2031 results about "Polycaprolactone" patented technology

The invention provides a high-temperature-resistant and high-salt-resistant nano imbibition agent as well as a preparation method and application thereof. The high-temperature-resistant and high-salt-resistant nano imbibition agent is prepared from amination modified mesoporous silica nanoparticles, nano cellulose, rhamnolipid, an anionic surfactant, citrate modified sodium zirconium phosphate, polyethylene glycol-b-polycaprolactone and a sulfydryl-carboxyl imidazoline derivative, therefore, the composite carrier formed by the aminated mesoporous silica nanoparticles and the nanocellulose has high mechanical strength and uniform dispersity, the oil-water interfacial tension is reduced through the synergistic effect of the rhamnolipid and the anionic surfactant, and the crude oil stripping efficiency is remarkably improved; the citrate modified sodium zirconium phosphate enables the salt resistance of the system to be greatly improved, and in a high-temperature and high-salt oil reservoir environment, the nano imbibition agent can remarkably improve the crude oil recovery rate and reduce the injection pressure and dosage; meanwhile, good adsorption resistance is achieved, and reservoir blockage is prevented; in addition, low-toxicity corrosion inhibition components protect equipment, and the service life of an oil well is prolonged.

The invention discloses an injection filler and a preparation method and application thereof, the filler is polycaprolactone particles, the polycaprolactone particles are spherical particles, the particle size of the spherical particles is 20-100 [mu] m, and the polycaprolactone particles have rough surfaces or unsmooth surfaces. The polycaprolactone microspheres have rough surfaces or unsmooth surfaces, so that the contact area with cells is increased, the adhesion ability and residence time of the cells are improved, the affinity of the polycaprolactone microspheres is improved, and the growth of collagen can be stimulated and accelerated. In the preparation process, the dosage of each component is scientifically screened, and on the basis of controlling the viscosity of a water-phase solution, the spherical polycaprolactone particles which are regular, rough in surface and uniform in particle size are obtained in cooperation with a rapid membrane emulsification method.

The invention discloses a double-layer microneedle patch and a preparation method thereof.The preparation method of the double-layer microneedle patch comprises the following steps that firstly, 3D printing is conducted through polydimethylsiloxane, and a PDMS mold similar to a machining microneedle is obtained; dispersing the medicine into the sericin solution to serve as an outer layer solution; dispersing germanium nanoparticles into the polycaprolactone solution to obtain an inner layer solution; and finally, adding the outer-layer solution into the needle-shaped groove of the PDMS mold, so that the needle-shaped groove is filled with the outer-layer solution, drying, adding the inner-layer solution, drying, and demolding to obtain the double-layer microneedle patch. When the double-layer microneedle patch is used for drug delivery, drugs can be dissolved and released in a short time, the inner layer is polycaprolactone (PCL) carrying photo-thermal agent germanium nanoparticles, degradation is slow, a photo-thermal effect is generated under irradiation of 808nm near-infrared light, residual tumor cells are induced to die immunogenicity, an immune microenvironment is programmed in a time sequence, and the double-layer microneedle patch has the advantages of being high in sensitivity, high in sensitivity and good in stability. Postoperative recurrence and metastasis of tumors are efficiently inhibited, and meanwhile operative wound repair is promoted.

The invention belongs to the field of biomedical materials, and particularly discloses a preparation method and application of a 3D printing porous composite scaffold. I-type collagen and silk fibroin composite gel is modified on a 3D printing three-element doped hydroxyapatite / polycaprolactone (PCL) composite scaffold with a polydopamine coating, the three-element doped hydroxyapatite is synthesized by using a chemical precipitation method, and Mg < 2 + >, Sr < 2 + > and SeO3 < 2-> ions are doped in crystal lattices. The 3D printing porous composite scaffold provided by the invention effectively simulates the structure and function of soft and hard combination of natural bones, is helpful for regulating and controlling the stem cell fate to improve the bone regeneration process, repairs bone defects while eliminating tumors, and can be applied to bone defect repair or osteosarcoma treatment.

The invention relates to the technical field of degradable plastics, and provides biodegradable plastic particles as well as a preparation method and application thereof. The biodegradable plastic particles comprise the following components in parts by weight: 50-80 parts of PLA, 20-50 parts of PBAT, 5-20 parts of a filler, 1-8 parts of a flexibilizer, 1-5 parts of a lubricant and 5-10 parts of a modifier. The modifier comprises a polylactic acid-polyethylene glycol block copolymer and a polycaprolactone-polyglycidyl methacrylate block copolymer in a mass ratio of (1: 19)-(19: 1). According to the technical scheme, the problems of poor flexibility and strength of plastic particles in related technologies are solved.

A biodegradable polymer composite, a method of making the same and use for same are provided. The biodegradable polymer composite has about 30 to 99.5% by weight of a polymer selected from a group consisting of polybutylene adipate terephthalate (PBAT), polybutylene succinate (PBS), polyhydroxyalkanoates (PHA), and polycaprolactone (PCL) grafted with a compatibilizer selected from a group consisting of maleic anhydride, glycidyl methacrylate, pyromellitic anhydride, acrylic acid, polyacrylic acid, methylene diphenyl diisocyanate, poly(glycidyl methacrylate, copolymer(s) of glycidyl methacrylate; and about 0.5 to 50 % by weight a nano-filler or a micro-filler. The biodegradable polymer composite does not contain polylactic acid. Surfaces of the nano-filler or the micro-filler may be modified using a grafting agent so that the biodegradable polymer composite has enhanced mechanical properties, increased heat resistance, compostablity and / or improved processability. The biodegradable polymer composite may be used to make flexible articles, such as a freezer wrap and a farming sheet.

The invention relates to the technical field of fertilizers, and discloses a coating material, a preparation method and application of the coating material in a trace element coating for potassium chloride particles. The preparation method comprises the following steps: reacting isophorone diisocyanate with polycaprolactone diol, tartaric acid and dimethylglyoxime to prepare a polyurethane prepolymer, continuously reacting the polyurethane prepolymer with chitosan oligosaccharide Schiff base to obtain chitosan oligosaccharide modified polyurethane, and mixing the chitosan oligosaccharide modified polyurethane, a cross-linking agent, silane modified isocyanate and a trace element solution to obtain the coating material. The coating material is good in mechanical property, contains trace elements, has a controlled release effect on the potassium chloride granulated fertilizer, and can be applied to the potassium chloride granulated fertilizer as a trace element coating.

The invention aims to solve the manufacturing problem of a biodegradable air-conditioning film, and discloses a biodegradable air-conditioning film with a multilayer structure, the biodegradable air-conditioning film comprises a first surface layer, a middle layer and a second surface layer, the air-conditioning film is sequentially formed by the first surface layer, the middle layer and the second surface layer through a co-extrusion process, and the first surface layer and the second surface layer are prepared from polylactic acid (PLA), polycaprolactone (PCL), polylactic acid (PLA), polycaprolactone (PCL) and polylactic acid (PLA). The biodegradable plastic polyester is one or more of poly (butylene terephthalate) or butylene adipate (PBAT), poly (butylene succinate) (PBS) and polyhydroxyalkanoate (PHA), the functional master batch is used as an auxiliary material (the addition amount is greater than or equal to 1%), and a small amount of auxiliary agent (the addition amount is less than 1%) is added; the middle layer takes polycarbon dioxide (PPC) as a main material, takes functional master batch as an auxiliary material (the addition amount is greater than or equal to 1%), and is added with a small amount of auxiliaries (the addition amount is less than 1%). The composite film is produced through a three-layer film co-extrusion process, meanwhile, a co-blowing process can be carried out, in-mold compounding and out-mold compounding can be carried out, and operation is more convenient.

The invention discloses a degradable bamboo fiber express packaging bag and a preparation method thereof, and belongs to the technical field of express packaging. The packaging bag is prepared from, by mass, 32-42 parts of pretreated bamboo fibers, 22-28 parts of poly (butylene succinate), 9-14 parts of modified nano calcium carbonate, 12-16 parts of polycaprolactone, 6-11 parts of acetylated chitosan and the like, and the key raw materials are all treated through an exclusive pretreatment or modification process. The preparation method comprises the steps of raw material plasma activation, segmented high-speed mixing, vacuum drying, precise-parameter twin-screw extrusion granulation, secondary drying, precise film blowing, high-precision heat-sealing bag making and the like, and the technological parameters of all the steps are clear. The product disclosed by the invention can be efficiently degraded in a natural environment, has excellent tensile resistance, puncture resistance and impact resistance, is stable and controllable in processing process, and is adaptive to actual requirements of express packaging and industrial batch production.

The invention discloses a Janus wound dressing with antibacterial and tissue repair promoting functions and a preparation method of the Janus wound dressing, belongs to the technical field of wound dressings, and aims to realize antibacterial, tissue repair promoting and moist wound healing microenvironment through freeze drying and electrostatic spinning technologies. Polycaprolactone (PCL), bioactive glass (BG) and curcumin Cur are used for preparing a hydrophobic inner layer capable of promoting tissue repair, methacrylated gelatin GelMA is used for preparing a hydrophilic outer layer with moisturizing performance, and the PCL-BG-Cur / GelMA composite wound dressing with antibacterial, moisturizing and repair promoting functions is constructed. Animal experiment results show that the dressing loaded with curcumin Cur and bioactive glass BG has multiple functions of synergistic antibiosis, moisturizing and the like, the result shows that the prepared dressing has the performance of promoting epithelization, collagen deposition, new hair follicle formation and the like, and the dressing has a considerable application prospect in the aspect of rapid wound repair.

The invention relates to the technical field of printing materials, in particular to a 3D printing material, a preparation method and application of the 3D printing material in shoe materials, and the 3D printing material comprises the following raw materials in parts by weight: 35-40 parts of TPU, 10-15 parts of polycaprolactone, 6-9 parts of nano silver powder, 3-5 parts of a compatilizer, 3-4 parts of a foaming agent, 2-3 parts of a foam stabilizer, 1-3 parts of a lubricant and 1-3 parts of an antioxidant. According to the 3D printing material disclosed by the invention, TPU is matched with polycaprolactone, functional aids such as a compatilizer, a lubricant and an antioxidant are added, nano silver powder is added to optimize the antibacterial property of a product, and meanwhile, the added carbon nano tube is blended with a nano attapulgite agent and a supplementing agent for supplementing and adjusting a modified filler to be mutually blended and matched, so that the obtained 3D printing material optimizes the raw material agglomeration property; the antibacterial property, the wear resistance and the mechanical tensile property of the product are improved in a balanced and coordinated manner, and the weather-proof and washing-resistant stability effects of the product are remarkable.

Disclosed in the present invention are a high-strength polylactic acid material, a preparation method therefor, and use thereof, belonging to the technical field of macromolecular materials. The high-strength polylactic acid material comprises the following components in parts by weight: 80-90 parts of polylactic acid, 10-20 parts of polybutylene adipate terephthalate, 1-5 parts of a nucleating agent, and 2-5 parts of a compatibilizing agent. The mesh number of the nucleating agent is 1500-2500 mesh; the compatibilizing agent is polycaprolactone, and the intrinsic viscosity thereof is 1.0-3.0 dL / g. The present invention lowers the melting temperature and shortens the melting time of PLA and PBAT, reduces the negative impact of polymer degradation and aging on mechanical properties, produces a heterogeneous nucleation effect, and performs the function of a crystallization nucleus in the cooling crystallization stage, improving crystallization speed and crystallinity, while causing the crystalline phase structure to tend toward a spherulitic state, improving the tensile strength of the polylactic acid material.

The invention discloses a biochar-based slow-release fertilizer and a preparation method thereof, and relates to the technical field of fertilizer production, the biochar-based slow-release fertilizer comprises a core, a carrier layer, a biological layer and a protective layer, the core is composed of macroelements, microelements and a nitrification inhibitor; the carrier layer comprises graphene quantum dot modified charcoal, chitosan, glycerol and cyclodextrin grafted starch; the biological layer is prepared from magnetic Fe3O4 and humic acid nanoparticles, alginic acid oligosaccharide and diatomite; the protective layer comprises a polylactic acid-polycaprolactone block copolymer, acetone, calcium lignosulphonate, a dynamic covalent cross-linking agent gelatin, nano cellulose and an anti-blocking agent. Therefore, by adopting the polylactic acid-polycaprolactone (PLA-PCL)-based segmented copolymer and the dynamic covalent network cross-linking agent, the self-repairing property is endowed. The slow-release fertilizer provided by the invention realizes precise regulation and control of the fertilizer efficiency release rate through a multi-level synergistic effect, has the functions of soil remediation and stress resistance, and significantly improves the utilization efficiency of the fertilizer and the crop adaptability.

The invention discloses a packaging bag with high sealing performance and a preparation process thereof, and belongs to the technical field of packaging materials, the packaging bag comprises the following raw materials: polylactic acid, polycaprolactone, a nano-silver filler composite antibacterial agent and an epoxy compatilizer; the nano-silver filler composite antibacterial agent is formed by depositing a hybrid modified coating on the surface of a nano two-dimensional filler and then loading nano-silver; the hybrid modified coating is prepared from polydopamine and hyperbranched polyethyleneimine. The polylactic acid and the polycaprolactone are used as main base materials, and the packaging bag is endowed with good mechanical properties by utilizing high mechanical strength of the polylactic acid and excellent flexibility of the polycaprolactone; a nano-silver filler composite antibacterial agent and an epoxy compatibilizer are also added, the nano-silver filler composite antibacterial agent takes a nano-two-dimensional filler as a raw material, the nano-two-dimensional filler has a high length-diameter ratio and can block permeation of gas molecules, and the dispersion performance is improved by combining the nano-two-dimensional filler with the epoxy compatibilizer; the barrier property and the mechanical property of the packaging bag are further improved.

The invention relates to the field of sponge materials, and provides an antibacterial degradable sponge material and a preparation method thereof. The material is prepared from protocatechuic acid modified quaternized chitosan, quaternary ammonium salt grafted gelatin, sodium alginate, polyhydroxybutyrate, polycaprolactone, a polylactic acid-glycolic acid copolymer, hexamethylene diisocyanate, a foaming agent, nano cellulose, vitamin E, polyethylene glycol, triethylamine and dimethylformamide. Protocatechuic acid and quaternized chitosan are subjected to amidation modification, and chitosan and gelatin are subjected to quaternization treatment by adopting 2, 3-epoxypropyl trimethyl ammonium chloride, so that the antibacterial property and biodegradability of the material are improved. In the material preparation process, through vacuum degassing, foaming vacuum degree and humidity control and a multi-step drying process, it is ensured that the average pore size of the material is uniform (50-200 microns) and the porosity is high (50%-90%), and the obtained material has excellent antibacterial property and degradability and has wide application value.

The invention discloses a degradable PLA composite material and a preparation method thereof, and belongs to the technical field of polylactic acid materials, the degradable PLA composite material comprises the following raw materials by mass: 80-95 parts of polylactic acid, 5-15 parts of carboxyl-terminated hyperbranched polycaprolactone, 3-5 parts of potassium titanate whisker, 0.1-3 parts of an antioxidant, 1-5 parts of a compatilizer and 1-2 parts of an anti-hydrolysis agent. By compounding carboxyl-terminated hyperbranched polycaprolactone and polylactic acid, a large number of flexible chain segments are introduced into a polylactic acid matrix material, so that the problem of high brittleness of polylactic acid can be well solved; the potassium titanate whiskers are also added into the composite material, and the thermal stability and mechanical properties of the material can be improved due to the excellent strength and stability of the potassium titanate whiskers. And the potassium titanate whisker can be used as a nucleating agent to solve the problem that the crystallization property of the polylactic acid is reduced due to compounding of the carboxyl-terminated hyperbranched polycaprolactone, and the crystallinity of the polylactic acid composite material is improved, so that the heat resistance of the polylactic acid composite material is improved.

The invention relates to the technical field of medical dressings, in particular to a perianal drug dressing of a multi-layer flow guide composite fabric and a preparation method and application of the perianal drug dressing of the multi-layer flow guide composite fabric. The perianal drug dressing is of a four-layer structure, a wet tissue adhesion layer is made of polydopamine modified chitosan / oxidized hyaluronic acid hydrogel, and wet-state adhesion is achieved; the drug sustained-release layer is used for dispersing mesoporous silica loaded with ciprofloxacin hydrochloride / defensin and chitosan microspheres loaded with epidermal growth factors / lonicera japonica into a polycaprolactone fiber membrane to achieve synergistic antibacterial and healing promotion; the directional flow guide layer is of a gradient wettability sandwich structure with a bionic micro-channel, and one-way rapid drainage can be achieved; the high-absorption outer layer is carboxymethyl cellulose / sodium polyacrylate composite sponge, liquid is locked efficiently, the wound surface is kept dry and comfortable, the clinical problem in perianal infection wound treatment can be effectively solved, and the treatment effect and the patient comfort are remarkably improved.

The invention relates to the technical field of high-barrier environment-friendly packaging films, and discloses a high-barrier environment-friendly packaging film with an antibacterial function, the high-barrier environment-friendly packaging film comprises a base layer, a nano composite barrier layer, a bio-based functional layer and an outer protective layer from bottom to top in sequence, and the layers are tightly attached through a coated starch-based adhesive. According to the high-barrier environment-friendly packaging film with the antibacterial function, good biodegradability of polyhydroxyalkanoate adopted in the base layer film, polycaprolactone which is adopted in the nano-composite barrier layer film and has a biodegradable function and konjac glucomannan in the biological functional layer film are utilized; the composite packaging film can be decomposed into carbon dioxide and water by microorganisms in various environments, has excellent flexibility and processability, can adapt to different packaging requirements, provides basic flexibility, structural support and green and environment-friendly effects for the whole packaging film, and has a wide application prospect. The procyanidine arranged in the outer protective layer film provides stronger antibacterial property and water solubility for the whole packaging film.

The invention discloses an anti-adhesion membrane loaded with nintedanib and a preparation method of the anti-adhesion membrane loaded with the nintedanib. The anti-adhesion membrane loaded with the nintedanib is prepared from a drug-loading substrate material and the nintedanib through electrostatic spinning, the material of the drug-loading substrate is one or more of polylactic acid, poly (p-dioxanone), a polylactic acid-glycolic acid copolymer, polycaprolactone and polyethylene glycol; a solvent adopted in the electrostatic spinning is hexafluoroisopropanol, and the voltage adopted in the electrostatic spinning is 10-14 kV. The nintedanib-loaded anti-adhesion membrane has the advantages that the tensile strength and the elongation at break are obviously improved, the mechanical property is obviously improved, the fiber distribution is uniform, the obvious anti-adhesion effect is realized, the nintedanib-loaded anti-adhesion membrane is suitable for common laparotomy, and the application prospect is wide.

The invention belongs to the technical field of conductive adhesives, and particularly relates to a salt-fog-resistant waterborne conductive adhesive and a preparation method thereof.The salt-fog-resistant waterborne conductive adhesive is mainly prepared from, by weight, 5-10 parts of salt-fog-resistant waterborne polyurethane; 5 to 10 parts of water-based tackifying resin; 30 to 50 parts of conductive silver powder; 10 to 20 parts of ethanol; 2-10 parts of an anti-hydrolysis agent; and 10-30 parts of deionized water. According to the salt-fog-resistant aqueous conductive adhesive, polyurethane resin with polytetrahydrofuran alcohol and polycaprolactone polyol as main structures is used as matrix resin, a system is endowed with excellent water resistance and salt-fog resistance, the salt-fog-resistant aqueous conductive adhesive shows outstanding hydrolysis-resistant stability after being cured, and the salt-fog-resistant aqueous conductive adhesive and the conductive silver powder have a synergistic effect, so that the anti-settling performance is effectively improved.

The invention discloses an implantable absorbable PLA composite material and a preparation method thereof, and relates to the technical field of medical materials. The implantable absorbable PLA composite material is prepared from the following raw materials in parts by weight: 60 to 70 parts of PLA, 5 to 10 parts of poly (lactic-co-glycolic acid), 8 to 12 parts of polycaprolactone, 5 to 8 parts of modified hydroxyapatite, 2 to 3 parts of a toughening agent and 0.2 to 0.6 part of an antioxidant, the toughening agent is prepared by the following steps: reacting hydroxyethyl methylacrylate with ethylenediamine to prepare a four-arm compound, reacting the four-arm compound with 1-chloro-4-isocyanatobutane to prepare an isocyanate compound, and finally reacting the isocyanate compound with polyethylene glycol. The implantable absorbable PLA composite material prepared by the invention has excellent tensile property and impact resistance, and can meet the application requirements of clinical medical treatment.

The invention belongs to the technical field of multifunctional fibers, and particularly relates to a preparation method of multifunctional jasmine, camellia and chamomile fibers, and the preparation method comprises the steps of preparation of beta-cyclodextrin microspheres, modification of carboxyl, adsorption, preparation of bis-aminated polyethylene glycol polycaprolactone and spinning. The prepared multifunctional jasmine, camellia and chamomile fiber has an excellent antibacterial effect and a natural antibacterial effect, the bacteriostasis rate to staphylococcus aureus is 98.5-99.2%, the bacteriostasis rate to candida albicans is 98.2-99%, the bacteriostasis rate to escherichia coli is 97.5-98.7% after the multifunctional jasmine, camellia and chamomile fiber is washed with water for 50 times, and the antibacterial standard of textiles is met; the antibacterial durability is good, and the average antibacterial loss rate after 50 times of washing is lower than 2%; the antioxidant and anti-mite effects are good, and the free radical scavenging rate is more than 96%; and the mite repelling rate is greater than 70%.

The invention relates to the technical field of dental restoration materials, in particular to a bacteriostatic dental restoration composite film and a preparation method thereof. The oral cavity restoration composite film is composed of an upper-layer antibacterial film, a middle-layer polycaprolactone fiber film and a lower-layer bone restoration film. The upper-layer antibacterial film is prepared from the following components in parts by weight: 3 to 4 parts of cinnamon essential oil, 0.5 to 1 part of xanthan gum, 0.5 to 1 part of seed meal protein, 0.1 to 0.15 part of tannic acid, 5 to 7 parts of silk fibroin, 1 to 1.5 parts of polylactic acid, 0.6 to 1 part of chitosan, 1 to 1.5 parts of polyvinyl alcohol and 1.5 to 2.5 parts of glycerol; the lower-layer bone repair membrane is prepared from the following raw materials in parts by weight: 2 to 3 parts of nano-hydroxyapatite, 3 to 5 parts of citric acid, 6 to 9 parts of lactic acid, 3 to 4 parts of tyrosine, 1 to 2 parts of glycollic acid, 2 to 3 parts of casein, 0.2 to 0.3 part of hyperoside and 1 to 2 parts of gelatin.

The invention discloses a method for preparing a fully degradable hydrophilic / hydrophobic double-layer nanofiber membrane based on an electrostatic spinning method. The preparation method comprises the following steps: selecting a degradable high polymer material, taking hexafluoroisopropanol as a solvent, preparing a hydrophilic layer spinning solution from polylactic acid-glycolic acid copolymer (PLGA), methoxypolyethylene glycol (mPEG) and carbon dots (CDs) with antibacterial and anti-inflammatory characteristics, preparing a hydrophobic layer spinning solution from polycaprolactone (PCL), preparing a hydrophilic layer spinning solution from the hydrophilic layer spinning solution, preparing a hydrophilic layer spinning solution from the hydrophobic layer spinning solution, and preparing a hydrophilic layer spinning solution from the hydrophilic layer spinning solution and the hydrophobic layer spinning solution; and preparing the hydrophilic / hydrophobic double-layer nanofiber membrane by adopting an electrostatic spinning machine. The preparation method is simple, and the prepared double-layer nanofiber membrane is uniform in fiber diameter distribution and good in hydrophilic / hydrophobic layer effect and has a good application prospect in the field of biology.

Provided are silicone elastomer particles having a crosslinked structure which is active with respect to biodegradability, and can provide texture and feel during use that is equal to or higher than conventional silicone elastomer particles when blended in a cosmetic composition or the like, a reactive group-containing polycaprolactone compound having a specific structure and useful as a raw material for synthesis reactions, and a method for producing the same. A polycaprolactone compound containing a reactive group having two or more modified polycaprolactone structures has the structural formula (1) as described herein, where in the formula, n is a number in the range 1 to 5 and Ra is a specific (meth)acryl terminal group or alkenyl terminal group, specifically, a compound selected from the aforementioned (meth)acryl-modified polycaprolactone compounds and alkenyl-modified polycaprolactone compounds.

The invention discloses a biodegradable polylactic acid composite material and a preparation method thereof, and relates to the technical field of polylactic acid materials. The method comprises the steps that firstly, chitosan activated through hydrochloric acid is subjected to graft modification through a KH550 silane coupling agent, meanwhile, nano-zinc oxide is subjected to surface modification through stearic acid, the chitosan and the nano-zinc oxide are mixed, spray drying is conducted, and antibacterial composite powder is prepared; the preparation method comprises the following steps: performing hydrochloric acid activation and KH570 silane coupling agent modification on nano silicon dioxide, performing hydroxypropylation modification on alkali lignin, and performing reflux crosslinking reaction on the modified alkali lignin, KH570 modified nano silicon dioxide, polycaprolactone, methyl methacrylate and azodiisobutyronitrile to prepare a heat-resistant reinforcer; uniformly mixing polylactic acid, poly (butylene succinate), the antibacterial composite powder, the heat-resistant reinforcer, tributyl citrate, polyethylene glycol and talcum powder, and extruding and granulating by using a twin-screw extruder to obtain the heat-resistant antibacterial material. The composite material prepared by the invention has excellent antibacterial property, heat resistance and biodegradability.

The invention relates to the technical field of functional materials, in particular to a polyvinyl butyral flexible material as well as a preparation method and application thereof. The molecular chain regularity is destroyed through an isobutyraldehyde branched chain, the crystallinity is reduced, and the flexibility is improved; cesium-tin co-doped tungsten oxide has high infrared rejection rate and good dispersity, and the influence on the flexibility of the material is reduced; magnesium salicylate and magnesium formate are compounded, so that the reaction activity with resin is reduced, and the bonding stability in the bending process is ensured; the flexibility and migration resistance of the material are synergistically improved through the flexible plasticizer, and the interlayer sheet is prevented from being sticky; the flexible reinforcing agent polycaprolactone micro powder is used for forming an elastic node, bending stress is absorbed, and the recovery performance is improved. The polyvinyl butyral flexible material provided by the invention has flexible bending performance, an efficient infrared barrier function and stable bonding performance, is suitable for scenes such as curved building curtain walls, special-shaped automobile sunroofs or arc-shaped rail traffic windows, and has a wide application prospect.

The invention discloses a quick-curing polyurethane seamless expansion joint material for roads and a preparation method, and belongs to the technical field of road engineering materials. The material is prepared from polyether polyol, polycaprolactone glycol, a bisphenol A epoxy-polyether block isocyanate terminated prepolymer, a methyl phenyl silicon-boron hybrid hydroxyl chain extender, diphenylmethane diisocyanate, calcium carbonate, wollastonite, a hindered amine anti-aging agent and dioctyl phthalate. Wherein the bisphenol A epoxy-polyether block isocyanate terminated prepolymer is prepared by the following steps: reacting bisphenol A with epoxy chloropropane to generate epoxy resin, reacting with polytetramethylene ether glycol, and introducing isophorone diisocyanate; the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation and ethylene glycol reaction on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester; and the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester. The material has the advantages of quick curing property, weather resistance and high-temperature stability, and is suitable for road seamless expansion joint scenes.

The invention discloses a high-dispersion graphene conductive adhesive solution for a battery and a preparation method of the high-dispersion graphene conductive adhesive solution, and belongs to the technical field of conductive adhesive solutions. The high-dispersion graphene conductive adhesive solution for the battery prepared by the invention is prepared from the following raw material components in parts by mass: 6 to 8 parts of high-dispersion graphene, 4.5 to 13.5 parts of an adhesive and 60 to 90 parts of a solvent, the preparation method comprises the following steps: ultrasonically dispersing graphene in a mixed solution of hexadecyl triyl ammonium bromide and deionized water, sequentially adding hexadecyl triyl ammonium bromide, sodium molybdate dehydrate, bismuth nitrate pentahydrate and cerium nitrate hexahydrate, uniformly stirring and dispersing, performing hydrothermal reaction, washing, drying, grinding and sieving to obtain the high-dispersion graphene. The adhesive is prepared from an amphiphilic polyethylene glycol-polycaprolactone block copolymer and amphiphilic polyacrylate.

The invention discloses a bone repair material based on pH controlled release and a preparation method thereof. The bone repair material comprises the following raw materials: polycaprolactone, nano hydroxyapatite and nano magnesium oxide. The composite bone repair scaffold has the beneficial effects that the composite bone repair scaffold with excellent biocompatibility, excellent osteogenesis performance, excellent degradation performance and pH controlled release of magnesium ions is prepared by printing the bone repair material through a 3D printing technology, a temporary three-dimensional structure can be provided for cells, cell adhesion, proliferation and differentiation are promoted, growth factors are released at the same time, and the growth rate of the cells is increased. The formation of new bone tissues is guided; the composite bone repair scaffold can continuously and quantitatively release magnesium ions through pH value control, when osteoarthritis or bone tissue inflammation occurs at a bone defect part due to improper operation and rejection reaction, the magnesium ion release speed of the composite bone repair scaffold is increased, the anti-inflammatory effect is achieved, and the magnesium ions which are continuously released can promote bone tissue repair.