Aluminium alloy brazing sheet, used for
brazing in an
inert gas
atmosphere without the use of a flux, with: a
brazing alloy material that is plated onto at least one side surface of a core material, where the core material is aluminum or an aluminum
alloy core material containing one or two or more of Fe of 1.50 wt% or less, Si of 1.50 wt% or less, Cu of 2.00 wt% or less, Mn of 2.00 wt% or less, Zn of 3.00 wt% or less, Cr of 0.30 wt% or less, Ti of 0.30 wt% or less, Zr of 0.30 wt% or less, In of 0.10 wt% or less and Sn of 0.10 wt% or less, the remainder being
aluminium and unavoidable impurities, is formed, wherein the brazing alloy material is an aluminum alloy brazing alloy material having Si of 4.00 to 13.00 wt% and one or two or more of Mg of more than 0.03 wt% and 3.00 wt% or less, Li of more than 0.03 wt% and 3.00 wt% or less, and Ca of more than 0.03 wt% and 3.00 wt% or less, the remainder being aluminum and unavoidable impurities, wherein an
oxide is formed on a surface of the
aluminium alloy brazing sheet by brazing heating, which has an
oxide of one or two or more of Mg, Li and Ca and has a
volume change ratio of 0.990 or less to a
surface oxide film formed before brazing heating, and an atomic
molar ratio of Mg, Ni and Ca to Al in the
oxide formed on the surface of the
aluminium alloy brazing sheet before brazing heating is 0.5 or less.