498 results about "Barium salt" patented technology

Two (or more), -component, body-implantable, absorbable, biocompatible, putty, and non-putty hemostatic tamponades for use in surgery. Component 1 is a finely powdered bulking material, preferably less than 50 microns, e.g. the calcium, magnesium, aluminum, or barium salts of saturated or unsaturated carboxylic acids containing about 6 to 22 carbon atoms, hydroxyapatite, DBM, polyglycolide, polylactide, poldioxinones, polycaprolactones, absorbable glasses, gelatin, collagens, mono, and polysaccharides starches.

Component 2, a dispersing vehicle, may be esters of C₈-C₁₈ monohydric alcohols with C₂-C₆ aliphatic monocarboxylic acids; C₂-C₁₈ monohydric alcohols with polycarboxylic acids; C₈-C₃₀ monohydric alcohols; tocopherol and esters thereof with C₂-C₁₀ aliphatic monocarboxylic acids or polycarboxylic acids; absorbable 10-14C hydrocarbons; free carboxylic acids such as oleic, capric, and lauric; dialkyl ethers and ketones; alkyl aryl ethers and ketones, polyhydroxy compounds and esters and ethers thereof; (ethylene oxide/propylene oxide copolymers), oils e.g. olive oil, castor oil and triglycerides.

Two (or more), component, body-implantable, absorbable, biocompatible, putty-like surgical mechanical hemostatic tamponades for use in surgery. Component 1, a carboxylic acid salt bulking material preferably less than 50 micron, preferably the calcium, magnesium, zinc, aluminum, lithium or barium salts of saturated or unsaturated carboxylic acids containing about 6 to 22 carbon atoms.

Component 2, a dispersing vehicle, may be esters of C₈-C₁₈ monohydric alcohols with C₂-C₆ aliphatic monocarboxylic acids; C₂-C₁₈ monohydric alcohols with polycarboxylic acids; C₈-C₃₀ monohydric alcohols; tocopherol and esters thereof with C₂-C₁₀ aliphatic monocarboxylic acids or polycarboxylic acids; absorbable 10-14C hydrocarbons; free carboxylic acids such as oleic, linoleic, caprylic, capric, and lauric; dialkyl ethers; alkyl aryl ethers; dialkyl ketones and alkyl aryl ketones; polyhydroxy compounds and esters and ethers thereof; oils such as olive oil and castor oil and triglycerides.

The invention discloses a method for preparing chloroethylene by catalytic reforming, which relates to a method for preparing the chloroethylene. The method comprises: a step of preparing a catalyst by using active carbon as a carrier, in which a barium salt is used as a catalyst, the active carbon is used as the catalyst carrier, and the barium salt is dissolved in water, absorbed by the active carbon and dried to obtain the catalyst carried by the active carbon; and a step of synthesizing the chloroethylene, in which acetylene gas and dichloroethane vapour are mixed and introduced to a reactor containing the catalyst carried by the active carbon to react, the reaction effluent is cooled to room temperature, unreacted dichloroethane is condensed to be separated out, and the remaining gas is compressed and frozen to give liquid chloroethylene. In the invention, a mercury free catalyst is adopted, the mercury pollution of the chloroethylene production industry is eliminated, and the reaction is performed spontaneously with little energy consumption.

The invention relates to a long-acting emulsion-type antirust fluid used for metal rust prevention. Every 100 parts of the antirust fluid include the following components according to parts by weight: 3-15 oil soluble surfactant, 1-10 alcohol ether type couplant, 1-10 oily-type rust preventive and the balance base oil, wherein the oil soluble surfactant is any one of petroleum sodium sulfonate with molecular weight ranging from 300 to 800, sodium heavy alkylbenzene sulfonate and sodium sulfanilate, the alcohol ether type couplant is any one of ethyl alcohol, ethyl ether, butyl ether, diethylene glycol monobutyl ether, diethylene glycol propyl ether, butyl glycol ether and ethylene glycol propyl ether, the oily-type rust preventive is any one of barium petroleum sulfonate, dinonyl naphthalenesulfonic acid barium salt and barium soap of petroleum ester oxide, and the base oil is any one of cycloalkyl base oil and paraffin base oil. The long-acting emulsion-type antirust fluid has the advantages of meeting the demands of short-term rust prevention of metal and having lower using cost.

The invention discloses a method for recovering nickel and molybdenum from a waste nickel-molybdenum catalyst. The method comprises the concrete steps of firstly carrying out primary low-temperature roasting, then carrying out secondary high-temperature alkali roasting, and transforming molybdenum and aluminum components in the waste catalyst into water-soluble sodium molybdate and sodium metaaluminate; then carrying out water leaching and solid-liquid separation to obtain a nickel slag and an alkaline filter liquor containing molybdenum and aluminum; carrying out acid leaching, evaporative crystallization and solid-liquid separation on the nickel slag to obtain a nickel sulfate product; and adding a barium salt precipitant into the filter liquor to separate the aluminum and the molybdenum, obtaining a refined aluminum-containing solution, adopting a chemical precipitation method to obtain an aluminum hydroxide precipitate, and calcining to obtain an aluminum oxide product. According to the method for recovering the nickel and the molybdenum from the waste nickel-molybdenum catalyst provided by the invention, valuable metals in the catalyst is comprehensively recycled, three products such as nickel sulfate, barium molybdate and aluminum oxide are obtained, the valuable metal recovery rate is high, the product added value is high, and the method has a certain application value.

The invention relates to a method for extracting vanadium and chromium from a vanadium chromate mixed solution. The method has the characteristics that the vanadium in the vanadium chromate mixed solution is separated and recycled through the crystallization precipitation method or the hydrolysis precipitation method or the calcium salt precipitation method at first, then the chromium in the enrichment solution is separated through the copper salt precipitation method or the barium salt precipitation method, an obtained chromium precipitation enrichment product is then transformed into chromium enrichment liquid, the chromium enrichment liquid is further processed into products of chromic acid and chromate, and production of vanadium-chromium reducing slag and ammonia-nitrogen wastewater in the separation and recycling process of the vanadium and the chromium in the solution is effectively avoided. The method for extracting the vanadium and the chromium from the vanadium chromate mixed solution has the advantages of being good in vanadium and chromium separation effect, short in technological process, high in metal recycling rate, easy and convenient to operate, low in production cost, environmentally friendly and the like and is suitable for industrial production and application.

The invention discloses a method for separating arsenic and selenium from copper anode slime alkaline leach liquor. The method comprises the following steps: 1) oxidation, namely adding an oxidizing agent or introducing oxidizing gas into the copper anode slime alkaline leach liquor, so that oxidized copper anode slime alkaline leach liquor is obtained; 2) arsenic precipitation, namely adding a calcium salt into the oxidized copper anode slime alkaline leach liquor, stirring the obtained mixture so as to produce a precipitate, and carrying out filtration and separation on the precipitate so as to obtain a calcium arsenate precipitate and arsenic post-precipitation liquid; and 3) selenium precipitation, namely adding a barium salt into the arsenic post-precipitation liquid obtained in the step 2), stirring the obtained mixture so as to produce a precipitate, carrying out filtration and separation on the precipitate so as to obtain a barium selenate precipitate and selenium post-precipitation liquid, and carrying out evaporative crystallization on the selenium post-precipitation liquid so as to recycle alkali, or directly returning to a leaching process. The method disclosed by the invention is short in technological process, less in equipment and simple in operation, and can be used for realizing the separation and enrichment of arsenic and selenium, the precipitation rate of arsenic is higher than 96%, and the precipitation rate of selenium is higher than 99%; by virtue of carrying out evaporative crystallization on a solution for recycling or directly returning the solution to a leaching process, the recovery of alkali is realized.

The invention discloses a high efficiency sulfate attack resistant concrete additive and a preparation method thereof. The technical scheme of the concrete additive comprises the following raw materials in parts by weight: 15-25 parts of barium salt, 5-10 parts of sorbitol, 15-30 parts of calcined diatomaceous earth, 0.5-1.0 part of a grinding aid, 30-50 parts of silica fume, 10-20 parts of ultrafine fly ash and 1.0-2.0 parts of a water reducer. The high efficiency sulfate attack resistant concrete additive can reduce the proper shrinkage cracks of concrete, improve the compactness, and greatly improve the multi-type attack resistant properties of the concrete effectively for a long time.

A resist composition comprising a base resin comprising acid labile group-containing recurring units and preferably acid generator-containing recurring units, and a sodium, magnesium, potassium, calcium, rubidium, strontium, yttrium, cesium, barium or cerium salt of α-fluorinated sulfonic acid bonded to an alkyl, alkenyl, alkynyl or aryl group exhibits a high resolution and sensitivity and forms a pattern of satisfactory profile with minimal LWR after exposure and development.

The invention discloses environment-friendly thixotropic antirust oil which consists of the following raw materials in parts by weight: 57-65 parts of paraffin-based base oil, 9-16 parts of naphthenic base oil, 6-11 parts of alkyl high-boiling residue base oil, 5-10 parts of barium-free antirust agent, 1-4 parts of thixotropic agent, 0.2-0.5 part of a phenolic antioxidant, 0.1-0.5 part of an anilino antioxidant, 0.2-1 part of an olefine acid antioxidant and 2-3 parts of a coalescing agent. The invention also provides a method for preparing the environment-friendly thixotropic antirust oil. The environment-friendly thixotropic antirust oil does not contain harmful barium salt decomposed substances and is environment-friendly; the product can rapidly form a stable oil film on the elevation face of a workpiece and does not flow away and waste is reduced; the antirust oil has excellent high temperature resistance, heat and humidity resistance, excellent high-salinity salt mist erosion resistance and excellent antirust performance, has good voltage resistance and is conveniently used for electrostatic spraying; and moreover, the antirust oil has good cleaning performance, and the antirust oil film can be easily removed by using neutral or alkaline water-based cleaning agents.

The invention discloses a method capable of improving selenium content for preparing polysaccharide selenite. The method comprises the steps of adding a selenium compound solution having the mass fraction of 60-80% by spraying to a polysaccharide or a polysaccharide complex under a stirring condition and reacting at a temperature in the range of 120-160 DEG C; after the reaction is completed, purifying and drying the reaction product to obtain polysaccharide selenite, wherein the selenium compound is seleninic acid or a selenite. The method is simple in process, easy in after-treatment, controllable in reaction conditions and good in repeatability; in the production process, the generation of toxic gases such as hydrogen selenide is avoided and the use of a strong acid and heavy metals such as a barium salt to catalyze the reaction and the use of toxic organic solvents such as pyridine and benzene are avoided, and therefore, the production process is green and environment-friendly; the polysaccharide selenite prepared by the method is low in toxicity and high in bioavailability, and the selenium content of the polysaccharide selenite is higher than 18% which is far higher than the selenium content of less than 2% of the present commercial organic selenium products.

The invention provides a barium residue detoxifying method which comprises the step of adding barium residue in the cement production process, wherein the barium residue is 0.2-0.8% of the cement raw material by mass percent. According to the barium residue detoxifying method provided by the invention, the aim of recycling the waste barium residues generated in the industrial production of barium salt is achieved; what is more, the barium residues are thoroughly detoxified to solve the pollution to the environment, particularly the pollution to the water quality; through the method, barium-containing cement is obtained; compared with the traditional Portland cement, due to the introduction of barium, the fracture resistance and the compressive strength of the cement are remarkably improved (both the early and later strengths of the calcium barium sulphoaluminate mineral are relatively high, and the Ba<2+> enters in the crystal lattice of C2S to enable the crystal to warp so as to improve the hydration activity of C2S), and strong absorption function is brought to the gamma-ray so as to bring a certain radiation protection performance.

The invention relates to a phosphating washing-free phosphating solution modified with barium salt at ambient temperature. The phosphating solution comprises a phosphoric acid, a nitric acid, and Zn2+, Ca2+, Mn2+, Ni2 plus salt thereof, ammonium molybdate,ammonium tungstate, phytate, H2O2 and barium nitrate or barium hydroxide. The pH value ranges from 1.6 to 4.2. The invention can be phosphated under soak, rinse, brush or the combined way thereof at 3 DEG C.to 45 DEG C.. The phosphating solution is stable and capable of automatically precipating and removing the SO42- inside the phosphating solution and therefore eliminating the influence of SO42- on quality; the phosphorizating membrane is continues, uniform and compact, the membrane weight is between 0.5g is multiplied by m and 3.0g is multiplied by m minus 2 and the iron-red epoxy primer is sprayed and the adhesion thereof can be 1 grade.

The invention provides a method for preparing SrCuSi4O10 and BaCuSi4O10 blue pigments through a hydrothermal technique, and belongs to the technical field of hydrothermal chemistry. The method uses copper oxide powder or copper salt, barium salt or strontium salt, and silicate as raw materials, and NH4OH as a mineralizing agent and comprises the following hydrothermal reaction processes: mixing a reactant with distilled water according to a stoichiometric ratio of an objective product, adjusting the pH value of a solution to be greater than 10 and less than 14, putting in a high-pressure reactor so as to enable the filling degree to reach 40%-90%, sealing and reacting for 5-72 hours at the temperature of 230-300 DEG C; and cooling and filtering so as to obtain products. The invention provides a new reaction route and a green preparation method for SrCuSi4O10 and BaCuSi4O10 difficult to prepare. The products are multi-level structure microparticles, have high purity, regular morphology and good dispersity and are uniform in particle size. The preparation method is simple, efficient and high in yield; waste liquid generated in a hydrothermal reaction process can be recycled.

The testing assembly comprises the glass tube, the indicating material in the glass tube and the diffusion control film on two ends of the glass tube. The indication scale for measuring value constitutes the indication window. The testing assembly and the scale are fixed on the carrier with badge shape. The indicating material comprises main agent, the inter surface modifying addition and ceramics powder in 80-120 mesh. One or several of lead acetate, lead nitrate and silver nitrate constitute the main agent. The intersurface modifying addition is soluble barium salt. The weight of the main agent is 1%-10% of the weight of the admixture. The invention provides the features of powerless, high sensitivity, good accuracy, low cost and convenience.

The invention relates to a preparation method of a nano flaky ferroelectric material for photocatalysis. The preparation method comprises the steps of preparing barium salt, strontium salt and titanium salt to obtain premix according to a barium strontium titanate (BaxSr1-xTiO3) molecular formula, mixing barium salt and strontium salt according to proportions and dissolving in water, adding NaOH, dissolving titanium salt in absolute ethyl alcohol, uniformly mixing the raw materials, carrying out thermal reaction for 24 hours in a high-pressure kettle at 160-200 DEG C, cooling to room temperature in air, filtering, washing and drying the mixture to obtain nano flaky barium strontium titanate powder. Compared with the prior art, the preparation method has the advantages that the process is simple and few aggregation phenomena of prepared nano particles exist; in comparison with barium strontium titanate nano powder prepared by a conventional hydrothermal method, the preparation method, which adopts butyl titanate as a titanium source, has the characteristics of high purity of a prepared sample, good crystallinity of powder and the like.

The invention discloses a removing method of magnesium sulfate from waste water solution with magnesium sulfate, which comprises the following steps: predisposing waste water solution with magnesium sulfate; transmitting the solution into micro-filter film device to remove micro-particle impurity; transmitting the solution into nano-filter film; obtaining percolation liquid with low-content magnesium sulfate and condensate with high-content of magnesium sulfate; freezing the condensate; extracting the solid of magnesium sulphate heptahydrate or adding calcium salt or barium salt to obtain calcium sulfate or barium sulfate; reacting magnesium salt and calcium hydroxide to produce magnesium hydroxide and calcium salt; saving the disposing cost; protecting environment; recycling magnesium sulfate.

The invention provides a sulfate-erosion-resistant preservative for an underground concrete structure. The preservative is prepared from, by mass, 40-60% of compacting components, 5-15% of reduction components, 20-30% of barium salt, 0.5-2.5% of ettringite inhibitors and 10-20% of thaumasite inhibitors, wherein the compacting components are one or more of silica fume, metakaolin and fly ash, the reduction components are composed of polydimethylsiloxane and 2-methyl-2,4-pentanediol, and the mass ratio of polydimethylsiloxane to 2-methyl-2,4-pentanediol is 1:1-3. The preservative is resistant to erosion of ettringite and thaumasite and is also easy to manufacture and low in cost.

Disclosed is a flame-retardant polyamide composition which is excellent in mechanical properties such as toughness, and heat resistance, flame retardancy and flow ability during a reflow soldering process. In addition, this polyamide composition exhibits high thermal stability during molding. Specifically disclosed is a flame-retardant polyamide composition containing (A) 20-80% by weight of a specific polyamide resin, (B) 10-20% by weight of a metal phosphinate, (C) 0.05-1% by weight of a lithium salt, a calcium salt, a barium salt, a zinc salt or an aluminum salt of montanic acid, behenic acid or stearic acid. It is preferable that this flame-retardant polyamide composition contains no halogen flame retardant.