The invention relates to an ultralow-loss single-mode
optical fiber and a preparation method thereof, the
optical fiber comprises a core layer and cladding
layers, the core layer is divided into two
layers, the
radius R1 of the first core layer is 1-2 [mu] m, the
delta n1 is-0.12--0.07%, the
radius R2 of the second core layer is 4-6 [mu] m, the
delta n2 is 0-0.05%, the inner cladding layer comprises a first inner cladding layer and a second inner cladding layer, the
radius R3 of the first inner cladding layer is 8-12 [mu] m, the
delta n3 is-0.28--0.23%, and the second inner cladding layer comprises a third inner cladding layer and a fourth inner cladding layer. The radius R4 of the first inner cladding layer is 20-40 [mu] m, the radius R4 of the second inner cladding layer is 20-40 [mu] m, the delta n4 is-0.36--0.25%, the delta n3-delta n4 is greater than or equal to 0, the delta n5 of the outer cladding layer is-0.25--0.15%, alkali metals are doped in the core
layers, the average content of the alkali metals in the first core layer is 500-600 ppm, and the average content of the alkali metals in the second core layer is 600-900 ppm. The defect that the concentration of
alkali metal is reduced along with the increase of the radius of the
fiber core due to the conventional thermal
diffusion doping technology is overcome, the
viscosity of the core layer is reduced as much as possible, and the
transmission loss of the
optical fiber is further reduced.