The invention relates to a
copper anode sludge silver separating
slag reutilization technique, particularly a method for comprehensively recovering valuable metals from
copper anode sludge silver separating
slag. The method comprises the following steps: carrying out hot acid leaching on silver separating
slag, filtering to obtain a hot acid leaching solution containing silver and
barium and hot acid leaching slag containing
tin and lead; diluting the hot acid leaching solution with water, filtering to obtain a precipitate, dissolving the precipitate with
nitric acid, and filtering to obtain a
barium sulfate precipitate and a
silver nitrate solution; reducing the solution to obtain silver
powder; leaching the hot acid leaching slag with acidic
chlorine salt, filtering to obtain a
chlorine salt leaching solution and
chlorine salt leaching slag; cooling the chlorine salt leaching solution to crystallize and precipitate
lead chloride; and carrying out alkali fusion,
water immersion and
evaporation crystallization on the chlorine salt leaching slag to obtain
sodium stannate. The method can effectively recover all the valuable metals with higher content in the silver separating slag, and the
recovery rates of the lead, silver,
tin and
barium are respectively up to higher than 97%, 92%, 90% and 95%. The method has the characteristics of simple technique, no emission of three wastes, high
metal recovery rate and the like, and is suitable for large-scale industrial production.