The invention provides a preparing method of
powder metallurgy tantalum powder and / or
niobium powder. The method comprises the steps that (1) heat treatment
sintering is conducted, wherein heat treatment
sintering is conducted on raw
tantalum powder and / or the
niobium powder and after
sintering is accomplished, cooling is conducted and then
passivation is conducted so that a sintered block can be obtained; (2) hydrogenation and powder preparation are conducted, wherein the sintered block obtained through heat treatment is hydrogenated and powder is prepared so that the hydrogenated
tantalum powder and / or the hydrogenated
niobium powder can be obtained; (3)
dehydrogenation and
oxygen reduction are conducted, wherein reducibility
metal is added to the hydrogenated tantalum powder and / or the niobium powder so that dehydrogenating and deoxygenating heat treatment can be conducted, and therefore a mixture of reducibility metallic
oxide, residue reducibility
metal, dehydrogenated and deoxidized tantalum powder and / or the niobium powder can be obtained; (4) acid
pickling and
impurity removal are conducted, wherein acid
pickling and
drying are conducted on a mixture obtained through
dehydrogenation and
oxygen reduction so that the tantalum powder and / or the niobium powder suitable for
powder metallurgy can be obtained. The method is suitable for recycling and treating the waste tantalum powder and / or the niobium powder generated in the process of production of the high-specific-volume tantalum powder and / or the niobium powder for a
capacitor so that the tantalum powder and / or the niobium powder suitable for
powder metallurgy can be prepared, investment of needed devices is small, the
adaptive capacity to raw materials is strong, the technological process is short, and the
safety coefficient of the treatment process is high.