The invention discloses plant composite engine oil containing graphene, which includes the following raw materials: castor oil, liquid graphene, modified castor oil, an antioxidant, an anti-corrosion agent, an anti-foam agent, an extreme pressure anti-wear agent, a pour point depressant, an anti-rust agent, a viscosity index improver, a dispersing agent, a cleaning agent, a lubrication modifier, an organic anti-aging agent, and modified nano cerium vanadate. By adding the liquid graphene to the plant composite engine oil, lubricating property of the engine oil is improved, wherein the mechanism of lubrication of the graphene is not same as that of an additive in the prior art. Because the molecular particle size of the graphene is very small, the graphene can generate a roll-ball effect during friction between a cylinder wall and a piston, thereby turning sliding friction into rolling friction, and also can flattening the uneven parts on the cylinder wall just like putty. The graphene, as an anti-wear agent, can promote low-viscosity engine oil better, and enables automobiles to be more energy-saving and environment-friendly.