997 results about "Cu2 ions" patented technology

The invention relates to an SSZ-39 molecular sieve and preparation and application thereof.The preparation method comprises the following steps that 1, after water, an alkali source and a template agent are mixed, mesoporous Y zeolite and a silicon source are added, the mixture is stirred to be uniform, and the mixture is aged to be in a white gel shape; (2) transferring the obtained white gel into a reaction kettle, carrying out crystallization treatment, and filtering, washing, drying and calcining a crystallized product to obtain a Na-SSZ-39 molecular sieve; (3) carrying out ammonium ion exchange on the Na-SSZ-39 molecular sieve, filtering, washing, drying and calcining to obtain an H-SSZ-39 molecular sieve; and (4) carrying out copper ion exchange on the H-SSZ-39 molecular sieve, filtering, washing, drying and calcining to obtain the Cu-SSZ-39 catalyst. Aluminum used in the method is provided by mesoporous Y zeolite, the pure-phase SSZ-39 molecular sieve can be synthesized in a wide gel range, the crystallization time is shortened to 24 h, and after copper ion exchange, the pure-phase SSZ-39 molecular sieve shows high denitration activity in the selective catalytic reduction reaction of nitrogen oxide ammonia.

The invention relates to a high-barrier antibacterial polylactic acid packaging material and a preparation method thereof, and belongs to the technical field of biodegradable packaging materials. The technical problems that a traditional polylactic acid material is insufficient in barrier property, poor in antibacterial performance and difficult to meet the packaging requirements of livestock and poultry meat, food and medicine are solved. A graphene oxide lamellar material is subjected to copper ion functionalization treatment and is bridged with tannic acid molecules through copper ions to form a nano filler, and then the filler is blended with a plasticized polylactic acid solution to prepare the membrane. The preparation method comprises the following steps: preparing a copper ion functionalized dispersion liquid from graphene oxide and copper nitrate, self-assembling the copper ion functionalized dispersion liquid and tannic acid under the condition that the pH is 8-10 to generate a nanofiller, uniformly dispersing the nanofiller, mixing the nanofiller with polylactic acid, polyethylene glycol and glycerol according to a specific mass ratio, coating to form a film, and controlling solvent volatilization conditions to obtain the high-performance packaging material. According to the method, the oxygen barrier property and the antibacterial activity of the material are remarkably improved through uniform dispersion of the nanofiller and reinforcement of a coordination network. The obtained material is suitable for packaging foods such as livestock and poultry meat.

The invention relates to the technical field of new material detection, in particular to a copper foil coating content detection method. The method comprises the following steps: preparing a plurality of mixed standard solutions; the mixed standard solution comprises copper ions and at least one to-be-detected element ion; in the plurality of mixed standard solutions, the copper ion concentrations are the same and are first preset concentration values; measuring a plurality of mixed standard solutions, and establishing a standard curve between a theoretical value and a measured value of the ion concentration of each to-be-measured element; dissolving a plating layer on the surface of the to-be-detected copper foil by using nitric acid, and filtering to obtain a to-be-detected sample solution; adding copper salt into the to-be-detected sample solution to obtain a to-be-detected analysis solution; measuring the to-be-measured analysis solution to obtain the measurement concentration of each to-be-measured element ion; according to the measured concentration of each to-be-measured element ion and the corresponding standard curve, the corrected content of each to-be-measured element ion is obtained. The problem that an existing copper foil coating content detection method is low in detection accuracy is solved.

This invention belongs to the field of wastewater treatment technology, specifically relating to a method for removing metallic impurities from acidic copper-containing etching wastewater at room temperature and pressure. The method includes the following steps: S1, adding an oxidant to the acidic copper-containing etching wastewater to conduct an oxidation-reduction reaction, obtaining a pretreatment solution; S2, adding phosphoric acid or soluble phosphate to the pretreatment solution, adjusting the pH to 1.3-1.7 using a pH adjuster, stirring, and filtering to obtain a purified copper-containing solution. The method provided by this invention achieves high removal rates for Fe, Ni, Zn, Ca, and Mg, while maintaining a high copper ion content. It can recycle and regenerate high-purity copper salt products for application in food, cosmetics, medical, electroplating, and other fields, while also reducing hazardous waste generation, improving economic efficiency, and significantly reducing costs.

The invention discloses a copper surface micro-etching coarsening solution for a fine circuit as well as a preparation method and application of the copper surface micro-etching coarsening solution, and relates to the technical field of printed circuit board manufacturing. The copper surface micro-etching coarsening solution for the fine circuit is prepared from, by mass concentration, 60 g / L to 100 g / L of sulfuric acid, 40 g / L to 60 g / L of hydrogen peroxide, 0.5 g / L to 2 g / L of zinc sulfate, 10 g / L to 30 g / L of copper ions, 0.5 g / L to 1 g / L of pyridine heterocycle-containing Schiff base, 10 g / L to 100 g / L of ethyl alcohol, 1 g / L to 3 g / L of 2-mercaptobenzothiazole, 1 g / L to 5 g / L of methionine and 1 g / L to 5 g / L of polyacrylamide. According to the copper surface micro-etching coarsening solution, the 2-mercaptobenzothiazole and the methionine in the copper surface micro-etching coarsening solution can enable the copper surface to form a honeycomb structure under the low micro-etching amount, the zinc sulfate and the pyridine heterocyclic ring-containing Schiff base can form a composite film layer with copper ions on the surface of the honeycomb structure, and the interlayer binding force is improved.

The invention discloses a copper ion complex based on a protein template as well as a preparation method and application of the copper ion complex. The copper ion complex takes a protein template as a carrier, and is obtained by in-situ complexing Cu < 2 + > with a copper ion carrier; the preparation method is a one-step green synthesis technology, mild synthesis conditions not only avoid the use of an organic solvent, but also do not need large-scale instruments and the like, so that the synthesis cost is greatly saved, and the formed copper ion complex has the advantages of high drug effect, small toxic and side effects, lasting effect, good stability and the like, and is suitable for industrial production. The problems that an existing copper ion complex is poor in solubility and low in bioavailability are solved, and the copper ion complex is applied to preparation of anti-tumor and / or antibacterial drugs and has extremely high anti-tumor and antibacterial activity.

The invention belongs to the technical field of water treatment, and particularly provides a nitrogen-oxygen co-doped hypha / spruce composite adsorption material and a copper-containing sewage treatment method. According to the invention, the copper-containing sewage is pretreated by using the solid fermentation product, and then the copper-containing sewage is post-treated by using the nitrogen-oxygen co-doped hypha / spruce composite adsorption material prepared under specific conditions; wherein in the pretreatment stage, microbial metabolites in a solid fermentation product preliminarily capture free copper ions (Cu < 2 + >) through complexation, the toxicity of the sewage is reduced, and meanwhile, the copper ions are partially converted into a form which is easier to adsorb. In the post-treatment stage, the nitrogen-oxygen co-doped hypha / spruce composite adsorption material plays a key role, and efficient interception and adsorption of copper ions are achieved. In conclusion, the treatment method for the copper-containing sewage comprises a pretreatment stage and a post-treatment stage, the two stages are in synergistic interaction, and finally the removal rate of the heavy metal copper can be effectively increased.

The invention relates to a carboxylic acid ligand-copper metal organic framework nano material, a preparation method thereof and an injection. The carboxylic acid ligand-copper metal organic framework nano material is of a polycrystal MOF structure formed by connecting carboxylic acid ligands and copper ions through coordinate bonds; the carboxylic acid ligand comprises at least one of dicarboxylic acid and tricarboxylic acid; preferably, the dicarboxylic acid comprises at least one of itaconic acid and fumaric acid, and the tricarboxylic acid comprises at least one of aconitic acid and citric acid; the valence states of the copper ions comprise zero valence, + 1 valence and + 2 valence; preferably, based on the total amount of the copper ions being 100 at%, the total content of Cu0 and Cu + is 85-90 at%, and the content of Cu2 + is 10-15 at%.

The invention discloses a natural plant-based spinning yarn and a preparation method thereof, and relates to the technical field of spinning yarns. When the natural plant-based spinning yarn is prepared, palm fibers are pretreated with a sodium chlorite solution and a sodium hydroxide solution, and pretreated palm fibers are prepared; reacting the pretreated palm fibers with ammonium dihydrogen phosphate to prepare phosphorylated modified palm fibers; reacting the phosphorylated modified palm fibers with calcium nitrate, diammonium hydrogen phosphate and allylphosphonic acid to grow hydroxyapatite in situ, so as to prepare hydroxyapatite composite palm fibers; 4-allyl thiosemicarbazide reacts with salicylaldehyde to prepare an antibacterial agent intermediate, and the antibacterial agent intermediate is complexed with copper ions to prepare an antibacterial agent; grafting an antibacterial agent and an anti-aging agent on the hydroxyapatite composite palm fibers to prepare modified palm fibers; and spinning the modified palm fiber to obtain the natural plant-based spun yarn. The prepared natural plant-based spinning yarn has the advantages of being high in breaking strength, antibacterial, flame-retardant and anti-aging.

The invention discloses a preparation method and application of pH-responsive double-synergistic-therapy hydrogel. The hydrogel is mainly prepared from oxidized fucoidin (OFU), carboxymethyl chitosan (CMCs), zinc peroxide / copper nanoparticles (ZnO < 2-Cu >) and arginine (L-ARG). Under a gastric acid condition, the hydrogel generates H2O2 through zinc peroxide, copper ions catalyze H2O2 through a Fenton-like reaction to generate OH <->, arginine can catalyze H2O2 to generate NO, and the copper ions and the arginine act together to destroy a helicobacter pylori biological membrane and kill bacteria. The hydrogel has good injectability, self-healing property and adhesivity, is beneficial to intragastric injection application and can be adhered to the stomach, and the administration concentration of an infected part is improved; the antibacterial effect is generated only under the gastric acid condition, the helicobacter pylori biological membrane can be destroyed, and the helicobacter pylori antibacterial agent can be applied to the helicobacter pylori which is difficult to eradicate in the stomach of the human body.

The invention discloses a preparation process of a high-strength anti-crack and anti-seepage vertical shaft lining concrete material, which comprises the following steps: (1) uniformly mixing aggregate with a solution containing copper ions, drying to remove moisture, dropwise adding saturated lime water containing alkaline substances into the mixture, and drying to remove moisture to obtain pretreated aggregate; and (2) the pretreated aggregate is placed in a carbon monoxide atmosphere for reduction treatment, the reduction temperature is higher than the melting point of copper, and the surface modified aggregate is obtained after reduction treatment is completed. The surface modified coarse aggregate and the surface modified fine aggregate are respectively prepared according to the method. And (3) uniformly mixing the cement binding material, the surface modified coarse aggregate, the surface modified fine aggregate, the modified fiber, the solid waste-based powder filler, emulsified asphalt and a water reducing agent, adding mixing water, and uniformly mixing to obtain the concrete material. The concrete material disclosed by the invention has good mechanical strength and crack resistance and also has good water seepage resistance, and the service life of the pumped storage power station vertical shaft is effectively prolonged.

The invention provides a simulated aging test method for an antifouling coating. The simulated aging test method comprises the following steps: S1, constructing a natural aging performance model of the antifouling coating; s2, constructing an accelerated aging model of the antifouling coating and acquiring an acceleration ratio N of natural aging to accelerated aging; s3, based on an accelerated aging model, acquiring an acceleration period Mi corresponding to a critical threshold R (temporary i) of a copper ion exudation rate, wherein the predicted life Lp (temporary i) of the antifouling coating is equal to Mi * N; and S4, based on a natural aging model, obtaining a predicted copper ion exudation rate R < pre-i > corresponding to the predicted life Lp < pre->, judging whether R < pre-i >-R < critical i > / R < critical i > is less than or equal to 10%, if so, outputting a near threshold R < critical i > and the predicted life Lp < pre-i >, and if not, adjusting the critical threshold of the copper ion exudation rate to R < critical i + 1 > and returning to the step S3. According to the method, the performance failure threshold value of the antifouling coating is taken as a boundary condition, the performance of the antifouling coating is rapidly evaluated, the service life of the antifouling coating is quantitatively predicted, the prediction result is subjected to cooperative cross validation through linkage double models, and the reliability is improved.

The invention relates to the field of biomedicine, particularly provides a copper-based nano-enzyme as well as a preparation method and application thereof, and aims to solve the problems that in the prior art, clinical treatment on primary sclerosing cholangitis (PSC) is difficult in diagnosis and lacks of effective treatment drugs. The copper-based nano-enzyme comprises a nano-enzyme carrier and a copper-based nano-enzyme, wherein the nano-enzyme carrier is a two-dimensional nanosheet formed by copper ions, gallic acid and ursodesoxycholic acid through coordinate bonds; the probe molecule is a cyanine dye molecule connected to the surface of the nano-enzyme carrier through a covalent bond; wherein the fluorescence intensity of the copper-based nano enzyme is enhanced after the action of the alkaline phosphatase. The three functions of alkaline phosphatase responsive diagnosis, nano-enzyme catalytic treatment and ursodesoxycholic acid hepatic targeting are innovatively and synergistically integrated into one nano platform, the treatment function can be executed while specific imaging diagnosis is performed on diseases, and a new strategy is provided for diagnosis and treatment of diseases such as PSC.

The invention relates to the technical field of ceramics, in particular to mottle crack glazed ceramic and a preparation method thereof.The ceramic comprises a green body, ground glaze and cover glaze, and the ground glaze is prepared from, by weight, 30-35 parts of kaolin, 25-30 parts of quartz, 20-25 parts of feldspar, 8-12 parts of ferric oxide, 5-8 parts of calcium carbonate and 3-5 parts of borax; the cover glaze is prepared from the following raw materials in parts by weight: 35 to 40 parts of feldspar, 25 to 30 parts of quartz, 6 to 10 parts of copper oxide, 5 to 8 parts of granular rock powder, 8 to 12 parts of borax and 5 to 8 parts of clay. Embedding porous particles into the green body to initiate explosion cracks, and fusing interlayer stress cracks and devitrification cracks to form a multi-stage composite crack network; iron ions in the ground glaze and copper ions in the cover glaze form ion gradient migration through the iron axe stone powder in the middle layer to generate red and green blended stripes; the microcapsule carbon powder regulates and controls the pores and texture of the glaze, and copper foil fragments are oxidized and reduced to form gilding-brown mottles.

The invention belongs to the field of nano-medicine and traditional Chinese medicine, and particularly discloses an antioxidant nano-material based on self-assembly of traditional Chinese medicine and copper ions and a preparation method thereof.The nano-material is prepared from BPCu nano-particles formed by self-assembly of berberine and procyanidine B2 under induction of the copper ions, the BPCu nano-particles are further subjected to surface modification through polyvinylpyrrolidone, and the antioxidant nano-material is prepared. And the stably dispersed PVP-coated BPCu nano structure is obtained. The material is small in particle size, uniform in distribution, good in water solubility and storage stability, excellent in free radical scavenging capacity and catalase-like activity and suitable for adjuvant therapy of oxidative stress related diseases, and the preparation method is easy and convenient to operate, does not need an organic solvent and has good industrialization and disease treatment potential.

The invention belongs to the technical field of wastewater treatment, and particularly relates to a method for removing metal impurities from acidic copper-containing etching wastewater at normal temperature and pressure. The method for removing the metal impurities from the acidic copper-containing etching wastewater at normal temperature and pressure comprises the following steps: S1, adding an oxidizing agent into the acidic copper-containing etching wastewater to carry out oxidation-reduction reaction to obtain a pretreatment solution; and S2, phosphoric acid or soluble phosphate is added into the pretreatment solution, the pH is adjusted to 1.3-1.7 through a pH adjusting agent, stirring and filtering are conducted, and the purified copper-containing solution is obtained. According to the method, the removal rate of Fe, Ni, Zn, Ca and Mg is high, high-content copper ions can be kept, a high-purity copper salt product can be recycled and regenerated to be applied to the fields of food, cosmetics, medical treatment, electroplating and the like, hazardous waste can be reduced, economic benefits are improved, and cost is greatly reduced.

The invention discloses an EGCG-Cu complex, an EGCG-Cu-Cs nanoparticle, a preparation method of the EGCG-Cu complex, and an application of the EGCG-Cu-Cs nanoparticle. The preparation method comprises the following steps: mixing an aqueous solution of EGCG and an aqueous solution containing copper ions, adjusting the pH value, stirring for reaction, dialyzing or centrifuging, and freeze-drying to obtain the EGCG-Cu complex; the EGCG-Cu complex is dissolved in water, a chitosan solution is added, stirring reaction, centrifugal washing and freeze drying are carried out, and the EGCG-Cu-Cs nanoparticles are obtained. The EGCG-Cu complex and the EGCG-Cu-Cs nanoparticles prepared by the invention are uniform in size and good in dispersity, and have excellent xanthine oxidase inhibition effect and free radical scavenging effect.

The invention belongs to the field of analytical chemistry, relates to material preparation, and particularly discloses a preparation method of a copper-doped covalent organic framework and application of the copper-doped covalent organic framework in adrenaline colorimetric detection. Firstly, 1H-indazole-4, 7-diamine (Iz) and 1, 3, 5-triformyl phloroglucinol (Tp) are used as monomers to synthesize a novel covalent organic framework (Iz-Tp COF) through a Schiff base reaction, copper ions are introduced into the Iz-Tp COF framework to prepare a novel metal covalent organic framework (Iz-Tp (at) Cu), and then according to the phenomenon that the Iz-Tp (at) Cu can catalyze oxidation color development of epinephrine, the metal covalent organic framework (Iz-Tp (at) Cu can catalyze oxidation color development of epinephrine. According to the present invention, the simple, sensitive and efficient adrenaline colorimetric detection method is established, the test conditions are finally optimized, the standard addition method is combined to accurately determine the adrenaline concentration in the urine, and the good practical application value is provided.

A desulfurizing agent according to the present disclosure is a desulfurizing agent for removing a sulfur compound from a fluid containing moisture and the sulfur compound, the desulfurizing agent comprising: at least one metal ion selected from the group consisting of aluminum ions, iron ions, and copper ions; and an organic ligand coordinated to a metal ion, the organic ligand containing isophthalic acid optionally having a substituent group at the 5-position of a benzene ring, and diffraction peaks respectively present in the range of diffraction angles of 10.9 DEG + / -0.3 DEG and the range of diffraction angles of 18.1 DEG + / -0.3 DEG in an X-ray diffraction pattern of the desulfurizing agent measured using Cu-K alpha rays.

The invention discloses a NiCu-based alloy catalyst for preparing high-value products through natural gas decarbonization and application of the NiCu-based alloy catalyst, and belongs to the technical field of natural gas high-value catalytic conversion. The preparation method of the NiCu-based alloy catalyst comprises the following steps: (1) adding nickel nitrate hexahydrate and urea into hot water, adding ethylene glycol, carrying out a stirring reaction at 120-150 DEG C, and calcining the obtained intermediate to obtain a nickel oxide precursor; (2) adding a copper nitrate aqueous solution and ammonia water into the nickel oxide precursor, so that copper ions are anchored on the surface of nickel oxide, drying and calcining to obtain a Ni-Cu alloy oxide precursor; and (3) adding the Ni-Cu alloy oxide precursor, bismuth trioxide and metallic tin into deionized water, adding a complexing agent, carrying out ultrasonic treatment, and carrying out H2 reduction calcination on the obtained precipitate to obtain the Ni < x > Cu < y > Bi < z > Snm alloy. The NiCu-based alloy catalyst is used in a natural gas decarburization high-value product preparation reaction, and the natural gas decarburization reaction is sufficient, and long-term efficient conversion and stable operation are achieved by combining the synergistic effect of ultrasonic waves and an alternating magnetic field.

According to the technical scheme, the copper-doped lasting antibacterial fresh-keeping material comprises a base body, an antibacterial nanofiber and copper ion loaded antibacterial hydrogel layer and a surface coating, the antibacterial nanofiber and copper ion loaded antibacterial hydrogel layer comprises antibacterial nanofibers and copper ion loaded antibacterial hydrogel, and the surface coating is coated with the antibacterial nanofibers and the copper ion loaded antibacterial hydrogel. The surface coating comprises microcapsules for contactable food products; the preparation method comprises the following steps: preparation of the copper-tannic acid coordination compound, preparation of the antibacterial nanofiber layer, preparation of the copper ion loaded antibacterial hydrogel, preparation of the substrate, interlayer compounding process, preparation of the sustained-release microcapsule coating, crosslinking and post-treatment. The humidity-responsive on-demand release of copper ions of the fresh-keeping material is realized, the antibacterial and fresh-keeping effects are good, the safety is high, and the environment-friendly effect is realized.

The invention relates to the technical field of coatings, and discloses a preparation process of a waterproof coating for roads and bridges, which comprises the following steps: reacting polyester polyol, an isocyanate monomer, 4-N, N-bis (2-hydroxyethyl) aminopyridine-2-formic acid and the like, and then adding water, nano cellulose, copper salt, a neutralizer, pigment and the like to obtain the waterproof coating for roads and bridges. According to the invention, copper ions are respectively coordinated with pyridine-2-formic acid of polyurethane and hydroxyl of nano-cellulose to play a role of a cross-linking agent, and the polyurethane and the nano-cellulose are subjected to ionic cross-linking, so that the interface bonding performance of the polyurethane and the nano-cellulose is improved, and the nano-cellulose has a better reinforcing effect; a paint film of the paint has higher pencil hardness, impact resistance and mechanical properties. Meanwhile, the waterproof and anti-corrosion performance is good, and good practical application is achieved in the fields of roads, bridges and the like.

The invention relates to the technical field of electro-catalysis, in particular to a Cu-In2O3 nanoparticle catalyst as well as a preparation method and application thereof. The method comprises the following steps: dissolving a soluble copper salt and a soluble indium salt in water together, mixing with an alkali solution, carrying out a precipitation reaction, and combining copper ions and indium ions with OH <-> ions in alkali in the precipitation reaction process to generate copper hydroxide and indium hydroxide so as to obtain a precipitate; freeze-drying the precipitate to obtain a precursor; and calcining the precursor in a mixed atmosphere of hydrogen and inert gas to obtain the Cu-In2O3 nanoparticle catalyst. The Cu-In2O3 nanoparticle catalyst disclosed by the invention not only has excellent catalytic activity and high selectivity to formic acid, but also has good stability and reusability. When the Cu-In2O3 nano-particle catalyst is applied to the electrocatalytic carbon dioxide reduction reaction, the energy consumption can be effectively reduced, and the production efficiency and the product quality of formic acid can be improved.

The invention discloses a preparation method and application of a metal covalent organic framework material, and the prepared metal covalent organic framework material can be used for adsorption separation of elemental iodine pollutants and shows excellent iodine adsorption capacity and rate. According to the preparation method, 1H-pyrazole-4-formaldehyde and copper nitrate trihydrate are subjected to a solvothermal reaction to prepare a copper ion ring trinuclear metal complex with an aldehyde group, and the copper ion ring trinuclear metal complex and 1, 3, 5-tri (4-aminophenyl) benzene are further subjected to a Schiff base reaction to prepare the metal covalent organic framework material containing copper ions. According to the metal covalent organic framework material disclosed by the invention, copper ion active adsorption sites in a chemical structure are also retained while a developed microporous structure is maintained, and the interaction strength of pore channels to iodine is remarkably enhanced, so that the iodine adsorption rate and capacity are remarkably improved. The preparation method is simple, convenient, universal and high in controllability, and large-scale production and manufacturing of the metal covalent organic framework adsorption material can be achieved.

The invention relates to a method for recovering tellurium from copper anode slime through cooperation of ultrasound and hydrogen peroxide, and belongs to the field of wet metallurgy of scattered metal. The method comprises the following steps: drying and grinding copper anode slime to obtain copper anode slime powder; the method comprises the following steps: adding copper anode slime powder into a sulfuric acid solution, mixing to obtain copper anode slime slurry, adding hydrogen peroxide into the copper anode slime slurry, carrying out ultrasonic enhanced leaching for 20-160min, and carrying out solid-liquid separation to obtain a leaching solution containing copper and tellurium and high-grade valuable metal leaching residues. According to the method, hydrogen peroxide is effectively promoted to be decomposed by ultrasound to generate hydroxyl radicals, the oxidation potential of a system is regulated and controlled, copper and tellurium are selectively converted into copper ions, tellurate radicals enter a solution, and valuable elements such as gold, silver and selenium are enriched in slag; necessary heat is provided for the reaction by utilizing the heat effect of ultrasonic and heat released by chemical reaction, and extra heating is not needed; strong jet flow generated by ultrasound effectively destroys raw material inclusion and secondary wrapping, reaction mass transfer is enhanced, and the leaching rate of tellurium is increased. The method disclosed by the invention is simple in leaching process operation, low in cost and high in reaction speed.

The invention discloses a synthesis process of chiral cyclic ether indole. The synthesis process comprises the following steps: reacting 4-bromobenzaldehyde with malonic acid under the catalysis of piperidine to generate olefin carboxylic acid CHP-1; carrying out condensation reaction to prepare CHP-2; under the catalysis of a copper reagent, carrying out Michael addition reaction to obtain CHP-3; preparing a chiral alcohol intermediate CHP-4 through a reduction reaction; trifluoromethanesulfonic acid is used, and a chiral ether intermediate CHP-5 is prepared through ring closing; reacting with protected hydrazine by using a copper ion catalyst to obtain an intermediate CHP-6; the method comprises the following steps: by taking alcohol as a solvent, adding strong acid, and removing a protecting group of hydrazine to obtain an intermediate CHP-7; and carrying out ring closing by taking lewis acid as a catalyst to obtain an indole product CHP-8. The use of a noble metal catalyst palladium is avoided, and the cost is greatly reduced. The chiral center is directly constructed through a chemical method, and SFC is not needed for resolution, so that the cost is remarkably reduced, and industrial production is successfully realized.

The near-infrared absorbing glass contains at least, as constituent ions, P ions; Cu ions; O ions; one or more ions selected from the group consisting of Li ions, Na ions and K ions; and one or more ions selected from the group consisting of Mg ions, Ca ions, Sr ions and Ba ions, wherein, in a glass composition expressed in cation %, the content of Cu ions is 15.0 cation % or lower; the content of P ions is 55.0 cation % or lower; and a cation ratio of the total content of Al ions and P ions relative to the total content of Mg ions, Ca ions, Sr ions, Ba ions, Zn ions and Cu ions ((Al ions+P ions) / (Mg ions+Ca ions+Sr ions+Ba ions+Zn ions+Cu ions)) is 5.300 or lower.

The invention belongs to the technical field of fuel cells, and discloses a metal organic framework material with proton conductivity and a preparation method and application thereof. Pyrazolo [3, 4-c] pyridine is used as a ligand, a binuclear cuprous cluster is used as a connection point, a two-dimensional layered structure is constructed through the ligand and the binuclear cuprous cluster, a cuprous multi-nitrogen heterocyclic metal organic framework is formed, the cuprous multi-nitrogen heterocyclic metal organic framework is oxidized, and the cuprous multi-nitrogen heterocyclic metal organic framework is obtained. Divalent copper ions and monovalent copper ions exist in the oxidized cuprous multi-nitrogen heterocyclic metal organic framework, and the metal organic framework material with proton conductivity is obtained. The proton conductivity of the metal organic framework material can be remarkably improved by adopting a metal post-synthesis modification oxidation technology, and the proton conductivity of the metal organic framework material is comparable with that of commercial Nafion, and an oxidized sample shows extremely high chemical stability; the problem of poor stability of a non-fluorinated hydrocarbon polymer proton exchange membrane and inorganic solid acid researched in the prior art is solved.

The invention provides the preparation method of the efficient photocatalyst which is simple and convenient, does not contain noble metals or toxic metals and does not need a cocatalyst. In the invention, a strategy for synergistically improving the catalytic performance by regulating and controlling sulfur vacancies and doping copper ions is provided, zinc indium sulfide (ZIS) is selected as a substrate material, the content of sulfur atoms is increased in the synthesis process through a solvothermal method to introduce the vacancies, and Cu (NO) is synchronously added to introduce Cu, so that the catalytic performance is improved. The Cin-VZIS catalyst is successfully prepared (n is a doping proportion relative to Zn). A TEOA aqueous solution is used as a sacrificial agent to carry out photocatalytic hydrogen production reaction, the synergistic effect of the two modification modes can significantly improve the performance of the catalyst, and when the copper doping ratio is 1.5%, the catalytic activity reaches the highest and is 1.799 mmol.g.h, which is 7.5 times of that of an original ZIS catalyst. The prepared catalyst is high in activity and good in stability, and a new way is provided for developing efficient and stable solar hydrogen production materials.

The invention discloses a method for preparing nano copper powder based on a microwave-assisted reduction method and application. The method comprises the following steps: a) preparing a copper ion solution; b) adding a dispersing agent and a surfactant; c) adding a reducing agent; d) microwave heating reaction; e) separating and purifying a product; and f) drying. According to the method, directional reduction and morphology regulation and control of copper ions are achieved through the synergistic effect of a microwave field and chemical reduction, the specific surface area of the obtained product reaches 25-35 m < 2 > / g, the oxygen content is lower than 0.8 wt%, and excellent performance is shown in the fields of electronic packaging and conductive ink; the method has the characteristics of short reaction time (shortened by 90% compared with the traditional method), low energy consumption (less than 0.5 kWh / kg), no harmful by-product and the like, and meets the requirements of green chemical industrial production.