2072 results about "Niobium" patented technology

The invention belongs to the technical field of solid electrolyte materials, and particularly relates to a novel preparation method of a solid electrolyte with high ionic conductivity. The lithium source, the lanthanum source, the niobium source and the fluorine source are mixed, and the solid-phase dispersing agent is added in the mixing process, so that more uniform mixing is facilitated. According to the preparation method, precursor powder is obtained after mixing, then pure-phase LLNOF powder can be directly obtained through one-step sintering, the difficulty that in an existing reported preparation process scheme, a product obtained through two-step sintering has an impure phase is overcome, the preparation process is simple, and batch production and industrialization are facilitated.

Disclosed are a flux-cored welding strip and a welding flux used in combination for submerged arc welding of a duplex stainless steel, and preparation methods and use thereof. The flux-cored welding strip is composed of a stainless steel shell and a flux core powder, the flux core powder consisting of the following components: in percentages by mass, ferrochrome nitride: 0.70% to 1.0%, a chromium powder: 26% to 27%, a nickel powder: 4.5% to 5.5%, a molybdenum powder: 3.7% to 4.2%, a manganese powder: 2.55% to 2.65%, a copper powder: 1.45% to 1.55%, a ferrosilicon powder: 1.1% to 1.2%, a tungsten powder: 1.0% to 1.15%, a niobium powder: 0.25% to 0.35%, an aluminum powder: 0.35% to 0.55%, a rhenium powder: 0.35% to 0.40%, a lanthanum powder: 0.1% to 0.15%, and a balance being an iron powder.

The invention relates to a preparation method of a niobium rod with uniformly crushed crystal grains, which comprises the following steps: firstly, casting an alloy raw material to obtain a cast ingot, and preheating the cast ingot to obtain a first blank; then the first blank is subjected to multiple times of axial forging and first heat treatment, and a second blank is obtained; then carrying out surface treatment on the second blank to remove defects on the surface of the second blank, and carrying out radial forging on the second blank to obtain a third blank; then, the third blank is subjected to oxidation treatment so that an oxidation film can be generated on the surface of the third blank to protect the third blank, hole pattern rolling is conducted on the third blank with the oxidation film generated multiple times, and a first bar is obtained; secondly, the first bar is subjected to rotary swaging and polishing, and a second bar is obtained; and finally, the second bar is subjected to second heat treatment, and a finished bar is obtained. Through multiple times of axial forging, radial rotary forging and groove rolling rotary forging, the obtained finished bar is uniform and fine in grain structure, the grain size GS is 7-9 grade, the elongation is larger than or equal to 40%, and the hardness (HV / 2.9 N) is smaller than or equal to 60.

The invention relates to the technical field of multi-source information analysis, in particular to a niobium-tantalum metal ore metallogenic evaluation system based on multi-source information analysis, which comprises a geologic structure association module, a mineral distribution interpretation module, a metallogenic environment adaptation module, a spatial feature analysis module and a potential region judgment module. According to the method, by introducing a multi-source data analysis and fusion method, the evaluation precision and comprehensive capability of resource exploration are effectively improved, analysis after information fusion is combined with relevance and spatial modes of different data types, it is ensured that mineralization potential evaluation is more accurate, the limitation of a single data source and manual analysis is overcome, and the method is suitable for popularization and application. According to the method, the identification precision and reliability of the mineralization law are improved, the potential area can be identified more accurately, resource potential analysis is optimized in combination with the adaptability of the mineralization environment, the efficiency and accuracy of determining the mineralization area are remarkably improved, the problems of information isolation and analysis deviation in a traditional method are avoided, and the scientificity and the practical application value of the exploration process are enhanced.

The invention belongs to the technical field of nickel-based alloy welding wires, and discloses a corrosion-resistant nickel-based alloy welding wire and a production process thereof, and the corrosion-resistant nickel-based alloy welding wire comprises the following components in percentage by mass: 50-65% of nickel, 16-24% of chromium, 8-10% of molybdenum, 3.5-5.5% of niobium and tantalum, 3-4.5% of copper, 3-4% of tungsten, 0.5-1.0% of tin, 0.1-0.3% of rare earth element, 0.1-0.5% of grain boundary optimizer, 2-5% of nano reinforced phase and the balance of Fe and other inevitable impurities. Through multi-element alloying design, nano reinforced phase compounding and gradient coating synergistic effect, comprehensive improvement of corrosion resistance, high-temperature mechanical property and welding manufacturability is achieved; a welding wire base body is based on nickel, a compact and self-repairing gradient oxidation film is formed by accurately regulating and controlling the atomic proportion of chromium, molybdenum and tungsten, and the chloride ion permeation resistance and the high-temperature oxidation resistance are remarkably improved; therefore, the welding wire has excellent corrosion resistance, high-temperature strength and welding adaptability.

The invention relates to a lithium manganese iron phosphate positive electrode material and a preparation method thereof, and an electrochemical device, the preparation method of the lithium manganese iron phosphate positive electrode material comprises the following steps: mixing a manganese source, an iron source, a first phosphorus source, a lithium source, a first carbon source and a magnesium source, and carrying out primary grinding to obtain a first slurry; carrying out primary sintering on the first slurry to obtain a lithium manganese iron phosphate precursor; mixing the lithium manganese iron phosphate precursor, a second phosphorus source, a second carbon source and a niobium source, and performing secondary grinding to obtain second slurry; the second slurry is subjected to secondary sintering, the lithium manganese iron phosphate positive electrode material is obtained, the magnesium element exists in a bulk phase of the lithium manganese iron phosphate positive electrode material in a doping mode, and the niobium element exists in a coating layer of the lithium manganese iron phosphate positive electrode material in a coating mode. According to the preparation method, magnesium and niobium are co-doped and coated, and through the synergistic effect of magnesium and niobium, the electron and ion conductivity, the specific capacity and the cycle performance of the lithium manganese iron phosphate positive electrode material are jointly improved.

Alloy elements are reasonably matched, N and nitrides are added to form elements such as tungsten W, vanadium V, niobium Nb, cobalt Co, rare earth RE and the like for microalloying smelting, a forged and rolled material finished product is subjected to proper heat treatment, and the stainless steel subjected to heat treatment has good heat treatment performance through metallographic observation. According to the stainless steel, nanoscale carbides are separated out in a solid solution state, and fine particles mainly containing nitrides are dispersed and separated out in crystals in a thermodynamic state, so that the material is strengthened and does not diffuse to a crystal boundary, and the room-temperature mechanical property and the high-temperature mechanical property of the material are greatly improved; and when the stainless steel material produced by the method is used for manufacturing related products, the thickness of the stainless steel material can be reduced, and the overall input of the stainless steel material is greatly reduced, so that the large-scale application of noble metal strategic resource nickel is saved, and the aims of saving resources, energy and investment are fulfilled.

The invention relates to the technical field of hafnium tetrachloride preparation, in particular to a process method for preparing low-niobium-content hafnium tetrachloride based on a hydrogen reduction method, which comprises the following steps: S1, raw material processing, S2, chlorination and impurity removal, S3, purification, S4, refining and S5, material receiving. According to the method, metal impurities in the hafnium-containing raw stone are removed step by step through the working procedures of raw material processing, chlorination and impurity removal, purification, refining and material receiving, high-purity hafnium tetrachloride with the low niobium content is obtained, in the refining working procedure, under the assistance of the supported catalyst, the metal niobium impurities are removed through a hydrogen reduction method, the removal rate is effectively increased, and the production cost is reduced. And moreover, the process flow is simplified, the energy consumption is reduced, and the method meets the environmental protection requirement.

The invention relates to a flotation method for niobium-containing minerals, and belongs to the technical field of mineral separation. The method comprises the steps that niobium-containing ore is subjected to crushing, ore grinding and size mixing, obtained ore pulp is subjected to weak magnetic treatment to remove strong magnetic minerals, after the pH of magnetic separation tailings is adjusted, a flotation reagent containing an iron mineral inhibitor and an amine collecting agent is added for silicon-niobium bulk flotation, and after the pH of obtained silicon-niobium bulk concentrate is adjusted, the obtained silicon-niobium bulk concentrate is subjected to flotation separation. And a flotation reagent containing a hydroximic acid metal organic complex collecting agent and a siliceous mineral inhibitor is added for silicon-niobium separation flotation, and niobium concentrate is obtained. According to the method, iron gangue mineral removal is achieved through step-by-step flotation by means of the amine collecting agent, silicon separation is achieved by means of the hydroximic acid metal organic complex collecting agent, efficient enrichment of the niobium mineral is achieved, the step of strong magnetic iron removal is avoided, the process is simplified, and the loss rate of the niobium mineral is reduced.

The medium-temperature radial forging method comprises the steps that pretreatment is conducted, specifically, a niobium-tungsten alloy extrusion bar blank is heated for 60-180 minutes at the temperature of 750-950 DEG C, rapid forging and straightening are conducted, and a medium-temperature radial forging bar blank is obtained and annealed for 60-120 minutes at the temperature of 1250-1450 DEG C; medium-temperature radial forging is conducted, specifically, a two-step method is adopted, in the first step, a bar blank is preheated to 80-100 DEG C and coated with Ta1350 high-temperature glass powder, heat preservation is conducted for 90-180 minutes at the temperature of 1050-1150 DEG C, and the bar blank is forged into a bar with the diameter of 70 + / -1 mm in the mode that the diameter is reduced by 7-10 mm every time; and in the second step, the heating and coating processes are repeated, the diameter is reduced by 5-7 mm every time, and the bar with the required specification is manufactured. By optimizing the medium-temperature forging and annealing process, the fine grain structure is controlled, the high-temperature mechanical property, creep resistance and oxidation resistance of the material are improved, and the material is suitable for aerospace engines and other high-temperature and high-pressure scenes. Compared with a traditional method, the technology improves the yield, shortens the production period, reduces the labor intensity, is suitable for large-scale production, reduces surface air suction, oxidation and burning loss, and improves the production efficiency and the finished product quality.

The invention discloses a method for displaying and observing aggregated niobium compounds causing stretching layering cracking of wheel steel. The method comprises the steps of sampling, grinding, low-power defect display, stripping, inlaying, grinding, polishing, corrosion, scanning electron microscope observation and phase component and element atomic ratio determination through an energy disperse spectroscopy. According to the method, the periphery is ground after sampling, then the segregation defect is displayed through corrosion of a low-power corrosive liquid, the sample is stripped off from the position 0.5-1 mm away from a segregation defect line through linear cutting, hot inlaying is conducted, and after grinding, polishing and corrosion are conducted, the shape, size and distribution of aggregated and distributed niobium compounds can be clearly displayed under a scanning electron microscope; and the components and atomic ratio of the phase can be determined by using an energy disperse spectroscopy.

The invention discloses a preparation method of a Nb3Sn superconducting wire for a light-emitting device and the Nb3Sn superconducting wire, and relates to the technical field of superconducting, and the method comprises the following steps: depositing a rare earth element film on the surface of a SnTi alloy rod to obtain a first rare earth element alloy rod; a hole is drilled in the center of the first rare earth element alloy rod, a CuTa alloy rod is inserted, and a second rare earth element alloy rod is obtained; the second rare earth element alloy bar is inserted into the inner tin method Ni3Sn CuNb composite pipe, and an inner tin method Ni3Sn subcomponent is obtained; a plurality of inner tin method Ni3Sn subcomponent clusters are loaded into a Ta tube and an oxygen-free copper tube, and an inner tin method Ni3Sn final blank is obtained; and stretching the internal tin method Ni3Tin final blank to obtain the Ni3Tin superconducting wire. The rare earth element film is deposited on the surface of the SnTi alloy bar, the application range of the Nb3Sn superconducting wire is expanded, and due to the existence of the CuTa alloy bar, the tensile strength of the wire is stable after the heat treatment process, and wire damage caused by collision is prevented.

The invention provides a surface-modified sulfide electrolyte and a preparation method thereof, and an all-solid-state battery, the surface-modified sulfide electrolyte comprises a sulfide electrolyte and a modification layer coated on the surface of the sulfide electrolyte, the chemical general formula of the modification layer is LiaMbNcXd, 0 < = a < = 3, 0 < = b < = 1, 0 < = c < = 1, 0 < = d < = 6, and 0 < = c < = 1. M is at least one element of magnesium, aluminum, calcium, iron, zirconium, niobium, tantalum, tungsten, gadolinium, yttrium, indium, hafnium, lanthanum and ytterbium, and X is at least one element of oxygen, sulfur, fluorine, chlorine, bromine and iodine. According to the surface-modified sulfide electrolyte, the modification layer with high ionic conductivity and high oxidation potential is coated outside the sulfide electrolyte, so that when the surface-modified sulfide electrolyte is applied to a positive electrode of an all-solid-state battery, the modification layer can improve the oxidation potential of the electrolyte on the premise of not reducing the ionic conductivity of the electrolyte; the effects of improving the interface stability between the positive electrode active material and the sulfide electrolyte and further improving the cycle performance of the battery are achieved.

The invention relates to the technical field of nodular cast iron, in particular to a silicon-molybdenum-chromium-nickel-niobium nodular cast iron material and a preparation method thereof. The material comprises the following chemical components in percentage by mass: 3.0%-3.5% of carbon, 4.3%-4.7% of silicon, 0.1%-0.3% of manganese, less than or equal to 0.05% of phosphorus, less than or equal to 0.02% of sulfur, 0.7%-1.0% of molybdenum, 0.6%-0.8% of chromium, 0.4%-0.7% of nickel, 0.3%-0.6% of niobium, 0.03%-0.06% of magnesium, 0.05%-0.1% of rare earth, 0.006%-0.012% of antimony and the balance of iron. The preparation method comprises the steps of smelting, first-time spheroidizing and inoculation, second-time spheroidizing, second-time inoculation and heat treatment in sequence. According to the obtained nodular cast iron material, the form of graphite and the number of graphite nodules are improved, carbon elements are separated out as many as possible in the form of high-carbon phase-spheroidal graphite, generation of pearlite is reduced, and the mechanical strength and high-temperature resistance of nodular cast iron are improved.

The invention discloses a method for converting niobium minerals in niobium rough concentrate into pyrochlore. The method comprises the following steps: (1) mixing the niobium rough concentrate with a modifier, a fluorine-containing reagent, a reducing agent and a binder, and carrying out compression molding; and (2) roasting the mixed blank for a set time, preserving heat, and quenching to obtain pyrochlore type rough concentrate. The method comprises the following steps: (1) carrying out magnetic separation on pyrochlore type rough concentrate; (2) performing heating and acid leaching on the magnetic separation tailings; and (3) carrying out flotation to obtain niobium concentrate. According to the method, iron components in the rough concentrate are reduced into magnetic iron minerals, niobium minerals are converted into non-magnetic pyrochlore, follow-up niobium-iron separation is facilitated, and the grade of niobium in the niobium concentrate obtained through production can be effectively improved; and the method is high in adaptability to niobium rough concentrate, is also applicable to alkaline or acidic niobium rough concentrate, is relatively small in gangue mineral change and low in conversion reaction temperature, and has the advantages of energy conservation and emission reduction compared with other regulation and control processes.

The invention belongs to the field of nickel-based alloy materials, and discloses a precipitation hardening type nickel-based alloy welding wire and a preparation method thereof.The precipitation hardening type nickel-based alloy welding wire comprises, by mass, 50%-60% of nickel, 15%-20% of chromium, 15%-20% of iron, 2%-4% of molybdenum, 2%-5% of niobium, 0.01%-2% of tantalum, 0.2%-2% of aluminum, 0.5%-1.2% of titanium, 0.03%-0.08% of carbon, 0.1%-0.5% of manganese, 0.1%-0.5% of silicon, 0.01%-0.05% of magnesium, 0.01%-0.05% of yttrium, 0.5%-2% of tungsten, 0.1%-0.6% of cobalt, 0.001%-0.02% of boron and the balance impurities; according to the precipitation hardening type nickel-based alloy welding wire and the preparation method thereof, through component optimization and process innovation, the nickel-based alloy welding wire with high-temperature strength, excellent hot crack resistance and welding toughness is provided.

The invention discloses a preparation method of a high-temperature-resistant, high-strength, high-electric-conductivity and high-heat-conductivity copper-niobium heterogeneous nano composite fine filament, which comprises the following steps of: 1, winding a copper strip and a niobium strip, placing the wound copper strip and niobium strip in a copper sheath, carrying out homogeneous heating and isothermal hot extrusion deformation, and then carrying out multi-pass straight drawing, intermediate annealing and disc drawing to obtain a copper-niobium composite wire; 2, bundling and assembling the copper-niobium composite wires, placing the copper-niobium composite wires in a copper sheath, carrying out homogeneous heating and isothermal hot extrusion deformation, and then carrying out multi-pass straight drawing, intermediate annealing and disc drawing to obtain a copper-niobium multi-core composite round wire; and 3, performing multi-pass drawing and vacuum annealing on the copper-niobium multi-core composite round wire in sequence. The ultra-plastic deformation process combining copper and niobium winding combination with cluster drawing is adopted, the fine wire with high tensile strength, good bending and tensile plasticity, excellent high-temperature thermal stability and high-temperature stress relaxation resistance, excellent radiation resistance and excellent strong current matching is obtained, the process is simple, control is easy, and the method is suitable for industrial production. The industrial batch production is easy to realize.

The invention relates to the technical field of flux-cored wires. The preparation method comprises the following steps: weighing the following raw materials in parts by weight: 4-6 parts of chromium carbide powder, 7-9 parts of molybdenum powder, 6-8 parts of nickel powder, 10-15 parts of niobium powder, 15-18 parts of tungsten carbide powder, 7-11 parts of a modified titanium carbide agent, 5-8 parts of a blending agent added based on boron and 2-4 parts of 30-mesh natural graphite; 1-2 parts of sodium fluosilicate; 1-2 parts of aluminum powder; and 70-75 parts of iron powder. The flux-cored wire can adapt to complex service environments of parts such as rollers and continuous casting crystallizers in the metallurgical industry, the service life of the parts subjected to surfacing repair is prolonged, the production efficiency of the parts subjected to surfacing repair is improved, the obtained flux-cored wire achieves balance of high-temperature performance, mechanical performance and low-temperature stability, and the comprehensive applicability of products is improved.

The invention relates to the technical field of high-hardness thick-specification high-wear-resistance steel plates, in particular to a high-hardness 30-80mm thick-specification flame-cutting-delayed-crack-free high-wear-resistance steel plate and a production method thereof. New flame cutting delayed crack preventing components and process design are adopted, the chemical components of the steel plate are mainly characterized by medium carbon, high silicon and niobium microalloying, and the wear-resistant steel plate with low impurity content, uniform and fine martensite and a certain amount of retained austenite structures is obtained after refining, continuous casting, controlled rolling and heat treatment. And formation and expansion of delayed cracks during flame cutting can be inhibited. And during flame cutting, thermal stress and structural stress formed in the cutting process of the thick steel plate are reduced through the cutting process of cutting with temperature and slow cooling with hot water after cutting, and the effect of no delayed crack after cutting is achieved. The surface hardness is larger than or equal to HB500, the tensile strength is larger than or equal to 1350 MPa, AKV at-40 DEG C is larger than or equal to 30 J, A is larger than or equal to 10%, retained austenite is 4%-6%, delayed cracks do not exist after flame cutting, and the flame cutting edge hardness is larger than or equal to HB460.

The present invention discloses a preparation method and application of a sulfide solid electrolyte material. The electrolyte has a Li6PS5Cl-type structure, and its chemical general formula is Li6Nb 1‑a P a S5X(0

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.7% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+Al+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0% ≤ Nickel ≤ 1% 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 30 to 40% when calculated in accordance with Bertotti method.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001 % ≤ Carbon ≤ 0.007 % 0.15% ≤ Manganese ≤ 0.2% 3% ≤ Silicon ≤ 3.6% 0.7% ≤ Aluminum ≤ 1.3 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% with 3.85% ≤ Si+AI+Mn ≤ 5.5% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1 % 0% ≤ Titanium ≤ 0.1 % 0% ≤ Vanadium ≤ 0.1 % 0% ≤ Chromium ≤ 1 % 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten ≤ 0.1 % 0% ≤ Cobalt ≤ 1 % 0% ≤ Arsenic ≤ 0.05% 0.001 % ≤ Calcium ≤ 0.01 % 0% ≤ Copper ≤ 1 % 0% ≤ Nickel ≤ 1 % 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, of 35 to 55% when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.635T to 1.670T.

The present invention discloses a method for separating niobium from niobium-containing ore, wherein the niobium coarse concentrate is mixed with a sulfiding agent to obtain a mixture, and the mixture is subjected to reduction smelting to obtain a reduced ore, and a niobium-rich product is directly obtained from the reduced ore, or the niobium-rich product is obtained after post-processing the reduced ore. Compared with the traditional reduction smelting process, the method for separating niobium from niobium-containing ore of the present invention can achieve separation of niobium from slag while achieving separation of slag and iron, and enrich niobium to obtain a high-grade niobium-rich product, which can be purified through further metallurgical processes. The process method of the present invention has strong operability, simple process, low requirements on load-bearing smelting equipment, and is easy to promote and apply industrially.

The invention relates to a diffusion-resistant layer enhanced high-temperature oxidation-resistant composite ceramic coating for a niobium surface and a preparation process thereof. The coating system is composed of a diffusion layer, an anti-diffusion layer and a composite ceramic coating in sequence. In the preparation process, the Al2O3 diffusion-resistant layer is accurately constructed by adopting a slurry spin-coating method, and the method can realize accurate regulation and control of the thickness of the diffusion-resistant layer, so that uniform distribution of the Al2O3 layer is ensured. The introduction of the diffusion-resistant layer significantly improves the high-temperature stability and oxidation resistance of the coating, effectively delays the oxidation process of the material under an extreme high-temperature condition, and greatly prolongs the service life of the material.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.2% ≤ Manganese ≤ 0.24% 3.1% ≤ Silicon ≤ 3.5% 0.8% ≤ Aluminum ≤ 1.1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less from 30% to 35% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.645T to 1.660T.

An embodiment of the present invention provides a steel material, for a pressure vessel, comprising, in weight %, 0.06-0.25% of carbon (C), 0.05-0.50% of silicon (Si), 1.0-2.0% of manganese (Mn), 0.005-0.40% of aluminum (Al), 0.010% or less of phosphorus (P), 0.0010% or less of sulfur (S), 0.001-0.03% of niobium (Nb), 0.001-0.03% of vanadium (V), 0.001-0.03% of titanium (Ti), 0.01-0.20% of chromium (Cr), 0.05-0.15% of molybdenum (Mo), 0.01-0.50% of copper (Cu), 0.05-0.50% of nickel (Ni), 0.0005-0.0050% of magnesium (Mg), 0.0005-0.0050% of calcium (Ca), 0.0020% or less of oxygen (O), and the remainder being Fe and other unavoidable impurities. A microstructure comprises in terms of area fraction 30% or less of pearlite and the remainder being ferrite. A non-metallic inclusion contains Mg—Al—Ca—O composite oxide.

The invention deals with a double cold rolled non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001% ≤ Carbon ≤ 0.007 % 0.1% ≤ Manganese ≤ 0.2% 3.1% ≤ Silicon ≤ 3.6% 0.8% ≤ Aluminum ≤ 1.1% Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1% 0% ≤ Titanium ≤ 0.1% 0% ≤ Vanadium ≤ 0.1% 0% ≤ Chromium ≤ 1% 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1% 0% ≤ Cobalt ≤ 1% 0% ≤ Arsenic ≤ 0.05% 0.001% ≤ Calcium ≤ 0.01% 0% ≤ Copper ≤ 1% 0.001% ≤ Nickel ≤ 0.01 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, is from 35% to 45% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000A / m (J50) from 1.64T to 1.66T.

The invention deals with a non-oriented electrical steel sheet having a composition comprising of the following elements, expressed in percentage by weight: 0.0001 % ≤ Carbon ≤ 0.007 % 0.09% ≤ Manganese ≤ 0.15% 2.5% ≤ Silicon ≤ 3% 0.1 % ≤ Aluminum ≤ 0.5 % Phosphorus ≤ 0.15 % Sulfur ≤ 0.006% Nitrogen ≤ 0.09% and can contain one or more of the following optional elements 0% ≤ Niobium ≤ 0.1 % 0% ≤ Titanium ≤ 0.1 % 0% ≤ Vanadium ≤ 0.1 % 0% ≤ Chromium ≤ 1 % 0% ≤ Molybdenum ≤ 0.5% 0% ≤ Tungsten≤ 0.1 % 0% ≤ Cobalt ≤ 1 % 0% ≤ Arsenic ≤ 0.05% 0.001 % ≤ Calcium ≤ 0.01 % 0% ≤ Copper ≤ 1 % 0% ≤ Nickel ≤ 1 % 0 % ≤ Boron ≤ 0.05% 0 % ≤ Lead ≤ 0.2% 0% ≤ Tin≤ 0.2% 0% ≤Antimony ≤ 0.2% the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of said steel sheet being made of ferrite and comprising in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 35% to 45% when calculated in accordance of Bertotti method.

The invention discloses a method for extracting tantalum and niobium by roasting and melting tantalum and niobium concentrate through villiaumite after multiple times of acid leaching, which comprises the following steps: fully grinding the tantalum and niobium concentrate through a grinding machine, sieving, and fully mixing with concentrated acid according to a certain mass ratio for first acid leaching; filtering the mixed solution, and washing with pure water; mixing the filter residues with concentrated acid according to a certain mass ratio, carrying out secondary acid leaching, filtering, and washing the filter residues with pure water; drying the filter residue, and fully mixing with villiaumite according to a certain mass ratio; fully grinding the mixed solid roasting material by using a grinding machine; roasting and melting the materials; and leaching the roasted material with water or dilute acid, filtering after leaching is completed, and collecting filtrate. According to the method, most impurity ions can be effectively removed through secondary acid leaching impurity removal in the leaching process. And the fluorine salt roasting cost is low, the tantalum-niobium leaching effect is good, the tantalum-niobium leaching rate can reach 90% or above, and the comprehensive utilization rate of resources is high.

The invention discloses a CCTO dielectric ceramic, and belongs to the technical field of dielectric ceramic synthesis. Calcium nitrate tetrahydrate, copper nitrate trihydrate, tetrabutyl titanate and niobium oxalate hydrate are used as raw materials, a precursor solution is prepared according to the molar ratio of calcium to copper to titanium to niobium being 1: 3: 4-x: x, the PH is adjusted, colloid obtained after aging is dried and ground, then high-temperature sintering is conducted in a muffle furnace, tabletting is conducted after the colloid is mixed with an adhesive, annealing is conducted, and finally the high-density, good-uniformity and high-temperature-resistant titanium-titanium alloy is obtained. And the single-doped CaCu3Ti (4-x) NbxO12 ceramic sample has the advantages of low dielectric loss and high dielectric constant.