The application belongs to the technical field of
palladium recovery, and particularly relates to an amino-substituted modified thioureido
ionic liquid and a preparation method and application thereof, and a liquid-liquid extraction method for Pd(II). The application provides an amino-substituted modified thioureido
ionic liquid, the
chemical formula of the
ionic liquid is shown as formula 1, the structure is that a terminal
nitrogen atom of S-n-decyl thioureido cation carries a
substituent group, the
substituent group is selected from an amino group or a guanidino group, and an anion is bis(trifluoromethylsulfonyl)
imide. By introducing an amino group or a guanidino group on a thioureido group, the ionic liquid [TSCC10][Tf2N] and [GTUC10][Tf2N] provided by the application significantly improves extraction
kinetics, and can reach extraction equilibrium within 2 hours; in an equimolar concentration
mixed metal ion solution and an actual waste
palladium catalyst leaching solution, the extraction rate of Pd(II) is as high as 99.93% or more, while the extraction rate of coexisting
base metal ions is less than 13.42%, and excellent selectivity is exhibited; the saturated extraction capacities are 212 mg / g and 195 mg / g, respectively. After multiple extraction-stripping-regeneration cycles, the ionic liquid still maintains good extraction activity. In summary, the
solvent-free extraction process provided by the application is simple in operation,
environmentally friendly, fast in extraction rate, high in selectivity, has a good industrial application prospect, and has significant economic and
social benefits.