95 results about "YTTERBIUM OXIDE" patented technology

The invention discloses high-wear-resistance ceramic, glaze water and a method for preparing a ceramic product, and belongs to the technical field of ceramic. The high-wear-resistance ceramic comprises a ceramic body and a ceramic glaze layer, the ceramic body comprises the following components: calcined kaolin, quartz, potassium feldspar, albite, carbon fiber powder, cerium oxide and ytterbium oxide, and the ceramic glaze layer is obtained by coating the surface of the ceramic body with ceramic glaze water and then firing. The ceramic glaze water comprises the following components: calcined kaolin, quartz, potassium feldspar, sodium carboxymethyl cellulose, carbon fiber powder, nano molybdenum disilicide, polyvinyl alcohol fiber, fly ash, corundum, sepiolite and cerium oxide. The high-wear-resistance ceramic product prepared by the invention has excellent glaze strength, and the glaze is finer and more glossy.

An improved ceramic material for heat insulation with selection of specific stabilizers and adapted proportions, includes zirconium oxide with 0.2 wt. % to 8.0 wt. % of the base stabilizers: yttrium oxide (Y2O3), hafnium oxide (HfO2), cerium oxide (CeO2), calcium oxide (CaO), and / or magnesium oxide (MgO), wherein at least yttrium oxide (Y2O3) is used, and optionally at least one of the additional stabilizers: 0.2 wt. % to 20 wt. % of erbium oxide (Er2O3) and / or ytterbium oxide (Yb2O3).

To provide an electrolyte particle for use in the manufacture of a solid oxide electrochemical cell, which is a solid electrolyte sintered body constituting a solid oxide electrochemical cell and which can be efficiently manufactured by sintering a densified sintered body having a high relative density at, for example, 1200°C or lower, and a dispersion liquid containing the electrolyte particle.SOLUTION: The present invention relates to an electrolyte particle containing at least one selected from (A) stabilized zirconia consisting of 3.0 to 10.0 mol% scandium oxide, 0 to 2.0 mol% cerium oxide, and 88.0 to 97.0 mol% zirconium oxide, (B) stabilized zirconia consisting of 0.5 to 15.0 mol% yttrium oxide and 85.0 to 99.5 mol% zirconium oxide, and (C) stabilized zirconia consisting of 0.5 to 15.0 mol% ytterbium oxide and 85.0 to 99.5 mol% zirconium oxide, and having a volume average particle diameter of 50 to 150 nm measured using a laser diffraction method.SELECTED DRAWING: Figure 1

The invention discloses a near-net-shape preparation process of high-light-transmittance large-size magnesium aluminate spinel ceramic, and belongs to the technical field of preparation of high-performance transparent ceramic. The process comprises the following steps: firstly, mixing magnesium aluminate spinel raw material powder with a lithium-free composite sintering aid according to a mass ratio, wherein the composite sintering aid consists of magnesium fluoride, ytterbium fluoride and ytterbium oxide according to a molar ratio; performing cold isostatic pressing on the mixed powder to prepare a preformed blank, crushing, and performing high-low pressure circulation pressurization near-net forming. The obtained green body is firstly subjected to hot pressing and presintering, then placed in a fluorine-containing atmosphere to be treated and finally subjected to hot isostatic pressing sintering, and a finished product is obtained through aftertreatment. According to the technology, the bottleneck of large-size component preparation is successfully overcome, net forming of the magnesium aluminate spinel ceramic with the diagonal size larger than 400 mm is achieved, the light transmittance of a finished product in the wavelength range of 400 nm to 800 nm exceeds 93%, the breaking strength reaches 194 MPa or above, and meanwhile the raw material cost and equipment dependence are remarkably reduced.

The invention discloses a transparent heat-insulating coating based on up-conversion luminescent nanoparticles as well as a preparation method and application thereof, and belongs to the technical field of inorganic polymer materials. The coating comprises the following raw materials in parts by weight: 100-150 parts of a substrate coating, 5-10 parts of a dispersing aid and 0.5-3 parts of up-conversion luminescent nanoparticles. Traditional inorganic nanoparticles are changed, zinc oxide (ZnO), tin oxide (SnO), gallium oxide (Ga2O3), ytterbium oxide (Yb3O4) and erbium oxide (Er2O3) are used for forming functional components, and the functional components are matched with one another, so that the light-transmitting and heat-insulating coating with low nanoparticle addition amount is constructed. By adding a small amount of up-conversion nanoparticles into the coating, the application range of the up-conversion material is expanded, the blank of application of the material in research in the field of building coatings is filled, the performance of a traditional transparent heat-insulating coating is improved through the up-conversion luminescent material, and the light-transmitting heat-insulating performance of a paint film is greatly improved.

The invention provides a terephthalic acid hydrogenation catalyst and a preparation method and application thereof, and belongs to the technical field of catalysts.The preparation method includes the steps that S1, after nanometer ytterbium oxide, potassium hydrogen oxalate, acridone acetic acid and polyarylene ether nitrile are mixed, heat treatment, cooling, ultrasonic treatment, washing and drying are conducted, and a catalyst carrier of a porous structure is obtained; s2, adding 4-(tert-butyldimethylsiloxy) phenylboronic acid into ethanol, stirring, adding the pretreated nickel-copper-iron-magnesium powder, homogenizing, heating, stirring, cooling, centrifuging, washing and drying to obtain catalyst powder; s3, adding the suspension of the catalyst powder into the suspension of the catalyst carrier, heating, stirring, cooling, centrifuging, washing and carrying out heat treatment to obtain the terephthalic acid hydrogenation catalyst. The catalyst provided by the invention not only can realize an excellent hydrogenation catalysis effect, but also has certain cost benefits.

The invention relates to the technical field of glass, in particular to a preparation process of 3D curved glass. The process comprises the following steps: S1, mixing diboron trioxide, ammonium dihydrogen phosphate, lithium oxide, calcium carbonate, cerium oxide, samarium oxide and ytterbium oxide, grinding, sieving, uniformly mixing, and heating to obtain a liquid phase substance; s2, clarifying the liquid-phase substance, introducing the clarified liquid-phase substance into a mold cavity, and carrying out hot bending forming to obtain a crude blank; and S3, annealing the rough blank, and carrying out fine trimming to obtain the 3D curved glass. The curved glass provided by the invention is excellent in mechanical property, high in impact resistance, uniform in display and free of deformation and distortion.

The invention discloses a rare earth doped upconversion single near-infrared luminescent scandium molybdate material and a preparation method thereof, and belongs to the technical field of luminescent materials. The structural formula of the up-conversion near-infrared luminescent material provided by the invention is (Sc < 1-x-y > Yb < x > Er < y >) < 2 > Mo < 3 > O < 12 >, x is equal to 0.1 to 0.3, and y is equal to 0.005 to 0.04. The preparation method is a high-temperature solid-phase method and comprises the following steps: weighing scandium oxide, ytterbium oxide, erbium oxide and molybdenum oxide as raw materials according to stoichiometry, uniformly mixing with absolute ethyl alcohol, drying, sufficiently grinding, pressing into sheets, presintering at 800 DEG C in a muffle furnace, heating to 1100 DEG C, and carrying out high-temperature solid-phase sintering. The prepared rare earth doped scandium molybdate up-conversion luminescent material has excellent near-infrared luminescence performance, and the regulation and control of the luminescence intensity can be realized by adjusting the rare earth doping proportion. Meanwhile, the preparation method is good in repeatability, high in yield, simple and feasible in preparation process, more energy-saving and environment-friendly in preparation process and suitable for industrial popularization.

This invention discloses a composite rare earth oxide co-stabilized zirconia ceramic microsphere and its preparation method, belonging to the technical field of zirconia ceramic microspheres. The zirconia ceramic microspheres are prepared from 80-90 parts by mass of tetragonal zirconia (ZrO2) powder, 0.5-1 parts by mass of alumina (Al2O3) powder, 5-10 parts by mass of yttrium oxide (Y2O3) powder, and 5-10 parts by mass of composite rare earth oxide powder. This invention uses tetragonal zirconia as the base material, adds yttrium oxide (Y2O3) as a stabilizer, and further adds composite rare earth oxides ytterbium oxide (Yb2O3) and nano-gadolinium oxide (Gd2O3). Yb2O3 serves as the second stabilizer, while Gd2O3 enhances the ferroelastic toughening effect of the ceramic. The combined effect of the two rare earth oxides increases the strength of the zirconia ceramic microspheres.

The invention relates to a preparation method of ytterbium oxide with specific granularity and specific surface area, and belongs to the technical field of rare earth oxide preparation. The preparation method comprises the following steps: preparing oxalic acid into an oxalic acid solution with the mass fraction of 5-15wt%; preparing ytterbium chloride into an ytterbium chloride solution with the concentration of 0.2-1.0 mol / L; a polyvinyl alcohol dispersing agent solution with the mass fraction of 0.8-1.5 wt% is added into the ytterbium chloride solution, the adding amount of the polyvinyl alcohol dispersing agent solution is 2-4% of the mass of the ytterbium chloride solution, and ytterbium chloride mixed liquid is obtained; warm water is added into a reaction kettle, the ytterbium chloride mixed solution is continuously added along with stirring operation, and then the oxalic acid solution is continuously added; and directly carrying out vacuum filtration without aging, collecting a filter cake, and calcining to obtain a finished product. By optimizing the using amount of the dispersing agent and the precipitation process and accurately controlling process parameters, the obtained product is stable in performance, uniform in particle size distribution, small in specific surface area deviation and good in reproducibility.

The invention discloses a series of high-stability negative temperature coefficient heat-sensitive materials based on seven-principal-element high-entropy rare earth stannate and application, and aims to solve the problem that existing stannate heat-sensitive materials with pyrochlore structures cannot meet long-term application in high-temperature environments. The series of heat-sensitive materials are prepared by mixing lanthanum trioxide, neodymium oxide, samarium oxide, europium oxide, gadolinium oxide, dysprosium oxide and tin dioxide with erbium oxide or ytterbium oxide respectively, and the preparation process comprises the steps of wet three-dimensional vibration ball milling, powder calcination, cold isostatic pressing, high-temperature sintering and the like. And finally obtaining the negative temperature coefficient heat-sensitive material with the pyrochlore structure. The electrical property parameters of the series of materials are as follows: B is equal to 13914-14067 + / -1.89% K, and rho 1500 DEG C is equal to 180.26-204.09 + / -1.38% omega.cm. The negative temperature coefficient heat-sensitive material has the negative temperature coefficient characteristic in the wide temperature range of 400-1500 DEG C and shows excellent high-temperature aging stability under the high-temperature condition of 1500 DEG C, and the resistance drift rate of the negative temperature coefficient heat-sensitive material is only 0.7% after an aging test for 500 hours.

The application discloses a kind of heterostructure supported catalyst and its preparation method and application, belong to catalytic technical field.The heterostructure supported catalyst provided by the application includes Yb oxide base and metal nanoparticles;The metal nanoparticles are loaded in the Yb oxide base;The metal nanoparticles include ruthenium and doped metal;The doped metal includes at least one of cobalt, iron or manganese.The application loads the metal nanoparticles of ruthenium and doped metal in Yb oxide base, constructs metal / oxide heterostructure, induces strong metal-support electron interaction, this interaction can effectively adjust the local electronic structure of active site, realizes the promotion of catalytic performance, so that the catalyst has the advantages of strong binding force, chemical interface stability, higher catalytic activity and stability, etc., can be prepared for good performance used in electrolytic water hydrogen evolution reaction cathode.

This invention discloses a ytterbium-doped fiber preform, a ytterbium-doped active fiber, and their preparation method. First, a quartz deposition tube with a porous core layer deposited on its inner surface is prepared using the MCVD process. After heating and breaking off one end of the tube, a solution containing ytterbium rare earth salt and a co-doperant is injected into the quartz deposition tube. After thorough soaking and drying / shrinking, a rare earth-doped core rod is obtained. During the liner shrinking stage, vapor containing ytterbium compounds is introduced into the tube to reduce the loss of ytterbium oxide due to diffusion and volatilization during the liner shrinking stage, thereby obtaining a uniformly doped ytterbium-doped fiber preform. The preform prepared by this invention has a uniform ytterbium ion concentration distribution in the core layer, and the ytterbium-doped fiber obtained by drawing exhibits high laser slope efficiency.

A wafer support body 10 is provided with: a substrate 16 that comprises a ceramic sintered compact; and a conducting member 18 that encapsulates at least part of the substrate. The substrate 16 contains at least 96% by mass of aluminum oxide, contains 0.47–1.83% by mass of zirconium as the zirconium oxide equivalent, and contains 0–0.48% by mass of yttrium or ytterbium as the yttrium oxide or ytterbium oxide equivalent.

The present invention discloses a nanometer dual-phase high-entropy zirconate material with nearly equal proportions, and a preparation method and application thereof, belonging to the technical field of thermal barrier coating materials. The present invention obtains five single rare earth metal salt solutions by dissolving lanthanum oxide, neodymium oxide, gadolinium oxide, dysprosium oxide and ytterbium oxide in acid solution respectively; the five single rare earth metal salt solutions are sequentially added to the zirconium salt solution in the order of ion radius from large to small to form a mixed solution with a uniform and stable tetramer structure, and then a precipitant is added to carry out precipitation reaction to obtain a gel-like precursor precipitate; the gel-like precursor precipitate is subjected to aging, ball milling and high-temperature calcination to obtain a high-entropy zirconate material. The zirconate material of the present invention exhibits extremely low thermal conductivity, extremely high thermal expansion coefficient, good mechanical properties and high-temperature stability through the synergistic effect of alloy components and nearly equal dual phases.

The application relates to a low-temperature calcined ytterbium oxide powder and a preparation method thereof, and belongs to the technical field of metal powder processing. The preparation method comprises the following steps: reacting ytterbium carbonate with malonic acid in an aqueous solution to generate a ytterbium malonate precursor; dispersing the ytterbium malonate precursor in a buffer solution, adding a dopamine salt for polymerization coating, and forming a polydopamine coating layer on the surface of the particles; and calcining the coated compound at 500-750 DEG C to obtain the ytterbium oxide powder. The ytterbium malonate is used to replace the traditional ytterbium carbonate precursor, so that the thermal decomposition temperature can be effectively reduced; the carbon coating layer formed by carbonization of the polydopamine plays a particle spacing protection role in the calcination process, effectively inhibits excessive grain growth and hard agglomeration, and high-dispersity and high-purity ytterbium oxide powder can be obtained at a low temperature. The method has low raw material cost, simple and controllable process, is green and environment-friendly, and is suitable for large-scale industrial production.

The present invention relates to a method for preparing ytterbium oxide for target materials, and belongs to the technical field of hydrometallurgy and material preparation. Ytterbium chloride liquid with a relative purity of rare earth greater than or equal to 99.99% is used as a raw material, and a refined oxalic acid solution is added thereto for precipitation reaction. During the precipitation reaction, a complexing agent is added to the precipitation slurry, and the precipitation is continued to be complete to obtain ytterbium oxalate. After washing, dehydration, and calcination, ytterbium oxide for target materials is obtained; the complexing agent is a composition of salicylic acid and acetylacetone. The method of the present invention is simple and easy to control, and the transition elements Fe, Cr, Cu, and Ni in the obtained ytterbium oxide product can reach a relatively low level. The transition elements Fe, Cr, Cu, and Ni content are detected by GD-MS, etc., and Fe≤0.06ug / g, Cr<0.05ug / g, Cu<0.05ug / g, and Ni<0.05ug / g are suitable for high-end materials such as metal targets.

The present application relates to waste resource utilization, environmental protection catalytic material and atmospheric pollution control field, disclose a kind of porous ceramic SCR denitration catalyst, the porous ceramic SCR denitration catalyst includes porous ceramic carrier, and active component and promoter supported on the surface of porous ceramic carrier;Wherein, the active component contains lanthanum oxychloride;The promoter contains ytterbium oxide and erbium oxide;Raw material in preparation the porous ceramic carrier contains waste steel slag, attapulgite, activated carbon, nano iron powder and forming agent.The porous ceramic SCR denitration catalyst of the application has higher NO x removal efficiency, low cost, with broad market prospect.

The present invention belongs to the field of high-temperature superconducting materials and particularly relates to a gadolinium ytterbium barium copper oxide superconducting film and a preparation method and application thereof. The preparation method comprises the following steps: S1, preparing a solution containing 2-thenoyltrifluoroacetone; S2, adding gadolinium oxide and ytterbium oxide to react with nitric acid to obtain a mixed solution containing gadolinium nitrate and ytterbium nitrate, mixing the solution obtained in S1 with the mixed solution, adding seed crystals to react, standing, separating and drying to obtain a gadolinium ytterbium coordination complex; S3, mixing the gadolinium ytterbium coordination complex obtained in S2, a barium source, a copper source and a solvent, and growing the gadolinium ytterbium barium copper oxide superconducting film on a substrate surface by an organometallic chemical vapor deposition method using oxygen as an oxygen source; the molar ratio of gadolinium nitrate to ytterbium nitrate is (0.7-0.78):(0.22-0.3). The gadolinium-ytterbium coordination complex prepared by the invention has good volatility and high thermal stability; the generated film has few impurities and holes, a smooth surface, and excellent electrical and magnetic field properties at low temperature and high field.

The application discloses a near-net forming preparation process of high-transmittance large-size magnesium-aluminum spinel ceramics, and belongs to the technical field of preparation of high-performance transparent ceramics. The process is characterized by the following steps: firstly, magnesium-aluminum spinel raw material powder is mixed with lithium-free composite sintering additives according to a mass ratio; the composite sintering additives are composed of magnesium fluoride, ytterbium fluoride and ytterbium oxide in a molar ratio; the mixed powder is cold isostatic pressed into a preform; after being crushed, the preform is subjected to high-low pressure cycle pressing near-net forming; the obtained blank is first hot-pressed and pre-sintered, then is treated in a fluorine-containing atmosphere, and finally is subjected to hot isostatic pressing sintering; and finally, the finished product is obtained through post-processing. The process successfully overcomes the bottleneck in the preparation of large-size components, realizes the net forming of the magnesium-aluminum spinel ceramic with a diagonal size greater than 400 mm, the transmittance of the finished product is more than 93% in the wavelength range of 400 nm to 800 nm, the bending strength is more than 194 MPa, and the raw material cost and equipment dependence are significantly reduced.

A sputtering method according to the present disclosure involves performing sputtering on a substrate (10) by using an Yb oxide as a target material (200) in a state in which the pressure in a chamber (110) filled with a noble gas is set to 2 Pa or higher.

The invention relates to a layer system (1) at least comprising (in wt.%) a metallic substrate (4), optionally a metallic adhesion promoter layer (7) on the substrate (4), and a ceramic base layer (10) made of partially stabilized, tetragonal zirconia, comprising Yttrium oxide, Ytterbium oxide, and Gadolinium oxide as stabilizers as well as a ceramic top layer (13) made of fully stabilized cubic zirconia on the ceramic base layer (10), wherein the proportion of stabilizers is between 17.5% and 25.5%.

The application relates to the field of wear-resistant ceramic materials, in particular to a preparation method of a high-wear-resistant ceramic material for a gas valve plate, wherein ceramic powder is ball milled to obtain slurry, a binder composed of carboxymethyl cellulose and fatty acid modified nanocellulose and a sulfuric acid ester surfactant are added into the slurry, the ball milling is continuously carried out, spray granulation is carried out to obtain composite powder, the composite powder is pressed into a blank, and finally, the blank is sintered in an inert gas atmosphere, the ceramic material prepared by the method has excellent mechanical properties, and has good compression resistance, heat resistance, corrosion resistance and wear resistance; through comparison, it is found that the addition of zirconium oxide, samarium oxide, ytterbium oxide, carboxymethyl cellulose, fatty acid modified nanocellulose and sodium dodecyl sulfate has a positive effect on improving the various properties of the ceramic material.

The invention relates to an ultrahigh-temperature thermal protection coating, a workpiece comprising the coating and a preparation method of the workpiece. The coating comprises a protective layer, the material of the protective layer is an ultrahigh-temperature-resistant ceramic composite powder material, the ultrahigh-temperature-resistant ceramic composite powder material is a solid solution compound prepared from hafnium oxide and rare earth oxide, the rare earth oxide is one or two of ytterbium oxide and lutetium oxide, and the protective layer is prepared from the following components in percentage by mole: 1-10% of ytterbium oxide and 1-10% of lutetium oxide. The content of hafnium oxide in the raw materials is 70 to 90 mol.%, and the content of the rare earth oxide in the raw materials is 10 to 30 mol.%. In a 2810 DEG C plasma long-time simulation ablation test, the coating prepared from the ceramic composite powder material does not generate obvious ablation damage within at least 300 seconds, preferably within 690 seconds, and more preferably within 730 seconds, and has good high temperature resistance.

The invention provides an infrared window structure and a preparation method thereof, the infrared window structure comprises a substrate and an antireflection film arranged on one side surface of the substrate, the substrate is a zinc oxide substrate, and the antireflection film is an ytterbium oxide film. According to the invention, the transparent conductive zinc oxide is used for replacing a traditional non-conductive material as a medium-wave infrared window material, and the ytterbium oxide film with a certain thickness is arranged on the surface of the zinc oxide single crystal, so that the transmittance of the zinc oxide single crystal material in medium-wave infrared is improved, and the electromagnetic wave interference resistance of the infrared window material is improved; the application range is widened, and the use performance is improved.

The invention discloses an Ag-loaded rare earth metal doped composite photocatalyst as well as a preparation method and application thereof. Sodium tungstate and bismuth nitrate are used as basic raw materials, ytterbium oxide, thulium oxide and silver nitrate are used as doping raw materials, and Bi2WO6: Yb < 3 + >, Tm < 3 + > / Ag is prepared by a hydrothermal method. The Ag-loaded and ytterbium-thulium rare earth co-doped Bi2WO6: Yb < 3 + >, Tm < 3 + > / Ag composite photocatalyst prepared by the invention inhibits the recombination of photon-generated carriers, and can effectively improve the energy conversion efficiency, thereby improving the near-infrared light catalytic efficiency. The Bi2WO6: Yb < 3 + >, Tm < 3 + > / Ag is used for degrading organic pollutants under irradiation of near-infrared light, and the Bi2WO6: Yb < 3 + >, Tm < 3 + > / Ag has important practical application value in environmental purification and clean energy production.

An improved ceramic material for heat insulation is achieved by means of the following selection of specific stabilizers and the adapted proportions: A ceramic material on the basis of zirconium oxide (ZrO2) containing 5.5 wt.% to 8.5 wt.% base stabilizers: yttrium oxide (Y2O3) and / or hafnium oxide (HfO2) and ytterbium oxide (Yb2O3) as an additional stabilizer: 14.0 wt.% to 16.0 wt.%.

A method and device for recovering enriched 176Yb generated during the preparation process of carrier-free 177Lu. The recovery method comprises: subjecting a waste liquid containing enriched 176Yb to acid removal and concentration, so as to obtain a solution to be precipitated; precipitating the solution to be precipitated, so as to obtain a precipitate containing 176Yb; and subjecting the precipitate containing 176Yb to high-temperature heating, so as to convert the precipitate containing 176Yb into ytterbium oxide. By subjecting the waste liquid to a pre-treatment by means of a column chromatography method, a phosphoric acid organic extractant having a relatively high content is removed from the liquid to be recovered, thereby lowering the level of difficulty of treating the waste liquid. The precipitate containing 176Yb is then obtained by using a precipitation method, and finally, by means of in-situ heating, evaporation and concentration, all of the precipitate is collected, thereby simplifying the process flow, improving the efficiency and effect of recovery and achieving an 176Yb recovery rate of 95%.

The invention provides an erbium-ytterbium co-doped optical fiber with a highly phosphorus-doped fiber core as well as a preparation method and application of the erbium-ytterbium co-doped optical fiber. The erbium-ytterbium co-doped optical fiber is sequentially provided with the fiber core, an inner cladding and a coating from inside to outside, the molar content of phosphorus pentoxide in the fiber core is 10 mol%-15 mol%, the molar content of erbium oxide in the fiber core is 0.02 mol%-0.12 mol%, the molar content of ytterbium oxide in the fiber core is 1 mol%-1.5 mol%, and the balance is silicon dioxide; the difference value of the molar content of phosphorus pentoxide in any two parts of the fiber core is smaller than or equal to 0.8 mol%. According to the erbium-ytterbium co-doped optical fiber, the content of phosphorus pentoxide in all positions in the fiber core is uniformly distributed while the fiber core is doped with high phosphorus content, and the gain performance and the gain consistency of the erbium-ytterbium co-doped optical fiber are improved.

The application provides a high thermal shock resistance arched ceramic coating part and a preparation method and an aero-engine, and relates to the technical field of ceramic coating. The high thermal shock resistance arched ceramic coating part comprises an arched alloy base material and an arched ceramic coating arranged on the surface of the arched alloy base material; the arched ceramic coating comprises a bottom layer, an intermediate layer and a surface layer which are sequentially arranged, and the bottom layer is adjacent to the arched alloy base material; the arched alloy base material comprises a nickel-based high-temperature alloy; the bottom layer comprises an MCrAlYHfSi alloy; the intermediate layer comprises nano-zirconium oxide and Y2O3; the surface layer comprises ytterbium oxide, gadolinium oxide and yttrium oxide modified zirconium oxide; the elastic modulus of the bottom layer, the intermediate layer and the surface layer is sequentially increased, and the thermal expansion coefficient is sequentially decreased. The arched structure design of the arched alloy base material and the arched ceramic coating is adopted, the stress distribution mode of the traditional plane coating is changed, the stress concentration is reduced, and the thermal shock resistance of the coating is enhanced.