing network by impregnating a main network solution carboxymethyl chitin and oxidized cellulose nanofilament and an auxiliary network dispersion liquid calcium alginate gel microspheres and a hyaluronic acid crosslinking body; forming micron protrusions through hexagonal nickel template hot pressing, and obtaining a base by electrostatic spraying modification of nano silicon dioxide; and obtaining the cotton soft towel through vacuum drying, slitting and sterilization after spraying of an essence liquid. The cotton soft towel has excellent water absorption performance through the synergistic effect of multistage pores, a super water-absorbing network and micro-nano surface modification, and the poly-caprolactone fibers and the cotton fibers used in the cotton soft towel are mixed, and both have good biodegradability.

The invention relates to the technical field of high-performance polyester, and discloses a modified preparation method of functionalized antibacterial polyester fibers, which comprises the following steps: S1, graphene is treated by oxygen-argon mixed plasma to obtain hydroxylated graphene; s2, after hydroxylated graphene is dispersed, cerium nitrate and sodium citrate are added, and cerium-based metallized graphene is obtained; s3, carrying out a reaction on the cerium-based metallized graphene and 3-(2-aminoethylamino) propyltrimethoxysilane, so as to obtain aminated graphene; s4, aminated graphene dicyandiamide, ammonium chloride tetraethoxysilane and hexadecyl trimethyl ammonium bromide are subjected to a reaction, and guanidyl-meso-porous silicon-metal composite graphene is obtained; s5, reacting the product with epsilon-polylysine and polycaprolactone to obtain a modified composite antibacterial agent; s6, treating the polyester fibers with a mixed solution of alkali and a surfactant; s7, the polyester fibers react with a solution containing an antibacterial agent, tetrabutyl titanate, an initiator and a dispersing agent, and a finished product is obtained.

A preparation method for a food nanofiber film having sustained-release antibacterial activity, and a use thereof, belonging to the technical field of food packaging films. A metal-organic framework material MIL-101(Fe) is used to encapsulate natural plant essential oils, while polylactic acid and polycaprolactone are used as film-forming substrates, to prepare a food nanofiber film capable of exerting a long-term and efficient antibacterial effect; by means of encapsulating highly volatile natural plant essential oils with MIL-101(Fe), the residence time of antibacterial substances in the top space of the packaging film can be extended, increasing the utilization of the essential oils and achieving long-lasting antibacterial effects. Moreover, MIL-101(Fe) has a specific surface area of 2865 m2 / g, which can greatly improve the encapsulation rate and sustained-release effect of the plant essential oils. At the same time, the film, prepared by electrospinning, has a high specific surface area, which is conducive to increasing the encapsulation rate of the plant essential oils. This preparation method is safe, environmentally friendly, simple to operate, and easy to promote and apply.

The invention belongs to the technical field of powder metallurgy, and particularly relates to a high-fluidity MIM metal feed and a forming process thereof.The high-fluidity MIM metal feed is composed of the following materials: metal powder: spherical metal powder (a titanium alloy TC4 material), polycaprolactone and graphene nanosheets; wherein the volume ratios are 68-72 vol%, 0.5-2 wt% (based on the mass of the metal powder) and 0.1-0.5 wt% (based on the mass of the metal powder) respectively; a powder oxide layer is removed through vacuum plasma cleaning (300-500 W, argon atmosphere), a metal core-PCL / graphene shell structure is prepared in combination with ultrasonic-assisted in-situ polymerization, lubrication and adhesion enhancement are synchronously achieved, the powder oxygen content is controlled to be smaller than 500 ppm, and sintering oxidation defects are reduced.

The invention relates to the technical field of manufacturing of coated paperboards, in particular to frame paper for cigarettes and a preparation process of the frame paper. The problem that the mechanical property and the barrier property cannot be considered at the same time in the prior art is solved. According to the frame paper for the cigarettes, the bleached hardwood pulp and the softwood pulp are compounded, and the calcium carbonate and the nanocellulose crystals are added to prepare the high-uniformity modified paper base; then, polycaprolactone diol, isophorone diisocyanate, dimethylolpropionic acid and 1, 4-butanediol are subjected to a reaction, aminopropyltriethoxysilane is used for blocking, obtained polyurethane emulsion is mixed with gelatinized starch and flaky kaolin step by step, and the composite coating is prepared; coating double surfaces of the modified paper base with the composite coating, and performing step-by-step drying, hot-pressing shaping and curing to obtain the paper. Through multi-stage cooperation of paper base-coating-process, the frame paper has excellent mechanical properties, high printing stability and high barrier property, and is suitable for the field of high-grade cigarette packaging with strict performance requirements.

The utility model provides a novel eye drug delivery and release system which sequentially comprises a main body base layer and a waterproof isolation layer from outside to inside, the main body base layer and the waterproof isolation layer are fixedly attached together, and at least one drug storage and release layer is attached to the waterproof isolation layer. The medicine storage and release layer is used for storing ophthalmology medicine and releasing the ophthalmology medicine into eyes when the ophthalmology medicine is in contact with the eyes, the medicine storage and release layer comprises a base layer and an upper layer which are attached together, the base layer is a methyl cellulose layer, and the upper layer is a polycaprolactone layer. According to the utility model, medicine is administrated on the bitamporal sides of two eyes, and medicine quickly passes through the lower lacrimal punctum, so that medicine loss is reduced; a patient does not need to directly face the medicine bottle, fear of the patient is reduced, and the medicine bottle is prevented from touching eyes by mistake; the disposable liquid medicine bottle is disposable, high in comfort level, convenient to operate, capable of being used in cooperation with most of liquid medicine and high in applicability. The effective duration and concentration of eyelid margin medication can be increased, and the effectiveness is higher; the eye cleaning device has various functions and can also be used for cleaning eye conjunctival sacs and eyelid margins.

The present disclosure relates to a transplantable cell therapy product composition for diabetes mellitus that contains an aggregate of insulin-secreting cells derived from stem cells. In the present disclosure, an NF microwell array membrane was fabricated by applying a molding process to an electrospun, permeable, biodegradable polycaprolactone (PCL) NF membrane and thus allows gases and soluble factors to permeate therethrough. The NF microwell of the present disclosure could provide more nutrients to the iPSC aggregates than conventional impermeable PDMS microwells, thus enhancing survival and differentiation capabilities of the cells. Additionally, the NF membrane was attached singly to the subcutaneous tissue and to the surface of organs such as liver and peritoneum without the need for a fixing material or separate sutures and was integrated with surrounding tissues, resulting in higher insulin secretion than PDMS microwells. Therefore, the present disclosure can be effectively utilized as a composition for the prevention or treatment of diabetes.

The invention relates to a high-wear-resistance floor coating based on TiC hybrid resin and a preparation process of the high-wear-resistance floor coating, and belongs to the technical field of floor coatings. The high-wear-resistance floor coating is prepared from a component A and a component B in parts by weight, wherein the component A is prepared from 90 to 100 parts of modified waterborne epoxy resin emulsion; the component B comprises the following components in parts by weight: 20-30 parts of modified fibrous wollastonite, 0.5-1.5 parts of a flatting agent, 0.5-1 part of a defoaming agent, 1-2 parts of a wetting dispersant, 30-45 parts of a water-based amine curing agent and 20-40 parts of water; the weight ratio of the component A to the component B is 1: (0.75-0.85); titanium carbide subjected to amination and surface grafting polycaprolactone treatment is added into the coating, so that the wear resistance of the floor coating can be improved.

The application relates to the technical field of shoe sole materials, in particular to a foamed composite material and application of the foamed composite material in shoe materials, which comprises EVA resin, ethylene-propylene-diene rubber, wear-resistant particles, a filler, a foaming agent, a crosslinking agent, a lubricant and an activator; wherein the wear-resistant particles are modified porous corundum, which is obtained by in-situ ring-opening polymerization of flexible PCL chains in and outside the pores of the porous corundum after surface activation; and the flexible PCL chains further have polyethylene glycol-stearic acid polymer brushes. Compared with the prior art, the application has the beneficial effects that: the EVA provides good processability and elasticity, the ethylene-propylene-diene rubber endows the material with excellent low-temperature performance and aging resistance; the corundum core of the modified porous corundum provides a high-hardness wear-resistant framework, significantly reduces the abrasion amount in a unit volume, the polycaprolactone main chain and the polyethylene glycol-stearic acid side chain compensate the rigidity of the corundum, and guarantee the high resilience, especially the low-temperature resilience, of the EVA material.

The invention provides a high-pressure wear-resistant valve rubber. The valve rubber is prepared from the following raw materials in parts by weight: 100 parts of a polyurethane prepolymer, 20 to 30 parts of a chain extender, 12 to 18 parts of a polycaprolactone coated boron nitride / molybdenum disulfide composite material and 0.5 to 2 parts of an antioxidant. Wherein the polycaprolactone coated boron nitride / molybdenum disulfide composite material is obtained by polymerizing an amino silane coupling agent modified boron nitride / molybdenum disulfide composite material, triethyl aluminum and epsilon-caprolactone in an organic solvent at 35-45 DEG C in an inert atmosphere. A polycaprolactone-coated boron nitride / molybdenum disulfide composite material is used as a filler, and boron nitride / molybdenum disulfide as an inner core forms a synergistic structure of a reinforced substrate and a lubricating surface layer, so that high-pressure load bearing and friction coefficient reduction are facilitated; and the polycaprolactone flexible shell layer is compatible with the matrix, so that the filler is uniformly dispersed in the matrix.

This invention relates to the field of casting technology for sand cores and sand shells, and particularly to a method for preparing high-precision casting sand cores and sand shell components based on a coated sand process. The method includes the following steps: rinsing quartz sand and reacting it with a sodium silicate solution to obtain coated quartz sand; adding 3-aminopropyltriethoxysilane and water to the coated quartz sand in a high-speed mixer; sequentially adding modified benzoxazine resin, calcium citrate, magnesium chloride, hyperbranched polyamide, and polycaprolactone-grafted starch to obtain finished coated sand; plasma-treated chromium-12 molybdenum-vanadium mold steel to obtain an amino-modified mold; sand-jetting the finished coated sand into left / right half-shells; shaping and pre-embedding chromite sand cores with chills to obtain left / right half-shell green blanks; milling the surfaces of the left / right half-shell green blanks, coating them with resin, butt-jointing, curing, and deburring to obtain the casting sand core and sand shell. This method solves the problems of poor mechanical strength, poor high-temperature stability, low production efficiency, and poor environmental performance in high-precision casting sand cores and sand shells.

The invention relates to a high-breathability and high-fitness in-vitro fixing device with a shape memory function and a preparation method of the high-breathability and high-fitness in-vitro fixing device, and relates to the field of biomedical materials, the high-breathability and high-fitness in-vitro fixing device comprises the following components in parts by mass: 40-45 parts of polycaprolactone, 40-45 parts of polylactic acid, 4-6 parts of a compatilizer, 0.5-1.5 parts of a cross-linking agent, 8-12 parts of nano-hydroxyapatite, 10-20 parts of biocompatible polyurethane and 0.1-0.3 part of a coloring agent. The preparation method comprises the following steps: mixing the raw materials, carrying out melt blending, and carrying out extrusion granulation to obtain composite particles; the composite particles are subjected to melt-blowing spinning, and non-woven cloth is obtained; and carrying out hot press molding on the non-woven fabric, shaping and cooling to obtain the high-breathability and high-fitness in-vitro fixing device with the shape memory function. The in-vitro fixing device prepared by the invention has a silk net structure, has good air permeability, a shape memory function and fitness, and has good mechanical properties and antibacterial properties.

The utility model relates to the technical field of production and processing of polycaprolactone microspheres, and discloses an emulsifying device which comprises a support, an emulsifying device body is fixedly mounted on the support, a first transmission pipe and a second transmission pipe are symmetrically arranged in the emulsifying device body, and a plurality of nozzles are mounted on the top surface in the emulsifying device body; the stirring structure is rotatably arranged in the emulsifying device body, the stirring structure comprises a rotating rod, a wall scraping rod, a filter cone, a stirring rod, a filter plate, a vortex plate and a vortex blade, the nozzle uniformly sprays a polycaprolactone solution into the emulsifying device body, and then rapid emulsification of the polycaprolactone solution and an emulsifying additive is accelerated by stirring and filtering of the filter plate and the filter cone. Therefore, the emulsification process is accelerated; the wall scraping rod scrapes off a polycaprolactone solution attached to the inner wall of the emulsifying device body, and centrifugal force eddy current formed by the vortex plates and the vortex blades accelerates emulsification, so that the polycaprolactone solution and an emulsifying additive are more sufficiently and uniformly emulsified.

The invention relates to the technical field of preparation of polycaprolactone porous membranes, in particular to a polycaprolactone porous membrane and a preparation method and application thereof.The polycaprolactone porous membrane is of a porous structure with macropores and small pores coexisting, the pore walls of the macropores and the small pores are all composed of polycaprolactone particles, and the polycaprolactone porous membrane is provided with pores with the pore walls composed of micron-sized particles. The polycaprolactone porous membrane is prepared from polycaprolactone, a composite hierarchical pore structure containing small pores in macropores is formed, a three-dimensional pore network internally communicated with one another is formed, the specific surface area is increased by the porous structure, the number of adhered cells is further increased, the interconnected porous structure allows cells to migrate into the polycaprolactone porous membrane, and meanwhile, the porous structure is convenient for conveying substances.

The invention discloses an ultraviolet-controlled photo-reversible dynamic crosslinking high polymer material with reversible antibacterial, shape deformation and toughening functions, and a preparation method thereof, belonging to the technical field of high polymer materials. Comprising the following steps: step 1) dissolving coumarin-3-formic acid, three-arm PCL (polycaprolactone), dicyclohexylcarbodiimide and 4-dimethylaminopyridine in dry dichloromethane in an inert atmosphere to obtain a reaction mixture; the invention relates to a preparation method of a coumarin-terminated three-arm polycaprolactone cross-linked polymer material.The preparation method comprises the following steps of (1) preparing coumarin-terminated three-arm polycaprolactone, (2) heating a reaction mixture obtained in the step (1) for set time, and filtering and separating an obtained product to obtain coumarin-terminated three-arm polycaprolactone, and (3) cross-linking and curing for set time through 365 nm ultraviolet to obtain a target product cross-linked polymer material.The function is highly integrated and dynamically adjustable, and the limitation that a traditional material is single in function is broken through.

The invention relates to the field of oilfield chemistry, in particular to an amphiphilic block poly-surfactant containing a surfactant functional group and a preparation method of the amphiphilic block poly-surfactant. Through molecular structure design, a self-made amphiphilic block copolymer macromonomer is added, a side chain of the macromonomer has a hydrophobic polycaprolactone block and a hydrophilic polyethylene glycol block at the same time, and the side chain with the built-in amphiphilic block integrates strong emulsification stripping and hydrophobic association effects at the same time; due to the strong emulsifying and stripping capacity to residual oil after water flooding and the deep profile control capacity to a reservoir, the recovery efficiency of an oil reservoir after water flooding is remarkably improved.

The invention discloses corrosion-resistant waterproof aluminum foil glass fabric and a preparation method thereof, and belongs to the technical field of aluminum foil composite glass fabric. The corrosion-resistant waterproof aluminum foil glass fabric sequentially comprises a waterproof glass fabric, a high-temperature-resistant adhesive layer and an aluminum foil from bottom to top, the waterproof glass fabric is obtained by padding a waterproof finishing agent; the waterproof finishing agent is mainly prepared from the following raw material components: a silane coupling agent, hydroxyl-terminated fluorine-containing dihydric alcohol, isophorone diisocyanate and polycaprolactone; the high-temperature-resistant adhesive is mainly prepared from the following raw material components: 4, 4 '-oxydiphthalic anhydride, 4, 4-(hexafluoroisopropyl) bis (p-phenoxy) diphenylamine, 3, 3'-diaminodiphenyl sulfone, 1, 3-bis (3-aminopropyl)-1, 1, 3, 3-tetramethyldisiloxane, 4-amino-2-hydroxybenzaldehyde and o-phenylenediamine, and the high-temperature-resistant adhesive is prepared from the following raw material components: 4, 4 '-oxydiphthalic anhydride, 4, 4-(hexafluoroisopropyl) bis (p-phenoxy) diphenylamine, 4, 4-(hexafluoroisopropyl) bis (p-phenoxy) diphenylamine, 3, 3'-diaminodiphenyl sulfone, 1, 3-bis (3-aminopropyl) The corrosion-resistant waterproof aluminum foil glass fiber cloth prepared by the invention is relatively good in high temperature resistance, corrosion resistance and waterproofness.

The invention provides yellow glue resistant to corrosion of a plasticizer and a preparation method of the yellow glue. The yellow glue is prepared from a polyurethane prepolymer, a chloroprene rubber sheet, methyl methacrylate, benzoyl peroxide, an anti-aging agent, butanone, cyclohexane, dimethyl carbonate and tackifying resin. The polyurethane prepolymer is prepared from the following components in parts by weight: 10 to 14 parts of 1, 4-butanediol adipic acid polyester polyol, 4 to 8 parts of polycaprolactone polyol, 1 to 3 parts of diphenylmethane diisocyanate, 0.05 to 0.15 part of 1, 6-hexanediol, 1 to 2 parts of hydroxyethyl methacrylate, 0.01 to 0.03 part of organic bismuth catalyst and 75 to 80 parts of butanone. The polyurethane prepolymer with specific crystallization performance is synthesized through cooperation of polycaprolactone polyol and polyester polyol, and the yellow glue is endowed with excellent plasticizer corrosion resistance and low-temperature activation capacity. Active groups in the polyurethane prepolymer are subjected to graft copolymerization with the chloroprene rubber adhesive and MMA, and a plasticizer-resistant polyurethane chain segment is introduced into a molecular chain of the chloroprene rubber adhesive, so that a hard segment-soft segment alternating block structure is formed, and corrosion resistance and viscoelasticity are both considered.

The invention discloses a gradient degradation type personalized absorbable sternum fracture fixing plate and a preparation process, and belongs to the technical field of medical implant materials. Comprising an anatomical adaptive plate body and an integrated locking assembly, the plate body is of a partitioned structure of a middle supporting area and an edge buffering area, a gradient pore array penetrating through the thickness direction is formed in the surface of the plate body, and a hydroxyapatite-collagen composite coating is loaded on the inner wall of a pore; the plate body is made of a composite absorbable material through 3D printing forming and hot pressing post-treatment, and the composite absorbable material comprises, by weight, 60%-70% of polylactic acid-glycolic acid copolymer (PLGA, LA / GA = 75 / 25), 15%-20% of silanized magnesium alloy microwires, 5%-10% of hydroxyapatite nano-particles and 5%-10% of polycaprolactone (PCL). Space-time matching of the degradation rate and the bone healing process is achieved through the partition gradient structure, the magnesium alloy microwires enhance the mechanical property and release active ions to promote osteogenesis, and the method has the advantages of personalized adaptation, gradient degradation, bone regeneration promotion and the like.

This invention relates to a method, apparatus, and packaging structure for in-situ packaging of fruits and vegetables using blown fiber spinning, addressing the current issues of efficiency and effectiveness in the use of nanofibers in fruit and vegetable packaging. This method selects carboxymethyl chitosan (CMCH) and polycaprolactone (PCL) as base materials, and uses SBS technology to directly deposit CMCH / PCL nanofibers layer by layer onto the surface of fruits and vegetables, forming a tightly adhered and stable fiber coating. The apparatus in this invention uses spiral-patterned conveyor rollers to simultaneously transport fruits and vegetables while performing blown spinning, achieving rapid and continuous in-situ packaging of fruits and vegetables. The in-situ packaging of this invention can be easily peeled off by hand, and it also serves as an excellent carrier for active substances, effectively inhibiting gray mold in fruits and vegetables. The in-situ packaging film forms a barrier on the surface of fruits and vegetables, reducing weight and hardness loss and delaying the ripening period after harvest.

The invention belongs to the technical field of materials, and particularly relates to a coating composition as well as a preparation method and application thereof. The coating composition provided by the invention comprises the following components in parts by weight: 30-50 parts of six-functionality polyurethane acrylic resin; the coating is prepared from the following components in parts by weight: 2-4 parts of a photoinitiator, 20-40 parts of a polycaprolactone type polyurethane prepolymer containing disulfide bonds (-S-S-), 3-8 parts of nano silicon dioxide, 0.1-0.5 part of a flatting agent, 0.1-0.5 part of a defoaming agent, 2-4 parts of an ultraviolet light absorber, 2-4 parts of a light stabilizer and 25-35 parts of a solvent. The prepared coating has extremely high elongation at break and toughness, can realize perfect synergistic deformation with a TPU base material, and is excellent in self-repairing capability and durability and long in service life.

The invention belongs to the technical field of exosomes, and discloses an exosome preparation method and application, the exosome preparation method comprises the following steps: S1, culturing target cells in an induction medium, and collecting the cells and a culture solution; s2, separating the culture solution to obtain supernate A and cell precipitate; s3, performing chromatographic purification and concentration on the supernate A to obtain the exosome; in the step S1, colchicine is also added in the process of culturing the target cells to synchronize the cell cycle; a polycaprolactone-gelatin composite microcarrier is suspended in the induction culture medium, and nicotinamide, an epidermal growth factor (EGF) and pyruvic acid are contained in the induction culture medium; the method further comprises a step S30 before the step S3, resuspending the cell precipitate obtained in the step S2 with a vesicle protection solution containing trehalose, sucrose and EDTA to obtain a supernatant B, and then combining the supernatant A with the supernatant B. According to the preparation method provided by the invention, the total secretion amount of target cells is large, the intracellular vesicle-exosome precursor can be collected, and the obtained exosome is high in concentration and low in impurity content.

The invention discloses a golf ball outer layer material composition, a golf ball and a manufacturing method of the golf ball, and relates to the technical field of ball sports equipment. The invention relates to an outermost layer material composition of a golf ball. The outermost layer material composition comprises 60-70 parts of thermoplastic polyurethane; 7-12 parts of a composite flow modifier; 4-8 parts of an interface enhancing system; 0.3 to 0.8 part of an antioxidant; 2-4 parts of color master batch; wherein the composite flow modifier is a compound of dioctyl adipate and polycaprolactone in a mass ratio of (2-3): 1; the interface reinforcing system comprises 3-5 parts of maleic anhydride grafted polyolefin elastomer and 1-3 parts of core-shell structure coated particles; the core-shell structure coated particle takes nano silicon dioxide as a core and an ethylene-vinyl acetate copolymer oligomer as a shell, and the mass ratio of the core to the shell is 1: (2-3). Through the dual synergistic effect of the composite flow modifier and the interface reinforcing system, the problems of flow eccentricity and interlayer bonding of the outermost layer material of the golf ball are systematically solved.

The present application relates to a kind of diaphragm and its preparation method and electric device.The diaphragm includes base film, and the base film includes opposite first surface and second surface along the thickness direction;The first surface is provided with first coating, and the first coating includes polycaprolactone, metal oxide catalyst and bismuth-tin eutectic alloy;The second surface is provided with second coating, and the second coating includes core-shell material, and the core-shell material includes inner core and polymer shell, and the inner core includes perfluoropolyether and azobisisobutyronitrile;The base film includes polyether ether ketone and polyphenylene sulfide.The diaphragm provided by the present application uses polyether ether ketone and polyphenylene sulfide as mixed base film, and the first coating and the second coating are differentially set, the diaphragm heat response is sensitive, effectively prevent the occurrence of thermal runaway, the safety performance of lithium ion battery is significantly improved, meanwhile, the energy density of battery has also been greatly improved, and the cycle performance of battery is good.