676 results about "Copper sulfate" patented technology

The invention discloses a preparation method for selectively oxidizing thioether into sulfoxide through photo-initiation, and belongs to the field of synthesis of medical compounds. The preparation method comprises the following steps that in the air atmosphere, a thioether compound is dissolved in an acetonitrile-water mixed solvent, inorganic metal salt catalysts such as ferric chloride and copper sulfate are added, the mixture reacts for 8-48 h at the temperature of 0-45 DEG C under illumination with the wavelength of 295-405 nm, selective oxidation is carried out, and the sulfoxide product is obtained, and the molar ratio of thioether to the catalysts is 5: 1. The method overcomes the problems of excessive oxidation risk, complicated operation, environmental pollution and the like caused by dependence of a noble metal catalyst and use of a strong oxidant in the existing thioether oxidation method, has the advantages of high catalytic efficiency, high yield and excellent selectivity, can greatly reduce the production cost, is suitable for later industrial synthesis and amplification, and has wide application prospects. The method has the advantages of no expensive metal catalyst or oxidant, simple preparation process, high efficiency, environmental protection, safety and cost saving.

The invention provides a preparation method of a porous copper foil with a regular polygonal hole array, which comprises the following steps of: grinding and polishing a titanium plate until the titanium plate is matte, punching holes with the regular polygonal hole array in the titanium plate by laser, finely trimming vertex angles of the regular polygonal holes by laser, and polishing and grinding the titanium plate to obtain the porous copper foil with the regular polygonal hole array. The method comprises the following steps: preparing a titanium plate, cleaning with pure water and alcohol to obtain a clean titanium plate, preparing a copper sulfate electrolyte, adding a proper amount of a brightener, a wetting agent and a high resistance agent into the electrolyte, mixing, pouring the mixed solution into an electrolytic bath, putting the clean titanium plate and a carbon plate into the electrolytic bath, and carrying out electrolytic foil generation by taking the titanium plate as a cathode and the carbon plate as an anode; and after foil generation is finished, the copper foil is stripped from the surface of the titanium plate, and the porous copper foil with the regular polygon holes is obtained. According to the method, the holes of the titanium plate are the regular polygon holes, and the vertex angles of the regular polygon holes are finely trimmed, so that the copper foil of the electrolytic raw foil is not easy to adhere to the titanium plate during stripping, and the production yield of the copper foil is further improved.

The invention discloses a preparation method of a 3-micron ultrathin lithium battery copper foil. The preparation method comprises the following steps: preparing a copper sulfate electrolyte; a wetting agent, a brightening agent and a high resistance agent are added into the copper sulfate electrolyte, the high resistance agent is at least one of thiazolidinethione, polyethyleneimine, 2-mercaptobenzimidazole and ethylene thiourea, and a mixed additive is formed; polishing and grinding a cathode roller by adopting a flying wing wheel, and carrying out electrolytic treatment on the mixed additive through the polished and ground cathode roller to obtain a first-stage copper foil; and the first-stage copper foil is placed in a nitrogen furnace to be subjected to annealing treatment, and the 3-micron ultrathin lithium battery copper foil is obtained. The invention aims to solve the technical problems that in the prior art, edge tearing, foil breaking, warping, dark appearance oxidation and the like are prone to occurring in the production process of the ultrathin copper foil, the tensile strength and the ductility are difficult to consider at the same time, and stable mass production of the 3-micron copper foil is still difficult.

The invention relates to the technical field of electrolytic copper foil processing, and particularly provides a method for reducing the rough surface roughness of an HVLP copper foil by using a composite additive, which comprises the following steps: step (1): enabling the composite additive to flow into a high-level tank through an additive flow pump, uniformly mixing the composite additive with a copper sulfate electrolyte, and enabling the mixture to flow into a crude foil machine; step (2), then adjusting process parameters of a crude foil machine, including current and line speed of a cathode roller; (3) foil generation and foil drawing are carried out; the composite additive comprises one or two of gelatin and collagen. One or more composite additives composed of gelatin, collagen, sodium dithiodipropane sulfonate, N, N-dimethyl-dithioformamide sodium propanesulfonate, 3-sulfydryl-1-sodium propane sulfonate, hydroxyethyl cellulose and polyethylene glycol are added into the raw foil electrolyte, so that the copper electrodeposition reaction potential can be effectively changed; and uniform and compact copper crystallization peaks are obtained, the rough surface roughness of the raw foil is reduced, and the uniformity of a plating layer is improved.

The invention discloses a nickel-iron alloy dissolving method which comprises the following steps: feeding a copper sulfate solution into a mixed feed liquid containing a first nickel-iron alloy and copper sulfate, carrying out primary replacement reaction to obtain copper-containing slag and a reaction liquid, maintaining c (Fe < 2 + >) / c (Cu < 2 + >) in the reaction liquid to be 50-90, and overflowing to obtain a nickel-iron-copper solution; wherein c (Fe < 2 + >) and c (Cu < 2 + >) are mass concentrations of Fe < 2 + > and Cu < 2 + > respectively, and the unit is g / L; and carrying out secondary replacement reaction on the nickel-iron-copper solution and a second nickel-iron alloy until the concentration of Cu < 2 + > in a liquid phase is lower than 5ppm, and carrying out solid-liquid separation to obtain a nickel-iron solution product and second copper-containing slag. According to the dissolving method of the ferro-nickel alloy, the recovery process of ferro-nickel in the ferro-nickel alloy can be simplified, the quality of the ferro-nickel solution is improved, the gas production phenomenon caused by acid dissolution is avoided, and the safety is higher.

The application provides a weathering steel surface rust layer stabilizing treatment agent for industrial atmospheric environment, and the chemical composition of the weathering steel surface rust layer stabilizing treatment agent is as follows in terms of mass fraction: 25-45% of acrylic resin, 2.0-6.0% of chromium sulfate, 3.0-8.0% of ferrous oxide, 2.0-6.0% of ferric oxide, 0.5-3.5% of copper sulfate, 0.3-1.5% of sodium bisulfite, 1.0-6.0% of sodium molybdate, 0.5-3.5% of nickel sulfate, 2.0-5.0% of potassium phosphate, 0.05-0.5% of surfactant, 0.05-0.5% of defoaming agent, 0.05-0.5% of dispersing agent, 0.05-0.5% of thickening agent, and the balance is water, wherein the amount of plasticizer added is 2-5% of the resin. The stabilizing treatment agent in the application can promote the weathering steel surface to form a stable and dense rust layer within 0.5-1 year after the surface of the weathering steel is treated before use.

The invention discloses a method for extracting copper fine powder by flotation of copper-containing ore, which belongs to the technical field of mineral processing, and comprises the following steps: after copper-containing raw ore is crushed, ground and classified by a cyclone, overflow enters flotation, and settled sand is returned for regrinding; sodium carbonate is added into graded overflow to adjust the pH, a sodium hexametaphosphate-polyacrylamide composite dispersant is added, and copper sulfate is added and stirred after low-temperature microwave heating; gradient flotation is conducted, specifically, copper sulfide is roughly selected, the pH is adjusted, an amino-sulfonic acid group synergistic modified layered double metal hydroxide / cobalt ferrite composite collecting agent is added, and rough concentrate 1 is obtained through high-frequency pulse air inflation flotation; copper oxide roughing is conducted, clear water is supplemented to adjust the pH, and a collecting agent is supplemented to obtain rough concentrate 2; scavenging is performed for three times, a collecting agent is added for flotation, and concentrate returns to the previous stage; the rough concentrates are combined, and magnetic impurities are removed through high-gradient magnetic separation to obtain magnetic concentrates; and carrying out microbiological leaching on tailings to recover copper. The composite collecting agent is prepared through layered double hydroxide carrier synthesis, amino modification, sulfonic acid group grafting and cobalt ferrite anchoring.

The invention discloses a high-calcium suspension fertilizer as well as a preparation method and application thereof, and relates to the technical field of chemical fertilizer production, the high-calcium suspension fertilizer comprises the following components in parts by weight: 20-30 parts of a macroelement fertilizer, 10-15 parts of a medium element fertilizer, 3-5 parts of a microelement fertilizer, 0.5-3 parts of an auxiliary agent and 30-50 parts of deionized water; the macroelement fertilizer is prepared from 30-50 parts of nitrogen fertilizer, 20-30 parts of phosphate fertilizer and 15-20 parts of potash fertilizer; the medium element fertilizer is modified nano calcium carbonate and magnesium carbonate; the trace element fertilizer is prepared from zinc amino acid, sodium tetraborate, ferric sodium ethylenediaminetetraacetate, molybdenum sodium ethylenediaminetetraacetate, manganese sulfate monohydrate and copper sulfate pentahydrate. Therefore, the nano calcium carbonate can be quickly absorbed by the plants, so that calcium ions can be supplemented in time in the growth process of the plants, and the growth of the plants is accelerated.

The invention provides a preparation method of ultrahigh-purity copper. The preparation method comprises the following steps: providing a first anode, a first cathode and an electrolyte; the electrolyte comprises the following components: a purified copper salt solution, inorganic acid, an oxidizing agent and an additive, the purified copper salt solution comprises purified copper salt and water, the purified copper salt comprises copper sulfate and copper nitrate, and the molar ratio of nitrate to sulfate in the purified copper salt solution is (1.5-9): 1; the additive comprises any one or a combination of at least two of an alcohol compound, polyacrylamide or a tetrazole compound; and the first cathode and the first anode are immersed in the electrolyte for electrochemical deposition, and the ultra-high-purity copper is obtained. The electrolyte composed of the purified copper salt solution, the inorganic acid, the oxidizing agent and the additive is adopted, the proportion of nitrate radicals to sulfate radicals in the purified copper salt solution is controlled, the impurity content of the sulfur element and the silver element in the electrolyte can be controlled, and preparation of the ultra-pure electrolytic copper is achieved.

The invention is applicable to the technical field of biomedical materials, and provides an anti-inflammatory hemostatic composite gel microsphere and a preparation method and application thereof, and the preparation method comprises the following steps: mixing sodium alginate and baicalin, dissolving in deionized water to obtain a mixed solution, spraying the mixed solution into a calcium chloride solution by utilizing electrospinning and electrospraying, and carrying out electrostatic spinning and electrospraying to obtain the anti-inflammatory hemostatic composite gel microsphere. Gel microspheres are formed through ionic crosslinking; washing the gel microspheres with a calcium chloride solution, and soaking the gel microspheres in a chitosan acetic acid solution to obtain chitosan-encapsulated gel microspheres; placing the gel microspheres in a copper sulfate solution, and performing low-temperature calcium-copper ion exchange to obtain baicalin / copper alginate composite gel microspheres; and filtering, washing and freeze-drying the composite gel microspheres. The electrospray technology is combined with ionic crosslinking, the size and morphology of the microspheres are accurately controlled, the antibacterial effect on escherichia coli and staphylococcus aureus is remarkable, the in-vitro blood coagulation time is shortened by 30%, the cytotoxicity is low, and good biocompatibility is achieved.

The invention discloses a blending method of a copper plating bearing agent, which comprises a blending device, and the blending device is provided with a structure for simultaneously starting multiple powers with a stirring structure for a feeding port and is used for blending the copper plating bearing agent; the method comprises the following steps: raw material pretreatment, device debugging, step-by-step feeding, and starting of a multi-power structure by a filter screen plate. And the concentration is finely adjusted until the concentration of the copper plating bearing agent reaches the standard, and qualified mixed liquid is guided out. By adopting the method, the adding uniformity of the copper sulfate pentahydrate powder and the overall blending efficiency are improved, accurate blending of the copper plating bearing agent is guaranteed, and accurate control over the concentration of the copper plating bearing agent can be achieved through step-by-step input, medium-term sampling detection and fine adjustment.

The invention discloses a high-chlorine industrial wastewater treatment and chlorine recovery method, which comprises the following steps: sequentially adding copper sulfate and a carbon-sulfur reducing agent into to-be-treated high-chlorine wastewater according to a ratio, adjusting the pH value, generating chlorine-containing residues, precipitating and separating out the chlorine-containing residues from a water body, and carrying out decoloration treatment on dechlorinated tail water by adopting an electrolytic bath, copper sponge deposited at the cathode is subjected to impurity removal treatment and then is merged into a copper salt circulating system; chlorine-containing residues are subjected to dissolution and quality-divided treatment, an obtained solution phase is concentrated / crystallized, KCl is recycled, an obtained copper-containing precipitate and the sponge copper are combined and collected, the mixture is dissolved by means of dilute sulfuric acid in the oxidizing atmosphere, and the whole mixture returns to a wastewater dechlorination treatment system. CuSO4 is reduced to generate Cu < + > ions to precipitate and remove chloride ions in the wastewater, the obtained KCl product is used at a high value, and the cuprous precipitate is subjected to conversion treatment and is completely reused in the dechlorination process, so that the wastewater treatment cost is remarkably reduced, and the method has the obvious advantages of high dechlorination efficiency, no generation of solid wastes and the like, and is suitable for industrial production. And the method has wide adaptability to industrial circulating water containing 2.5-8.5 g / L of chlorine, membrane-process strong brine and the like.

The invention discloses a method for improving copper plating uniformity of a circuit board. The method comprises the following steps: performing surface treatment on a drilled circuit board; the circuit board is placed in the electroplating solution to be electroplated, and the technological conditions are that the temperature of the electroplating solution is 20-30 DEG C, and the current density is 1.5-2.5 A / dm < 2 >; the main chemical components of the electroplating solution comprise copper sulfate pentahydrate, sulfuric acid, hydrochloric acid and an additive, the concentration of the copper sulfate pentahydrate is 200-250 g / L, the concentration of the sulfuric acid is 50-70 g / L, and the concentration of chloride ions is 70-90 ppm. According to the method for improving the copper plating uniformity of the circuit board, by optimizing the components of the electroplating liquid and the parameters of the electroplating process, a plating layer is more uniform, the copper thickness range inside and outside holes is controlled to be about 8.0 microns, and the requirements of high-reliability PCBs (such as HDI and carrier plates) with the thickness-diameter ratio larger than 8: 1, such as 5G communication backboards and the like are met.

The invention discloses a device for preparing copper sulfate from waste etching liquid. The device comprises a box body, wherein a separation chamber, a reaction chamber and a concentration chamber are sequentially arranged inside the box body from bottom to top, the separation chamber and the reaction chamber being connected via a connecting pipe. A buffer tank and a plurality of filter tanks are fixed on the top of the box body and are connected via a connecting pipe to the top of the concentration chamber. The concentration chamber is provided with a heating pipe. A stirring assembly is provided on one side of the reaction chamber. An extraction assembly is provided on the top of the separation chamber. A concentrated sulfuric acid tank is provided on one side of the box body and is connected via a connecting pipe to the top of one side of the reaction chamber. A fan is provided on the other side of the box body and is connected to the top of one side of the separation chamber. An air outlet pipe is also provided and is connected to the tops of the concentration chamber and the separation chamber, respectively. The air outlet pipe is connected to a purifier. Several of the connecting pipes are provided with flow meters and solenoid valves.

The invention relates to a method for preparing a magnetic Fe3O4 / Cu / nitrogen-doped carbon composite material by a one-step method and an application of the magnetic Fe3O4 / Cu / nitrogen-doped carbon composite material, and aims to solve the problems of poor catalytic activity, complex separation and recovery and complex synthesis method of the existing PMS activated catalytic material. According to the method, melamine is selected as a carbon source and a nitrogen source, ferric nitrate and copper sulfate are selected as an iron source and a copper source respectively, and the magnetic Fe3O4 / Cu / nitrogen-doped carbon composite material is synthesized in one step by adopting a high-temperature pyrolysis method. The adsorbent not only has excellent adsorption performance on dye-methylene blue, but also can realize high-efficiency oxidative degradation. The magnetic Fe3O4 / Cu / nitrogen-doped carbon composite material prepared by the invention not only has excellent catalytic performance, but also is easy to magnetically separate and recycle, and is suitable for efficient treatment of dye wastewater. The method is applied to the field of catalytic degradation of wastewater.

The invention relates to a copper sulfate-free copper-zinc sulfide ore flotation separation method, and relates to the technical field of mineral flotation separation. The method comprises the following steps: obtaining copper-zinc sulfide ore pulp; by taking ethionine ester as a collecting agent and lime as an inhibitor, carrying out copper-zinc bulk flotation on the copper-zinc sulfide ore pulp to obtain copper-zinc bulk concentrate and discardable tailings; zinc sulfate serves as an inhibitor, the copper-zinc bulk concentrate is subjected to regrinding treatment, and copper-zinc bulk concentrate pulp is obtained; copper flotation is conducted on the copper-zinc bulk concentrate pulp, and copper concentrate and copper tailing pulp are obtained; with ethionine ester as a collecting agent, the copper tailing ore pulp is subjected to sphalerite activation under the condition of aeration stirring, and activated sphalerite ore pulp is obtained; and carrying out flotation on the activated sphalerite by using lime as an inhibitor to obtain zinc concentrate. The scheme provided by the invention has the advantages that heavy metal pollution is avoided, the mineral separation cost is reduced, and the process adaptability is high.

The application discloses a kind of high-altitude area weathering bridge steel member rust layer stabilizing treatment agent and use method, mainly solve the rust layer of high-altitude area weathering bridge steel member is difficult to stabilize and surface rust layer color is not uniform, rust liquid flow and other problems.The stabilizing treatment agent is composed of fast rusting agent and rust layer stabilizer, the fast rusting agent is composed of ferric chloride, copper sulfate, hydrogen peroxide, ethylene glycol and deionized water, the rust layer stabilizer is composed of sodium polyphosphate, sodium bisulfite and methanol and deionized water.The treatment agent of the application is suitable for the harsh environment of low temperature, oxygen is rare, inorganic salt system treatment agent is prone to icing in high sea area, the surface of high-altitude area weathering bridge steel member after processing forms brown rust layer with uniform color, no rust liquid flow.The rust layer of weathering bridge steel member can be stabilized within 8 hours by using the application, the thickness of the rust layer after processing is greater than or equal to 50 μm, the surface rust layer color difference value ΔE of different parts of the component is less than or equal to 10, and the amount of surface rust layer of the component is greater than or equal to 15 g / m 2 .

The invention provides a method for preparing a functional copper current collector, the method comprises the operation of thickening a copper elementary substance layer through water electroplating treatment, and an electroplating solution adopted in the water electroplating treatment contains copper sulfate, sulfuric acid and a copper-cyanogen complex; in the electroplating solution, the mass concentration of copper sulfate is 58 g / L-70 g / L, and the mass concentration of copper sulfate to the mass concentration of sulfuric acid is 1: 2.5-4. In the method for preparing the functional copper current collector, the electroplating liquid is adopted on the basis of water electroplating treatment related to the functional copper current collector, so that a copper simple substance formed on the surface of a foil material through the water electroplating treatment can reach a finer grain size, the tensile strength and the elongation of the functional copper current collector are both improved, the resistivity is reduced, and the service life of the functional copper current collector is prolonged. Therefore, the surface smoothness of the prepared functional copper current collector is higher, the stability of the functional copper current collector when the functional copper current collector is used as a current collector of a secondary battery is improved, the service life of the secondary battery is prolonged, and the safety performance of the secondary battery is improved.

The application discloses a preparation method and purification process of copper hydroxide, a certain amount of anhydrous copper sulfate is accurately weighed, and a certain volume of deionized water is added to prepare a solution with a certain concentration, a copper ammonia solution is prepared: slurry is prepared from circuit board sludge, screening is performed, ammonium bicarbonate or ammonium carbonate is added for reaction, and a copper ammonia solution containing carbonate or bicarbonate is obtained through purification; in addition, high-purity copper powder is added into concentrated ammonia water, concentrated hydrogen peroxide solution is slowly dropped into the concentrated ammonia water, and the dropping is continued until no large amount of bubbles is generated in the solution, and the solution is filtered to obtain a clear indigo blue solution. The production process adds the step of adding a stabilizer and stirring, guarantees the stable state of the copper hydroxide crystal, and enables the copper hydroxide crystal to remain unchanged into copper oxide for one year in an environment with a temperature as high as 60 degrees.

The present application provides a kind of prevention and control method of green moss in water lily planting pool, specifically belongs to water quality control technical field.The prevention and control method of green moss in water lily planting pool described in the present application includes the following steps: before planting water lily, water injection, water level is controlled at 15~20cm, copper sulfate is applied to kill green moss and its spores, keep water body not to flow during disinfection;After disinfection, apply sodium thiosulfate, and plant water lily;After planting water lily, keep replenishing water, control water level to 40~50cm, when green moss first outbreak, apply mineral fulvic acid potassium and composite bacillus;Subsequent green moss outbreak, apply mineral fulvic acid potassium, or apply mineral fulvic acid potassium and composite bacillus.The prevention and control method described in the present application is safe and efficient, which can quickly and effectively remove green moss without inhibiting the growth of water lily, and also does not affect the harvest of water lily.

The invention discloses an ellagic acid-copper metal organic framework nano material, a preparation method thereof and application of the nano material as an anti-tumor drug carrier. According to the nano material, natural polyphenol ellagic acid is used as an organic ligand, copper ions are used as a metal center, and a three-dimensional supramolecular frame structure is formed through coordination. The preparation method comprises the following steps: mixing an N-methyl pyrrolidone solution of ellagic acid with a methanol solution of copper sulfate, and stirring and reacting at room temperature to efficiently synthesize the copper sulfate. The nano material has excellent antibacterial activity and efficient anti-tumor drug loading capacity, has the intelligent drug release characteristic of dual response of pH and glutathione, and can accurately release drugs in a tumor microenvironment. The nano material provided by the invention can be used as an anti-tumor drug carrier, synchronously realizes anti-tumor and antibacterial dual effects, effectively prevents and treats bacterial infection complications in tumor treatment, and provides a new material for developing a new strategy for tumor synergistic treatment.

The utility model discloses a copper sulfate recovery machine, include: stirring device, including vertical jar, be located in the stirring paddle of vertical jar, drive the motor of stirring paddle agitates, the vertical jar inside holds microetching solution, the stirring paddle is used for stirring the microetching solution in the vertical jar, crystallization device, including annular board, set up in the cooling pipe of annular board inside, the radial outer surface of annular board with the radial inner surface of vertical jar is matched, the cooling pipe is along the circumferential spiral of annular board and extends, scrape out device, including annular scraper, drive the first power part of annular scraper and lift, the inboard of annular scraper with annular board is matched, the inboard of annular scraper holds the stirring paddle, the inboard of annular scraper moves downward to scrape out the crystalline body of annular board inboard. The utility model can solve the problem that the jar wall crystal of traditional equipment is difficult to fall off, and the continuous production efficiency is improved significantly.

The invention discloses a multi-band high-stability ferrite magnetic material composite formula and a preparation process, and relates to the technical field of magnetic materials. The ferrite magnetic material composite formula comprises 38-42 parts of ferric oxide powder, 37-41 parts of ferroferric oxide powder, 6-12 parts of graphene nanosheets, 5-7 parts of hydroxypropyl methyl cellulose, 6-9 parts of lanthanum oxide, 4-6 parts of scandium oxide, 1-3 parts of nano titanium dioxide, 4-6 parts of bismuth magnesium boron, 9-13 parts of ferric sulfate, 3-5 parts of manganese sulfate, 4-6 parts of zinc sulfate, 2-4 parts of copper sulfate and 2-3 parts of samarium sulfate. By utilizing a physical vapor deposition gradient doping process, the problems that an existing ferrite magnetic material is single in electromagnetic performance, cannot stably and efficiently work in a multi-frequency-band complex electromagnetic environment and cannot meet the requirements of the fields of communication, radar, electronic countermeasure and the like for wide-frequency-band and high-performance magnetic materials can be solved.

The application provides a method for promoting mist culture rooting of Pinus squamaeformis, and relates to the technical field of Pinus squamaeformis cutting propagation. The method for promoting mist culture rooting of Pinus squamaeformis comprises the following steps: soaking Pinus squamaeformis cuttings in a citric acid solution in an ice water bath, disinfecting the cuttings, and treating the cuttings with a rooting agent; and then performing mist culture on the cuttings by adding a nutrient agent containing calcium nitrate, potassium nitrate, magnesium sulfate, copper sulfate, indole butyric acid, sodium phytate and lauryl alcohol polyether-4. The method overcomes the shortcomings of the prior art, effectively promotes rapid rooting of Pinus squamaeformis branches, guarantees the growth of root systems, provides a fast and convenient method for stable seedling raising of Pinus squamaeformis, and guarantees artificial breeding of Pinus squamaeformis.

The present invention discloses a method for preparing an electrolyte for microporous copper foil, comprising the following steps: adding copper raw material, sulfuric acid, and deionized water according to a process ratio into a copper dissolving tank for mixing; introducing steam to cause the copper to oxidize and react with the sulfuric acid to form a copper sulfate solution; filtering the copper sulfate solution to obtain a copper sulfate electrolyte; and adding the copper sulfate electrolyte to the electrolyte tank. The present invention prepares the copper sulfate electrolyte and adds the required copper foil additives to the copper sulfate electrolyte to obtain a microporous copper foil with uniform micropore size, uniform micropore distribution, and a bright foil surface. The microporous region has dense and smooth crystals and high tensile strength, making it suitable for use in various fields such as all-solid-state secondary batteries, polymer secondary batteries, and lithium-ion supercapacitors.

The invention discloses a method for electrochemical gradient extraction of gold and copper in electronic waste, which comprises the following steps: taking a mixed solution composed of sulfuric acid and copper sulfate as a first electrolyte, taking the electronic waste as an anode, carrying out a first electrolytic reaction, then taking out the degolded electronic waste, and carrying out solid-liquid separation and drying on an anode chamber solution to obtain the gold and copper in the electronic waste. Gold foil is obtained; and taking a mixed solution consisting of sodium chloride, sulfuric acid, copper sulfate and diethylenetriamine pentaacetic acid as a second electrolyte, adding the degolded electronic waste into the anode chamber, carrying out a second electrolytic reaction, then collecting sediments in the cathode chamber, and passivating, cleaning and drying to obtain the copper foil. According to the method, gold in the electronic waste is directly extracted through an electrochemical method, copper is continuously extracted through a slurry electrolysis method, the process of extracting gold and copper from the electronic waste is shortened, the recovery rate of obtained gold and copper is high, and the purity of copper is high; the used medicament is simple, easy to treat and good in environmental benefit.

The utility model discloses a cathode protection copper sulfate evaporator, which is characterized in that a plurality of anodes are arranged in the copper sulfate evaporator, the anodes are inserted in a copper sulfate solution in the copper sulfate evaporator, and the anodes, a cathode binding post and a reference electrode are all connected with a constant potential controller; the constant potential controller, the anode, the copper sulfate solution in the copper sulfate evaporator and the copper sulfate evaporator body form a current loop, the controller outputs direct current, and the protection potential of the equipment is changed by automatically controlling the magnitude of the output direct current until the potential of the equipment reaches the protection potential ranging from-0.1 V to-0.6 V; a cathode protection anti-corrosion technology is applied to the copper sulfate evaporator, uniform corrosion and pitting corrosion caused by high-temperature dilute sulphuric acid and high-concentration chloride ions of equipment materials in a copper sulfate solution are prevented, the corrosion speed is reduced, and the service life is prolonged.

The invention discloses a method for evaluating the crack self-repairing performance of a cement-based material, and belongs to the field of cement-based materials. Comprising the following steps: (1) preparing a cement-based material test piece, and curing in a curing box; (2) manufacturing a through crack in the maintained test piece by using a splitting method, and placing the through crack in tap water to obtain a repaired test block; and (3) dividing the test block obtained in the step (2) into two halves along the crack, uniformly dropwise adding a copper sulfate solution along the crack surface, standing, and observing the color of each region. The evaluation method further comprises the following steps: acquiring a crack surface image, processing the crack surface image by using a binarization method, and calculating a crack surface repair rate. According to the evaluation method for the crack self-repairing performance of the cement-based material, the effect of qualitatively and quantitatively distinguishing the distribution condition of the hydrogel in the crack area can be achieved.

The present application mainly relates to a kind of preparation of sulfur-rich amino acid protein CMd-copper nanoclusters and its detection mercury ion method, comprising: a) by prokaryotic expression obtains CMd protein, and the protein concentration of 5 mg / mL-25 mg / mL CMd protein solution is obtained by purification.b) CMd is reacted with reducing agent TCEP after opening protein disulfide bond.c) the protein solution after reduction is reacted with anhydrous copper sulfate, and preparation high fluorescence CMd-copper nanocluster.d) CMd-copper nanocluster is applied to detect heavy metal mercury ion.The application method can be synthesized under mild aqueous conditions by "one-step method" structure controllable, stable CMd-copper nanocluster, widens the raw material of copper nanocluster synthesized with protein as template, avoids the use of organic solvent and strong reducing agent, and reduces the cost and environmental burden brought by noble metal raw material, and also has higher selectivity to mercury ion.

The invention discloses a method for preparing a corrosion-resistant composite film by using an acyl fluoride byproduct, and belongs to the technical field of preparation of corrosion-resistant films on surfaces of steel materials. The method comprises the following steps: by taking a perfluoropropylene oxide (HFPO) acyl fluoride byproduct as a raw material, mixing the raw material with a solvent and an acid-binding agent to prepare a film-forming agent; and double-layer self-assembly of a polyacrylic acid layer and an acyl fluoride by-product film layer is carried out on the surface of the steel by combining a polyacrylic acid mixed solution, and the corrosion-resistant composite film is formed on the surface of the steel after high-temperature curing. According to the invention, the high value of the HFPO byproduct is realized, the dripping time of the copper sulfate of the composite film reaches 298-426 s, and the electrochemical corrosion resistance is excellent; and chromizing and phosphating pollution processes are not needed, the process is simple and convenient, the cost is low, and the method is suitable for steel materials and can be popularized to the field of manufacturing of buildings, automobiles and major equipment.